CN108947251A - A kind of glaze formula with antibiotic property - Google Patents
A kind of glaze formula with antibiotic property Download PDFInfo
- Publication number
- CN108947251A CN108947251A CN201811017848.XA CN201811017848A CN108947251A CN 108947251 A CN108947251 A CN 108947251A CN 201811017848 A CN201811017848 A CN 201811017848A CN 108947251 A CN108947251 A CN 108947251A
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- China
- Prior art keywords
- parts
- glaze
- oxide
- silica
- zirconium phosphate
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of glaze formulas with antibiotic property, including opaque glaze, fritted glaze, Suzhou soil, antibacterial agent and deionized water, wherein, in parts by weight: the opaque glaze includes 50~60 parts of silica, 5~15 parts of aluminium oxide, 10~20 parts of calcium oxide, 2~5 parts of magnesia, 5~10 parts of alkali metal oxide, 1~3 part of zirconium dioxide；The fritted glaze includes 2~5 parts of potassium oxide, 5~15 parts of alkaline earth oxide, 3~8 parts of zinc oxide, 2~5 parts of aluminium oxide, 70~80 parts of silica, 1~3 part of diboron trioxide, 1~4 part of zirconium dioxide；The antibacterial agent is the mixture that basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion.Mixture of the glaze by the way that basic zirconium phosphate load silver ion and basic zirconium phosphate are loaded copper ion in the present invention can reach good, lasting anti-microbial property as antibacterial agent, and, glaze good fluidity is not easy to foaming.
Description
Technical field
The present invention relates to glaze technical fields, more particularly to a kind of glaze formula with antibiotic property.
Background technique
With the development and the improvement of people's living standards of society, requirement of the people to the quality of life is higher and higher, people
To environmental protection consciousness more enhance, anti-biotic material is just increasingly valued by people.Anti-bacteria ceramic is a kind of protection environment
New function material, be the product and material science and microbiology phase of antibacterial agent, antimicrobial technology in conjunction with ceramic material
In conjunction with product.It increases disinfection, sterilization and chemistry drop while keeping ceramic original using function and decorative effect
The function of solution.Therefore it is widely used in the industries such as health, medical treatment, family room, civilian or industrial building.
Natural antibacterial agent is natural material as antibacterial agent, common are behenyl, Meng Zongzhu, peppermint, lemonlike citrus leaf etc.
Extract in plant, the chitosan and natural minerals refined from crab, shrimp and the medium animal of oyster shell for example cinnabar, arsenic, red lead,
Gallbladder is all etc..They have killing effect to multiple-microorganism, but effectively antimicrobial component content is less, and duration of efficacy is short, resistance to
Long property is poor, and less varieties, is restricted by conditions such as safety, and large-scale production is difficult to realize.
For this reason, it is necessary to be able to solve existing skill in view of the above-mentioned problems, propose a kind of glaze formula with antibiotic property
The problem of art.
Summary of the invention
The purpose of the present invention is to provide a kind of glaze formulas with antibiotic property, to overcome deficiency in the prior art.
To achieve the above object, the invention provides the following technical scheme:
A kind of glaze formula with antibiotic property, including opaque glaze, fritted glaze, Suzhou soil, antibacterial agent and deionized water,
In, in parts by weight: the opaque glaze includes 50~60 parts of silica, and 5~15 parts of aluminium oxide, 10~20 parts of calcium oxide,
2~5 parts of magnesia, 5~10 parts of alkali metal oxide, 1~3 part of zirconium dioxide；The fritted glaze includes 2~5 parts of potassium oxide, alkali
5~15 parts of soil metal oxide, 3~8 parts of zinc oxide, 2~5 parts of aluminium oxide, 70~80 parts of silica, diboron trioxide 1~3
Part, 1~4 part of zirconium dioxide；The antibacterial agent is the mixture that basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion.
Preferably, the weight of the opaque glaze in the glaze formula, fritted glaze, Suzhou soil, antibacterial agent and deionized water it
Than for 20:10:5:1:30.
Preferably, the weight ratio of the basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion is 1:1~3.
Preferably, the weight ratio of the basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion is 1:2.
Preferably, in parts by weight: the opaque glaze includes 52~58 parts of silica, and 7.5~12.5 parts of aluminium oxide,
13~18 parts of calcium oxide, 2.75~4.25 parts of magnesia, 6~9 parts of alkali metal oxide, 1.5~2.5 parts of zirconium dioxide；It is described
Fritted glaze includes 2.75~4.25 parts of potassium oxide, and 8~12 parts of alkaline earth oxide, 4~6.5 parts of zinc oxide, aluminium oxide 2.75
~4.25 parts, 73~78 parts of silica, 1.5~2.5 parts of diboron trioxide, 1.5~3.5 parts of zirconium dioxide.
Preferably, in parts by weight: the opaque glaze includes 55 parts of silica, and 10 parts of aluminium oxide, 15 parts of calcium oxide,
3.5 parts of magnesia, 7.5 parts of alkali metal oxide, 2 parts of zirconium dioxide；The fritted glaze includes 3.5 parts of potassium oxide, alkaline-earth metal
10 parts of oxide, 5.5 parts of zinc oxide, 3.5 parts of aluminium oxide, 75 parts of silica, 2 parts of diboron trioxide, 2.5 parts of zirconium dioxide.
Compared with the prior art, the advantages of the present invention are as follows: the glaze in the present invention is by by basic zirconium phosphate load silver ion
Mixture with basic zirconium phosphate load copper ion can reach good, lasting anti-microbial property as antibacterial agent, and, glaze stream
Dynamic property is good, not easy to foaming.
Specific embodiment
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of glaze formula with antibiotic property, including opaque glaze, fritted glaze, Suzhou soil, antibacterial agent and
Deionized water, wherein in parts by weight: the opaque glaze includes 50~60 parts of silica, 5~15 parts of aluminium oxide, is aoxidized
10~20 parts of calcium, 2~5 parts of magnesia, 5~10 parts of alkali metal oxide, 1~3 part of zirconium dioxide；The fritted glaze includes oxidation
2~5 parts of potassium, 5~15 parts of alkaline earth oxide, 3~8 parts of zinc oxide, 2~5 parts of aluminium oxide, 70~80 parts of silica, three
Aoxidize 1~3 part of two boron, 1~4 part of zirconium dioxide；The antibacterial agent is that basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion
Mixture.
Wherein, the weight ratio of the opaque glaze in the glaze formula, fritted glaze, Suzhou soil, antibacterial agent and deionized water
For 20:10:5:1:30；The weight ratio of the basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion is 1:1~3,
Preferably, the weight ratio of the basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion is 1:2.
Following glaze formulas being illustrated with specifically embodiment in the present invention with antibiotic property.
Embodiment 1
In parts by weight: the opaque glaze includes 50 parts of silica, and 5 parts of aluminium oxide, 10 parts of calcium oxide, magnesia 2
Part, 5 parts of alkali metal oxide, 1 part of zirconium dioxide；The fritted glaze includes 2 parts of potassium oxide, 5 parts of alkaline earth oxide, is aoxidized
3 parts of zinc, 2 parts of aluminium oxide, 70 parts of silica, 1 part of diboron trioxide, 1 part of zirconium dioxide.
Embodiment 2
In parts by weight: the opaque glaze includes 52 parts of silica, and 7.5 parts of aluminium oxide, 13 parts of calcium oxide, magnesia
2.75 parts, 6 parts of alkali metal oxide, 1.5 parts of zirconium dioxide；The fritted glaze includes 2.75 parts of potassium oxide, alkaline-earth metal oxide
8 parts of object, 4 parts of zinc oxide, 2.75 parts of aluminium oxide, 73 parts of silica, 1.5 parts of diboron trioxide, 1.5 parts of zirconium dioxide.
Embodiment 3
In parts by weight: the opaque glaze includes 55 parts of silica, and 10 parts of aluminium oxide, 15 parts of calcium oxide, magnesia
3.5 parts, 7.5 parts of alkali metal oxide, 2 parts of zirconium dioxide；The fritted glaze includes 3.5 parts of potassium oxide, alkaline earth oxide
10 parts, 5.5 parts of zinc oxide, 3.5 parts of aluminium oxide, 75 parts of silica, 2 parts of diboron trioxide, 2.5 parts of zirconium dioxide.
Embodiment 4
In parts by weight: the opaque glaze includes 58 parts of silica, 12.5 parts of aluminium oxide, 18 parts of calcium oxide, is aoxidized
4.25 parts of magnesium, 9 parts of alkali metal oxide, 2.5 parts of zirconium dioxide；The fritted glaze includes 4.25 parts of potassium oxide, alkaline-earth metal oxygen
12 parts of compound, 6.5 parts of zinc oxide, 4.25 parts of aluminium oxide, 78 parts of silica, 2.5 parts of diboron trioxide, 3.5 parts of zirconium dioxide.
Embodiment 5
In parts by weight: the opaque glaze includes 60 parts of silica, and 15 parts of aluminium oxide, 20 parts of calcium oxide, magnesia 5
Part, 10 parts of alkali metal oxide, 3 parts of zirconium dioxide；The fritted glaze includes 5 parts of potassium oxide, and 15 parts of alkaline earth oxide, oxygen
Change 8 parts of zinc, 5 parts of aluminium oxide, 80 parts of silica, 3 parts of diboron trioxide, 4 parts of zirconium dioxide.
In glaze in above-described embodiment 1~5, by the way that basic zirconium phosphate load silver ion and basic zirconium phosphate are loaded the mixed of copper ion
Object is closed as antibacterial agent, good, lasting anti-microbial property can be reached, and, glaze good fluidity is not easy to foaming.It will be above-mentioned
After glaze in Examples 1 to 5 is coated onto porcelain surface and fires successfully, 28 DEG C effect under 30min, germicidal efficiency be 52~
58%.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that include a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (6)
1. a kind of glaze formula with antibiotic property, which is characterized in that including opaque glaze, fritted glaze, Suzhou soil, antibacterial agent and go
Ionized water, wherein in parts by weight: the opaque glaze includes 50~60 parts of silica, and 5~15 parts of aluminium oxide, calcium oxide
10~20 parts, 2~5 parts of magnesia, 5~10 parts of alkali metal oxide, 1~3 part of zirconium dioxide；The fritted glaze includes potassium oxide
2~5 parts, 5~15 parts of alkaline earth oxide, 3~8 parts of zinc oxide, 2~5 parts of aluminium oxide, 70~80 parts of silica, three oxygen
Change 1~3 part of two boron, 1~4 part of zirconium dioxide；The antibacterial agent is that basic zirconium phosphate load silver ion and basic zirconium phosphate load copper ion
Mixture.
2. the glaze formula according to claim 1 with antibiotic property, which is characterized in that the milkiness in the glaze formula
Glaze, fritted glaze, Suzhou soil, antibacterial agent and deionized water weight ratio be 20:10:5:1:30.
3. the glaze formula according to claim 1 with antibiotic property, which is characterized in that the basic zirconium phosphate load silver ion
Weight ratio with basic zirconium phosphate load copper ion is 1:1~3.
4. the glaze formula according to claim 3 with antibiotic property, which is characterized in that the basic zirconium phosphate load silver ion
Weight ratio with basic zirconium phosphate load copper ion is 1:2.
5. the glaze formula according to claim 1 with antibiotic property, which is characterized in that in parts by weight: the cream
Turbid glaze includes 52~58 parts of silica, and 7.5~12.5 parts of aluminium oxide, 13~18 parts of calcium oxide, 2.75~4.25 parts of magnesia,
6~9 parts of alkali metal oxide, 1.5~2.5 parts of zirconium dioxide；The fritted glaze includes 2.75~4.25 parts of potassium oxide, alkaline earth gold
8~12 parts of oxide of category, 4~6.5 parts of zinc oxide, 2.75~4.25 parts of aluminium oxide, 73~78 parts of silica, diboron trioxide
1.5~2.5 parts, 1.5~3.5 parts of zirconium dioxide.
6. the glaze formula according to claim 5 with antibiotic property, which is characterized in that in parts by weight: the cream
Turbid glaze includes 55 parts of silica, and 10 parts of aluminium oxide, 15 parts of calcium oxide, 3.5 parts of magnesia, 7.5 parts of alkali metal oxide, dioxy
Change 2 parts of zirconium；The fritted glaze includes 3.5 parts of potassium oxide, and 10 parts of alkaline earth oxide, 5.5 parts of zinc oxide, 3.5 parts of aluminium oxide,
75 parts of silica, 2 parts of diboron trioxide, 2.5 parts of zirconium dioxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017848.XA CN108947251A (en) | 2018-09-02 | 2018-09-02 | A kind of glaze formula with antibiotic property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017848.XA CN108947251A (en) | 2018-09-02 | 2018-09-02 | A kind of glaze formula with antibiotic property |
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| Publication Number | Publication Date |
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| CN108947251A true CN108947251A (en) | 2018-12-07 |
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ID=64475489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811017848.XA Withdrawn CN108947251A (en) | 2018-09-02 | 2018-09-02 | A kind of glaze formula with antibiotic property |
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| Country | Link |
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| CN (1) | CN108947251A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112429968A (en) * | 2020-12-28 | 2021-03-02 | 湖州南浔百迪电子商务有限公司 | Antibacterial glaze for bathroom products and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106986541A (en) * | 2017-05-04 | 2017-07-28 | 山东省无棣海洋贝瓷有限公司 | A kind of easy clean antibacterial functions shellfish glaze and preparation method thereof |
| CN108033682A (en) * | 2017-12-08 | 2018-05-15 | 惠达卫浴股份有限公司 | The sheen glaze and glaze noodle producing method of glazed tile |
-
2018
- 2018-09-02 CN CN201811017848.XA patent/CN108947251A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106986541A (en) * | 2017-05-04 | 2017-07-28 | 山东省无棣海洋贝瓷有限公司 | A kind of easy clean antibacterial functions shellfish glaze and preparation method thereof |
| CN108033682A (en) * | 2017-12-08 | 2018-05-15 | 惠达卫浴股份有限公司 | The sheen glaze and glaze noodle producing method of glazed tile |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112429968A (en) * | 2020-12-28 | 2021-03-02 | 湖州南浔百迪电子商务有限公司 | Antibacterial glaze for bathroom products and preparation method thereof |
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| PB01 | Publication | ||
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| WW01 | Invention patent application withdrawn after publication | ||
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Application publication date: 20181207 |