CN106752779A - A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof - Google Patents
A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof Download PDFInfo
- Publication number
- CN106752779A CN106752779A CN201611102253.5A CN201611102253A CN106752779A CN 106752779 A CN106752779 A CN 106752779A CN 201611102253 A CN201611102253 A CN 201611102253A CN 106752779 A CN106752779 A CN 106752779A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- stirred
- added
- antibacterial
- powdery paints
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of power switch cabinet antibacterial powdery paints of uvioresistant, it is made up of the raw material of following weight parts：Polyoxyethylene sorbitan monoleate 0.1 0.3, lanthana 0.0.8 0.2, m-hydroxybenzoic acid sodium 24,8 oxyquinolines 57, Triton X-100 10 14, butyl titanate 36 40, cyclohexanol 20 25, unsaturated polyester resin 100 120, scolecite 10 14, hydroxyethyl cellulose 23, calcium ricinoleate 0.6 1, ultra-violet absorber UV 3290.1 0.3, the methylimidazole 0.5 1 of polyvinylbenzenesulfonic acid 12,1,2, DAAM 0.1 0.6, casein 12, ATEC 34.Present invention adds the uvioresistant performance that ultra-violet absorber can effectively improve finished product, the combination property of finished product is improve.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of power switch cabinet with the antibacterial powdery paints of uvioresistant and its
Preparation method.
Background technology
With social development, the demand of anti-biotic material will constitute huge market, and the production of antiseptic and its product will be into
It is important new industry field.Substantially, temperature tolerance is poor, service life is short for the short-term bactericidal effect of organic antiseptic；Inorganic
Antiseptic working life is long, and high temperature resistant has side effect.And complex antimicrobials greatly improve antibacterial rationally using both advantages
Agent performance and the scope of application, overcome the limitation of single antibacterial antiplaque agent spectrum.Composite antibacterial material will be that anti-biotic material is sent out from now on
Open up direction and the main points of application；
M-hydroxybenzoic acid has active anticancer by suppressing xanthine oxidase, and 8-hydroxyquinoline also has certain antibacterial
Activity.Rare earth-septichen -8-hydroxyquinoline ternary complex has been synthesized, rare earth-P-hydroxybenzoic acid -8- hydroxyls
Quinoline ternary complex has also been synthesized.But, the synthesis of rare earth-m-hydroxybenzoic acid -8-hydroxyquinoline ternary complex,
Structure and property research are not reported so far, the synthesis and the antibacterial that have m-hydroxybenzoic acid phenanthroline complex of rarely seen report
Property Quality Research, but this complex is only higher in concentration（>500ppm）When just show bacteriostasis property.Rare earth ion due to
Its special electron structure, can stop the metabolic process of mushroom, with extensive antibacterial action.Left beautiful duckweed et al. proves
In excessive earth solution, Niger's aspergillus fungi can be combined rapidly with rare earth ion, make the breathing of fungal cell and grape
Utilizing for sugar reduces, until stopping.Rare earth ion has anti-inflammatory, sterilization, anticancer, anticoagulation, analgesic activity again simultaneously.Due to dilute
Native ion can strengthen its fungistatic effect after forming complex, therefore in recent years, this field progressively causes attention and the pass of people
Note.Lin Feng, what water sample, Wang Liufang have been respectively synthesized different rare earth compoundings and have made bacteriostatic experiment, it was demonstrated that complex it is antibacterial
Ability is better than independent part and corresponding rare earth ion.In addition, China is the abundant country of rare earth resources, rare earth resources are developed
It is the long-term fundamental state policy of one, China.The research application of Rare Earth Functional Materials has important economic implications and social effect.Cause
This, study on the synthesis has the rare earth compounding of good bacteriostasis property, develops new application field, explores rational production procedure etc.
With important theory and realistic meaning.
Antibacterial powder paint refers to that the film that powdery paints is made has antibiotic property, can kill or suppress to attach on film
Bacterium.Powdery paints is widely used in goods showing cabinet, refrigerator, water dispenser, bed product, furniture of steel, kitchen utensils, food work
Industry equipment, hospital facility etc..These be all people often in contact with utensil.Therefore, the development and Application of antibacterial powder paint has
Important social effect.Since the nineties, the western developed country such as Japan has developed antimicrobial form powdery paints in succession, and
China is still in the starting stage in this respect.With the continuous improvement of people's living standard and environmental protection consciousness not
Disconnected enhancing, antimicrobial form powdery paints opens a new approaches for health for powdery paints application field.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of power switch cabinet antibacterial powder of uvioresistant
Last coating and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of power switch cabinet antibacterial powdery paints of uvioresistant, it is made up of the raw material of following weight parts：
Polyoxyethylene sorbitan monoleate 0.1-0.3, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8-hydroxyquinoline 5-7, poly- second two
Alcohol octyl phenyl ether 10-14, butyl titanate 36-40, cyclohexanol 20-25, unsaturated polyester resin 100-120, scolecite 10-
14th, hydroxyethyl cellulose 2-3, calcium ricinoleate 0.6-1, ultra-violet absorber UV-3290.1-0.3, polyvinylbenzenesulfonic acid 1-2,1,
2- methylimidazoles 0.5-1, DAAM 0.1-0.6, casein 1-2, ATEC 3-4.
A kind of described power switch cabinet preparation method of the antibacterial powdery paints of uvioresistant, comprises the following steps：
（1）Above-mentioned m-hydroxybenzoic acid sodium, hydroxyethyl cellulose are mixed, the deionization of 40-50 times of compound weight is added to
In water, stir, add above-mentioned casein, insulated and stirred 10-17 minutes at 60-64 DEG C, obtain fiber dispersion；
（2）Above-mentioned scolecite is calcined 1-2 hours at 650-700 DEG C, is cooled down, wear into fine powder, be added to 20-30 times of the amount of thinking highly of
, in the sodium hydroxide solution of 10-13mol/l, soak 50-60 minute, the above-mentioned polyoxyethylene sorbitan monoleate of addition stirs, and must boil
Stone dispersion liquid；
（3）Above-mentioned lanthana is added in 47-50 times of its weight, 30-40% hydrochloric acid solution, is stirred, obtain chlorination dilute
Native solution；
（4）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add above-mentioned fiber dispersion, obtain premix dispersion liquid；
（5）Above-mentioned 1,2- methylimidazoles are added in the absolute ethyl alcohol of 10-14 times of its weight, are stirred, added above-mentioned
Zeolite dispersion, calcium ricinoleate, it is 60-70 DEG C to rise high-temperature, insulated and stirred 20-30 minutes, adds above-mentioned butyl titanate, is stirred
Mix to normal temperature, obtain metatitanic acid ester alcohol liquid；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, premix dispersion liquid, it is ultrasonic 10-14 minutes, above-mentioned metatitanic acid ester alcohol liquid is added, stir 3-4 hours, centrifugation, will be heavy
Shallow lake acetone, absolute ethyl alcohol, deionized water are washed 3-4 times successively, are placed in drying box, and it is small to dry 6-7 at 100-110 DEG C
When, obtain antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion, cooling,
Sieving, obtains final product the powdery paints.
It is an advantage of the invention that：
8-hydroxyquinoline of the invention can suppress the formation of bacterial cell membrane, and also there is m-hydroxybenzoic acid certain antibacterial to make
With；After forming nano-antibacterial complex, because the carboxyl on complex and cellular phospholipid and peptide chain has stronger affinity, can be steady
It is scheduled on cell membrane and lysosome membrane, so that suppress lysosome release anti-inflammatory agent, on the one hand can be with the transfer ribose of bacterium
Phosphoryl bonding in nucleic acid, it is suppressed that the activity and function of its nuclease, so that the growth of bacterium is suppressed：The opposing party
Face, after forming complex, the molecular weight and conjugation of complex all strengthen, and fat-soluble enhancing is penetrated to cell membrane
Or damage capability enhancing, biology growing and the key component of metabolism needs are lost in, cause organism to complete normally
Operating.Rare earth ion has an effect of the intracellular Ca2+ of antagonism, and Ca2+ be maintain cell normal physiological activity from
Son, it is interfered to bacterial cell normal activities, causes bacterial death；
Titanium dioxide prepared by present invention addition tetra-n-butyl titanate has certain anti-microbial property because of its photocatalytic activity, enters
One step improves the biocidal property and polyacrylic compatibility of composite, improves the stability and antiseptic property of finished product；
Present invention adds the uvioresistant performance that ultra-violet absorber can effectively improve finished product, the comprehensive of finished product is improve
Energy.
Specific embodiment
A kind of power switch cabinet antibacterial powdery paints of uvioresistant, it is made up of the raw material of following weight parts：
Polyoxyethylene sorbitan monoleate 0.1, lanthana 0.0.8, m-hydroxybenzoic acid sodium 2,8-hydroxyquinoline 5, Triton X-100
10th, butyl titanate 36, cyclohexanol 20, unsaturated polyester resin 100, scolecite 10, hydroxyethyl cellulose 2, calcium ricinoleate
0.6th, ultra-violet absorber UV, the methylimidazole 0.5 of polyvinylbenzenesulfonic acid 1,1,2, DAAM 0.1, casein 1,
ATEC 3.
A kind of described power switch cabinet preparation method of the antibacterial powdery paints of uvioresistant, comprises the following steps：
（1）Above-mentioned m-hydroxybenzoic acid sodium, hydroxyethyl cellulose are mixed, the deionized water of 40 times of compound weight is added to
In, stir, above-mentioned casein is added, insulated and stirred 10 minutes, obtain fiber dispersion at 60 DEG C；
（2）Above-mentioned scolecite is calcined 1 hour at 650 DEG C, is cooled down, wear into fine powder, be added to 20 times of the amount of thinking highly of, 10mol/
In the sodium hydroxide solution of l, soak 50 minutes, add above-mentioned polyoxyethylene sorbitan monoleate, stir, obtain Zeolite dispersion；
（3）Above-mentioned lanthana is added in 47 times of its weight, 30% hydrochloric acid solution, is stirred, obtain rare earth chloride molten
Liquid；
（4）30%, the 25% of cyclohexanol weight of above-mentioned Triton X-100 weight is taken, is mixed, stirred, in addition
8 oxyquinolines are stated, is stirred, add above-mentioned fiber dispersion, obtain premix dispersion liquid；
（5）Above-mentioned 1,2 methylimidazole is added in the absolute ethyl alcohol of 10 times of its weight, is stirred, add above-mentioned zeolite
Dispersion liquid, calcium ricinoleate, it is 60 DEG C to rise high-temperature, and insulated and stirred 20 minutes adds above-mentioned butyl titanate, stirs to normal temperature,
Obtain metatitanic acid ester alcohol liquid；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, premix dispersion liquid, ultrasound 10 minutes add above-mentioned metatitanic acid ester alcohol liquid, stir 3 hours, and precipitation is used third by centrifugation
Ketone, absolute ethyl alcohol, deionized water are washed 3 times successively, are placed in drying box, are dried 6 hours at 100 DEG C, obtain antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion, cooling,
Sieving, obtains final product the powdery paints.
Performance test：
Impact resistance：≥50kg/cm；
Hardness：2H.
Claims (2)
1. a kind of power switch cabinet antibacterial powdery paints of uvioresistant, it is characterised in that it is by the raw material group of following weight parts
Into：
Polyoxyethylene sorbitan monoleate 0.1-0.3, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8-hydroxyquinoline 5-7, poly- second two
Alcohol octyl phenyl ether 10-14, butyl titanate 36-40, cyclohexanol 20-25, unsaturated polyester resin 100-120, scolecite 10-
14th, hydroxyethyl cellulose 2-3, calcium ricinoleate 0.6-1, ultra-violet absorber UV-3290.1-0.3, polyvinylbenzenesulfonic acid 1-2,1,
2- methylimidazoles 0.5-1, DAAM 0.1-0.6, casein 1-2, ATEC 3-4.
2. a kind of power switch cabinet as claimed in claim 1 preparation method of the antibacterial powdery paints of uvioresistant, its feature exists
In comprising the following steps：
（1）Above-mentioned m-hydroxybenzoic acid sodium, hydroxyethyl cellulose are mixed, the deionization of 40-50 times of compound weight is added to
In water, stir, add above-mentioned casein, insulated and stirred 10-17 minutes at 60-64 DEG C, obtain fiber dispersion；
（2）Above-mentioned scolecite is calcined 1-2 hours at 650-700 DEG C, is cooled down, wear into fine powder, be added to 20-30 times of the amount of thinking highly of
, in the sodium hydroxide solution of 10-13mol/l, soak 50-60 minute, the above-mentioned polyoxyethylene sorbitan monoleate of addition stirs, and must boil
Stone dispersion liquid；
（3）Above-mentioned lanthana is added in 47-50 times of its weight, 30-40% hydrochloric acid solution, is stirred, obtain chlorination dilute
Native solution；
（4）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add above-mentioned fiber dispersion, obtain premix dispersion liquid；
（5）Above-mentioned 1,2- methylimidazoles are added in the absolute ethyl alcohol of 10-14 times of its weight, are stirred, added above-mentioned
Zeolite dispersion, calcium ricinoleate, it is 60-70 DEG C to rise high-temperature, insulated and stirred 20-30 minutes, adds above-mentioned butyl titanate, is stirred
Mix to normal temperature, obtain metatitanic acid ester alcohol liquid；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, premix dispersion liquid, it is ultrasonic 10-14 minutes, above-mentioned metatitanic acid ester alcohol liquid is added, stir 3-4 hours, centrifugation, will be heavy
Shallow lake acetone, absolute ethyl alcohol, deionized water are washed 3-4 times successively, are placed in drying box, and it is small to dry 6-7 at 100-110 DEG C
When, obtain antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion, cooling,
Sieving, obtains final product the powdery paints.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611102253.5A CN106752779A (en) | 2016-12-05 | 2016-12-05 | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611102253.5A CN106752779A (en) | 2016-12-05 | 2016-12-05 | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106752779A true CN106752779A (en) | 2017-05-31 |
Family
ID=58883682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611102253.5A Pending CN106752779A (en) | 2016-12-05 | 2016-12-05 | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106752779A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373758A (en) * | 2018-02-12 | 2018-08-07 | 浙江华彩新材料有限公司 | A kind of environment-friendly type antibiotic resistance and fingerprint resistance ultrafine powder paint and preparation method thereof |
| CN108745319A (en) * | 2018-06-27 | 2018-11-06 | 邱小艳 | A kind of antibacterial sorbing material and preparation method thereof |
| CN111019494A (en) * | 2019-12-31 | 2020-04-17 | 南京德嘉玻璃钢材料有限公司 | High-weather-resistance gel coat and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN104530934A (en) * | 2014-12-26 | 2015-04-22 | 任成生 | High-efficiency antibacterial powder paint |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
| CN106118443A (en) * | 2016-07-13 | 2016-11-16 | 蚌埠市正园电子科技有限公司 | A kind of weather resistant waterborne polyester coating and preparation method thereof |
-
2016
- 2016-12-05 CN CN201611102253.5A patent/CN106752779A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN104530934A (en) * | 2014-12-26 | 2015-04-22 | 任成生 | High-efficiency antibacterial powder paint |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
| CN106118443A (en) * | 2016-07-13 | 2016-11-16 | 蚌埠市正园电子科技有限公司 | A kind of weather resistant waterborne polyester coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108373758A (en) * | 2018-02-12 | 2018-08-07 | 浙江华彩新材料有限公司 | A kind of environment-friendly type antibiotic resistance and fingerprint resistance ultrafine powder paint and preparation method thereof |
| CN108745319A (en) * | 2018-06-27 | 2018-11-06 | 邱小艳 | A kind of antibacterial sorbing material and preparation method thereof |
| CN111019494A (en) * | 2019-12-31 | 2020-04-17 | 南京德嘉玻璃钢材料有限公司 | High-weather-resistance gel coat and preparation method thereof |
| CN111019494B (en) * | 2019-12-31 | 2021-10-01 | 南京德嘉玻璃钢材料有限公司 | High-weather-resistance gel coat and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106752779A (en) | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof | |
| CN102125055A (en) | Sliver-carried nano-montmorillonite antibacterial agent and preparation method thereof | |
| CN105694229B (en) | A kind of PP antibiotic plastics and preparation method thereof | |
| CN103881193A (en) | Polyethylene antibacterial mildew-resistant master batch and preparation method thereof | |
| CN101999736A (en) | Compound preservative | |
| CN107459802A (en) | A kind of polycarbonate plastic of antibacterial | |
| CN108271773A (en) | Composite antibacterial particle, preparation method and application | |
| CN105175974A (en) | Composite metal oxide antibacterial masterbatch and preparation method thereof | |
| CN106590370A (en) | Carbon nanometer tube enhanced bacteriostatic powder paint for electric power switch cabinet and preparation method thereof | |
| CN113647454A (en) | Chitosan-based fruit and vegetable coating preservation material and preparation method thereof | |
| CN108793740A (en) | A kind of preparation method of phosphate antibiosis glass | |
| CN107242233A (en) | Composite leather mildewproof bacteria remover and preparation method thereof | |
| CN106752780A (en) | A kind of power switch cabinet antibacterial powdery paints and preparation method thereof | |
| CN106854426A (en) | A kind of power switch cabinet antibacterial polyester resin powder coating and preparation method thereof | |
| CN106752781A (en) | A kind of power switch cabinet hydrophobic antibacterial powdery paints of silicon substrate and preparation method thereof | |
| CN106700856A (en) | Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating | |
| CN108793760A (en) | A kind of preparation method of antimicrobial textiles | |
| CN105038063A (en) | Antibacterial composite plastic | |
| CN105647099A (en) | Preparation method of antibacterial ABS resin | |
| CN107805447A (en) | The preparation method that a kind of wood furniture is painted with flame-proof antibiotic | |
| CN106854427A (en) | A kind of power switch cabinet nylon is combined antibacterial powdery paints and preparation method thereof | |
| CN106590369A (en) | Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material | |
| CN105131336A (en) | Antibacterial agent, preparation method and application thereof | |
| CN105670238A (en) | Sterilizing polyester resin | |
| CN104262750B (en) | A kind of antibacterial macromolecular material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
| RJ01 | Rejection of invention patent application after publication |