CN108439797A - A kind of composite antibacterial ceramic glaze - Google Patents
A kind of composite antibacterial ceramic glaze Download PDFInfo
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- CN108439797A CN108439797A CN201810677410.8A CN201810677410A CN108439797A CN 108439797 A CN108439797 A CN 108439797A CN 201810677410 A CN201810677410 A CN 201810677410A CN 108439797 A CN108439797 A CN 108439797A
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- antibacterial ceramic
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- Chemical Kinetics & Catalysis (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composite antibacterial ceramic glazes, include according to parts by weight composition：20~40 parts of albite, 5~25 parts of silica 1,25~35 parts of diboron trioxide, 1~4 part of manganese dioxide, 0.1~1 part of zirconium dioxide, 5~10 parts of calcirm-fluoride, 1~5 part of sodium metasilicate, 2~6 parts of magnesium carbonate, 1~3 part of barium carbonate, 0.5~2 part of titanium dioxide, 0.5~1.5 part of silver powder.Composite antibacterial ceramic glaze in the present invention, can reach good, lasting anti-microbial property, have broad application prospects.
Description
Technical field
The present invention relates to ceramic glaze technical fields, more particularly to a kind of composite antibacterial ceramic glaze.
Background technology
With the development and the improvement of people's living standards of society, requirement of the people to the quality of life is higher and higher, people
To environmental protection consciousness more enhance, anti-biotic material is just increasingly valued by people.Anti-bacteria ceramic is a kind of environmental protection
New function material, be the product and material science and microbiology phase that antiseptic, antimicrobial technology are combined with ceramic material
In conjunction with product.It increases disinfection, sterilization and chemistry drop while keeping ceramic original using function and decorative effect
The function of solution.Therefore it is widely used in the industries such as health, medical treatment, family room, civilian or industrial building.
Natural antibacterial agent is natural material as antiseptic, common are behenyl, Meng Zongzhu, peppermint, lemonlike citrus leaf etc.
Extract in plant, the chitosan and natural minerals refined from crab, shrimp and the medium animal of oyster shell for example cinnabar, arsenic, red lead,
Courage is all etc..They have killing effect to multiple-microorganism, but effectively antimicrobial component content is less, and duration of efficacy is short, resistance to
Long property is poor, and less varieties, is restricted by conditions such as safety, and large-scale production is difficult to realize.
For this reason, it is necessary in view of the above-mentioned problems, propose a kind of composite antibacterial ceramic glaze, can solve in the prior art
There are the problem of.
Invention content
The purpose of the present invention is to provide a kind of composite antibacterial ceramic glazes, to overcome deficiency in the prior art.
To achieve the above object, the present invention provides the following technical solutions：
A kind of composite antibacterial ceramic glaze, according to parts by weight composition include：20~40 parts of albite, silica 1 5~25
Part, 25~35 parts of diboron trioxide, 1~4 part of manganese dioxide, 0.1~1 part of zirconium dioxide, 5~10 parts of calcirm-fluoride, sodium metasilicate 1~
5 parts, 2~6 parts of magnesium carbonate, 1~3 part of barium carbonate, 0.5~2 part of titanium dioxide, 0.5~1.5 part of silver powder.
Preferably, include according to parts by weight composition：25~40 parts of albite, 7.5~25 parts of silica 1, three oxidations two
27.5~35 parts of boron, 2~4 parts of manganese dioxide, 0.3~1 part of zirconium dioxide, 6~10 parts of calcirm-fluoride, 2~5 parts of sodium metasilicate, carbonic acid
3~6 parts of magnesium, 1.5~3 parts of barium carbonate, 0.8~2 part of titanium dioxide, 0.8~1.5 part of silver powder.
Preferably, include according to parts by weight composition：30~40 parts of albite, 20~25 parts of silica, diboron trioxide
30~35 parts, 2.5~4 parts of manganese dioxide, 0.5~1 part of zirconium dioxide, 7.5~10 parts of calcirm-fluoride, 3~5 parts of sodium metasilicate, carbonic acid
4~6 parts of magnesium, 2~3 parts of barium carbonate, 1~2 part of titanium dioxide, 1~1.5 part of silver powder.
Preferably, include according to parts by weight composition：35 parts of albite, 22 parts of silica, 32 parts of diboron trioxide, dioxy
Change 3 parts of manganese, 0.6 part of zirconium dioxide, 8 parts of calcirm-fluoride, 3.5 parts of sodium metasilicate, 4.5 parts of magnesium carbonate, 2.25 parts of barium carbonate, titanium dioxide
1.2 parts, 1.2 parts of silver powder.
Preferably, include according to parts by weight composition：38 parts of albite, 24 parts of silica, 34 parts of diboron trioxide, dioxy
Change 3.5 parts of manganese, 0.8 part of zirconium dioxide, 9 parts of calcirm-fluoride, 4.5 parts of sodium metasilicate, 5 parts of magnesium carbonate, 2.75 parts of barium carbonate, titanium dioxide
1.6 parts, 1.4 parts of silver powder.
Compared with the prior art, the advantages of the present invention are as follows：Composite antibacterial ceramic glaze in the present invention, can reach good
Good, lasting anti-microbial property, has broad application prospects.
Specific implementation mode
The present invention is described further by the following example：According to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of composite antibacterial ceramic glaze, includes according to parts by weight composition：20~40 parts of albite, dioxy
15~25 parts of SiClx, 25~35 parts of diboron trioxide, 1~4 part of manganese dioxide, 0.1~1 part of zirconium dioxide, calcirm-fluoride 5~10
Part, 1~5 part of sodium metasilicate, 2~6 parts of magnesium carbonate, 1~3 part of barium carbonate, 0.5~2 part of titanium dioxide, 0.5~1.5 part of silver powder.
Following antibacterial ceramic glazes illustrated with specifically embodiment in the present invention.
Embodiment 1
Include according to parts by weight composition：20 parts of albite, 5 parts of silica 1,25 parts of diboron trioxide, manganese dioxide 1
Part, 0.1 part of zirconium dioxide, 5 parts of calcirm-fluoride, 1 part of sodium metasilicate, 2 parts of magnesium carbonate, 1 part of barium carbonate, 0.5 part of titanium dioxide, silver powder
0.5 part.
Embodiment 2
Include according to parts by weight composition：25 parts of albite, 7.5 parts of silica 1,27.5 parts of diboron trioxide, titanium dioxide
2 parts of manganese, 0.3 part of zirconium dioxide, 6 parts of calcirm-fluoride, 2 parts of sodium metasilicate, 3 parts of magnesium carbonate, 1.5 parts of barium carbonate, 0.8 part of titanium dioxide,
0.8 part of silver powder.
Embodiment 3
Include according to parts by weight composition：30 parts of albite, 20 parts of silica, 30 parts of diboron trioxide, manganese dioxide 2.5
Part, 0.5 part of zirconium dioxide, 7.5 parts of calcirm-fluoride, 3 parts of sodium metasilicate, 4 parts of magnesium carbonate, 2 parts of barium carbonate, 1 part of titanium dioxide, silver powder 1
Part.
Embodiment 4
Include according to parts by weight composition：35 parts of albite, 22 parts of silica, 32 parts of diboron trioxide, manganese dioxide 3
Part, 0.6 part of zirconium dioxide, 8 parts of calcirm-fluoride, 3.5 parts of sodium metasilicate, 4.5 parts of magnesium carbonate, 2.25 parts of barium carbonate, titanium dioxide 1.2
Part, 1.2 parts of silver powder.
Embodiment 5
Include according to parts by weight composition：38 parts of albite, 24 parts of silica, 34 parts of diboron trioxide, manganese dioxide 3.5
Part, 0.8 part of zirconium dioxide, 9 parts of calcirm-fluoride, 4.5 parts of sodium metasilicate, 5 parts of magnesium carbonate, 2.75 parts of barium carbonate, 1.6 parts of titanium dioxide,
1.4 parts of silver powder.
Embodiment 6
Include according to parts by weight composition：40 parts of albite, 25 parts of silica, 35 parts of diboron trioxide, manganese dioxide 4
Part, 1 part of zirconium dioxide, 10 parts of calcirm-fluoride, 5 parts of sodium metasilicate, 6 parts of magnesium carbonate, 3 parts of barium carbonate, 2 parts of titanium dioxide, silver powder 1.5
Part.
Composite antibacterial ceramic glaze in above-described embodiment 1~6, can reach good, lasting anti-microbial property, have
Wide application prospect.After composite antibacterial ceramic glaze in above-described embodiment 1~6 is coated onto pottery surface and is fired successfully,
30min under being acted at 25 DEG C, germicidal efficiency are 50~60%.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that including a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (5)
1. a kind of composite antibacterial ceramic glaze, which is characterized in that include according to parts by weight composition：20~40 parts of albite, dioxy
15~25 parts of SiClx, 25~35 parts of diboron trioxide, 1~4 part of manganese dioxide, 0.1~1 part of zirconium dioxide, calcirm-fluoride 5~10
Part, 1~5 part of sodium metasilicate, 2~6 parts of magnesium carbonate, 1~3 part of barium carbonate, 0.5~2 part of titanium dioxide, 0.5~1.5 part of silver powder.
2. composite antibacterial ceramic glaze according to claim 1, which is characterized in that include according to parts by weight composition：Sodium is long
25~40 parts of stone, 7.5~25 parts of silica 1,27.5~35 parts of diboron trioxide, 2~4 parts of manganese dioxide, zirconium dioxide 0.3
~1 part, 6~10 parts of calcirm-fluoride, 2~5 parts of sodium metasilicate, 3~6 parts of magnesium carbonate, 1.5~3 parts of barium carbonate, titanium dioxide 0.8~2
Part, 0.8~1.5 part of silver powder.
3. composite antibacterial ceramic glaze according to claim 1, which is characterized in that include according to parts by weight composition：Sodium is long
30~40 parts of stone, 20~25 parts of silica, 30~35 parts of diboron trioxide, 2.5~4 parts of manganese dioxide, zirconium dioxide 0.5~
1 part, 7.5~10 parts of calcirm-fluoride, 3~5 parts of sodium metasilicate, 4~6 parts of magnesium carbonate, 2~3 parts of barium carbonate, 1~2 part of titanium dioxide, silver
1~1.5 part of powder.
4. composite antibacterial ceramic glaze according to claim 1, which is characterized in that include according to parts by weight composition：Sodium is long
35 parts of stone, 22 parts of silica, 32 parts of diboron trioxide, 3 parts of manganese dioxide, 0.6 part of zirconium dioxide, 8 parts of calcirm-fluoride, sodium metasilicate
3.5 parts, 4.5 parts of magnesium carbonate, 2.25 parts of barium carbonate, 1.2 parts of titanium dioxide, 1.2 parts of silver powder.
5. composite antibacterial ceramic glaze according to claim 1, which is characterized in that include according to parts by weight composition：Sodium is long
38 parts of stone, 24 parts of silica, 34 parts of diboron trioxide, 3.5 parts of manganese dioxide, 0.8 part of zirconium dioxide, 9 parts of calcirm-fluoride, silicic acid
4.5 parts of sodium, 5 parts of magnesium carbonate, 2.75 parts of barium carbonate, 1.6 parts of titanium dioxide, 1.4 parts of silver powder.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810677410.8A CN108439797A (en) | 2018-06-27 | 2018-06-27 | A kind of composite antibacterial ceramic glaze |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810677410.8A CN108439797A (en) | 2018-06-27 | 2018-06-27 | A kind of composite antibacterial ceramic glaze |
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| CN108439797A true CN108439797A (en) | 2018-08-24 |
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| CN201810677410.8A Withdrawn CN108439797A (en) | 2018-06-27 | 2018-06-27 | A kind of composite antibacterial ceramic glaze |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112250305A (en) * | 2020-10-26 | 2021-01-22 | 辽宁大学 | Antibacterial ceramic glaze based on boric sludge and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843995A (en) * | 2006-05-12 | 2006-10-11 | 丁文战 | Antibacterial enamel and preparation method thereof |
| CN103265335A (en) * | 2013-05-30 | 2013-08-28 | 浙江华仁科技有限公司 | Ceramic glaze with composite mold resistance |
| CN105293914A (en) * | 2015-11-20 | 2016-02-03 | 常熟市永达化工设备厂 | Antibacterial enamel glass storage tank and manufacturing method thereof |
-
2018
- 2018-06-27 CN CN201810677410.8A patent/CN108439797A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1843995A (en) * | 2006-05-12 | 2006-10-11 | 丁文战 | Antibacterial enamel and preparation method thereof |
| CN103265335A (en) * | 2013-05-30 | 2013-08-28 | 浙江华仁科技有限公司 | Ceramic glaze with composite mold resistance |
| CN105293914A (en) * | 2015-11-20 | 2016-02-03 | 常熟市永达化工设备厂 | Antibacterial enamel glass storage tank and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112250305A (en) * | 2020-10-26 | 2021-01-22 | 辽宁大学 | Antibacterial ceramic glaze based on boric sludge and preparation method and application thereof |
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Application publication date: 20180824 |
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