CN103936404A - Muyu-stone ceramic tile and preparation method thereof - Google Patents

Abstract

The invention discloses a Muyu-stone ceramic tile and a preparation method thereof. The Muyu-stone ceramic tile is prepared from the following raw materials in parts by weight: 40-50 parts of silica powder, 20-30 parts of zeolite, 10-15 parts of illite, 4-8 parts of jade powder, 3-6 parts of mirabilite, 20-25 parts of Muyu-stone, 12-18 parts of tuff, 6-9 parts of calcium hydrogen phosphate, 15-20 parts of waste ceramic, 10-15 parts of montmorillonite, 5-10 parts of furnace ash, 7-11 parts of andalusite and 15-25 parts of modified clay. The Muyu-stone ceramic tile disclosed by the invention has the effects of adjusting metabolism of human bodies, promoting blood circulation, improving immunity of the human bodies, relaxing mind and bodies, relieving fatigue resisting bacteria and the like, so that the ceramic tile has a relatively good healthcare function, the added value of the ceramic tile is increased, meanwhile, the ceramic tile provides guarantee for the health of people, and therefore, the ceramic tile has broad development prospect.

Description

A kind of MUSYUSHI ceramic tile and preparation method thereof

Technical field

The present invention relates to a kind of MUSYUSHI ceramic tile and preparation method thereof, belong to building ceramics field.

Background technology

ceramic tile is by clay, quartz sand and other inorganic non-metallic raw materials, through the tabular or block ceramic of the explained hereafter such as batching, ball milling, powder process, moulding, sintering, is widely used in decorating and metope and the ground of protecting buildings, structures.Along with developing rapidly of real estate, the production and consumption of ceramic tile is all got a larger development, but ceramic tile is in the market only as decorating, there is no nourishing function, a kind ofly be applied in family or the health tile of office space if can develop, for improving people's body constitution and environment purification, huge social benefit and economic interests will be there are.

Summary of the invention

The object of the present invention is to provide a kind of health care to be worth higher MUSYUSHI ceramic tile and preparation method thereof.

For achieving the above object, the technical solution used in the present invention is as follows:

A kind of MUSYUSHI ceramic tile, is made up of the raw material of following weight part: silicon powder 40-50, zeolite 20-30, illite 10-15, jade powder 4-8, saltcake 3-6, MUSYUSHI 20-25, tuff 12-18, secondary calcium phosphate 6-9, waste ceramic 15-20, montmorillonite 10-15, boiler ash sediment 5-10, andaluzite 7-11, modified clay 15-25;

The preparation method of described modified clay is as follows: a, 4-8:3-6:2-3 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 60-70 DEG C, insulation 0.5-1h, filter, be washed with distilled water to neutrality, dry, 460-520 DEG C of calcining 1-2h, pulverize, cross 150-250 mesh sieve, stand-by; B, take a certain amount of chitosan and be added in the acetum that volumetric concentration is 1-2%, stirring and dissolving, being mixed with concentration expressed in percentage by weight is the chitosan gum liquid solution of 10-15%, then add the Silver Nitrate of solution weight 3-4%, gac, the nano zine oxide of 1-2% and the poly-Union carbide A-162 of 2-3% of 2-3%, stir 20-30min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 2-3:1, stirs into pasty state, dries, and pulverizes, and crosses 200-300 mesh sieve.

The preparation method of MUSYUSHI ceramic tile of the present invention, comprises the following steps:

(1) getting zeolite, illite, tuff, montmorillonite, boiler ash sediment mixes, pulverize, cross 150-200 mesh sieve, then the spent pulping liquor that adds powder weight 12-16%, stirs, and then makes the particle that particle diameter is 1.5-2.5mm, dry, 1200-1250 DEG C of roasting 8-12min, naturally cools to normal temperature, stand-by;

(2) getting silicon powder, MUSYUSHI, secondary calcium phosphate, saltcake, waste ceramic, andaluzite mixes, pulverize, cross the particle mixing 3-5min making with step (1) after 200-300 mesh sieve, then add remaining raw material mixing 2-3min, then the water glass mixing 15-25min that the solid content that adds compound weight 2-4% is 30%, leaves standstill 5-10h;

(3) compound step (2) being made is delivered to forming machine compression moulding under 60-70MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 2-3%;

(4) dry adobe is warming up to 1160-1220 DEG C with the speed of 10-15 DEG C/min, insulation 1.5-2h, then be cooled to 720-760 DEG C with the speed of 5-10 DEG C/min, insulation 0.5-1h, then be warming up to 1320-1360 DEG C with the speed of 8-12 DEG C/min, insulation 2-3h, is then cooled to 850-900 DEG C with the speed of 4-8 DEG C/min, insulation 1-1.5h, be cooled to 440-480 DEG C with the speed of 3-6 DEG C/min again, insulation 0.5-1h, naturally cools to normal temperature, gets product through edging, packaging.

Above-mentioned modified clay adopts the collaborative Chitosan-coated clay of the materials such as Silver Nitrate, gac, nano zine oxide and poly-Union carbide A-162; not only there is good anti-microbial activity; can suppress the growth and breeding of some fungies, bacterium and virus; the indoor harmful gas such as all right adsorption-decomposition function formaldehyde, benzene, ammonia, sulfurous gas;, lavatory smelly, rubbish smelly, animal smelly etc. smelly to cigarette plays deodourizing effect; to protect mankind is healthy; can improve the performances such as the uvioresistant of ceramic tile, ageing-resistant, water tolerance simultaneously, extend the use work-ing life of ceramic tile.

Beneficial effect of the present invention:

MUSYUSHI ceramic tile of the present invention has the metabolism of the human body of adjusting, stimulate circulation, improve body immunity, the body and mind of releiving, alleviating fatigue, the effect such as antibacterial, make ceramic tile there is higher nourishing function, greatly improve the value added of ceramic tile, also brought guarantee for people's health simultaneously, there is vast potential for future development.

Embodiment

A kind of MUSYUSHI ceramic tile, is made up of the raw material of following weight (kg): silicon powder 45, zeolite 25, illite 10, jade powder 6, saltcake 4, MUSYUSHI 22, tuff 15, secondary calcium phosphate 7, waste ceramic 18, montmorillonite 12, boiler ash sediment 8, andaluzite 9, modified clay 20;

The preparation method of described modified clay is as follows: a, 7:4:2 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into concentration and be 18% hydrochloric acid soln, heating in water bath to 70 DEG C, insulation 0.5h, filter, be washed with distilled water to neutrality, dry, 460 DEG C of calcining 2h, pulverize, cross 250 mesh sieves, stand-by; B, taking a certain amount of chitosan, to be added to volumetric concentration be in 1.5% acetum, stirring and dissolving, be mixed with concentration expressed in percentage by weight and be 10% chitosan gum liquid solution, then add Silver Nitrate, 2% gac, 2% nano zine oxide and 3% the poly-Union carbide A-162 of solution weight 3%, stir 30min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 3:1, stirs into pasty state, dries, and pulverizes, and crosses 300 mesh sieves.

The preparation method of MUSYUSHI ceramic tile, comprises the following steps:

(1) get zeolite, illite, tuff, montmorillonite, boiler ash sediment and mix, pulverize, cross 200 mesh sieves, then add the spent pulping liquor of powder weight 14%, stir, then make the particle that particle diameter is 2mm, dry, 1220 DEG C of roasting 10min, naturally cool to normal temperature, stand-by;

(2) getting silicon powder, MUSYUSHI, secondary calcium phosphate, saltcake, waste ceramic, andaluzite mixes, pulverize, cross the particle mixing 4min making with step (1) after 250 mesh sieves, then add remaining raw material mixing 3min, then the water glass mixing 20min that the solid content that adds compound weight 3% is 30%, leaves standstill 8h;

(3) compound step (2) being made is delivered to forming machine compression moulding under 70MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 2.5%;

(4) dry adobe is warming up to 1180 DEG C with the speed of 15 DEG C/min, insulation 1.5h, then be cooled to 740 DEG C with the speed of 8 DEG C/min, insulation 0.5h, then be warming up to 1340 DEG C with the speed of 10 DEG C/min, insulation 2.5h, is then cooled to 860 DEG C with the speed of 6 DEG C/min, insulation 1h, be cooled to 450 DEG C with the speed of 4 DEG C/min again, insulation 0.5h, naturally cools to normal temperature, gets product through edging, packaging.

The ceramic tile of producing, its water-intake rate is 6.1%, folding strength is 17.9MPa.

This MUSYUSHI ceramic tile has the metabolism of the human body of adjusting, stimulates circulation, and improves body immunity, the body and mind of releiving, alleviating fatigue, the effect such as antibacterial, make ceramic tile there is higher nourishing function, greatly improved the value added of ceramic tile, simultaneously also for people's health has been brought guarantee.

Claims (2)

1. a MUSYUSHI ceramic tile, it is characterized in that, made by the raw material of following weight part: silicon powder 40-50, zeolite 20-30, illite 10-15, jade powder 4-8, saltcake 3-6, MUSYUSHI 20-25, tuff 12-18, secondary calcium phosphate 6-9, waste ceramic 15-20, montmorillonite 10-15, boiler ash sediment 5-10, andaluzite 7-11, modified clay 15-25;

The preparation method of described modified clay is as follows: a, 4-8:3-6:2-3 takes bauxitic clay, kaolin, attapulgite in mass ratio, mix, put into the hydrochloric acid soln that concentration is 15-20%, heating in water bath is to 60-70 DEG C, insulation 0.5-1h, filter, be washed with distilled water to neutrality, dry, 460-520 DEG C of calcining 1-2h, pulverize, cross 150-250 mesh sieve, stand-by; B, take a certain amount of chitosan and be added in the acetum that volumetric concentration is 1-2%, stirring and dissolving, being mixed with concentration expressed in percentage by weight is the chitosan gum liquid solution of 10-15%, then add the Silver Nitrate of solution weight 3-4%, gac, the nano zine oxide of 1-2% and the poly-Union carbide A-162 of 2-3% of 2-3%, stir 20-30min, stand-by; The chitosan gum liquid solution that c, the clay that step a is processed are processed with step b mixes by weight the ratio of 2-3:1, stirs into pasty state, dries, and pulverizes, and crosses 200-300 mesh sieve.

2. the preparation method of MUSYUSHI ceramic tile as claimed in claim 1, is characterized in that comprising the following steps:

(1) getting zeolite, illite, tuff, montmorillonite, boiler ash sediment mixes, pulverize, cross 150-200 mesh sieve, then the spent pulping liquor that adds powder weight 12-16%, stirs, and then makes the particle that particle diameter is 1.5-2.5mm, dry, 1200-1250 DEG C of roasting 8-12min, naturally cools to normal temperature, stand-by;

(2) getting silicon powder, MUSYUSHI, secondary calcium phosphate, saltcake, waste ceramic, andaluzite mixes, pulverize, cross the particle mixing 3-5min making with step (1) after 200-300 mesh sieve, then add remaining raw material mixing 2-3min, then the water glass mixing 15-25min that the solid content that adds compound weight 2-4% is 30%, leaves standstill 5-10h;

(3) compound step (2) being made is delivered to forming machine compression moulding under 60-70MPa, and then the adobe suppressing being delivered to and being dried to water content in dry kiln is 2-3%;

(4) dry adobe is warming up to 1160-1220 DEG C with the speed of 10-15 DEG C/min, insulation 1.5-2h, then be cooled to 720-760 DEG C with the speed of 5-10 DEG C/min, insulation 0.5-1h, then be warming up to 1320-1360 DEG C with the speed of 8-12 DEG C/min, insulation 2-3h, is then cooled to 850-900 DEG C with the speed of 4-8 DEG C/min, insulation 1-1.5h, be cooled to 440-480 DEG C with the speed of 3-6 DEG C/min again, insulation 0.5-1h, naturally cools to normal temperature, gets product through edging, packaging.