CN106747273A - A kind of anti-bacteria ceramic composite and preparation method thereof - Google Patents
A kind of anti-bacteria ceramic composite and preparation method thereof Download PDFInfo
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- CN106747273A CN106747273A CN201611056195.7A CN201611056195A CN106747273A CN 106747273 A CN106747273 A CN 106747273A CN 201611056195 A CN201611056195 A CN 201611056195A CN 106747273 A CN106747273 A CN 106747273A
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- parts
- diatom ooze
- powder
- kaolin
- golden
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- 239000000919 ceramic Substances 0.000 title claims abstract description 51
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 31
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 34
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 32
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 30
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 17
- 241000345998 Calamus manan Species 0.000 claims abstract description 17
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 17
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004927 clay Substances 0.000 claims abstract description 17
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000012950 rattan cane Nutrition 0.000 claims abstract description 17
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 17
- 229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 15
- 239000000454 talc Substances 0.000 claims abstract description 15
- 235000012222 talc Nutrition 0.000 claims abstract description 15
- 229910052623 talc Inorganic materials 0.000 claims abstract description 15
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 14
- 239000011034 rock crystal Substances 0.000 claims abstract description 14
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 14
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 10
- 239000000047 product Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 206010013786 Dry skin Diseases 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- XRRQZKOZJFDXON-UHFFFAOYSA-N nitric acid;silver Chemical compound [Ag].O[N+]([O-])=O XRRQZKOZJFDXON-UHFFFAOYSA-N 0.000 claims 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000006641 stabilisation Effects 0.000 abstract description 3
- 238000011105 stabilization Methods 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 7
- 238000006424 Flood reaction Methods 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 208000034874 Product colour issue Diseases 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052956 cinnabar Inorganic materials 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3281—Copper oxides, cuprates or oxide-forming salts thereof, e.g. CuO or Cu2O
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/3427—Silicates other than clay, e.g. water glass
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Abstract
The present invention provides a kind of anti-bacteria ceramic composite and preparation method thereof, and the weight portion of each component is：100~120 parts of kaolin, 50~60 parts of ceramic clay, 30~40 parts of diatom ooze, 10~20 parts of potassium feldspar, 5~15 parts of cupric oxide, 5~10 parts of alundum (Al2O3), 1~5 part of di-iron trioxide, 5~8 parts of tin oxide, 5~10 parts of rock quartz, 5~15 parts of talcum, golden 20~30 parts of clock rattan powder, 15~20 parts of calcium nitrate, 15~20 parts of silver nitrate.The present invention carries out by through oversintering, preparing after repeatedly compound that low cost, antibacterial effect be affected by environment and non-discoloring anti-bacteria ceramic to raw material；Preparation process is simple, it is easy to operate, it is suitable to large-scale production industrially；And anti-microbial property stabilization, have a wide range of application.
Description
Technical field
The present invention relates to technical field of composite materials, and in particular to a kind of anti-bacteria ceramic composite and preparation method thereof.
Background technology
With the development and the improvement of people's living standards of society, the requirement more and more higher of quality of the people to living, people
To environmental protection consciousness more strengthen, anti-biotic material is just increasingly valued by people.Anti-bacteria ceramic is a kind of environmental protection
New function material, be product that antiseptic, antimicrobial technology are combined with ceramic material, be also material science and microbiology phase
With reference to product.It increases sterilization, sterilized and chemistry drop while the original use function of ceramic and decorative effect is kept
The function of solution.Therefore it is widely used in the industries such as health, medical treatment, family room, civilian or industrial building, by the weight of various countries
Depending on.Natural antibacterial agent be natural material as antiseptic, in common are the plant of behenyl, Meng Zongzhu, peppermint, lemonlike citrus leaf etc.
Extract, the shitosan and natural minerals such as cinnabar, arsenic, red lead, courage refined from crab, shrimp and the medium animal of oyster shell is all
Deng.They have killing action to multiple-microorganism, but effectively antimicrobial component content is less, and duration of efficacy is short, durability
Difference, and less varieties, are restricted by conditions such as safety, are difficult to realize large-scale production.
Antiseptic is introduced in the biscuiting carcass of ceramics, ceramics is possessed antibacterial functions, there is some inherent advantages, such as antiseptic group
Close and enter ceramic biscuiting base substrate.Existing anti-bacteria ceramic and production method have following weak point：Operate loaded down with trivial details, technique difficult
Control, production cost are higher；Antibacterial effect is protected from environmental larger；Easily cause product discoloration.
The content of the invention
In view of the shortcomings of the prior art, the invention provides a kind of anti-bacteria ceramic composite and preparation method thereof, raw material is entered
Low cost, antibacterial effect be affected by environment and non-discoloring anti-bacteria ceramic by through oversintering, preparing after repeatedly compound for row；
Preparation process is simple, it is easy to operate, it is suitable to large-scale production industrially；And anti-microbial property stabilization, have a wide range of application.
To realize object above, the present invention is achieved by the following technical programs：
A kind of anti-bacteria ceramic composite, the weight portion of each component is：100~120 parts of kaolin, 50~60 parts of ceramic clay,
30~40 parts of diatom ooze, 10~20 parts of potassium feldspar, 5~15 parts of cupric oxide, 5~10 parts of alundum (Al2O3), di-iron trioxide 1~5
Part, 5~8 parts of tin oxide, 5~10 parts of rock quartz, 5~15 parts of talcum, golden 20~30 parts of clock rattan powder, 15~20 parts of calcium nitrate,
15~20 parts of silver nitrate.
100 parts of the kaolin, 50 parts of ceramic clay, 30 parts of diatom ooze, 10 parts of potassium feldspar, 5 parts of cupric oxide, three oxidations two
5 parts of aluminium, 1 part of di-iron trioxide, 5 parts of tin oxide, 5 parts of rock quartz, 5 parts of talcum, golden 20 parts of clock rattan powder, 15 parts of calcium nitrate, nitre
Sour 15 parts of silver.
120 parts of the kaolin, 60 parts of ceramic clay, 40 parts of diatom ooze, 20 parts of potassium feldspar, 15 parts of cupric oxide, three oxidations
Two 10 parts of aluminium, 5 parts of di-iron trioxide, 8 parts of tin oxide, 10 parts of rock quartz, 15 parts of talcum, golden 30 parts of clock rattan powder, calcium nitrate 20
Part, 20 parts of silver nitrate.
110 parts of the kaolin, 55 parts of ceramic clay, 35 parts of diatom ooze, 15 parts of potassium feldspar, 10 parts of cupric oxide, three oxidations
Two 8 parts of aluminium, 4 parts of di-iron trioxide, 7 parts of tin oxide, 8 parts of rock quartz, 10 parts of talcum, golden 25 parts of clock rattan powder, 18 parts of calcium nitrate,
18 parts of silver nitrate.
Described diatom ooze wherein contains the sodium lauryl tri(oxyethyl) sulfate of quality 5%.
The preparation method of anti-bacteria ceramic composite, its preparation process is：（1）By kaolin, ceramic clay and diatom ooze
It is well mixed according to the above ratio, powder thing A is then made by grinder；（2）By potassium feldspar, cupric oxide, alundum (Al2O3), three
Aoxidize two iron, tin oxide, rock quartz, talcum, golden clock rattan powder, calcium nitrate and silver nitrate mixing and then crushed by grinder,
The ammoniacal liquor that mass fraction is 5% is added into again and floods mixture, then container is carried out to be heated to 85 DEG C, while using agitator
2~3h is stirred, suction filtration then is carried out to it, filter cake is put into baking oven and is dried, be drawn off being put into pulverizer
Crushed, sieve to obtain 180~200 mesh powder thing B；（3）The substance A and B are well mixed, control pressure will for 45MPa
Powder pressing is molded, then 60~80 DEG C of dryings 2~4 hours, and the product obtained after drying is placed in baking furnace, controls the temperature to be
1150~1250 DEG C are fired 2~3 hours, reverse mould, and cooling obtains final product antimicrobial ceramic product.
Beneficial effect of the present invention：The present invention is carried out to raw material by, through oversintering, preparing low cost, resisting after multiple being combined
Bacterium effect is affected by environment and non-discoloring anti-bacteria ceramic；Preparation process is simple, it is easy to operate, it is suitable to big rule industrially
Mould is produced；And anti-microbial property stabilization, have a wide range of application.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, to this
Technical scheme in inventive embodiments is clearly and completely described, it is clear that described embodiment is that a part of the invention is real
Example is applied, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation
Property work under the premise of the every other embodiment that is obtained, belong to the scope of protection of the invention.
Embodiment 1：
A kind of anti-bacteria ceramic composite, the weight portion of each component is：100 parts of the kaolin, 50 parts of ceramic clay, diatom ooze
30 parts, it is 10 parts of potassium feldspar, 5 parts of cupric oxide, 5 parts of alundum (Al2O3), 1 part of di-iron trioxide, 5 parts of tin oxide, 5 parts of rock quartz, sliding
5 parts of stone, golden 20 parts of clock rattan powder, 15 parts of calcium nitrate, 15 parts of silver nitrate；Described diatom ooze wherein contains the 12 of quality 5%
Sodium alkylether sulphate.
The preparation method of anti-bacteria ceramic composite, its preparation process is：（1）By kaolin, ceramic clay and diatom ooze
It is well mixed according to the above ratio, powder thing A is then made by grinder；（2）By potassium feldspar, cupric oxide, alundum (Al2O3), three
Aoxidize two iron, tin oxide, rock quartz, talcum, golden clock rattan powder, calcium nitrate and silver nitrate mixing and then crushed by grinder,
The ammoniacal liquor that mass fraction is 5% is added into again and floods mixture, then container is carried out to be heated to 85 DEG C, while using agitator
2~3h is stirred, suction filtration then is carried out to it, filter cake is put into baking oven and is dried, be drawn off being put into pulverizer
Crushed, sieve to obtain 180~200 mesh powder thing B；（3）The substance A and B are well mixed, control pressure will for 45MPa
Powder pressing is molded, then 60~80 DEG C of dryings 2~4 hours, and the product obtained after drying is placed in baking furnace, controls the temperature to be
1150~1250 DEG C are fired 2~3 hours, reverse mould, and cooling obtains final product antimicrobial ceramic product.
Embodiment 2：
A kind of anti-bacteria ceramic composite, the weight portion of each component is：120 parts of the kaolin, 60 parts of ceramic clay, silicon
40 parts of algae mud, 20 parts of potassium feldspar, 15 parts of cupric oxide, 10 parts of alundum (Al2O3), 5 parts of di-iron trioxide, 8 parts of tin oxide, rock quartz
10 parts, 15 parts of talcum, golden 30 parts of clock rattan powder, 20 parts of calcium nitrate, 20 parts of silver nitrate；Described diatom ooze wherein contains quality
5% sodium lauryl tri(oxyethyl) sulfate.
The preparation method of anti-bacteria ceramic composite, its preparation process is：（1）By kaolin, ceramic clay and diatom ooze
It is well mixed according to the above ratio, powder thing A is then made by grinder；（2）By potassium feldspar, cupric oxide, alundum (Al2O3), three
Aoxidize two iron, tin oxide, rock quartz, talcum, golden clock rattan powder, calcium nitrate and silver nitrate mixing and then crushed by grinder,
The ammoniacal liquor that mass fraction is 5% is added into again and floods mixture, then container is carried out to be heated to 85 DEG C, while using agitator
2~3h is stirred, suction filtration then is carried out to it, filter cake is put into baking oven and is dried, be drawn off being put into pulverizer
Crushed, sieve to obtain 180~200 mesh powder thing B；（3）The substance A and B are well mixed, control pressure will for 45MPa
Powder pressing is molded, then 60~80 DEG C of dryings 2~4 hours, and the product obtained after drying is placed in baking furnace, controls the temperature to be
1150~1250 DEG C are fired 2~3 hours, reverse mould, and cooling obtains final product antimicrobial ceramic product.
Embodiment 3：
A kind of anti-bacteria ceramic composite, the weight portion of each component is：110 parts of the kaolin, 55 parts of ceramic clay, diatom ooze
35 parts, it is 15 parts of potassium feldspar, 10 parts of cupric oxide, 8 parts of alundum (Al2O3), 4 parts of di-iron trioxide, 7 parts of tin oxide, 8 parts of rock quartz, sliding
10 parts of stone, golden 25 parts of clock rattan powder, 18 parts of calcium nitrate, 18 parts of silver nitrate；Described diatom ooze wherein contains the 12 of quality 5%
Sodium alkylether sulphate.
The preparation method of anti-bacteria ceramic composite, its preparation process is：（1）By kaolin, ceramic clay and diatom ooze
It is well mixed according to the above ratio, powder thing A is then made by grinder；（2）By potassium feldspar, cupric oxide, alundum (Al2O3), three
Aoxidize two iron, tin oxide, rock quartz, talcum, golden clock rattan powder, calcium nitrate and silver nitrate mixing and then crushed by grinder,
The ammoniacal liquor that mass fraction is 5% is added into again and floods mixture, then container is carried out to be heated to 85 DEG C, while using agitator
2~3h is stirred, suction filtration then is carried out to it, filter cake is put into baking oven and is dried, be drawn off being put into pulverizer
Crushed, sieve to obtain 180~200 mesh powder thing B；（3）The substance A and B are well mixed, control pressure will for 45MPa
Powder pressing is molded, then 60~80 DEG C of dryings 2~4 hours, and the product obtained after drying is placed in baking furnace, controls the temperature to be
1150~1250 DEG C are fired 2~3 hours, reverse mould, and cooling obtains final product antimicrobial ceramic product.
The present invention is carried out to raw material by, through oversintering, preparing low cost, antibacterial effect and not receiving environment after multiple being combined
Influence and non-discoloring anti-bacteria ceramic；Preparation process is simple, it is easy to operate, it is suitable to large-scale production industrially；And antibacterial
Stable performance, has a wide range of application.
It should be noted that herein, such as first and second or the like relational terms are used merely to a reality
Body or operation make a distinction with another entity or operation, and not necessarily require or imply these entities or deposited between operating
In any this actual relation or order.And, term " including ", "comprising" or its any other variant be intended to
Nonexcludability is included, so that process, method, article or equipment including a series of key elements not only will including those
Element, but also other key elements including being not expressly set out, or also include being this process, method, article or equipment
Intrinsic key element.In the absence of more restrictions, the key element limited by sentence "including a ...", it is not excluded that
Also there is other identical element in process, method, article or equipment including the key element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention has been described in detail, it will be understood by those within the art that：It still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent to which part technical characteristic；And these modification or
Replace, do not make the spirit and scope of the essence disengaging various embodiments of the present invention technical scheme of appropriate technical solution.
Claims (6)
1. a kind of anti-bacteria ceramic composite, it is characterised in that：The weight portion of each component is：100~120 parts of kaolin, ceramics
50~60 parts of clay, 30~40 parts of diatom ooze, 10~20 parts of potassium feldspar, 5~15 parts of cupric oxide, 5~10 parts of alundum (Al2O3), three
Aoxidize 1~5 part of two iron, 5~8 parts of tin oxide, 5~10 parts of rock quartz, 5~15 parts of talcum, golden 20~30 parts of clock rattan powder, nitric acid
15~20 parts of calcium, 15~20 parts of silver nitrate.
2. anti-bacteria ceramic composite as claimed in claim 1, it is characterised in that 100 parts of the kaolin, ceramic clay 50
Part, 30 parts of diatom ooze, 10 parts of potassium feldspar, 5 parts of cupric oxide, 5 parts of alundum (Al2O3), 1 part of di-iron trioxide, 5 parts of tin oxide, crystal
5 parts of stone, 5 parts of talcum, golden 20 parts of clock rattan powder, 15 parts of calcium nitrate, 15 parts of silver nitrate.
3. anti-bacteria ceramic composite as claimed in claim 1, it is characterised in that 120 parts of the kaolin, ceramic clay 60
Part, 40 parts of diatom ooze, 20 parts of potassium feldspar, 15 parts of cupric oxide, 10 parts of alundum (Al2O3), 5 parts of di-iron trioxide, 8 parts of tin oxide, water
10 parts of spar, 15 parts of talcum, golden 30 parts of clock rattan powder, 20 parts of calcium nitrate, 20 parts of silver nitrate.
4. anti-bacteria ceramic composite as claimed in claim 1, it is characterised in that 110 parts of the kaolin, ceramic clay 55
Part, 35 parts of diatom ooze, 15 parts of potassium feldspar, 10 parts of cupric oxide, 8 parts of alundum (Al2O3), 4 parts of di-iron trioxide, 7 parts of tin oxide, water
8 parts of spar, 10 parts of talcum, golden 25 parts of clock rattan powder, 18 parts of calcium nitrate, 18 parts of silver nitrate.
5. anti-bacteria ceramic composite as claimed in claim 1, it is characterised in that described diatom ooze wherein contains quality
5% sodium lauryl tri(oxyethyl) sulfate.
6. the preparation method of anti-bacteria ceramic composite as claimed in claim 1, it is characterised in that its preparation process is：（1）
Kaolin, ceramic clay and diatom ooze are well mixed according to the above ratio, powder thing A is then made by grinder；（2）By potassium
Feldspar, cupric oxide, alundum (Al2O3), di-iron trioxide, tin oxide, rock quartz, talcum, golden clock rattan powder, calcium nitrate and nitric acid
Silver mixing and then crushed by grinder, then be added into the ammoniacal liquor that mass fraction is 5% and flood mixture, then container is carried out
85 DEG C are heated to, while being stirred 2~3h using agitator, suction filtration then are carried out to it, filter cake is put into baking oven to be carried out
Drying, is drawn off being put into pulverizer and being crushed, and sieve to obtain 180~200 mesh powder thing B；（3）The substance A and B are mixed
Close uniform, be molded for powder pressing for 45MPa by control pressure, then 60~80 DEG C of dryings 2~4 hours, the product obtained after drying
Product are placed in baking furnace, control temperature to be fired 2~3 hours for 1150~1250 DEG C, and reverse mould, cooling obtains final product antimicrobial ceramic product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107188536A (en) * | 2017-07-03 | 2017-09-22 | 四川锦泓佳建筑装饰工程有限公司 | A kind of use in toilet floor tile |
| CN109824352A (en) * | 2019-04-03 | 2019-05-31 | 福建省德化正和陶瓷有限公司 | A kind of highly effective nano antibiotic functional ceramic product and its manufacturing process |
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| CN103641439A (en) * | 2013-12-04 | 2014-03-19 | 佛山市新战略知识产权文化有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN104193303A (en) * | 2014-09-05 | 2014-12-10 | 佛山市新战略知识产权文化有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN105036804A (en) * | 2015-06-16 | 2015-11-11 | 德化均能手造陶瓷有限公司 | Health-preserving antimicrobial ceramic glaze |
| CN105646006A (en) * | 2016-01-07 | 2016-06-08 | 江苏锦宇环境工程有限公司 | Preparation method of environment-friendly antimicrobial ceramic |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103641439A (en) * | 2013-12-04 | 2014-03-19 | 佛山市新战略知识产权文化有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN104193303A (en) * | 2014-09-05 | 2014-12-10 | 佛山市新战略知识产权文化有限公司 | Antibacterial ceramic tile and preparation method thereof |
| CN105036804A (en) * | 2015-06-16 | 2015-11-11 | 德化均能手造陶瓷有限公司 | Health-preserving antimicrobial ceramic glaze |
| CN105646006A (en) * | 2016-01-07 | 2016-06-08 | 江苏锦宇环境工程有限公司 | Preparation method of environment-friendly antimicrobial ceramic |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107188536A (en) * | 2017-07-03 | 2017-09-22 | 四川锦泓佳建筑装饰工程有限公司 | A kind of use in toilet floor tile |
| CN109824352A (en) * | 2019-04-03 | 2019-05-31 | 福建省德化正和陶瓷有限公司 | A kind of highly effective nano antibiotic functional ceramic product and its manufacturing process |
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