CN108585495A - A kind of preparation method of antibacterial ceramic glaze - Google Patents
A kind of preparation method of antibacterial ceramic glaze Download PDFInfo
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- CN108585495A CN108585495A CN201810729766.1A CN201810729766A CN108585495A CN 108585495 A CN108585495 A CN 108585495A CN 201810729766 A CN201810729766 A CN 201810729766A CN 108585495 A CN108585495 A CN 108585495A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
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Abstract
The invention discloses a kind of preparation methods of antibacterial ceramic glaze, include the following steps：(1) it is 5g to press mass volume ratio:Mass parts are that 0.5~1.5 part of potassium hexafluorosilicate is added to the water dissolving by 100mL, and the antibacterial powder that mass parts are 1~3 part is then added, is uniformly dispersed, is 80~90% in 90~110 DEG C of heating evaporations to solid-to-liquid ratio, obtains antibacterial slurry；(2) following mass parts are pressed and carries out dispensing：60~70 parts of silica, 3~8 parts of aluminium oxide, 5~15 parts of diboron trioxide, 5~10 parts of calcium oxide, 0.5~1.5 part of magnesia, 10~20 parts of sodium oxide molybdena, 1~3 part of potassium oxide, 0.8~1.5 part of cobalt oxide, 1.5~2.5 parts of iron oxide, 0.3~0.8 part of manganese oxide, mixing, 3~5h of ball milling crosses 90~110 mesh sieve, obtains mixture；(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.In the ceramic glaze of the present invention, by the way that antibacterial powder is added, good, lasting antibiotic property can be reached, had broad application prospects.
Description
Technical field
The present invention relates to ceramic materials preparation technology fields, more particularly to a kind of preparation method of antibacterial ceramic glaze.
Background technology
With the development and the improvement of people's living standards of society, requirement of the people to the quality of life is higher and higher, people
To environmental protection consciousness more enhance, anti-biotic material is just increasingly valued by people.Anti-bacteria ceramic is a kind of environmental protection
New function material, be the product and material science and microbiology phase that antiseptic, antimicrobial technology are combined with ceramic material
In conjunction with product.It increases disinfection, sterilization and chemistry drop while keeping ceramic original using function and decorative effect
The function of solution.Therefore it is widely used in the industries such as health, medical treatment, family room, civilian or industrial building.
Natural antibacterial agent is natural material as antiseptic, common are behenyl, Meng Zongzhu, peppermint, lemonlike citrus leaf etc.
Extract in plant, the chitosan and natural minerals refined from crab, shrimp and the medium animal of oyster shell for example cinnabar, arsenic, red lead,
Courage is all etc..They have killing effect to multiple-microorganism, but effectively antimicrobial component content is less, and duration of efficacy is short, resistance to
Long property is poor, and less varieties, is restricted by conditions such as safety, and large-scale production is difficult to realize.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of preparation method of antibacterial ceramic glaze, existing skill can be solved
The problem of art.
Invention content
The purpose of the present invention is to provide a kind of preparation methods of antibacterial ceramic glaze, to overcome deficiency in the prior art.
To achieve the above object, the present invention provides the following technical solutions：
A kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) it is 5g to press mass volume ratio:The potassium hexafluorosilicate that mass parts are 0.5~1.5 part is added to the water molten by 100mL
Solution, it is 1~3 part of antibacterial powder that mass parts, which are then added, is uniformly dispersed, 90~110 DEG C of heating evaporations to solid-to-liquid ratio be 80~
90%, obtain antibacterial slurry；
(2) following mass parts are pressed and carries out dispensing：60~70 parts of silica, 3~8 parts of aluminium oxide, diboron trioxide 5~15
Part, 5~10 parts of calcium oxide, 0.5~1.5 part of magnesia, 10~20 parts of sodium oxide molybdena, 1~3 part of potassium oxide, cobalt oxide 0.8~1.5
Part, 1.5~2.5 parts of iron oxide, 0.3~0.8 part of manganese oxide, mixing, 3~5h of ball milling cross 90~110 mesh sieve, obtain mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
Preferably, in step (1), the antibacterial powder is the mixture of zinc oxide and titanium dioxide.
Preferably, the mass ratio of the zinc oxide and the titanium dioxide is 2~4:1.
Preferably, the mass ratio of the zinc oxide and the titanium dioxide is 3:1.
Preferably, in step (2), dispensing is carried out by following mass parts：65 parts of silica, 5 parts of aluminium oxide, three oxidations two
10 parts of boron, 7.5 parts of calcium oxide, 1 part of magnesia, 15 parts of sodium oxide molybdena, 2 parts of potassium oxide, 1.2 parts of cobalt oxide, 2 parts of iron oxide, oxidation
0.5 part of manganese.
Preferably, in step (2), the ratio of grinding media to material in mechanical milling process is 2~3:1.
Compared with the prior art, the advantages of the present invention are as follows：It, can by the way that antibacterial powder is added in the ceramic glaze of the present invention
Reach good, lasting antibiotic property, has broad application prospects.
Specific implementation mode
The present invention is described further by the following example：According to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of preparation method of antibacterial ceramic glaze, includes the following steps：
(1) it is 5g to press mass volume ratio:The potassium hexafluorosilicate that mass parts are 0.5~1.5 part is added to the water molten by 100mL
Solution, it is 1~3 part of antibacterial powder that mass parts, which are then added, is uniformly dispersed, 90~110 DEG C of heating evaporations to solid-to-liquid ratio be 80~
90%, obtain antibacterial slurry；
(2) following mass parts are pressed and carries out dispensing：60~70 parts of silica, 3~8 parts of aluminium oxide, diboron trioxide 5~15
Part, 5~10 parts of calcium oxide, 0.5~1.5 part of magnesia, 10~20 parts of sodium oxide molybdena, 1~3 part of potassium oxide, cobalt oxide 0.8~1.5
Part, 1.5~2.5 parts of iron oxide, 0.3~0.8 part of manganese oxide, mixing, 3~5h of ball milling cross 90~110 mesh sieve, obtain mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
Wherein, the antibacterial powder is the mixture of zinc oxide and titanium dioxide, the zinc oxide and the titanium dioxide
Mass ratio is 2~4:1, it is preferred that the mass ratio of the zinc oxide and the titanium dioxide is 3:1.
Following antibacterial ceramic glazes illustrated with specifically embodiment in the present invention.
Embodiment 1
(1) it is 5g to press mass volume ratio:Mass parts are that 0.5 part of potassium hexafluorosilicate is added to the water dissolving by 100mL, so
The antibacterial powder that mass parts are 1 part is added afterwards, is uniformly dispersed, is 80% in 90 DEG C of heating evaporations to solid-to-liquid ratio, obtains antibacterial slurry；
(2) following mass parts are pressed and carries out dispensing：60 parts of silica, 3 parts of aluminium oxide, 5 parts of diboron trioxide, calcium oxide 5
Part, 0.5 part of magnesia, 10 parts of sodium oxide molybdena, 1 part of potassium oxide, 0.8 part of cobalt oxide, 1.5 parts of iron oxide, 0.3 part of manganese oxide, mixing,
Ball milling 3h crosses 90 mesh sieve, obtains mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
Embodiment 2
(1) it is 5g to press mass volume ratio:Mass parts are that 1 part of potassium hexafluorosilicate is added to the water dissolving by 100mL, then
The antibacterial powder that mass parts are 2 parts is added, is uniformly dispersed, is 85% in 100 DEG C of heating evaporations to solid-to-liquid ratio, obtains antibacterial slurry；
(2) following mass parts are pressed and carries out dispensing：65 parts of silica, 5 parts of aluminium oxide, 10 parts of diboron trioxide, calcium oxide
7.5 parts, 1 part of magnesia, 15 parts of sodium oxide molybdena, 2 parts of potassium oxide, 1.2 parts of cobalt oxide, 2 parts of iron oxide, 0.5 part of manganese oxide, mixing,
Ball milling 4h, sieves with 100 mesh sieve, and obtains mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
Embodiment 3
(1) it is 5g to press mass volume ratio:Mass parts are that 1.5 parts of potassium hexafluorosilicate is added to the water dissolving by 100mL, so
The antibacterial powder that mass parts are 3 parts is added afterwards, is uniformly dispersed, is 90% in 110 DEG C of heating evaporations to solid-to-liquid ratio, obtains antibacterial slurry
Material；
(2) following mass parts are pressed and carries out dispensing：70 parts of silica, 8 parts of aluminium oxide, 15 parts of diboron trioxide, calcium oxide
10 parts, 1.5 parts of magnesia, 20 parts of sodium oxide molybdena, 3 parts of potassium oxide, 1.5 parts of cobalt oxide, 2.5 parts of iron oxide, 0.8 part of manganese oxide, mix
Even, ball milling 5h crosses 110 mesh sieve, obtains mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
In the ceramic glaze of the present invention, by the way that antibacterial powder is added, good, lasting antibiotic property can be reached, had wide
Application prospect.After antibacterial ceramic glaze in above-described embodiment 1~3 is coated onto pottery surface and is fired successfully, acted at 25 DEG C
Lower 35min, germicidal efficiency are 58~65%.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that including a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (6)
1. a kind of preparation method of antibacterial ceramic glaze, which is characterized in that include the following steps：
(1) it is 5g to press mass volume ratio:Mass parts are that 0.5~1.5 part of potassium hexafluorosilicate is added to the water dissolving by 100mL,
Then it is 1~3 part of antibacterial powder that mass parts, which are added, is uniformly dispersed, 90~110 DEG C of heating evaporations to solid-to-liquid ratio be 80~
90%, obtain antibacterial slurry；
(2) following mass parts are pressed and carries out dispensing：60~70 parts of silica, 3~8 parts of aluminium oxide, 5~15 parts of diboron trioxide,
5~10 parts of calcium oxide, 0.5~1.5 part of magnesia, 10~20 parts of sodium oxide molybdena, 1~3 part of potassium oxide, 0.8~1.5 part of cobalt oxide,
1.5~2.5 parts of iron oxide, 0.3~0.8 part of manganese oxide, mixing, 3~5h of ball milling cross 90~110 mesh sieve, obtain mixture；
(3) above-mentioned mixture is added in antibacterial slurry, stirs evenly, obtains antibacterial ceramic glaze.
2. the preparation method of antibacterial ceramic glaze according to claim 1, which is characterized in that in step (1), the antibacterial powder
For the mixture of zinc oxide and titanium dioxide.
3. the preparation method of antibacterial ceramic glaze according to claim 2, which is characterized in that the zinc oxide and the dioxy
The mass ratio for changing titanium is 2~4:1.
4. the preparation method of antibacterial ceramic glaze according to claim 3, which is characterized in that the zinc oxide and the dioxy
The mass ratio for changing titanium is 3:1.
5. the preparation method of antibacterial ceramic glaze according to claim 1, which is characterized in that in step (2), by following quality
Part carries out dispensing：65 parts of silica, 5 parts of aluminium oxide, 10 parts of diboron trioxide, 7.5 parts of calcium oxide, 1 part of magnesia, sodium oxide molybdena
15 parts, 2 parts of potassium oxide, 1.2 parts of cobalt oxide, 2 parts of iron oxide, 0.5 part of manganese oxide.
6. the preparation method of antibacterial ceramic glaze according to claim 1, which is characterized in that in step (2), in mechanical milling process
Ratio of grinding media to material be 2~3:1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810729766.1A CN108585495A (en) | 2018-07-05 | 2018-07-05 | A kind of preparation method of antibacterial ceramic glaze |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810729766.1A CN108585495A (en) | 2018-07-05 | 2018-07-05 | A kind of preparation method of antibacterial ceramic glaze |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052952A (en) * | 2018-10-16 | 2018-12-21 | 义乌倍肯新材料科技有限公司 | A kind of antibacterial glaze composition and with its ceramic obtained |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843995A (en) * | 2006-05-12 | 2006-10-11 | 丁文战 | Antibacterial enamel and preparation method thereof |
| CN101580342A (en) * | 2009-06-26 | 2009-11-18 | 潮州市澳丽泰陶瓷实业有限公司 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
| CN102515866A (en) * | 2011-12-15 | 2012-06-27 | 广东顺祥陶瓷有限公司 | Ceramic glaze with antibacterial capability and preparation method thereof |
| CN104761289A (en) * | 2015-03-23 | 2015-07-08 | 济南大学 | Water-soluble antibiosis ceramic glaze preparation method |
-
2018
- 2018-07-05 CN CN201810729766.1A patent/CN108585495A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843995A (en) * | 2006-05-12 | 2006-10-11 | 丁文战 | Antibacterial enamel and preparation method thereof |
| CN101580342A (en) * | 2009-06-26 | 2009-11-18 | 潮州市澳丽泰陶瓷实业有限公司 | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof |
| CN102515866A (en) * | 2011-12-15 | 2012-06-27 | 广东顺祥陶瓷有限公司 | Ceramic glaze with antibacterial capability and preparation method thereof |
| CN104761289A (en) * | 2015-03-23 | 2015-07-08 | 济南大学 | Water-soluble antibiosis ceramic glaze preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109052952A (en) * | 2018-10-16 | 2018-12-21 | 义乌倍肯新材料科技有限公司 | A kind of antibacterial glaze composition and with its ceramic obtained |
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Application publication date: 20180928 |