CN106082948A - A kind of pottery with bactericidal purifying effect and preparation method thereof - Google Patents
A kind of pottery with bactericidal purifying effect and preparation method thereof Download PDFInfo
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- CN106082948A CN106082948A CN201610377706.9A CN201610377706A CN106082948A CN 106082948 A CN106082948 A CN 106082948A CN 201610377706 A CN201610377706 A CN 201610377706A CN 106082948 A CN106082948 A CN 106082948A
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- galapectite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of pottery with bactericidal purifying effect and preparation method thereof, be made up of according to the raw material of weight portion following: galapectite 25 55 parts, kaolin 10 15 parts, tarragon 15 22 parts, cloves 39 parts, blue fragrant 8 13 parts of stone, wolf's milk 37 parts, castor leaf 25 parts, zinc chloride 2.5 6.8 parts, silver nitrate 18 26 parts, 22 34 parts of diatomite, 11 19 parts of aluminum oxide and 0.8 2.4 parts of nano-photo catalytic composite.The present invention also disclosed the preparation method of this pottery.Production technology of the present invention is simple, use galapectite, diatomite and aluminum oxide as raw material, galapectite is natural nano tubulose silicate clay mineral, there is the similar hollow tubular structure of CNT, there is very high specific surface area, unique adsorptivity, excellent biocompatibility and chemically and thermally stability, thus there is excellent antibacterial and absorption property, and there is good compound and doping performance;Have employed herbal powder as antiseptic, the ceramic adsorbent strainability made is good.
Description
Technical field
The present invention relates to a kind of pottery, specifically a kind of pottery with bactericidal purifying effect and preparation method thereof.
Background technology
With the raising of social progress and people's living standard, quality of the life is had higher requirement by people, people
Life and the air regime of living environment are increasingly paid attention to, common people's house-purchase, house decoration and oil, coal, natural gas, change
The application of work goods, automobile etc. and popularization, while improving our living standard, bring to our indoor and outdoors air
A certain degree of pollution, house decoration is day by day luxurious especially in recent years, and a large amount of of home-use chemicals use smoking, culinary art et al.
Can not be ignored for the Indoor Air Pollution with outdoor Air Pollution problem that activity causes, and the quality of air ambient directly affects the health of people
Healthy.People use air purifier, air freshener or purification pottery to purify air, have the pottery of this function at present
Material is little, and the aspect such as adsorption rate, Bacteria suppression rate is all very low, does not has very big benefit to the healthy of people.
Content of the invention
It is an object of the invention to provide a kind of pottery with bactericidal purifying effect, to solve above-mentioned background technology carries
The problem going out.
For achieving the above object, the present invention provides following technical scheme:
A kind of pottery with bactericidal purifying effect, is made up of according to the raw material of weight portion following: galapectite 25-55 part,
Kaolin 10-15 part, tarragon 15-22 part, cloves 3-9 part, blue fragrant stone 8-13 part, wolf's milk 3-7 part, castor leaf 2-5 part, chlorination
Zinc 2.5-6.8 part, silver nitrate 18-26 part, diatomite 22-34 part, aluminum oxide 11-19 part and nano-photo catalytic composite 0.8-
2.4 part.
As the further scheme of the present invention: be made up of according to the raw material of weight portion following: galapectite 35-55 part, kaolinite
Soil 12-15 part, tarragon 18-22 part, cloves 5-9 part, blue fragrant stone 10-13 part, wolf's milk 4-7 part, castor leaf 3-5 part, zinc chloride
3-6.8 part, silver nitrate 20-26 part, diatomite 25-34 part, aluminum oxide 13-19 part and nano-photo catalytic composite 1.2-2.4
Part.
As the further scheme of the present invention: be made up of according to the raw material of weight portion following: galapectite 43 parts, kaolin 14
Part, tarragon 20 parts, cloves 7 parts, blue fragrant 12 parts of stone, wolf's milk 6 parts, castor leaf 4 parts, zinc chloride 5.2 parts, silver nitrate 23 parts, silicon
Diatomaceous earth 29 parts, 16 parts of aluminum oxide and 1.9 parts of nano-photo catalytic composite.
The preparation method of the described pottery with bactericidal purifying effect, specifically comprises the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, system
Obtain herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add by step 2
Ionized water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added by the rotating speed ball milling 2-4 hour of 100-120rpm in ball mill, then in temperature by step 3
Calcining in the Muffle furnace that degree is 700-900 degree Celsius, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material, with 320-650r/s in agitator by step 4
Rotating speed stirring 0.5-1.2 hour, add zinc chloride and silver nitrate stirring 0.2-0.8 hour, obtain final raw material;
Final raw material is sintered 3-6 hour in the Muffle furnace that temperature is 800-1100 degree Celsius, finally will become by step 5
Product are positioned over shady place and are dried.
Compared with prior art, the invention has the beneficial effects as follows: prepared by the present invention has the pottery of bactericidal purifying effect,
Production technology is simple, the silver ion containing antibacterial ability in raw material, has wide spectrum, efficient, safe, durable advantage to sterilization;
Using galapectite, diatomite and aluminum oxide as raw material, galapectite is natural nano tubulose silicate clay mineral, has carbon and receives
The similar hollow tubular structure of mitron, has very high specific surface area, unique adsorptivity, excellent biocompatibility and change
Learning and heat endurance, thus having excellent antibacterial and absorption property, and have good compound and doping performance, aluminum oxide is
Good catalyst carrier, has very high specific surface area, absorption property and higher physical strength, and diatomite has porosity
Greatly, absorbability is strong, stable chemical nature, the feature such as wear-resisting, heat-resisting;Have employed herbal powder as antiseptic, the pottery made
Porcelain Adsorption Filtration Properties is good.
Detailed description of the invention
It is described in more detail below in conjunction with the technical scheme to this patent for the detailed description of the invention.
Embodiment 1
A kind of pottery with bactericidal purifying effect, is made up of according to the raw material of weight portion following: galapectite 25 parts, kaolinite
10 parts of soil, tarragon 15 parts, cloves 3 parts, blue fragrant 8 parts of stone, wolf's milk 3 parts, castor leaf 2 parts, zinc chloride 2.5 parts, silver nitrate 18 parts,
22 parts of diatomite, 11 parts of aluminum oxide and 0.8 part of nano-photo catalytic composite.
The preparation method of the described pottery with bactericidal purifying effect, specifically comprises the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, system
Obtain herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add by step 2
Ionized water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added in ball mill with the rotating speed ball milling 2 hours of 100rpm, then in temperature is by step 3
The Muffle furnace of 700 degrees Celsius is calcined, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material by step 4, turning with 320r/s in agitator
Speed stirring 0.5 hour, adds zinc chloride and silver nitrate stirs 0.2 hour, obtains final raw material;
Final raw material is sintered in the Muffle furnace that temperature is 800 degrees Celsius 3 hours, finally places finished product by step 5
It is dried in shady place.
Embodiment 2
A kind of pottery with bactericidal purifying effect, is made up of according to the raw material of weight portion following: galapectite 35 parts, kaolinite
12 parts of soil, tarragon 18 parts, cloves 5 parts, blue fragrant 10 parts of stone, wolf's milk 4 parts, castor leaf 3 parts, zinc chloride 3 parts, silver nitrate 20 parts,
25 parts of diatomite, 13 parts of aluminum oxide and 1.2 parts of nano-photo catalytic composite.
The preparation method of the described pottery with bactericidal purifying effect, specifically comprises the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, system
Obtain herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add by step 2
Ionized water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added in ball mill with the rotating speed ball milling 3 hours of 110rpm, then in temperature is by step 3
The Muffle furnace of 800 degrees Celsius is calcined, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material by step 4, turning with 400r/s in agitator
Speed stirring 0.8 hour, adds zinc chloride and silver nitrate stirs 0.5 hour, obtains final raw material;
Final raw material is sintered in the Muffle furnace that temperature is 900 degrees Celsius 4 hours, finally places finished product by step 5
It is dried in shady place.
Embodiment 3
A kind of pottery with bactericidal purifying effect, is made up of according to the raw material of weight portion following: galapectite 43 parts, kaolinite
14 parts of soil, tarragon 20 parts, cloves 7 parts, blue fragrant 12 parts of stone, wolf's milk 6 parts, castor leaf 4 parts, zinc chloride 5.2 parts, silver nitrate 23
Part, 29 parts of diatomite, 16 parts of aluminum oxide and 1.9 parts of nano-photo catalytic composite.
The preparation method of the described pottery with bactericidal purifying effect, specifically comprises the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, system
Obtain herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add by step 2
Ionized water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added in ball mill with the rotating speed ball milling 4 hours of 120rpm, then in temperature is by step 3
The Muffle furnace of 900 degrees Celsius is calcined, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material by step 4, turning with 560r/s in agitator
Speed stirring 1 hour, adds zinc chloride and silver nitrate stirs 0.6 hour, obtains final raw material;
Final raw material is sintered in the Muffle furnace that temperature is 1000 degrees Celsius 5 hours, finally places finished product by step 5
It is dried in shady place.
Embodiment 4
A kind of pottery with bactericidal purifying effect, is made up of according to the raw material of weight portion following: galapectite 55 parts, kaolinite
15 parts of soil, tarragon 22 parts, cloves 9 parts, blue fragrant 13 parts of stone, wolf's milk 7 parts, castor leaf 5 parts, zinc chloride 6.8 parts, silver nitrate 26
Part, 34 parts of diatomite, 19 parts of aluminum oxide and 2.4 parts of nano-photo catalytic composite.
The preparation method of the described pottery with bactericidal purifying effect, specifically comprises the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, system
Obtain herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add by step 2
Ionized water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added in ball mill with the rotating speed ball milling 4 hours of 120rpm, then in temperature is by step 3
The Muffle furnace of 900 degrees Celsius is calcined, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material by step 4, turning with 650r/s in agitator
Speed stirring 1.2 hours, adds zinc chloride and silver nitrate stirs 0.8 hour, obtains final raw material;
Final raw material is sintered in the Muffle furnace that temperature is 1100 degrees Celsius 6 hours, finally places finished product by step 5
It is dried in shady place.
Following table is experiments performed by applicants, it is demonstrated experimentally that the embodiment sterilizing rate that above-described embodiment 1-4 provides all exceedes
93%, averagely reach 95.75%, it can be seen that, the pottery of the above embodiments has very strong bactericidal effect.
Embodiment | Sterilizing rate |
Embodiment 1 | 95% |
Embodiment 2 | 93% |
Embodiment 3 | 97% |
Embodiment 4 | 98% |
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art is possessed, can also be on the premise of without departing from this patent objective
Make a variety of changes.
Claims (4)
1. a pottery with bactericidal purifying effect, it is characterised in that be made up of according to the raw material of weight portion following: galapectite
25-55 part, kaolin 10-15 part, tarragon 15-22 part, cloves 3-9 part, blue fragrant stone 8-13 part, wolf's milk 3-7 part, castor leaf 2-
5 parts, zinc chloride 2.5-6.8 part, silver nitrate 18-26 part, diatomite 22-34 part, aluminum oxide 11-19 part and nano-photo catalytic are combined
Material 0.8-2.4 part.
2. the pottery with bactericidal purifying effect according to claim 1, it is characterised in that by following according to weight portion
Raw material forms: galapectite 35-55 part, kaolin 12-15 part, tarragon 18-22 part, cloves 5-9 part, blue fragrant stone 10-13 part, humid euphorbia
Grass 4-7 part, castor leaf 3-5 part, zinc chloride 3-6.8 part, silver nitrate 20-26 part, diatomite 25-34 part, aluminum oxide 13-19 part and
Nano-photo catalytic composite 1.2-2.4 part.
3. the pottery with bactericidal purifying effect according to claim 1, it is characterised in that by following according to weight portion
Raw material forms: galapectite 43 parts, kaolin 14 parts, tarragon 20 parts, cloves 7 parts, blue fragrant 12 parts of stone, wolf's milk 6 parts, castor leaf 4
Part, zinc chloride 5.2 parts, silver nitrate 23 parts, 29 parts of diatomite, 16 parts of aluminum oxide and 1.9 parts of nano-photo catalytic composite.
4. the preparation method of the pottery with bactericidal purifying effect as described in claim 1-3 is arbitrary, it is characterised in that
Specifically comprise the following steps that
Tarragon, cloves, Lan Xiangshi, wolf's milk and castor leaf are mixed, are first dried, then pulverize by step one, in preparing
Herbal powder;
Galapectite, kaolin, diatomite and aluminum oxide are respectively adopted ball mill and pulverize, add deionization by step 2
Water continues processing, until being processed into the mud that grain fineness is 200 mesh;
Herbal powder is added in ball mill by the rotating speed ball milling 2-4 hour of 100-120rpm, then in temperature is by step 3
The Muffle furnace of 700-900 degree Celsius is calcined, prepares secondary ceramic raw material;
Nano-photo catalytic composite is added in secondary ceramic raw material by step 4, turning with 320-650r/s in agitator
Speed stirring 0.5-1.2 hour, adds zinc chloride and silver nitrate stirring 0.2-0.8 hour, obtains final raw material;
Final raw material is sintered 3-6 hour in the Muffle furnace that temperature is 800-1100 degree Celsius, finally puts finished product by step 5
It is placed in shady place to be dried.
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CN201610377706.9A CN106082948A (en) | 2016-05-31 | 2016-05-31 | A kind of pottery with bactericidal purifying effect and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108308176A (en) * | 2018-01-12 | 2018-07-24 | 中国建筑材料科学研究总院有限公司 | Diatom soil matrix plants antimicrobial composite material and preparation method |
CN109095886A (en) * | 2018-10-09 | 2018-12-28 | 揭阳市腾晟科技咨询有限公司 | A kind of anti-bacteria ceramic raw material |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108308176A (en) * | 2018-01-12 | 2018-07-24 | 中国建筑材料科学研究总院有限公司 | Diatom soil matrix plants antimicrobial composite material and preparation method |
CN109095886A (en) * | 2018-10-09 | 2018-12-28 | 揭阳市腾晟科技咨询有限公司 | A kind of anti-bacteria ceramic raw material |
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Application publication date: 20161109 |