CN101955352B - Preparation method of carbon ceramic container for containing water - Google Patents

Preparation method of carbon ceramic container for containing water Download PDF

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CN101955352B
CN101955352B CN 201010250949 CN201010250949A CN101955352B CN 101955352 B CN101955352 B CN 101955352B CN 201010250949 CN201010250949 CN 201010250949 CN 201010250949 A CN201010250949 A CN 201010250949A CN 101955352 B CN101955352 B CN 101955352B
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charcoal
water
high temperature
temperature resistant
powdered carbon
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CN101955352A (en
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涂志龙
张明敏
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Abstract

The invention relates to a china clay-baked container, in particular to a carbon ceramic container for containing water and a preparation method thereof. The carbon ceramic container comprises the following components in percentage by mass: 0.05 to 5 percent of high temperature-resistant inorganic antibacterial material, 5 to 55 percent of powdered carbon and 45 to 90 percent of clay. The carbon ceramic container for containing water has the advantages of no production of bacterial plaque when containing water and making tea for a long time or in a humid environment, excellent performance of purifying water quality, and black or dark grey whole body.

Description

A kind of preparation method of the charcoal pottery container be used to being filled with water
Technical field
The present invention relates to a kind of potter's clay and fire the container that is filled with water, relate in particular to a kind of charcoal pottery container that is filled with water.
Background technology
It is a kind of pottery that contains powdered carbon that charcoal is made pottery, and has namely added powdered carbon in its raw material of firing, and powdered carbon mainly is a kind of in bamboo charcoal powder, wood charcoal powder or the gac powdered carbon.The characteristics of charcoal pottery product are that entire body is black or Dark grey, and ruptured surface also is black or grey.Except manufacturability and practicality with conventional ceramic, have especially following physical function during charcoal is made pottery: 1. have suitable adsorptive power, the mildew-resistant of drying is eliminated peculiar smell, fresh air; 2. making pottery with charcoal is filled with water or is placed in the water, eliminates the chlorinated lime flavor in the boiling water, the potential of hydrogen of regulating tap water, make water quality trend weakly alkaline, make water softening, stripping is to human body beneficial's mineral substance potassium, magnesium, calcium, iron, phosphorus, manganese etc., for absorption of human body, replenish the trace element of human body; 3. be used for making tea, make coffee and other Instant Drinks product, can remove bitter taste, taste is more pure, and the shelf-time is longer.The pottery of firing after powdered carbon and potter's clay are compound, hole obviously increases, so that making pottery, charcoal has stronger absorption property, close especially organism, and the charcoal pottery container of the usefulness that is filled with water mainly is to be used for purification of water quality and moisture absorption mildew-resistant by adsorption function, often touches water, adds the pore passage structure of itself behind the organism in planar water, under dark and damp environment, be fit to very much the growth of each bacterioid and fungi, for example common intestinal bacteria, staphylococcus and mould that some are common.In sum, the deficiency that exists of the existing charcoal pottery container that is filled with water be filled with water or very moist environment under use and grow easily bacterial plaque.
Summary of the invention
In order to use the defective of growing easily bacterial plaque under being filled with water of solving that the above-mentioned existing charcoal pottery container that is filled with water exists, the moist environment, goal of the invention of the object of the invention is to disclose a kind of charcoal pottery container of being filled with water of being used for that is difficult for growing bacterial plaque, and another goal of the invention of the present invention is to disclose a kind of preparation method who is used for the charcoal pottery container that is filled with water who is difficult for growing bacterial plaque.
In order to realize the foregoing invention purpose, the present invention has adopted following technical scheme:
A kind of charcoal pottery container be used to being filled with water comprises following component: high temperature resistant inorganic antimicrobial material 0.05-5%, powdered carbon 5-55%, clay 45-90% by weight percentage.
As preferably, described high temperature resistant inorganic antimicrobial material is high temperature resistant colour fastness inorganic antimildew and antibacterial material, the characteristics of charcoal pottery container products are that entire body is black or Dark grey, ruptured surface also is black or grey, the high temperature resistant inorganic antimicrobial material that adds is high temperature resistant colour fastness inorganic antimildew and antibacterial material, guaranteed that it adds the charcoal pottery container nondiscoloration that burns out afterwards, still keeps charcoal pottery entire body to be the characteristics of black or Dark grey.
As preferably, described powdered carbon is a kind of in bamboo charcoal powder, wood charcoal powder or the gac powdered carbon, and its particle diameter is below 20 orders, and above-mentioned three kinds of powdered carbons are the most commonly used, the powdered carbon of particle diameter below 20 orders is convenient to mix fully with clay, guaranteed the homogeneity of the charcoal pottery container entire body color that is fired into.
As preferably, described inorganic antibacterial material is any one of Silver Nitrate, zinc chloride, cupric chloride, zinc oxide, cupric oxide, titanium oxide, calcium oxide.
As preferably, described by weight hundred water glass that also comprise 0.1-2% increase viscosity and fastness that charcoal is made pottery.
As preferably, described by weight hundred maifanite powders that also comprise 0.1-5% can make Acidic water become weakly alkaline.
A kind of preparation method of the charcoal pottery container be used to being filled with water comprises the steps: successively
(1) high temperature resistant inorganic antimicrobial material and water mix and blend are made contained the anti-biotic material aqueous solution, add powdered carbon, anti-biotic material is loaded in the charcoal, specifically in the hole of charcoal;
(2) clay is poured in the powdered carbon aqueous solution that contains high temperature resistant inorganic antimicrobial material, fully stirred, form charcoal pottery embryo slurry;
(3) old more than 24 hours, then draw embryo, moulding, drying treatment, fire, naturally cooling.
A kind of preparation method of the charcoal pottery container be used to being filled with water comprises the steps: to comprise the steps: successively successively
(1) powdered carbon and clay are added entry, fully stir, form charcoal pottery embryo slurry;
(2) oldly draw embryo more than 24 hours, moulding;
(3) high temperature resistant inorganic antimicrobial material and water be mixed contain the anti-biotic material aqueous solution, be sprayed at the idiosome surface, drying treatment, fire, naturally cooling.
As preferably, sintering temperature is controlled between the 800-1100 degree in the described sintering procedure.Contain normally the ceramic sintering temperature of charcoal between the 600-1200 degree.Sintering temperature is higher than 1200 degree, then charcoal pottery vitreous, and the adsorptivity that charcoal is made pottery and water-absorbent can be very poor.Firing temperature is lower than 600 degree, does not have sintering as the clay of carrier, and the insufficient strength that charcoal is made pottery is just broken easily.And as charcoal pottery container, its a big chunk purposes is exactly contain fluid, is exactly at most water, and for the performance that is conducive to purify water that guarantees that it is the highest, its sintering temperature is best between the 800-1100 degree.
As preferably, described powdered carbon is the bamboo charcoal powder of particle diameter below 20 orders, and the absorption of bamboo charcoal, the performance that purifies water are best, and the far-infrared functional of bamboo charcoal can dwindle water clusters, is more conducive to absorption of human body after drinking, and replenishes human nutrition moisture.
Adopted a kind of charcoal pottery container be used to being filled with water of technique scheme and preparation method thereof, its advantage be charcoal pottery container be filled with water for a long time, make tea or in wet environment, use after can not grow bacterial plaque yet, the performance that purifies water is very good, and entire body is black or Dark grey.
Embodiment
Embodiment 1
A kind of charcoal pottery container be used to being filled with water comprises following component by total amount hundred: high temperature resistant inorganic antimicrobial material 5%, powdered carbon 50%, clay 45%.Powdered carbon is bamboo charcoal powder, and bamboo charcoal powder is good absorption purifier, and also as good carrier, but the load high temperature resistant inorganic antimicrobial material plays absorption, antibacterial and catalyticing decomposition action better.High temperature resistant inorganic antimicrobial material is high temperature resistant colour fastness inorganic antimildew and antibacterial material, the inorganic antimildew and antibacterial agent of preferred Beijing Non-Ferrous Metal Research General Academy development.Charcoal pottery container entire body is black or Dark grey, and ruptured surface also is that black or grey powdered carbon are bamboo charcoal powder, and its particle diameter is below 20 orders.
A kind of preparation method of the charcoal pottery container be used to being filled with water, step is as follows:
High temperature resistant inorganic antimicrobial material and water mix and blend made contain the anti-biotic material aqueous solution, add powdered carbon, high temperature resistant inorganic antimicrobial material is water-soluble, fully stir, make and contain the anti-biotic material aqueous solution, with powdered carbon and mentioned solution mix and blend, leave standstill, anti-biotic material is loaded in the charcoal, specifically in the hole of charcoal, then powdered carbon is adding clay again as the anti-biotic material in the abundant absorbent solution of carrier, and clay passes through first washing and screening or pulverizing, fully stir, form charcoal pottery embryo slurry.Old more than 24 hours; Draw by hand embryo; Mold filling grouting or pressure embryo forming; The idiosome surface light is processed, engraving; Drying treatment, air-dry or oven dry all can; The dress cellar for storing things; High-temperature firing; Naturally cooling; Unload kiln; Clean.Wherein sintering temperature is controlled between 800 degree-1100 degree, the charcoal pottery container that this sintering temperature is fired performance on adsorptivity especially water-absorbent is the most excellent, the most favourable and water container is brought into play following function: 1. remove the heavy metal contaminants such as chlorine residue, pesticide residue and lead harmful in the water, cadmium, mercury, eliminate the chlorinated lime flavor in the boiling water; 2. suppress the make pottery growth of under dark and damp environment each bacterioid and fungi of charcoal; 3. regulate the potential of hydrogen of tap water, make water quality trend weakly alkaline, make water softening; 4. stripping for absorption of human body, replenishes the trace element of human body to human body beneficial's mineral substance potassium, magnesium, calcium, iron, phosphorus, manganese etc.; 5. be conducive to most bamboo charcoal and bring into play its far-infrared functional and can dwindle water clusters, be more conducive to absorption of human body after drinking, replenish human nutrition moisture.
Embodiment 2
A kind of charcoal pottery container be used to being filled with water comprises following component by total amount hundred: high temperature resistant inorganic antimicrobial material 0.1%, powdered carbon 10%, clay 89.9%.Powdered carbon is bamboo charcoal powder.High temperature resistant inorganic antimicrobial material is high temperature resistant colour fastness inorganic antimildew and antibacterial material, the inorganic antimildew and antibacterial agent of preferred Beijing Non-Ferrous Metal Research General Academy development.Charcoal pottery container entire body is black or Dark grey, and ruptured surface also is black or grey, and its particle diameter is below 20 orders.
A kind of preparation method of the charcoal pottery container be used to being filled with water, step is as follows:
Powdered carbon and clay are added entry, and clay passes through first washing and screening or pulverizing, fully stirs, and forms charcoal pottery embryo slurry; Old more than 24 hours; Draw by hand embryo; Mold filling grouting or pressure embryo forming; The idiosome surface light is processed, engraving; High temperature inorganic antibacterial material and water is mixed contains the anti-biotic material aqueous solution, will contain the anti-biotic material aqueous solution and be sprayed at the idiosome surface; Drying treatment, air-dry or oven dry all can; The dress cellar for storing things; High-temperature firing, naturally cooling unload kiln, clean.Wherein sintering temperature is controlled between 800 degree-1100 degree.
Embodiment 3
A kind of charcoal pottery container be used to being filled with water comprises following component by total amount hundred: high temperature resistant inorganic antimicrobial material 0.05%, and bamboo charcoal powder 40%, the water glass of clay 57.95%, 2%, water glass increases viscosity and the fastness that charcoal is made pottery.Inorganic antibacterial material is any one of Silver Nitrate, zinc chloride, cupric chloride, zinc oxide, cupric oxide, titanium oxide, calcium oxide.Other is identical with embodiment 1.
Embodiment 4
A kind of charcoal pottery container be used to being filled with water comprises following component by total amount hundred: high temperature resistant inorganic antimicrobial material 3%, bamboo charcoal powder 40%, clay 50%, medical stone 7%, charcoal pottery container is teapot or teacup specifically, medical stone has increased the calcium content in the water quality, increases the alkalescence of water quality.Other is identical with embodiment 2.
Embodiment 5
A kind of charcoal pottery container be used to being filled with water comprises following component by total amount hundred: high temperature resistant inorganic antimicrobial material 5%, bamboo charcoal powder 35%, clay 60%.Other is identical with embodiment 1.
Anti-biotic material is of a great variety, but great majority especially organic antibacterial agent can not tolerate thousand degree high temperature, Antibacterial Mechanism is complicated, safety performance is unstable, easily produces toxic byproduct, is unwell to charcoal and makes pottery compound.In conjunction with all conditions and requirement, select high temperature resistant inorganic antimicrobial material could solve high temperature resistant, safety non-toxic, the antibiotic requirement of spectrum, and the high temperature resistant inorganic antimicrobial material Antibacterial Mechanism mostly is contact or passive type, is suitable for the charcoal especially antibiotic requirement of bamboo charcoal ceramic of making pottery.Again the inorganic antibacterial material safety performance be harmless to the health well, non-secondary pollution, last, high temperature resistant inorganic antimicrobial material has broad-spectrum antimicrobial, lasting, especially has water-fast, acid and alkali-resistance, wash fast advantage, is suitable for very much as using in the container.Above-mentioned inorganic antibacterial material refers to utilize the inorganic antibacterial ability of the metals such as silver, copper, zinc, titanium and oxide compound, by methods such as physical adsorption, ion-exchanges, the metals such as silver, copper, zinc, titanium or its ion are fixed on the antiseptic-germicide that make on the surface of the porous materials such as zeolite, silica gel, gac, bamboo charcoal.Method by ion-exchange or physical adsorption is with metal or its ions and antibiotic oxide carried in the charcoal micro mist of bamboo charcoal powder, wood charcoal powder or gac powdered carbon such as silver, copper, zinc, titaniums, again this functional type powdered carbon with antibacterial ability is stirred and mix with clay, fire the charcoal pottery container that obtains being filled with water.
Above-mentioned charcoal pottery container be used to being filled with water can be water tumbler, tea set etc.Above-described embodiment only is preferably embodiment of this patent; for example powdered carbon can be a kind of in bamboo charcoal powder, wood charcoal powder or the gac powdered carbon, the structure that all employing the technical program are described, feature and the variation on its spiritual principle, modifies the protection domain that all belongs to this patent.

Claims (3)

1. the preparation method for the charcoal pottery container that is filled with water is characterized in that comprising the steps: successively
(1) high temperature resistant inorganic antimicrobial material and water mix and blend are made contained the anti-biotic material aqueous solution, add powdered carbon, anti-biotic material is loaded in the charcoal; (2) clay is poured in the powdered carbon aqueous solution that contains high temperature resistant inorganic antimicrobial material, fully stirred, form charcoal pottery embryo slurry; (3) old more than 24 hours, then draw embryo, moulding, drying treatment, fire, naturally cooling; Above-mentioned charcoal pottery container comprises following component by weight percentage: high temperature resistant inorganic antimicrobial material 0.05-5%, and powdered carbon 5-55%, clay 45-90%, water glass 0.1-2%, maifanite powder 0.1-5%, each component sum is 100%; Described high temperature resistant inorganic antimicrobial material is high temperature resistant colour fastness inorganic antimildew and antibacterial material, and described high temperature resistant colour fastness inorganic antimildew and antibacterial material is Silver Nitrate.
2. the preparation method of a kind of charcoal pottery container be used to being filled with water according to claim 1 is characterized in that described powdered carbon is a kind of in bamboo charcoal powder, wood charcoal powder or the gac powdered carbon, and its particle diameter is below 20 orders.
3. the preparation method of a kind of charcoal pottery container be used to being filled with water according to claim 1 is characterized in that sintering temperature is controlled between 800-1100 degree centigrade in the sintering procedure.
CN 201010250949 2010-08-09 2010-08-09 Preparation method of carbon ceramic container for containing water Active CN101955352B (en)

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CN102499573A (en) * 2011-11-18 2012-06-20 宁海县六六电器有限公司 Charcoal cooker and manufacturing process thereof
CN102491727A (en) * 2011-12-09 2012-06-13 水经(上海)生物科技有限公司 Negative ion carbon pot and preparation method thereof
CN104055420B (en) * 2013-03-20 2016-09-28 邱志群 A kind of kettle
CN103449799A (en) * 2013-08-22 2013-12-18 刘德军 Green ceramic product containing activated carbon and preparation method thereof
CN104591779A (en) * 2015-01-13 2015-05-06 江苏省环境科学研究院 Nano-silver-particle-embedded porous ceramic sheet as well as preparation method and application thereof
CN106673107A (en) * 2016-12-22 2017-05-17 浙江碧岩环保材料股份有限公司 Multifunctional water purification inner core and manufacturing technology thereof
US20180328606A1 (en) * 2017-05-12 2018-11-15 Anaele Diala Iroh Climate control materials, apparatus, and systems
CN108285345A (en) * 2018-01-19 2018-07-17 大田县源生竹业有限公司 A kind of preparation process for purifying the nano silver bamboo charcoal haydite of air
CN108178612A (en) * 2018-01-19 2018-06-19 大田县源生竹业有限公司 A kind of preparation process of the antibacterial bamboo charcoal ceramic tile of damping
CN108191388A (en) * 2018-01-19 2018-06-22 大田县源生竹业有限公司 A kind of preparation process of anti-bacterial bamboo charcoal crockery

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JP2002035741A (en) * 2000-07-27 2002-02-05 Yaskawa Electric Corp Water cleaning device
CN101734906B (en) * 2008-11-14 2012-07-04 刘见财 Baking flow of high-temperature carbon ceramics

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