CN106986541A - A kind of easy clean antibacterial functions shellfish glaze and preparation method thereof - Google Patents
A kind of easy clean antibacterial functions shellfish glaze and preparation method thereof Download PDFInfo
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- CN106986541A CN106986541A CN201710307147.9A CN201710307147A CN106986541A CN 106986541 A CN106986541 A CN 106986541A CN 201710307147 A CN201710307147 A CN 201710307147A CN 106986541 A CN106986541 A CN 106986541A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
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Abstract
The present invention relates to a kind of production method of domestic ceramics glaze, more particularly to a kind of easy clean antibacterial functions shellfish glaze and preparation method thereof.The proportioning of described glaze in parts by weight is：80 90 parts of frit, 5 10 parts of novel inorganic anti-biotic material, 5 10 parts of kaolin.The easy clean antibacterial functions shellfish porcelain products that the present invention is made, glaze is moist, penetrating, product qualification rate can reach more than 90%, and the easy clean property of product reaches 0.3g/ ㎡, and greasy dirt above can completely dispense with liquid detergent, can only be rinsed well with a small amount of water.
Description
Technical field
The present invention relates to a kind of production method of domestic ceramics glaze, more particularly to a kind of easy clean antibacterial functions shellfish glaze
And preparation method thereof.
Background technology
Ceramic material microstructure is made up of crystalline phase, glass phase and stomata, and its final products has 5%~10% stomata
Rate, if these holes are exposed to outside, can adhere to substantial amounts of pollutant.These pollutants are in Van der Waals force, capillary force, hydrogen
In the presence of a variety of physically or chemically power such as key, it is easily accumulated in the concavo-convex place on surface or enters in micropore, to the surface of ceramics
Pollute, had a strong impact on the cleaning of ceramic surface and attractive in appearance.If these dirts on ceramic surface are cleaned not in time, just
The soil of bacteria breed can be turned into, be bound to the healthy of the entail dangers to mankind.Conventional solution is by chemical detergent
Periodically cleaned.Liquid detergent is used for a long time and also results in skin disease, infringement is brought to healthy.Reported according to relevant experiment
Announcement is pointed out, if cleaning is incomplete, and the cleaning agent of residual enters after human body, takes care of the pence, the liver of human body can be caused damage.
Often usually feel that hand has the dry and cracked phenomenon felt nervous using the people of cleaning agent, because surfactant also can while decontamination
The oiliness protective layer of skin surface is removed, and then corrodes skin.Other chemical substances can also suppress the activity of oxidizing ferment, cause skin
Melanin in skin is changed into black from colourless, and then large area pigmentation occurs.Liquid detergent raffinate enters blood circulation, can damage
Hinder the cell membrane of red blood cell, make membranolysis, so as to cause haemolysis.All add to increase in clean result, detergent
Increasing net agent is entered, while phosphorous in most detergent, the phosphatic waste water after washing is discharged into water body, is to cause water
Body eutrophication, a major reason for destroying aquatic ecosystem.
Therefore, the ceramic material with easy clean, antibacterial, anti-pollution function is developed imperative, so without any detergent
Ceramic can be rinsed well, both save water resource, turn avoid because using detergent to human body and environment caused by
Harm.
China is studied anti-biotic material since the 90's of 20th century.In the research and development process of anti-bacteria ceramic
In, there are many problems needs solution, and the ceramic preparation technology of such as photocatalysis antibacterial is complicated, requires high to action condition;
And introduce after anti-biotic material, cause ceramic surface cross-color, gloss is deteriorated;The combination of anti-biotic material and ceramic matrix
Loosely, durability is poor etc..And on tableware greasy dirt washing needs liquid detergent, rinsing out remaining liquid detergent needs a large amount of water, this
It is unfavorable for saving resource, environmental protection, healthy living.
The content of the invention
To make up the deficiencies in the prior art, the invention provides a kind of easy clean antibacterial functions shellfish glaze and its preparation side
Method.
The present invention is achieved through the following technical solutions：
A kind of easy clean antibacterial functions shellfish glaze, it is characterised in that：The proportioning of described glaze in parts by weight is：Frit 80-
90 parts, 5-10 parts of novel inorganic anti-biotic material, 5-10 parts of kaolin.
The present invention more excellent technical scheme be：
The proportioning of the frit in parts by weight is：20-25 parts of oyster shell whiting, 25-30 parts of feldspar powder, 20-25 parts of silica flour, clay
0-5 parts, 5-10 parts of borax, 0-5 parts of zinc oxide, 0-5 parts of lithium carbonate, 0-5 parts of talcum.
The proportioning in parts by weight of the novel inorganic anti-biotic material is：1-5 parts of inorganic antibacterial material, far infrared radiation
1-10 parts of material.
Described inorganic antibacterial material is inorganic complex antimicrobials or inorganic silver-series antibacterial agent.The far-infrared radiation material
For natural minerals and the compound of rare earth material, complex method is known technology, i.e. rare earth nitrate solution and natural ore deposit
Thing material is well mixed, and is heated in Muffle furnace, and maximum heating temperature is 150 ~ 500 DEG C.
Above-mentioned inorganic antibacterial material is one kind in inorganic complex antimicrobials and inorganic silver-series antibacterial agent, is known production
Product, can be made or commercially available by known method.The embodiment of the present invention use for earth composite phosphate therein without
Machine anti-biotic material,（See reference document：Liang Jinsheng etc., earth composite phosphate inorganic antibacterial material is to ceramic activated water performance
Influence [J] China rare earth journals, 2003,21 (2), 241-243.）, but do not mean that the present invention is only defined in this.
The rare earth material quality is the 1 ~ 5% of far-infrared radiation material gross mass.The natural minerals are electric
One or more in stone, medical stone, jade.
The rare earth material is cerium oxide, neodymia or lanthana.
The preparation method of described easy clean antibacterial functions shellfish glaze, it is characterized in that, comprise the following steps：（1）Glaze system
It is standby：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, and industrial chemicals is technical pure, by shellfish
Shell powder, feldspar powder, silica flour, clay, borax, zinc oxide, lithium carbonate, talcum are uniformly mixed, 1200-1300 DEG C of melting, water quenching
Frit is made.By frit, kaolin and novel inorganic anti-biotic material mixed grinding to granularity be less than 10 μm of particle account for 90% with
On, that is, the remaining glaze slip less than 0.01% of 10000-hole sieve；
（2）Porcelain body glazing：Apply special easy clean antibacterial functions shellfish glaze, i.e., introduced in glaze antiseptic and rich in calcium and pearl into
Part shell, not only base glaze adaptability enhancing, and with energy-conserving and environment-protective, green and healthy the characteristics of；
（3）Finished product is fired：By the porcelain body after glazing glaze firing 10-15 minutes at a temperature of 1150-1180 DEG C, finished product is burnt till.
It is preferably：
Step（1）In, the particle that the mixture granularity after grinding is less than 10 μm accounts for more than 90%, that is, 10000-hole sieve is remaining less than 0.01%
Glaze slip.
The present invention adds inorganic antibacterial material on the basis of existing ocean shellfish porcelain preparation technology directly in shellfish glaze
Material, far-infrared radiation material functional additive.Wherein, inorganic antibacterial material is commercially available inorganic complex antimicrobials or inorganic silver system
Antiseptic, can suppress Escherichia coli and staphylococcus aureus growth and bactericidal action；Far-infrared radiation material is tourmaline, wheat
One or more in meal stone, jade are combined with one kind in cerium, neodymium, lanthanum, can be improved glaze far infrared radiation rate, be activated
Water, reduces oil water interfacial tension, prevents grease soils from depositing and being readily cleaned in glaze；The addition of two kinds of additives makes glaze mask
There are easy clean antibacterial functions.
Although the present invention additionally adds the functional additive of inorganic antibacterial material, far-infrared radiation material, do not change
Become original ceramic process, without other equipment investment.
The easy clean antibacterial functions shellfish porcelain products being made using the present invention, glaze is moist, penetrating, product qualification rate can reach
More than 90%, the easy clean property of product reaches 0.3g/ ㎡, and greasy dirt above can completely dispense with liquid detergent, can only be rushed with a small amount of water
Wash clean.The antibiotic rate of Escherichia coli and staphylococcus aureus reaches more than 96%, lead, quantity of cadmium release inspection result it is also remote
Less than national standard, the purpose of saving water resource, health environment-friendly is realized.
（Four）Brief description of the drawings
The invention will be further described below in conjunction with the accompanying drawings.
Fig. 1 is easy clean antibacterial functions shellfish glaze sintering curve；
Fig. 2 is the infrared emission collection of illustrative plates of heat treatment far-infrared radiation material.
（Five）Embodiment
Embodiment 1
（1）It is prepared by glaze：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, industrial chemicals
For technical pure, 20 parts of oyster shell whiting, 25 parts of feldspar powder, 20 parts of silica flour, 5 parts of clay, 5 parts of borax, 5 parts of zinc oxide are uniformly mixed
Close, frit is made in 1200-1300 DEG C of melting, water quenching.By 80 parts of frit, 5 parts of kaolin, earth composite phosphate inorganic antibacterial material
1 part of material, 3wt% cerium oxide mix 4 parts of miscellaneous tourmaline mixed grindings to particle of the granularity less than 10 μm and account for more than 90%, that is, 10000-hole sieve
It is remaining be less than 0.01% glaze slip.
（2）Porcelain body glazing：Special easy clean antibacterial functions shellfish glaze is applied, i.e., antiseptic is introduced in glaze and rich in calcium and treasure
The shell of pearl composition.
（3）Finished product is fired：By the porcelain body after glazing at a temperature of 1160 DEG C glaze firing 15 minutes, burn till finished product.
Embodiment 2
（1）It is prepared by glaze：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, industrial chemicals
For technical pure, by 20 parts of oyster shell whiting, 27 parts of feldspar powder, 23 parts of silica flour, 3 parts of clay, 7 parts of borax, 1 part of zinc oxide, lithium carbonate 1
Part, the uniform mixing of 3 parts of talcum, frit is made in 1200-1300 DEG C of melting, water quenching.85 parts of frit, 7 parts of kaolin, rare earth are combined
2 parts of phosphate inorganic anti-biotic material, 3wt% cerium oxide are mixed 5 parts of miscellaneous tourmaline mixed grindings to particle of the granularity less than 10 μm and accounted for
More than 90%, that is, the remaining glaze slip less than 0.01% of 10000-hole sieve.
（2）Porcelain body glazing：Special easy clean antibacterial functions shellfish glaze is applied, i.e., antiseptic is introduced in glaze and rich in calcium and treasure
The shell of pearl composition.
（3）Finished product is fired：By the porcelain body after glazing at a temperature of 1160 DEG C glaze firing 15 minutes, burn till finished product.
Embodiment 3
（1）It is prepared by glaze：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, industrial chemicals
For technical pure, 23 parts of oyster shell whiting, 27 parts of feldspar powder, 23 parts of silica flour, 8 parts of borax, 3 parts of zinc oxide, 3 parts of lithium carbonate are uniformly mixed
Close, frit is made in 1200-1300 DEG C of melting, water quenching.By 87 parts of frit, 8 parts of kaolin, earth composite phosphate inorganic antibacterial material
3 parts of material, 3wt% cerium oxide mix 6 parts of miscellaneous tourmaline mixed grindings to particle of the granularity less than 10 μm and account for more than 90%, that is, 10000-hole sieve
It is remaining be less than 0.01% glaze slip.
（2）Porcelain body glazing：Special easy clean antibacterial functions shellfish glaze is applied, i.e., antiseptic is introduced in glaze and rich in calcium and treasure
The shell of pearl composition.
（3）Finished product is fired：By the porcelain body after glazing at a temperature of 1160 DEG C glaze firing 15 minutes, burn till finished product.
Embodiment 4
（1）It is prepared by glaze：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, industrial chemicals
For technical pure, by 25 parts of oyster shell whiting, 30 parts of feldspar powder, 25 parts of silica flour, the uniform mixing of 5 parts of borax, 1200-1300 DEG C of melting,
Frit is made in water quenching.90 parts of frit, 10 parts of kaolin, 5 parts of earth composite phosphate inorganic antibacterial material, 3wt% cerium oxide are mixed
The particle that 5 parts of miscellaneous tourmaline mixed grindings are less than 10 μm to granularity accounts for more than 90%, that is, the remaining glaze slip less than 0.01% of 10000-hole sieve.
（2）Porcelain body glazing：Special easy clean antibacterial functions shellfish glaze is applied, i.e., antiseptic is introduced in glaze and rich in calcium and treasure
The shell of pearl composition.
（3）Finished product is fired：By the porcelain body after glazing at a temperature of 1160 DEG C glaze firing 15 minutes, burn till finished product.
Property indices testing result to above-described embodiment is as follows：
Claims (10)
1. a kind of easy clean antibacterial functions shellfish glaze, it is characterised in that：The proportioning of described glaze in parts by weight is：Frit
80-90 parts, 5-10 parts of novel inorganic anti-biotic material, 5-10 parts of kaolin.
2. easy clean antibacterial functions shellfish glaze according to claim 1, it is characterised in that：The frit matching somebody with somebody in parts by weight
Than for：20-25 parts of oyster shell whiting, 25-30 parts of feldspar powder, 20-25 parts of silica flour, 0-5 parts of clay, 5-10 parts of borax, zinc oxide 0-5
Part, 0-5 parts of lithium carbonate, 0-5 parts of talcum.
3. easy clean antibacterial functions shellfish glaze according to claim 1, it is characterised in that：The novel inorganic anti-biotic material
Proportioning in parts by weight be：1-5 parts of inorganic antibacterial material, 1-10 parts of far-infrared radiation material.
4. easy clean antibacterial functions shellfish glaze according to claim 3, it is characterised in that：Described inorganic antibacterial material is
Inorganic complex antimicrobials or inorganic silver-series antibacterial agent.
5. easy clean antibacterial functions shellfish glaze according to claim 3, it is characterised in that：The far-infrared radiation material is
The compound of natural minerals and rare earth material.
6. easy clean antibacterial functions shellfish glaze according to claim 5, it is characterised in that：The rare earth material quality is remote
The 1 ~ 5% of infrared radiant material gross mass.
7. easy clean antibacterial functions shellfish glaze according to claim 5, it is characterised in that：The natural minerals are electricity
One or more in gas stone, medical stone, jade.
8. easy clean antibacterial functions shellfish glaze according to claim 4, it is characterised in that：The rare earth material is oxidation
Cerium, neodymia or lanthana.
9. a kind of preparation method of easy clean antibacterial functions shellfish glaze as claimed in claim 1, it is characterized in that, including following step
Suddenly：（1）It is prepared by glaze：Glaze uses fritted glaze, and fritted glaze is raw materials used to select one-level material, and fineness is 80 mesh, industrial chemicals
For technical pure, oyster shell whiting, feldspar powder, silica flour, clay, borax, zinc oxide, lithium carbonate, talcum are uniformly mixed, 1200-
Frit is made in 1300 DEG C of meltings, water quenchings, and frit, kaolin and novel inorganic anti-biotic material mixed grinding to granularity are less than into 10 μm
Particle account for more than 90%, that is, 10000-hole sieve it is remaining be less than 0.01% glaze slip；（2）Porcelain body glazing：Apply special easy clean antibacterial functions shellfish
Antiseptic and the shell rich in calcium and pearl component are introduced in glaze, i.e. glaze；（3）Finished product is fired：By the porcelain body after glazing
Glaze firing 10-15 minutes at a temperature of 1150-1180 DEG C, finished product is burnt till.
10. the preparation method of easy clean antibacterial functions shellfish glaze according to claim 9, it is characterised in that：Step（1）
In, the particle that the mixture granularity after grinding is less than 10 μm accounts for more than 90%, that is, the remaining glaze slip less than 0.01% of 10000-hole sieve.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108585487A (en) * | 2018-06-28 | 2018-09-28 | 济南生禾生物科技有限公司 | A kind of production method of glass device for sobering drunken people |
| CN108751699A (en) * | 2018-05-30 | 2018-11-06 | 济南生禾生物科技有限公司 | A method of it activating antibacterial functions glass material and prepares glassware |
| CN108947251A (en) * | 2018-09-02 | 2018-12-07 | 张家港市沐和新材料技术开发有限公司 | A kind of glaze formula with antibiotic property |
| CN110040960A (en) * | 2019-05-28 | 2019-07-23 | 包头中科陶瓷科技有限公司 | A kind of rare earth anti-bacteria ceramic glaze and preparation method thereof |
| CN110317043A (en) * | 2019-07-08 | 2019-10-11 | 韩山师范学院 | Utilize the method and shellfish matter porcelain of shell preparation shellfish matter porcelain |
| CN111269589A (en) * | 2020-03-15 | 2020-06-12 | 雷志刚 | Method for preparing modified calcined kaolin for paint and ceramic |
| CN111517653A (en) * | 2020-04-09 | 2020-08-11 | 福建良瓷科技有限公司 | Sanitary antibacterial ceramic, antibacterial glaze and preparation process thereof |
| CN112110651A (en) * | 2020-09-14 | 2020-12-22 | 九牧厨卫股份有限公司 | Preparation method of ultra-smooth sanitary ceramic antibacterial glaze |
| CN112340995A (en) * | 2017-11-28 | 2021-02-09 | 福建省德化县晖德陶瓷有限公司 | Low-temperature frit for matt ceramic glaze and preparation process for preparing matt glaze ceramic product by using low-temperature frit |
| IT202100000347A1 (en) | 2021-01-11 | 2022-07-11 | Ceramiche Noi Soc Cooperativa | PROCEDURE FOR COATING CERAMIC PRODUCTS |
| CN115893839A (en) * | 2022-12-20 | 2023-04-04 | 箭牌家居集团股份有限公司 | Composite glaze as well as preparation method and application thereof |
| CN116332509A (en) * | 2022-12-21 | 2023-06-27 | 德州市乐华陶瓷洁具有限公司 | Lanthanide rare earth antibacterial blue light self-cleaning glaze and preparation method thereof |
| CN116396057A (en) * | 2023-03-23 | 2023-07-07 | 四川美术学院 | Selenium-rich ceramic and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112340995A (en) * | 2017-11-28 | 2021-02-09 | 福建省德化县晖德陶瓷有限公司 | Low-temperature frit for matt ceramic glaze and preparation process for preparing matt glaze ceramic product by using low-temperature frit |
| CN108751699A (en) * | 2018-05-30 | 2018-11-06 | 济南生禾生物科技有限公司 | A method of it activating antibacterial functions glass material and prepares glassware |
| CN108585487A (en) * | 2018-06-28 | 2018-09-28 | 济南生禾生物科技有限公司 | A kind of production method of glass device for sobering drunken people |
| CN108947251A (en) * | 2018-09-02 | 2018-12-07 | 张家港市沐和新材料技术开发有限公司 | A kind of glaze formula with antibiotic property |
| CN110040960A (en) * | 2019-05-28 | 2019-07-23 | 包头中科陶瓷科技有限公司 | A kind of rare earth anti-bacteria ceramic glaze and preparation method thereof |
| CN110317043A (en) * | 2019-07-08 | 2019-10-11 | 韩山师范学院 | Utilize the method and shellfish matter porcelain of shell preparation shellfish matter porcelain |
| CN111269589A (en) * | 2020-03-15 | 2020-06-12 | 雷志刚 | Method for preparing modified calcined kaolin for paint and ceramic |
| CN111517653A (en) * | 2020-04-09 | 2020-08-11 | 福建良瓷科技有限公司 | Sanitary antibacterial ceramic, antibacterial glaze and preparation process thereof |
| CN112110651A (en) * | 2020-09-14 | 2020-12-22 | 九牧厨卫股份有限公司 | Preparation method of ultra-smooth sanitary ceramic antibacterial glaze |
| CN112110651B (en) * | 2020-09-14 | 2022-07-29 | 九牧厨卫股份有限公司 | Preparation method of ultra-smooth sanitary ceramic antibacterial glaze |
| IT202100000347A1 (en) | 2021-01-11 | 2022-07-11 | Ceramiche Noi Soc Cooperativa | PROCEDURE FOR COATING CERAMIC PRODUCTS |
| CN115893839A (en) * | 2022-12-20 | 2023-04-04 | 箭牌家居集团股份有限公司 | Composite glaze as well as preparation method and application thereof |
| CN115893839B (en) * | 2022-12-20 | 2023-09-29 | 箭牌家居集团股份有限公司 | Composite glaze and preparation method and application thereof |
| CN116332509A (en) * | 2022-12-21 | 2023-06-27 | 德州市乐华陶瓷洁具有限公司 | Lanthanide rare earth antibacterial blue light self-cleaning glaze and preparation method thereof |
| CN116396057A (en) * | 2023-03-23 | 2023-07-07 | 四川美术学院 | Selenium-rich ceramic and preparation method thereof |
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