CN108558210A - A kind of antibacterial ceramic glaze and preparation method thereof - Google Patents
A kind of antibacterial ceramic glaze and preparation method thereof Download PDFInfo
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- CN108558210A CN108558210A CN201810729756.8A CN201810729756A CN108558210A CN 108558210 A CN108558210 A CN 108558210A CN 201810729756 A CN201810729756 A CN 201810729756A CN 108558210 A CN108558210 A CN 108558210A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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Abstract
The invention discloses a kind of antibacterial ceramic glazes, include according to parts by weight composition：60~80 parts of silica, 15~30 parts of silicon carbide, 8~12 parts of aluminium oxide, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, 1~3 part of nano zircite, 2~4 parts of iron oxide, 1~3 part of compound antibacterial powder, wherein the compound antibacterial powder includes that weight ratio is 1:1~3 silver oxide and titanium dioxide.The present invention also provides a kind of preparation methods of antibacterial ceramic glaze, including：(1) raw material for weighing above-mentioned parts by weight, is mixed evenly, and 2~3h, cooled to room temperature are calcined under conditions of 1050~1200 DEG C；(2) it is added a certain amount of deionized water into the raw material after calcination in step (1), ball milling 12~for 24 hours, it is ground to the glaze that fineness is 100~200 mesh, dry 1~2h, obtains antibacterial ceramic glaze under conditions of 90~110 DEG C.By the way that compound antibacterial powder is added in ceramic glaze in the present invention, good, lasting antibiotic property can be reached.
Description
Technical field
The present invention relates to field of ceramic preparation technology, more particularly to a kind of antibacterial ceramic glaze and preparation method thereof.
Background technology
With the development and the improvement of people's living standards of society, requirement of the people to the quality of life is higher and higher, people
To environmental protection consciousness more enhance, anti-biotic material is just increasingly valued by people.Anti-bacteria ceramic is a kind of environmental protection
New function material, be the product and material science and microbiology phase that antiseptic, antimicrobial technology are combined with ceramic material
In conjunction with product.It increases disinfection, sterilization and chemistry drop while keeping ceramic original using function and decorative effect
The function of solution.Therefore it is widely used in the industries such as health, medical treatment, family room, civilian or industrial building.
Natural antibacterial agent is natural material as antiseptic, common are behenyl, Meng Zongzhu, peppermint, lemonlike citrus leaf etc.
Extract in plant, the chitosan and natural minerals refined from crab, shrimp and the medium animal of oyster shell for example cinnabar, arsenic, red lead,
Courage is all etc..They have killing effect to multiple-microorganism, but effectively antimicrobial component content is less, and duration of efficacy is short, resistance to
Long property is poor, and less varieties, is restricted by conditions such as safety, and large-scale production is difficult to realize.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of antibacterial ceramic glaze and preparation method thereof, can solve existing
The problem of technology.
Invention content
The purpose of the present invention is to provide a kind of antibacterial ceramic glaze and preparation method thereof, with overcome it is in the prior art not
Foot.
To achieve the above object, the present invention provides the following technical solutions：
A kind of antibacterial ceramic glaze, according to parts by weight composition include：60~80 parts of silica, 15~30 parts of silicon carbide, oxygen
Change 8~12 parts of aluminium, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, 1~3 part of nano zircite, iron oxide
2~4 parts, 1~3 part of compound antibacterial powder, wherein the compound antibacterial powder includes that weight ratio is 1:1~3 silver oxide and dioxy
Change titanium.
Preferably, become according to parts by weight group：70~80 parts of silica, 20~30 parts of silicon carbide, aluminium oxide 9~12
Part, 12~15 parts of calcium phosphate, 6~10 parts of magnesium carbonate, 6~8 parts of sodium oxide molybdena, 1.75~3 parts of nano zircite, iron oxide 2.5~4
Part, 1.75~3 parts of compound antibacterial powder.
Preferably, become according to parts by weight group：75 parts of silica, 25 parts of silicon carbide, 10 parts of aluminium oxide, calcium phosphate 14
Part, 8 parts of magnesium carbonate, 7 parts of sodium oxide molybdena, 2.5 parts of nano zircite, 3.5 parts of iron oxide, 2.5~3 parts of compound antibacterial powder.
Preferably, it is 1 that the compound antibacterial powder, which includes weight ratio,:2 silver oxide and titanium dioxide.
The present invention also provides a kind of preparation methods of antibacterial ceramic glaze, include the following steps：
(1) composition of following parts by weight is weighed：60~80 parts of silica, 15~30 parts of silicon carbide, aluminium oxide 8~12
Part, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, 1~3 part of nano zircite, 2~4 parts of iron oxide, again
1~3 part of antibacterial powder is closed, is mixed evenly, 2~3h, cooled to room temperature are calcined under conditions of 1050~1200 DEG C；
(2) it is added a certain amount of deionized water into the raw material after calcination in step (1), ball milling 12~for 24 hours, it is ground to thin
Degree is the glaze of 100~200 mesh, and dry 1~2h, obtains antibacterial ceramic glaze under conditions of 90~110 DEG C.
Preferably, in step (1), calcination temperature is 1100 DEG C.
Compared with the prior art, the advantages of the present invention are as follows：By the way that compound antibacterial powder is added in ceramic glaze in the present invention,
Good, lasting antibiotic property can be reached.
Specific implementation mode
The present invention is described further by the following example：According to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of antibacterial ceramic glaze, includes according to parts by weight composition：60~80 parts of silica, silicon carbide 15
~30 parts, 8~12 parts of aluminium oxide, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, nano zircite 1~3
Part, 2~4 parts of iron oxide, 1~3 part of compound antibacterial powder, wherein the compound antibacterial powder includes that weight ratio is 1:1~3 oxygen
Change silver and titanium dioxide.
The present invention also provides a kind of preparation methods of antibacterial ceramic glaze, include the following steps：
(1) composition of following parts by weight is weighed：60~80 parts of silica, 15~30 parts of silicon carbide, aluminium oxide 8~12
Part, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, 1~3 part of nano zircite, 2~4 parts of iron oxide, again
1~3 part of antibacterial powder is closed, is mixed evenly, 2~3h, cooled to room temperature are calcined under conditions of 1050~1200 DEG C；
(2) it is added a certain amount of deionized water into the raw material after calcination in step (1), ball milling 12~for 24 hours, it is ground to thin
Degree is the glaze of 100~200 mesh, and dry 1~2h, obtains antibacterial ceramic glaze under conditions of 90~110 DEG C.
Following antibacterial ceramic glazes illustrated with specifically embodiment in the present invention.
Embodiment 1
Include according to parts by weight composition：60 parts of silica, 15 parts of silicon carbide, 8 parts of aluminium oxide, 10 parts of calcium phosphate, carbonic acid
5 parts of magnesium, 5 parts of sodium oxide molybdena, 1 part of nano zircite, 2 parts of iron oxide, 1 part of compound antibacterial powder.
A kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) composition of following parts by weight is weighed：60 parts of silica, 15 parts of silicon carbide, 8 parts of aluminium oxide, 10 parts of calcium phosphate,
5 parts of magnesium carbonate, 5 parts of sodium oxide molybdena, 1 part of nano zircite, 2 parts of iron oxide, 1 part of compound antibacterial powder are mixed evenly, in 1050
2h, cooled to room temperature are calcined under conditions of DEG C；
(2) a certain amount of deionized water is added in the raw material into step (1) after calcination, ball milling 12h, being ground to fineness is
The glaze of 100 mesh, dry 1h, obtains antibacterial ceramic glaze under conditions of 90 DEG C.
Embodiment 2
Include according to parts by weight composition：70 parts of silica, 20 parts of silicon carbide, 9 parts of aluminium oxide, 12 parts of calcium phosphate, carbonic acid
6 parts of magnesium, 6 parts of sodium oxide molybdena, 1.75 parts of nano zircite, 2.5 parts of iron oxide, 1.75 parts of compound antibacterial powder.
A kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) composition of following parts by weight is weighed：70 parts of silica, 20 parts of silicon carbide, 9 parts of aluminium oxide, 12 parts of calcium phosphate,
6 parts of magnesium carbonate, 6 parts of sodium oxide molybdena, 1.75 parts of nano zircite, 2.5 parts of iron oxide, 1.75 parts of compound antibacterial powder are mixed equal
It is even, 2.5h, cooled to room temperature are calcined under conditions of 1100 DEG C；
(2) a certain amount of deionized water is added in the raw material into step (1) after calcination, ball milling 18h, being ground to fineness is
The glaze of 150 mesh, dry 1.5h, obtains antibacterial ceramic glaze under conditions of 100 DEG C.
Embodiment 3
Include according to parts by weight composition：75 parts of silica, 25 parts of silicon carbide, 10 parts of aluminium oxide, 14 parts of calcium phosphate, carbonic acid
8 parts of magnesium, 7 parts of sodium oxide molybdena, 2.5 parts of nano zircite, 3.5 parts of iron oxide, 2.5 parts of compound antibacterial powder.
A kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) composition of following parts by weight is weighed：75 parts of silica, 25 parts of silicon carbide, 10 parts of aluminium oxide, calcium phosphate 14
Part, 8 parts of magnesium carbonate, 7 parts of sodium oxide molybdena, 2.5 parts of nano zircite, 3.5 parts of iron oxide, 2.5 parts of compound antibacterial powder, mixing is
It is even, 2.5h, cooled to room temperature are calcined under conditions of 1100 DEG C；
(2) a certain amount of deionized water is added in the raw material into step (1) after calcination, ball milling 18h, being ground to fineness is
The glaze of 150 mesh, dry 1.5h, obtains antibacterial ceramic glaze under conditions of 100 DEG C.
Embodiment 4
Include according to parts by weight composition：80 parts of silica, 30 parts of silicon carbide, 12 parts of aluminium oxide, 15 parts of calcium phosphate, carbonic acid
10 parts of magnesium, 8 parts of sodium oxide molybdena, 3 parts of nano zircite, 4 parts of iron oxide, 3 parts of compound antibacterial powder.
A kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) composition of following parts by weight is weighed：80 parts of silica, 30 parts of silicon carbide, 12 parts of aluminium oxide, calcium phosphate 15
Part, 10 parts of magnesium carbonate, 8 parts of sodium oxide molybdena, 3 parts of nano zircite, 4 parts of iron oxide, 3 parts of compound antibacterial powder are mixed evenly, in
3h, cooled to room temperature are calcined under conditions of 1200 DEG C；
(2) a certain amount of deionized water is added in the raw material into step (1) after calcination, for 24 hours, be ground to fineness is ball milling
The glaze of 200 mesh, dry 2h, obtains antibacterial ceramic glaze under conditions of 110 DEG C.
By the way that compound antibacterial powder is added in ceramic glaze in the present invention, good, lasting antibiotic property can be reached.It will be upper
It states after the antibacterial ceramic glaze in Examples 1 to 4 is coated onto pottery surface and fires successfully, 35min under being acted at 25 DEG C, sterilization effect
Rate is 60~68%.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that including a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (6)
1. a kind of antibacterial ceramic glaze, which is characterized in that include according to parts by weight composition：60~80 parts of silica, silicon carbide 15
~30 parts, 8~12 parts of aluminium oxide, 10~15 parts of calcium phosphate, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, nano zircite 1~3
Part, 2~4 parts of iron oxide, 1~3 part of compound antibacterial powder, wherein the compound antibacterial powder includes that weight ratio is 1:1~3 oxygen
Change silver and titanium dioxide.
2. antibacterial ceramic glaze according to claim 1, which is characterized in that become according to parts by weight group：Silica 70~
80 parts, 20~30 parts of silicon carbide, 9~12 parts of aluminium oxide, 12~15 parts of calcium phosphate, 6~10 parts of magnesium carbonate, 6~8 parts of sodium oxide molybdena,
1.75~3 parts of nano zircite, 2.5~4 parts of iron oxide, 1.75~3 parts of compound antibacterial powder.
3. antibacterial ceramic glaze according to claim 2, which is characterized in that become according to parts by weight group：75 parts of silica,
25 parts of silicon carbide, 10 parts of aluminium oxide, 14 parts of calcium phosphate, 8 parts of magnesium carbonate, 7 parts of sodium oxide molybdena, 2.5 parts of nano zircite, iron oxide
3.5 parts, 2.5 parts of compound antibacterial powder.
4. antibacterial ceramic glaze according to claim 1, which is characterized in that the compound antibacterial powder includes that weight ratio is 1:
2 silver oxide and titanium dioxide.
5. a kind of preparation method of antibacterial ceramic glaze, which is characterized in that include the following steps：
(1) composition of following parts by weight is weighed：60~80 parts of silica, 15~30 parts of silicon carbide, 8~12 parts of aluminium oxide, phosphorus
10~15 parts of sour calcium, 5~10 parts of magnesium carbonate, 5~8 parts of sodium oxide molybdena, 1~3 part of nano zircite, 2~4 parts of iron oxide are compound anti-
1~3 part of bacterium powder, is mixed evenly, and 2~3h, cooled to room temperature are calcined under conditions of 1050~1200 DEG C；
(2) it is added a certain amount of deionized water into the raw material after calcination in step (1), ball milling 12~for 24 hours, being ground to fineness is
The glaze of 100~200 mesh, dry 1~2h, obtains antibacterial ceramic glaze under conditions of 90~110 DEG C.
6. the preparation method of antibacterial ceramic glaze according to claim 5, which is characterized in that in step (1), calcination temperature is
1100℃。
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| CN201810729756.8A CN108558210A (en) | 2018-07-05 | 2018-07-05 | A kind of antibacterial ceramic glaze and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109970341A (en) * | 2019-04-23 | 2019-07-05 | 廖祥胜 | Antifouling and antibiosis ceramic glaze and preparation method thereof |
| CN117859768A (en) * | 2024-03-11 | 2024-04-12 | 佛山市东鹏陶瓷有限公司 | Composite antiviral agent and preparation method thereof, protective glaze, ceramic tile and preparation method thereof |
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| CN1333193A (en) * | 2001-05-30 | 2002-01-30 | 和成欣业股份有限公司 | Anti-dirt and anti-bacterial high-temp. ceramic glaze material ceramic glaze surfance and making method thereof |
| CN101580342A (en) * | 2009-06-26 | 2009-11-18 | 潮州市澳丽泰陶瓷实业有限公司 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
| CN102515866A (en) * | 2011-12-15 | 2012-06-27 | 广东顺祥陶瓷有限公司 | Ceramic glaze with antibacterial capability and preparation method thereof |
| CN105152683A (en) * | 2015-08-25 | 2015-12-16 | 山东建筑大学 | Method for manufacturing nanometer antibacterial ceramic glaze layers |
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2018
- 2018-07-05 CN CN201810729756.8A patent/CN108558210A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1333193A (en) * | 2001-05-30 | 2002-01-30 | 和成欣业股份有限公司 | Anti-dirt and anti-bacterial high-temp. ceramic glaze material ceramic glaze surfance and making method thereof |
| CN101580342A (en) * | 2009-06-26 | 2009-11-18 | 潮州市澳丽泰陶瓷实业有限公司 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
| CN102515866A (en) * | 2011-12-15 | 2012-06-27 | 广东顺祥陶瓷有限公司 | Ceramic glaze with antibacterial capability and preparation method thereof |
| CN105152683A (en) * | 2015-08-25 | 2015-12-16 | 山东建筑大学 | Method for manufacturing nanometer antibacterial ceramic glaze layers |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109970341A (en) * | 2019-04-23 | 2019-07-05 | 廖祥胜 | Antifouling and antibiosis ceramic glaze and preparation method thereof |
| CN117859768A (en) * | 2024-03-11 | 2024-04-12 | 佛山市东鹏陶瓷有限公司 | Composite antiviral agent and preparation method thereof, protective glaze, ceramic tile and preparation method thereof |
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Application publication date: 20180921 |
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