CN108947658A - Amino acid Water soluble fertilizer and preparation method thereof - Google Patents
Amino acid Water soluble fertilizer and preparation method thereof Download PDFInfo
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- CN108947658A CN108947658A CN201810831765.8A CN201810831765A CN108947658A CN 108947658 A CN108947658 A CN 108947658A CN 201810831765 A CN201810831765 A CN 201810831765A CN 108947658 A CN108947658 A CN 108947658A
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- amino acid
- raw material
- water soluble
- soluble fertilizer
- acid water
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C21/00—Methods of fertilising, sowing or planting
- A01C21/005—Following a specific plan, e.g. pattern
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- Life Sciences & Earth Sciences (AREA)
- Soil Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of amino acid Water soluble fertilizers, its raw material includes the ingredient of following weight percent: free amino acid powder 3%~15%, microelement 0.045%~0.09%, egg raw material 0.005%~0.02%, bone meal 0.0005%~0.045%, maize raw material 0.0005%~0.04%, soya bean raw material 0.0015%~0.045%, peanut cake 0.0025%~0.035%, sugar 0.1%~4.5%, calcium powder 0.3%~4.5%, saccharomycetes to make fermentation aqua 0.001%~0.05%, vinegar 0.04%~0.45%, white wine 0.015%~0.03%, surplus is processing water.Amino acid Water soluble fertilizer of the present invention can replace chemical fertilizer, organic fertilizer and farmyard manure, it is suitble to major part agricultural crops and industrial crops, applicability is wide, and application amino acid Water soluble fertilizer of the present invention can solve agricultural product source and give mankind's bring various unsound factors, really solves food source health problem.
Description
Technical field
The invention belongs to agriculture fields, are related to a kind of agriculture plants fertilizer, and in particular to a kind of amino acid Water soluble fertilizer
And preparation method thereof.
Background technique
The development of planting industry in agricultural production be unable to do without fertilizer, and the whole world all provides nutrients using excessive chemical fertilizer,
To support plant growth, nutritional ingredient contained in the type and fertilizer of fertilizer directly influences the yield and product of agricultural product
Matter.It is high same devoting exclusive attention to output with the continuous improvement of people's living standards, the requirement to quality of agricultural product also increases accordingly
When, also there is higher requirement to the quality of agricultural product.
Although chemical fertilizer provides benefit for agricultural modernization, traditional compound fertilizer easily causes fertilizer loss, water
Body eutrophication, seriously destruction soil texture, nutrient imbalance etc..Chemical fertilizer is excessively used and already leads to soil hardening and corrosion, and
And have resulted in yield reduction and the reduction of fertilizer application efficiency.Furthermore the fertilizer in China is various, and fertilizer quality is irregular not
Together, effect is passed different judgements on, and most fertilizer all has an extensive subject, but and not all subject all have
Apparent disease-resistant or synergistic effect.
Water-soluble fertilizer avoids the disadvantage of conventional composite fertilizer as emerging environment-friendly type fertilizer, is a kind of to be fully soluble in water
New high-efficiency fertilizer has and dissolves, without the remarkable advantages such as residue, quick, easy to use.But current water-soluble fertilizer tool
Defect below: it firstly, existing Water soluble fertilizer is accordingly designed according to the nutrient uptake feature of Different Crop, sells in the market
The Water-soluble fertilizer special for having all kinds of crops such as vegetables, fruit tree, flowers, grain, cotton, oils, specific aim is stronger, without a suitable
Close the generality Water soluble fertilizer of the agricultural plants such as each planting fruit-trees, melon dish, gardens plant.Secondly, the current Water soluble fertilizer market price is general
All over higher, cause the planting cost of agricultural crops to increase, be unfavorable for popularizing.Again, traditional Water soluble fertilizer is difficult to long-term in the soil
It saves, fertilizer application amount wants strict control, if single use is slightly more, will result in fertilizer loss, seriously destroys soil texture, both dropped
The economic benefit of low fertilising is not achieved the purpose of High yield, also will cause the pollution of water environment, be unfavorable for sustainable development
Exhibition.
Summary of the invention
The amino acid that the object of the present invention is to provide a kind of inexpensive, easy to use, effects preferably, applicability is wider is water-soluble
Fertilizer.
To achieve the goals above, the technical solution of the present invention is as follows: providing a kind of amino acid Water soluble fertilizer, raw material include with
The ingredient of lower weight percent: free amino acid powder 3%~15%, microelement 0.045%~0.09%, egg raw material
0.005%~0.02%, bone meal 0.0005%~0.045%, maize raw material 0.0005%~0.04%, soya bean raw material
0.0015%~0.045%, peanut cake 0.0025%~0.035%, sugared 0.1%~4.5%, calcium powder 0.3%~4.5%, ferment
Female bacterium fermentation aqua 0.001%~0.05%, vinegar 0.04%~0.45%, white wine 0.015%~0.03%, surplus are processing
Water;The processing water is that soda ash and licorice powder are added in water to obtain.
Further, the microelement is iron, zinc, boron.
Further, the egg raw material is egg white and yolk.
Further, the maize raw material is corn or zein.
Further, the soya bean raw material is soya bean or soya bean protein.
Further, the sugar is molasses or white granulated sugar.
Further, the additive amount of the soda ash and licorice powder be respectively water weight 0.04%~0.45%,
0.01%~0.45%.
The preparation method of the amino acid Water soluble fertilizer, comprising the following steps:
(1) said ratio is pressed, soda ash and licorice powder are added into water, stirred evenly, obtains processing water;
(2) maize raw material, soya bean raw material, peanut cake are pulverized into powder;
(3) said ratio is pressed, by microelement, egg raw material, bone meal, maize raw material powder, soya bean raw material powder, peanut
Cake powder, sugar, calcium powder, vinegar are mixed, and take the 20% of processing water inventory to be added, stir evenly, after sealing displays 2~4 days,
Obtain nutrient solution;
(4) it is stirred evenly after white wine, saccharomycetes to make fermentation aqua being added to nutrient solution, is sealed by fermentation 3~6 days, is sent out
Zymotic fluid;
(5) the processing water of residue 80% is added in fermentation liquid and is stirred evenly, continued to beat within 3~8 days oxygen, obtain aerobic water
Agent;
(6) aerobic aqua is filtered, is put into reaction kettle after filtered aerobic aqua addition free amino acid powder and carries out 1
It is stirred to react within~5 days, obtains amino acid Water soluble fertilizer.
Further, the additive amount that free amino acid powder is added in aerobic aqua is 100~300g/L.
Amino acid Water soluble fertilizer of the present invention is applied fertilizer applied to agricultural plant, and it is particularly applicable to most fruit trees, melon dish, gardens
The agricultural crops such as plant and industrial crops.
16~20 times of irrigations of dilution or pouring application when amino acid Water soluble fertilizer of the present invention uses, i.e. 1 kilogram of liquid fertilizer converts 16~
20 kg of water, fruit tree two weeks discharges primary under normal circumstances, about 10 kilograms every plant, as a result when can suitably increase to 15 kilograms.
Forest 3 months or half a year discharge primary, can discharge 400 kilograms (after being watered dilution) per acre.
Vegetable category discharges 400 kilograms (after being watered dilution) per acre, discharges within every ten days primary.
Flowers class is discharged 500 kilograms (after being watered dilution) per acre, is discharged within every 15 days primary.
Amino acid Water soluble fertilizer of the present invention have it is below the utility model has the advantages that
1, the various agricultural product planted using amino acid Water soluble fertilizer of the present invention, yield is high, higher than originating in amount under normal circumstances
Out 15~31%, and excellent product quality, peel smooth, pulp are fragrant and sweet, in good taste.
2, applying amino acid Water soluble fertilizer of the present invention can reach the good result of improvement soil, under normal circumstances, apply 3 months
98% or more effect can be can reach after application 6 months up to 70~90% effects to acid, alkali, saline soil improvement.It simultaneously can also
The regeneration development for ensuring soil trace element, makes vegetation back to nature state.
3, amino acid Water soluble fertilizer of the present invention can replace chemical fertilizer, organic fertilizer and farmyard manure, be suitble to major part crops and economy
Crop, applicability is wide, apply amino acid Water soluble fertilizer of the present invention can solve agricultural product source to mankind's bring it is various it is unhealthy because
Element really solves food source health problem.
4, amino acid Water soluble fertilizer preparation method of the present invention is unique, does not add any antibiotic, hormone in preparation process and moves
Object excrement substance, it is ensured that fertilizer source health.
5, both soda ash and licorice powder are combined first in amino acid Water soluble fertilizer preparation method of the present invention and are added into water,
Its water body is set to have the function that acid-base balance and sterilization.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.In the following examples, the experimental methods for specific conditions are not specified, usually
According to normal conditions, or according to the normal condition proposed by manufacturer.
The equipment and material that amino acid Water soluble fertilizer of the present invention and preparation method thereof uses are as follows:
1, reaction kettle;2, agitator tank;3, cement pond or plastic barrel;4, pulverizer;5, thermometer;6, amino acid reacts
Tank;7, giant;8, pressure pan;9, balance claims;10, culture medium;11, sterilizer;12, microscope;13, bobbing machine;14, net
Change workbench;15, examination and test of products equipment;16, refrigerator;17, water filter is handled;18, amino acid culture pond.
Embodiment 1
Amino acid Water soluble fertilizer of the present invention, raw material include the ingredient of following weight percent: free amino acid powder 3%, micro-
Secondary element (iron, zinc, boron arbitrarily compare) 0.045%, egg raw material (egg white and yolk) 0.02%, bone meal 0.0005%, corn
0.04%, soya bean protein 0.0015%, peanut cake 0.0025%, molasses 4.5%, calcium powder 0.3%, saccharomycetes to make fermentation aqua
0.001%, vinegar 0.04%, white wine 0.015%, surplus are processing water;
The preparation of amino acid Water soluble fertilizer:
(1) licorice powder of 0.04% soda ash and 0.01% is added into water by weight percentage, is stirred evenly, obtained
Water must be handled;
(2) corn, peanut cake are pulverized into powder;
(3) press said ratio, by microelement, egg raw material, bone meal, corn powder, soya bean protein, peanut cake powder,
Molasses, calcium powder, vinegar are mixed, and take the 20% of processing water inventory to be added, stir evenly, and after sealing displays 2 days, obtain nutrition
Liquid;
(4) it is stirred evenly after white wine, saccharomycetes to make fermentation aqua being added to nutrient solution, is sealed by fermentation 4 days, is fermented
Liquid;
(5) the processing water of residue 80% is added in fermentation liquid and is stirred evenly, continued to beat oxygen in 3 days, obtain aerobic aqua;
(6) aerobic aqua is filtered, adds trip in the ratio that mass volume ratio is 100g/L in filtered aerobic aqua
Isolated amino acid powder is then placed in reaction kettle and be stirred to react within 2 days, obtains amino acid Water soluble fertilizer.
Embodiment 2
Amino acid Water soluble fertilizer of the present invention, raw material include the ingredient of following weight percent: free amino acid powder 10%, micro-
Secondary element (iron, zinc, boron arbitrarily compare) 0.09%, egg raw material (egg white and yolk) 0.02%, bone meal 0.045%, zein
0.04%, soya bean 0.045%, peanut cake 0.035%, white granulated sugar 4.5%, calcium powder 4.5%, saccharomycetes to make fermentation aqua 0.05%,
Vinegar 0.45%, white wine 0.03%, surplus are processing water;The processing water is that soda ash and licorice powder are added in water to obtain.
The preparation method of the amino acid Water soluble fertilizer, comprising the following steps:
(1) licorice powder of 0.4% soda ash and 0.4% is added into water by weight percentage, is stirred evenly, obtained
Handle water;
(2) soya bean, peanut cake are pulverized into powder;
(3) press said ratio, by microelement, egg raw material, bone meal, zein, soya bean powder, peanut cake powder,
White granulated sugar, calcium powder, vinegar are mixed, and take the 20% of processing water inventory to be added, stir evenly, after sealing displays 3 days, are sought
Nutrient solution;
(4) it is stirred evenly after white wine, saccharomycetes to make fermentation aqua being added to nutrient solution, is sealed by fermentation 5 days, is fermented
Liquid;
(5) the processing water of residue 80% is added in fermentation liquid and is stirred evenly, continued to beat oxygen in 5 days, obtain aerobic aqua;
(6) aerobic aqua is filtered, adds trip in the ratio that mass volume ratio is 300g/L in filtered aerobic aqua
Isolated amino acid powder is then placed in reaction kettle and be stirred to react within 3 days, obtains amino acid Water soluble fertilizer.
Embodiment 3
Amino acid Water soluble fertilizer of the present invention, raw material include the ingredient of following weight percent: free amino acid powder 15%, micro-
Secondary element (iron, zinc, boron arbitrarily compare) 0.06%, egg raw material (egg white and yolk) 0.01%, bone meal 0.03%, corn
0.04%, soya bean 0.03%, peanut cake 0.035%, white granulated sugar 4.0%, calcium powder 3.5%, saccharomycetes to make fermentation aqua 0.01%, vinegar
0.35%, white wine 0.03%, surplus are processing water;The processing water is that soda ash and licorice powder are added in water to obtain.
The preparation method of the amino acid Water soluble fertilizer, comprising the following steps:
(1) licorice powder of the soda ash of weight 0.35% and weight 0.25% is added into water by weight percentage, is stirred
It mixes uniformly, obtains processing water;
(2) corn, soya bean, peanut cake are pulverized into powder;
(3) press said ratio, by microelement, egg raw material, bone meal, corn powder, soya bean powder, peanut cake powder,
White granulated sugar, calcium powder, vinegar are mixed, and take the 20% of processing water inventory to be added, stir evenly, after sealing displays 4 days, are sought
Nutrient solution;
(4) it is stirred evenly after white wine, saccharomycetes to make fermentation aqua being added to nutrient solution, is sealed by fermentation 6 days, is fermented
Liquid;
(5) the processing water of residue 80% is added in fermentation liquid and is stirred evenly, continued to beat oxygen in 8 days, obtain aerobic aqua;
(6) aerobic aqua is filtered, adds trip in the ratio that mass volume ratio is 300g/L in filtered aerobic aqua
Isolated amino acid powder is then placed in reaction kettle and be stirred to react within 5 days, obtains amino acid Water soluble fertilizer.
Every liter of filtered aerobic aqua contains the free amino acid powder of 300g.
Test process:
1, application of the amino acid Water soluble fertilizer that three embodiments of the invention prepare on mango:
It tests and is carried out in highest-ranking imperial concubine's mango planting base in the Compounds in Dongfang City of Hainan Province town Ba Suo, highest-ranking imperial concubine's mango Post flowering starts to try
It tests.Control is the rich phosphorus and potassium type foliar fertilizer and clear water of prior art production.
Test method: processing A: conventional fertilizer application+embodiment of the present invention prepares amino acid Water soluble fertilizer, and when use dilutes 20
Times.Handle B: conventional fertilizer application+rich phosphorus and potassium type foliar fertilizer.Handle C: conventional fertilizer application+spray clear water.Each processing is repeated 3 times.
Test result is as shown in table 1, and after spraying three embodiment amino acid Water soluble fertilizers of the invention, highest-ranking imperial concubine's Mango Output is obvious
Increase, the yield highest in all processing, compared with compareing rich phosphorus and potassium type foliar fertilizer, embodiment 1 increases production 976 kilograms per acre, increases
Long rate is up to 27.8%, and embodiment 2 increases production 996 kilograms per acre, and for growth rate up to 28.4%, embodiment 3 increases production 1068 kilograms per acre, increases
Long rate is up to 29%.Therefore, compared with other foliar fertilizers, amino acid Water soluble fertilizer of the invention has increasing both production and income to highest-ranking imperial concubine's mango
Effect, and highest-ranking imperial concubine's mango is good in taste, it is sweet and dilitious.
Table 1 is influence of the different disposal to highest-ranking imperial concubine's Mango Output (kg/acre)
For the first time | Second | For the third time | Mean value | |
It handles A (embodiment 1) | 4500 | 4320 | 4621 | 4480 |
It handles A (embodiment 2) | 4300 | 4610 | 4590 | 4500 |
It handles A (embodiment 3) | 4210 | 4653 | 4701 | 4521 |
Handle B | 3200 | 3452 | 3860 | 3504 |
Handle C | 1689 | 2171 | 1982 | 1947 |
2, application of the amino acid Water soluble fertilizer that three embodiments of the invention prepare on melon dish:
The green cucumber planting site tested in Zhanjiang, Guangdong Province fiber crops Zhang Zhen carries out, and green cucumber seedling starts to test.Control is existing skill
The red cubic humic acid water-soluble fertilizer of the strong sprout type of art production and clear water.
Test method: processing A: conventional fertilizer application+embodiment of the present invention prepares amino acid Water soluble fertilizer, and when use dilutes 16
Times.Handle B: the red cubic humic acid water-soluble fertilizer of conventional fertilizer application+strong sprout type.Handle C: conventional fertilizer application+spray clear water.Each processing weight
It is 3 times multiple.
Test result is as shown in table 1, and after spraying three embodiment amino acid Water soluble fertilizers of the invention, green cucumber yield obviously increases
Add, the yield highest in all processing, compared with the red cubic humic acid water-soluble fertilizer of control strong sprout type, embodiment 1 increases production 521 per acre
Kilogram, growth rate is up to 26.7%, and embodiment 2 increases production 500 kilograms per acre, and for growth rate up to 25.6%, embodiment 3 increases production 516 per acre
Kilogram, growth rate is up to 26.4%.Therefore, compared with other Water soluble fertilizers, amino acid Water soluble fertilizer of the invention has volume increase to green cucumber
The effect increased income.
Table 2 is influence of the different disposal to green cucumber yield (kg/acre)
For the first time | Second | For the third time | Mean value | |
It handles A (embodiment 1) | 2589 | 2145 | 2673 | 2469 |
It handles A (embodiment 2) | 2145 | 2360 | 2840 | 2448 |
It handles A (embodiment 3) | 2564 | 2378 | 2450 | 2464 |
Handle B | 1692 | 2140 | 2012 | 1948 |
Handle C | 1120 | 986 | 789 | 965 |
Above disclosed is only presently preferred embodiments of the present invention, cannot limit the right of the present invention with this certainly
Range, therefore equivalent changes made in accordance with the claims of the present invention still fall within the range that the present invention is covered.
Claims (10)
1. a kind of amino acid Water soluble fertilizer, which is characterized in that raw material includes the ingredient of following weight percent: free amino acid powder
3%~15%, microelement 0.045%~0.09%, egg raw material 0.005%~0.02%, bone meal 0.0005%~
0.045%, maize raw material 0.0005%~0.04%, soya bean raw material 0.0015%~0.045%, peanut cake 0.0025%~
0.035%, sugared 0.1%~4.5%, calcium powder 0.3%~4.5%, saccharomycetes to make fermentation aqua 0.001%~0.05%, vinegar
0.04%~0.45%, white wine 0.015%~0.03%, surplus are processing water;The processing water is by soda ash and licorice powder
It is added in water and obtains.
2. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the microelement is iron, zinc, boron.
3. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the egg raw material is egg white and yolk.
4. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the maize raw material is corn or zein.
5. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the soya bean raw material is soya bean or soya bean protein.
6. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the sugar is molasses or white granulated sugar.
7. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the additive amount of the soda ash and licorice powder difference
It is 0.04%~0.45%, the 0.01%~0.45% of water weight.
8. the preparation method of amino acid Water soluble fertilizer as described in claim 1, which comprises the following steps:
(1) said ratio is pressed, soda ash and licorice powder are added into water, stirred evenly, obtains processing water;
(2) maize raw material, soya bean raw material, peanut cake are pulverized into powder;
(3) said ratio is pressed, by microelement, egg raw material, bone meal, maize raw material powder, soya bean raw material powder, groundnut meal
End, sugar, calcium powder, vinegar are mixed, and take the 20% of processing water inventory to be added, stir evenly, and after sealing displays 2~4 days, obtain
Nutrient solution;
(4) it stirs evenly, is sealed by fermentation 3~6 days after white wine, saccharomycetes to make fermentation aqua being added to nutrient solution, obtain fermentation liquid;
(5) the processing water of residue 80% is added in fermentation liquid and is stirred evenly, continued to beat oxygen in 3~8 days, obtain aerobic aqua;
(6) aerobic aqua is filtered, is put into reaction kettle after filtered aerobic aqua addition free amino acid powder and carries out 1~5
It is stirred to react, and obtains amino acid Water soluble fertilizer.
9. the preparation method of amino acid Water soluble fertilizer as claimed in claim 8, it is characterised in that: added in aerobic aqua free
The additive amount of powder of amino acids is 100~300g/L.
10. amino acid Water soluble fertilizer as described in claim 1, it is characterised in that: the amino acid Water soluble fertilizer is applied to agriculture plants
Fertilising dilutes 16~20 times of irrigations or pours application.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110357725A (en) * | 2019-08-13 | 2019-10-22 | 天峨县平昌生态农业有限公司 | A kind of foliar fertilizer and preparation method improving nutrient quality |
CN111362748A (en) * | 2020-04-02 | 2020-07-03 | 宁夏顺宝现代农业股份有限公司 | Preparation method and application of amino acid fermentation liquor |
CN112521184A (en) * | 2020-12-07 | 2021-03-19 | 山东宜昇生物科技有限公司 | Amino acid animal and plant nutritional protein fertilizer and preparation method thereof |
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CN105237125A (en) * | 2015-08-27 | 2016-01-13 | 马鞍山市安康菌业有限公司 | Modified urea-formaldehyde resin water- and fertilizer-retention high-effective culture medium for flammulina velutipes and preparation method thereof |
CN106008085A (en) * | 2016-05-18 | 2016-10-12 | 吴健 | Water-soluble amino acid fertilizer and preparation method thereof |
CN107935783A (en) * | 2017-12-22 | 2018-04-20 | 苗强 | A kind of microelement type water-soluble fertilizer containing amino-acid liquid and its production technology |
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CN1534004A (en) * | 2003-03-28 | 2004-10-06 | 吴永常 | Organic liquid fertilizer |
CN101440007A (en) * | 2008-12-18 | 2009-05-27 | 杨雪枣 | Growth promoting type composite bio-organic liquid fertilizer |
CN105237125A (en) * | 2015-08-27 | 2016-01-13 | 马鞍山市安康菌业有限公司 | Modified urea-formaldehyde resin water- and fertilizer-retention high-effective culture medium for flammulina velutipes and preparation method thereof |
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CN110357725A (en) * | 2019-08-13 | 2019-10-22 | 天峨县平昌生态农业有限公司 | A kind of foliar fertilizer and preparation method improving nutrient quality |
CN111362748A (en) * | 2020-04-02 | 2020-07-03 | 宁夏顺宝现代农业股份有限公司 | Preparation method and application of amino acid fermentation liquor |
CN112521184A (en) * | 2020-12-07 | 2021-03-19 | 山东宜昇生物科技有限公司 | Amino acid animal and plant nutritional protein fertilizer and preparation method thereof |
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