CN104072130B - A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof - Google Patents

A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof Download PDF

Info

Publication number
CN104072130B
CN104072130B CN201410334157.8A CN201410334157A CN104072130B CN 104072130 B CN104072130 B CN 104072130B CN 201410334157 A CN201410334157 A CN 201410334157A CN 104072130 B CN104072130 B CN 104072130B
Authority
CN
China
Prior art keywords
insulation
ceramic tile
ramp
cooled
bacteriostasis
Prior art date
Application number
CN201410334157.8A
Other languages
Chinese (zh)
Other versions
CN104072130A (en
Inventor
任新年
任浩楠
黄冉
Original Assignee
任新年
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 任新年 filed Critical 任新年
Priority to CN201410334157.8A priority Critical patent/CN104072130B/en
Publication of CN104072130A publication Critical patent/CN104072130A/en
Application granted granted Critical
Publication of CN104072130B publication Critical patent/CN104072130B/en

Links

Abstract

The invention discloses a kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof, it is made up of the raw material of following weight part: zircon sand 80-100, fiery rock mud 40-60, hokutolite 35-55, cinder 28-36, magnetic wave stone 20-30, calcite 15-25, lapis amiridis 12-18, ball clay 10-15, green bean rock 14-26, sepiolite 20-25, crushed-gravel 30-40, nano barium titanate calcium 10-15, blast-furnace slag 15-20, Chinese medicine slag ashes 5-10, waste glass powder 18-27.The ceramic tile that the present invention obtains has the feature of broad-spectrum antimicrobial, have various common pathogenic bacterium and well suppress and killing action, can effective the growing of mould fungus inhibition, simultaneously ceramic tile of the present invention can absorb toluene, formaldehyde etc. and fits up the objectionable impuritiess such as the dusty gas that causes and second hand smoking, and remove the peculiar smell such as indoor stink, purify the air of a room environment, and ceramic tile of the present invention to have intensity high, the advantages such as water-intake rate is low, and wear resistance is good, shock resistance is good, marketable value is huge.

Description

A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof
Technical field
The present invention relates to a kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof, belong to stupalith field.
Background technology
Ceramic tile is by clay and other inorganic non-metallic raw materials, through tabular or the Bulk ceramic goods of the explained hereafter such as shaping, sintering, it is as important architectural decorative and fitting materials, has wide range of application in the energy, medical treatment, national defence, space flight and aviation, electronics, petrochemical complex and domestic life field.In recent years, along with developing rapidly of building trade, people progressively attempt changing the single decoration functions of ceramic tile, give its more utility function.
Summary of the invention
The object of the present invention is to provide a kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof, this ceramic tile has bacteria mildew-proof, removes peculiar smell, adsorb harmful components, the function that purifies air.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of bacteriostasis, and deodorization ceramic tile, is made up of the raw material of following weight part: zircon sand 80-100, fiery rock mud 40-60, hokutolite 35-55, cinder 28-36, magnetic wave stone 20-30, calcite 15-25, lapis amiridis 12-18, ball clay 10-15, green bean rock 14-26, sepiolite 20-25, crushed-gravel 30-40, nano barium titanate calcium 10-15, blast-furnace slag 15-20, Chinese medicine slag ashes 5-10, waste glass powder 18-27.
The preparation method of bacteriostasis, and deodorization ceramic tile of the present invention, comprises the following steps:
(1) fiery rock mud, calcite, sepiolite, crushed-gravel, ball clay are mixed, then with the ramp of 10-15 DEG C/min to 860-920 DEG C, insulation 1-2h, be cooled to 500-550 DEG C with the speed of 4-6 DEG C/min again, insulation 3-4h, then with the ramp of 3-5 DEG C/min to 840-880 DEG C, insulation 2-3h, be cooled to 350-400 DEG C with the speed of 5-7 DEG C/min again, insulation 4-5h, takes out and shrend, pulverize after shrend, cross 150-200 mesh sieve, dry, stand-by;
(2) zircon sand, hokutolite, magnetic wave stone, green bean rock, cinder are mixed, pulverize, cross 200-300 mesh sieve, the slurries that concentration is 45-55% are made in the making beating that adds water, then regulate slurries PH to 4.5-5.5, speed lapping 15-20min under 80-90 DEG C of bath temperature with the hydrochloric acid soln that concentration is 1-2mol/L, then regulate slurries PH to neutral with the sodium hydroxide solution that concentration is 0.5-1mol/L, be spray dried to powder, stand-by;
(3) powder that particle obtained for step (1), step (2) obtain is mixed with remaining raw material, and then to add the solid content being equivalent to compound weight 5-10% be the water glass of 40%, being uniformly mixed compression moulding under 70-80MPa condition after 30-40min, is then the dry body of 2-4% by the brick bat drying suppressed to water content;
(4) by above-mentioned obtained dry body with the ramp of 5-10 DEG C/min to 780-820 DEG C, insulation 3-6h, again with the ramp of 3-5 DEG C/min to 1180-1240 DEG C, insulation 5-10h, is then cooled to 340-380 DEG C with the speed of 8-12 DEG C/min, insulation 2-3h, again with the ramp of 4-6 DEG C/min to 900-950 DEG C, insulation 4-8h, is cooled to room temperature, gets product through edging, packaging.
Beneficial effect of the present invention:
The ceramic tile that the present invention obtains has the feature of broad-spectrum antimicrobial, have various common pathogenic bacterium and well suppress and killing action, can effective the growing of mould fungus inhibition, simultaneously ceramic tile of the present invention can absorb toluene, formaldehyde etc. and fits up the objectionable impuritiess such as the dusty gas that causes and second hand smoking, and remove the peculiar smell such as indoor stink, purify the air of a room environment, and ceramic tile of the present invention to have intensity high, the advantages such as water-intake rate is low, and wear resistance is good, shock resistance is good, marketable value is huge.
Embodiment
Embodiment 1
A kind of bacteriostasis, and deodorization ceramic tile, is made up of the raw material of following weight (kg): zircon sand 80, fiery rock mud 40, hokutolite 35, cinder 28, magnetic wave stone 20, calcite 15, lapis amiridis 12, ball clay 10, green bean rock 14, sepiolite 20, crushed-gravel 30, nano barium titanate calcium 10, blast-furnace slag 15, Chinese medicine slag ashes 5, waste glass powder 18.
The preparation method of bacteriostasis, and deodorization ceramic tile, comprises the following steps:
(1) fiery rock mud, calcite, sepiolite, crushed-gravel, ball clay are mixed, then with the ramp to 860 DEG C of 10 DEG C/min, insulation h, be cooled to 500 DEG C with the speed of 4 DEG C/min again, insulation 4h, then with the ramp to 840 DEG C of 3 DEG C/min, insulation 3h, be cooled to 350 DEG C with the speed of 5 DEG C/min again, insulation 5h, takes out and shrend, pulverize after shrend, cross 150 mesh sieves, dry, stand-by;
(2) zircon sand, hokutolite, magnetic wave stone, green bean rock, cinder are mixed, pulverize, cross 200 mesh sieves, the slurries that concentration is 45% are made in the making beating that adds water, then regulate slurries PH to 5.5, speed lapping 20min under 80 DEG C of bath temperatures with the hydrochloric acid soln that concentration is 1mol/L, then regulate slurries PH to neutral with the sodium hydroxide solution that concentration is 0.5mol/L, be spray dried to powder, stand-by;
(3) powder that particle obtained for step (1), step (2) obtain is mixed with remaining raw material, and then to add the solid content being equivalent to compound weight 5% be the water glass of 40%, being uniformly mixed compression moulding under 70MPa condition after 30min, is then the dry body of 2% by the brick bat drying suppressed to water content;
(4) by above-mentioned obtained dry body with the ramp to 780 DEG C of 5 DEG C/min, insulation 6h, again with the ramp to 1180 DEG C of 3 DEG C/min, insulation 10h, is then cooled to 340 DEG C with the speed of 8 DEG C/min, insulation 3h, again with the ramp to 900 DEG C of 4 DEG C/min, insulation 8h, is cooled to room temperature, gets product through edging, packaging.
The folding strength of above-mentioned obtained ceramic tile is 19.2MPa, and water-intake rate is 2.1%, volume wear 148mm 3.And there is bacteria mildew-proof, remove peculiar smell, adsorb harmful components, the function that purifies air.
Embodiment 2
A kind of bacteriostasis, and deodorization ceramic tile, is made up of the raw material of following weight (kg): zircon sand 90, fiery rock mud 50, hokutolite 45, cinder 32, magnetic wave stone 25, calcite 20, lapis amiridis 16, ball clay 12, green bean rock 18, sepiolite 22, crushed-gravel 35, nano barium titanate calcium 12, blast-furnace slag 16, Chinese medicine slag ashes 8, waste glass powder 23.
The preparation method of bacteriostasis, and deodorization ceramic tile, comprises the following steps:
(1) fiery rock mud, calcite, sepiolite, crushed-gravel, ball clay are mixed, then with the ramp to 900 DEG C of 12 DEG C/min, insulation 1.5h, be cooled to 520 DEG C with the speed of 5 DEG C/min again, insulation 3.5h, then with the ramp to 860 DEG C of 4 DEG C/min, insulation 2.5h, be cooled to 380 DEG C with the speed of 6 DEG C/min again, insulation 4.5h, takes out and shrend, pulverize after shrend, cross 150 mesh sieves, dry, stand-by;
(2) zircon sand, hokutolite, magnetic wave stone, green bean rock, cinder are mixed, pulverize, cross 250 mesh sieves, the slurries that concentration is 50% are made in the making beating that adds water, then regulate slurries PH to 5.0, speed lapping 18min under 85 DEG C of bath temperatures with the hydrochloric acid soln that concentration is 1.5mol/L, then regulate slurries PH to neutral with the sodium hydroxide solution that concentration is 0.7mol/L, be spray dried to powder, stand-by;
(3) powder that particle obtained for step (1), step (2) obtain is mixed with remaining raw material, and then to add the solid content being equivalent to compound weight 8% be the water glass of 40%, being uniformly mixed compression moulding under 75MPa condition after 35min, is then the dry body of 3% by the brick bat drying suppressed to water content;
(4) by above-mentioned obtained dry body with the ramp to 800 DEG C of 8 DEG C/min, insulation 4h, again with the ramp to 1200 DEG C of 4 DEG C/min, insulation 8h, is then cooled to 360 DEG C with the speed of 10 DEG C/min, insulation 2.5h, again with the ramp to 920 DEG C of 5 DEG C/min, insulation 6h, is cooled to room temperature, gets product through edging, packaging.
The folding strength of above-mentioned obtained ceramic tile is 18.5MPa, and water-intake rate is 1.8%, volume wear 156mm 3.And there is bacteria mildew-proof, remove peculiar smell, adsorb harmful components, the function that purifies air.
Embodiment 3
A kind of bacteriostasis, and deodorization ceramic tile, is made up of the raw material of following weight (kg): zircon sand 100, fiery rock mud 60, hokutolite 55, cinder 36, magnetic wave stone 30, calcite 25, lapis amiridis 18, ball clay 15, green bean rock 26, sepiolite 25, crushed-gravel 40, nano barium titanate calcium 15, blast-furnace slag 20, Chinese medicine slag ashes 10, waste glass powder 27.
The preparation method of bacteriostasis, and deodorization ceramic tile, comprises the following steps:
(1) fiery rock mud, calcite, sepiolite, crushed-gravel, ball clay are mixed, then with the ramp to 920 DEG C of 15 DEG C/min, insulation 1h, 550 DEG C are cooled to again, insulation 3h, the then ramp to 880 DEG C of 5 DEG C/min with the speed of 6 DEG C/min, insulation 2h, be cooled to 400 DEG C with the speed of 7 DEG C/min again, insulation 4h, takes out and shrend, pulverize after shrend, cross 200 mesh sieves, dry, stand-by;
(2) zircon sand, hokutolite, magnetic wave stone, green bean rock, cinder are mixed, pulverize, cross 300 mesh sieves, the slurries that concentration is 55% are made in the making beating that adds water, then regulate slurries PH to 4.5, speed lapping 15min under 90 DEG C of bath temperatures with the hydrochloric acid soln that concentration is 2mol/L, then regulate slurries PH to neutral with the sodium hydroxide solution that concentration is 1mol/L, be spray dried to powder, stand-by;
(3) powder that particle obtained for step (1), step (2) obtain is mixed with remaining raw material, and then to add the solid content being equivalent to compound weight 10% be the water glass of 40%, being uniformly mixed compression moulding under 80MPa condition after 40min, is then the dry body of 4% by the brick bat drying suppressed to water content;
(4) by above-mentioned obtained dry body with the ramp to 820 DEG C of 10 DEG C/min, insulation 3h, again with the ramp to 1240 DEG C of 5 DEG C/min, insulation 5h, is then cooled to 380 DEG C with the speed of 12 DEG C/min, insulation 2h, again with the ramp to 950 DEG C of 6 DEG C/min, insulation 4h, is cooled to room temperature, gets product through edging, packaging.
The folding strength of above-mentioned obtained ceramic tile is 18.9MPa, and water-intake rate is 2.3%, volume wear 161mm 3.And there is bacteria mildew-proof, remove peculiar smell, adsorb harmful components, the function that purifies air.

Claims (1)

1. a bacteriostasis, and deodorization ceramic tile, it is characterized in that, be made up of the raw material of following weight part: zircon sand 80-100, fiery rock mud 40-60, hokutolite 35-55, cinder 28-36, magnetic wave stone 20-30, calcite 15-25, lapis amiridis 12-18, ball clay 10-15, green bean rock 14-26, sepiolite 20-25, crushed-gravel 30-40, nano barium titanate calcium 10-15, blast-furnace slag 15-20, Chinese medicine slag ashes 5-10, waste glass powder 18-27;
The preparation method of described bacteriostasis, and deodorization ceramic tile, comprises the following steps:
Step (1), fiery rock mud, calcite, sepiolite, crushed-gravel, ball clay to be mixed, then with the ramp of 10-15 DEG C/min to 860-920 DEG C, insulation 1-2h, be cooled to 500-550 DEG C with the speed of 4-6 DEG C/min again, insulation 3-4h, then with the ramp of 3-5 DEG C/min to 840-880 DEG C, insulation 2-3h, be cooled to 350-400 DEG C with the speed of 5-7 DEG C/min again, insulation 4-5h, takes out and shrend, pulverize after shrend, cross 150-200 mesh sieve, dry, stand-by;
Step (2), zircon sand, hokutolite, magnetic wave stone, green bean rock, cinder to be mixed, pulverize, cross 200-300 mesh sieve, the slurries that concentration is 45-55% are made in the making beating that adds water, then regulate slurries pH to 4.5-5.5, speed lapping 15-20min under 80-90 DEG C of bath temperature with the hydrochloric acid soln that concentration is 1-2mol/L, then regulate slurries pH to neutral with the sodium hydroxide solution that concentration is 0.5-1mol/L, be spray dried to powder, stand-by;
The powder that step (3), particle step (1) obtained, step (2) obtain mixes with remaining raw material, and then to add the solid content being equivalent to compound weight 5-10% be the water glass of 40%, being uniformly mixed compression moulding under 70-80MPa condition after 30-40min, is then the dry body of 2-4% by the brick bat drying suppressed to water content;
Step (4), by above-mentioned obtained dry body with the ramp of 5-10 DEG C/min to 780-820 DEG C, insulation 3-6h, again with the ramp of 3-5 DEG C/min to 1180-1240 DEG C, insulation 5-10h, is then cooled to 340-380 DEG C with the speed of 8-12 DEG C/min, insulation 2-3h, again with the ramp of 4-6 DEG C/min to 900-950 DEG C, insulation 4-8h, is cooled to room temperature, gets product through edging, packaging.
CN201410334157.8A 2014-07-15 2014-07-15 A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof CN104072130B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410334157.8A CN104072130B (en) 2014-07-15 2014-07-15 A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410334157.8A CN104072130B (en) 2014-07-15 2014-07-15 A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104072130A CN104072130A (en) 2014-10-01
CN104072130B true CN104072130B (en) 2015-08-19

Family

ID=51593790

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410334157.8A CN104072130B (en) 2014-07-15 2014-07-15 A kind of bacteriostasis, and deodorization ceramic tile and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104072130B (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104876537A (en) * 2015-04-11 2015-09-02 苏州市博群生物科技有限公司 Ashtray containing Chinese herbal medicines
CN104842437A (en) * 2015-04-11 2015-08-19 苏州市博群生物科技有限公司 Manufacturing method of ashtray containing Chinese herbal medicines
CN104847091A (en) * 2015-04-23 2015-08-19 苏州市博群生物科技有限公司 Chinese herbal medicine ceramic waistline tile
CN104860698A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Impact-resisting ceramic tile and preparation method thereof
CN104860666A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Ceramic tile strengthened with nanometer magnesium titanate and manufacturing method thereof
CN104987051A (en) * 2015-06-02 2015-10-21 安徽省含山瓷业股份有限公司 Antibacterial and bactericidal ceramic bowl and preparation method thereof
CN105884348A (en) * 2016-04-12 2016-08-24 陈雪琴 High-strength ceramic tile capable of removing peculiar smells and preparation method of high-strength ceramic tile
CN106087548A (en) * 2016-06-16 2016-11-09 铜陵锋帆彩色印务有限公司 Anti-abnormal flavour cardboard and preparation method thereof
CN107586095B (en) * 2017-10-13 2021-02-05 湖州品创孵化器有限公司 Heat-insulating building material and preparation method thereof
CN109180197A (en) * 2018-09-04 2019-01-11 湖州同泰新材料有限公司 Resistance to compression construction material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584343A (en) * 2012-01-16 2012-07-18 淄博博纳科技发展有限公司 Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic
CN103449805A (en) * 2012-05-29 2013-12-18 鹤山市雷迅新农机械科技有限公司 Environment purification material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584343A (en) * 2012-01-16 2012-07-18 淄博博纳科技发展有限公司 Energy ceramic with antimicrobial, easy cleaning and water activation functions and preparation method for energy ceramic
CN103449805A (en) * 2012-05-29 2013-12-18 鹤山市雷迅新农机械科技有限公司 Environment purification material and preparation method thereof

Also Published As

Publication number Publication date
CN104072130A (en) 2014-10-01

Similar Documents

Publication Publication Date Title
CN102850081B (en) Foam cement insulation board containing industrial solid waste and preparation method thereof
CN103951402B (en) A kind of high-strength ceramic brick and preparation method thereof
CN103360103A (en) Fly ash concrete aerated insulating brick and production method thereof
CN104788050B (en) A kind of haydite light-weight aggregate structural concrete and preparation method thereof
CN103951396B (en) A kind of Antiblotic mildew-proof ceramic brick and preparation method thereof
CN103951390B (en) Corrosion-resistant ceramic tile and preparation method thereof
CN102942916B (en) Ultra-low density ceramsite proppant and preparation method thereof
CN103011769B (en) A kind of method utilizing municipal sludge to produce building light-weight and energy-saving brick
CN103936402B (en) A kind of Ceramic Tiles that can releasing negative oxygen ion and preparation method thereof
CN103936444B (en) A kind of refractory brick and preparation method thereof
KR101205491B1 (en) Water permeable unsintered cement block with photocatalyst coating and method of preparing the same
CN101429429B (en) High-strength, high-density porcelain granule support agent and method of producing the same
CN103553448B (en) Ceramsite water permeable brick and preparation method thereof
CN106866052B (en) A kind of red mud-slag geo-polymer and preparation method thereof
CN105131933B (en) Ultra-low-density ceramic proppant and preparation method thereof
CN105461345A (en) Environmentally friendly tile blank capable of purifying air, and tile made thereofrom
CN106116509A (en) A kind of light energy saving brick and preparation method thereof
CN103253925A (en) Plant ash concrete air-entrapping heat-insulating brick and production method thereof
CN103936403B (en) Ceramic tile containing loess-doll and preparation method thereof
CN102167622B (en) Aluminum-silicon light heat insulation brick and preparation method thereof
CN104475020A (en) Environment-friendly active carbon particle with good absorption degradation effect and method for preparing environment-friendly active carbon particle with good absorption degradation effect
CN103566890A (en) Eggplant straw modified activated carbon water purifying agent and preparation method thereof
CN103265305A (en) Concrete cement foaming insulation brick and manufacturing method thereof
CN104098303B (en) A kind of waste and old garment fabric light cellular partition board and preparation method thereof
CN103951399B (en) Stone needle ceramic tile and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
CB03 Change of inventor or designer information

Inventor after: Ren Xinnian

Inventor after: Ren Haonan

Inventor after: Huang Ran

Inventor before: Ren Xinnian

C53 Correction of patent for invention or patent application
COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: REN XINNIAN TO: REN XINNIAN REN HAONAN HUANG RAN

C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20171026

Address after: The 400000 northern New District of Chongqing municipality Mount Huangshan Middle Road No. 66 A207

Patentee after: Chongqing AOPO Ruisen Technology Co. Ltd.

Address before: 325200 Zhejiang city of Wenzhou province Ruian Xincheng Experimental Primary School

Patentee before: Ren Xinnian

TR01 Transfer of patent right

Effective date of registration: 20171117

Address after: 401120 Chongqing Longxi street, California city garden, Yubei District, 3, 8-5

Patentee after: CHONGQING FANCHAO BRAND MANAGEMENT CO., LTD.

Address before: The 400000 northern New District of Chongqing municipality Mount Huangshan Middle Road No. 66 A207

Patentee before: Chongqing AOPO Ruisen Technology Co. Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190506

Address after: 444199 No. 210, South End of Changban Road, Dangyang City, Yichang City, Hubei Province

Patentee after: HUBEI KAIXUAN CERAMICS CO., LTD.

Address before: 401120 Chongqing Yubei District Longxi Street 3 California City Garden 8-5

Patentee before: CHONGQING FANCHAO BRAND MANAGEMENT CO., LTD.