CN106700856A - Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating - Google Patents
Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses an antibacterial anti-oxidation powder coating for an electric switch cabinet. The antibacterial anti-oxidation powder coating consists of the following raw materials in parts by weight: 10-14 parts of polyethylene glycol octylphenol ether, 0.7-1 part of ammonium metaborate, 0.1-0.2 part of nonyl phenol, 0.4-1 part of tertiary butyl p-di-phenol, 0.08-0.2 part of lanthanum oxide, 2-4 parts of 3-hydroxy-benzoic acid monosodium salt, 5-7 parts of 8-hydroxyquinoline, 36-40 parts of tetrabutyl titanate, 20-25 parts of cyclohexanol, 100-120 parts of unsaturated polyester resin, 3-4 parts of polyvinyl alcohol, 1-2 parts of glyceryl monostearate, 0.4-1 part of zinc dialkyl phosphorodithioate, 10-13 parts of kaolin, 0.1-0.3 part of hexabromocyclododecane and 1-2 parts of barium metaborate. Due to addition of nonyl phenol, tertiary butyl p-di-phenol and the like, the oxidation resistance of a finished product can be effectively improved, and the stability strength of the finished product can be improved.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of power switch cabinet with antibacterial anti-oxidant powdery paints and its
Preparation method.
Background technology
With social development, the demand of anti-biotic material will constitute huge market, and the production of antiseptic and its product will be into
It is important new industry field.Substantially, temperature tolerance is poor, service life is short for the short-term bactericidal effect of organic antiseptic；Inorganic
Antiseptic working life is long, and high temperature resistant has side effect.And complex antimicrobials greatly improve antibacterial rationally using both advantages
Agent performance and the scope of application, overcome the limitation of single antibacterial antiplaque agent spectrum.Composite antibacterial material will be that anti-biotic material is sent out from now on
Open up direction and the main points of application；
M-hydroxybenzoic acid has active anticancer by suppressing xanthine oxidase, and 8-hydroxyquinoline also has certain antibacterial
Activity.Rare earth-septichen -8-hydroxyquinoline ternary complex has been synthesized, rare earth-P-hydroxybenzoic acid -8- hydroxyls
Quinoline ternary complex has also been synthesized.But, the synthesis of rare earth-m-hydroxybenzoic acid -8-hydroxyquinoline ternary complex,
Structure and property research are not reported so far, the synthesis and the antibacterial that have m-hydroxybenzoic acid phenanthroline complex of rarely seen report
Property Quality Research, but this complex is only higher in concentration（>500ppm）When just show bacteriostasis property.Rare earth ion due to
Its special electron structure, can stop the metabolic process of mushroom, with extensive antibacterial action.Left beautiful duckweed et al. proves
In excessive earth solution, Niger's aspergillus fungi can be combined rapidly with rare earth ion, make the breathing of fungal cell and grape
Utilizing for sugar reduces, until stopping.Rare earth ion has anti-inflammatory, sterilization, anticancer, anticoagulation, analgesic activity again simultaneously.Due to dilute
Native ion can strengthen its fungistatic effect after forming complex, therefore in recent years, this field progressively causes attention and the pass of people
Note.Lin Feng, what water sample, Wang Liufang have been respectively synthesized different rare earth compoundings and have made bacteriostatic experiment, it was demonstrated that complex it is antibacterial
Ability is better than independent part and corresponding rare earth ion.In addition, China is the abundant country of rare earth resources, rare earth resources are developed
It is the long-term fundamental state policy of one, China.The research application of Rare Earth Functional Materials has important economic implications and social effect.Cause
This, study on the synthesis has the rare earth compounding of good bacteriostasis property, develops new application field, explores rational production procedure etc.
With important theory and realistic meaning.
Antibacterial powder paint refers to that the film that powdery paints is made has antibiotic property, can kill or suppress to attach on film
Bacterium.Powdery paints is widely used in goods showing cabinet, refrigerator, water dispenser, bed product, furniture of steel, kitchen utensils, food work
Industry equipment, hospital facility etc..These be all people often in contact with utensil.Therefore, the development and Application of antibacterial powder paint has
Important social effect.Since the nineties, the western developed country such as Japan has developed antimicrobial form powdery paints in succession, and
China is still in the starting stage in this respect.With the continuous improvement of people's living standard and environmental protection consciousness not
Disconnected enhancing, antimicrobial form powdery paints opens a new approaches for health for powdery paints application field.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of power switch cabinet is with antibacterial anti-oxidant powder
Last coating and preparation method thereof.
The present invention is achieved by the following technical solutions：
With antibacterial anti-oxidant powdery paints, it is made up of a kind of power switch cabinet the raw material of following weight parts：
Triton X-100 10-14, ammonium metaborate 0.7-1, nonyl phenol 0.1-0.2, the tert-butyl group are to biphenol 0.4-
1st, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8-hydroxyquinoline 5-7, butyl titanate 36-40, cyclohexanol 20-
25th, unsaturated polyester resin 100-120, polyvinyl alcohol 3-4, glycerol monostearate monoesters 1-2, zinc dialkyl dithiophosphate
0.4-1, kaolin 10-13, HBCD 0.1-0.3, barium metaborate 1-2.
A kind of described power switch cabinet preparation method of antibacterial anti-oxidant powdery paints, comprises the following steps：
（1）Above-mentioned kaolin is calcined 1-2 hours at 700-800 DEG C, is cooled down, fine powder is worn into, with above-mentioned lanthana, metaboric acid
Ammonium mixes, in hydrochloric acid solution that be added to 14-20 times of compound weight, that concentration is 30-40%, stirring reaction 40-50 minutes,
Obtain re chloride；
（2）Above-mentioned m-hydroxybenzoic acid sodium is added in the deionized water of 50-60 times of its weight, is stirred；
（3）Above-mentioned zinc dialkyl dithiophosphate is added in the absolute ethyl alcohol of 16-20 times of its weight, is stirred, raised
Temperature is 70-73 DEG C, adds above-mentioned nonyl phenol, insulated and stirred 10-20 minutes, adds above-mentioned glycerol monostearate monoesters, is stirred
Mix to normal temperature, obtain alcohol dispersion liquid；
（4）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add above-mentioned m-hydroxybenzoic acid sodium water solution, obtain premix dispersion liquid；
（5）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, stirs, and mixes with above-mentioned premix dispersion liquid, stirs, and adds above-mentioned butyl titanate, alcohol dispersion liquid, stirs
Mix 3-4 hours, precipitation acetone, absolute ethyl alcohol, deionized water are washed 3-4 times in centrifugation successively, are placed in drying box,
Dried at 100-110 DEG C 6-7 hours, obtain antibacterial dispersant；
（6）Above-mentioned polyvinyl alcohol is taken, is sent in 90-96 DEG C of water bath with thermostatic control, insulated and stirred 10-20 minutes, discharging, in addition
Antibacterial dispersant, HBCD are stated, it is ultrasonic 20-30 minutes, obtain antibacterial dispersion alcohol liquid；
（7）Above-mentioned antibacterial dispersion alcohol liquid is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion is cold
But, sieve, obtain final product the powdery paints.
It is an advantage of the invention that：
8-hydroxyquinoline of the invention can suppress the formation of bacterial cell membrane, and also there is m-hydroxybenzoic acid certain antibacterial to make
With；After forming nano-antibacterial complex, because the carboxyl on complex and cellular phospholipid and peptide chain has stronger affinity, can be steady
It is scheduled on cell membrane and lysosome membrane, so that suppress lysosome release anti-inflammatory agent, on the one hand can be with the transfer ribose of bacterium
Phosphoryl bonding in nucleic acid, it is suppressed that the activity and function of its nuclease, so that the growth of bacterium is suppressed：The opposing party
Face, after forming complex, the molecular weight and conjugation of complex all strengthen, and fat-soluble enhancing is penetrated to cell membrane
Or damage capability enhancing, biology growing and the key component of metabolism needs are lost in, cause organism to complete normally
Operating.Rare earth ion has an effect of the intracellular Ca2+ of antagonism, and Ca2+ be maintain cell normal physiological activity from
Son, it is interfered to bacterial cell normal activities, causes bacterial death；
Titanium dioxide prepared by present invention addition tetra-n-butyl titanate has certain anti-microbial property because of its photocatalytic activity, enters
One step improves the biocidal property and polyacrylic compatibility of composite, improves the stability and antiseptic property of finished product；
Nonyl phenol, the tert-butyl group that the present invention is added effectively raise the antioxygenic property of finished product to biphenol etc., improve into
The stability_intensity of product.
Specific embodiment
With antibacterial anti-oxidant powdery paints, it is made up of a kind of power switch cabinet the raw material of following weight parts：
Triton X-100 10, ammonium metaborate 0.7, the nonyl phenol 0.1, tert-butyl group are to biphenol 0.4, lanthana
0.0.8, m-hydroxybenzoic acid sodium 2,8 oxyquinolines 5, butyl titanate 36, cyclohexanol 20, unsaturated polyester resin 100, poly- second
Enol 3, glycerol monostearate monoesters 1, zinc dialkyl dithiophosphate 0.4, kaolin 10, HBCD 0.1, metaboric acid
Barium 1.
A kind of described power switch cabinet preparation method of antibacterial anti-oxidant powdery paints, comprises the following steps：
（1）Above-mentioned kaolin is calcined 1 hour at 700 DEG C, is cooled down, wear into fine powder, mixed with above-mentioned lanthana, ammonium metaborate
Close, in hydrochloric acid solution that be added to 14 times of compound weight, that concentration is 30%, stirring reaction 40 minutes obtains rare earth chloride molten
Liquid；
（2）Above-mentioned m-hydroxybenzoic acid sodium is added in the deionized water of 50 times of its weight, is stirred；
（3）Above-mentioned zinc dialkyl dithiophosphate is added in the absolute ethyl alcohol of 16 times of its weight, is stirred, rise high-temperature
It is 70 DEG C, adds above-mentioned nonyl phenol, insulated and stirred 10 minutes adds above-mentioned glycerol monostearate monoesters, stirs to normal temperature, obtains
Alcohol dispersion liquid；
（4）30%, the 25% of cyclohexanol weight of above-mentioned Triton X-100 weight is taken, is mixed, stirred, in addition
8 oxyquinolines are stated, is stirred, add above-mentioned m-hydroxybenzoic acid sodium water solution, obtain premix dispersion liquid；
（5）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, stirs, and mixes with above-mentioned premix dispersion liquid, stirs, and adds above-mentioned butyl titanate, alcohol dispersion liquid, stirs
Mix 3 hours, centrifugation, precipitation acetone, absolute ethyl alcohol, deionized water are washed 3 times successively, be placed in drying box, 100
Dried 6 hours at DEG C, obtain antibacterial dispersant；
（6）Above-mentioned polyvinyl alcohol is taken, is sent in 90 DEG C of water bath with thermostatic control, insulated and stirred 10 minutes, discharging is added above-mentioned antibacterial
Dispersant, HBCD, ultrasound 20 minutes obtain antibacterial dispersion alcohol liquid；
（7）Above-mentioned antibacterial dispersion alcohol liquid is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion is cold
But, sieve, obtain final product the powdery paints.
Performance test：
Impact resistance：≥50kg/cm；
Hardness：2H.
Claims (2)
1. a kind of power switch cabinet is with antibacterial anti-oxidant powdery paints, it is characterised in that it is by the raw material group of following weight parts
Into：
Triton X-100 10-14, ammonium metaborate 0.7-1, nonyl phenol 0.1-0.2, the tert-butyl group are to biphenol 0.4-
1st, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8-hydroxyquinoline 5-7, butyl titanate 36-40, cyclohexanol 20-
25th, unsaturated polyester resin 100-120, polyvinyl alcohol 3-4, glycerol monostearate monoesters 1-2, zinc dialkyl dithiophosphate
0.4-1, kaolin 10-13, HBCD 0.1-0.3, barium metaborate 1-2.
2. a kind of power switch cabinet as claimed in claim 1 preparation method of antibacterial anti-oxidant powdery paints, its feature exists
In comprising the following steps：
（1）Above-mentioned kaolin is calcined 1-2 hours at 700-800 DEG C, is cooled down, fine powder is worn into, with above-mentioned lanthana, metaboric acid
Ammonium mixes, in hydrochloric acid solution that be added to 14-20 times of compound weight, that concentration is 30-40%, stirring reaction 40-50 minutes,
Obtain re chloride；
（2）Above-mentioned m-hydroxybenzoic acid sodium is added in the deionized water of 50-60 times of its weight, is stirred；
（3）Above-mentioned zinc dialkyl dithiophosphate is added in the absolute ethyl alcohol of 16-20 times of its weight, is stirred, raised
Temperature is 70-73 DEG C, adds above-mentioned nonyl phenol, insulated and stirred 10-20 minutes, adds above-mentioned glycerol monostearate monoesters, is stirred
Mix to normal temperature, obtain alcohol dispersion liquid；
（4）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add above-mentioned m-hydroxybenzoic acid sodium water solution, obtain premix dispersion liquid；
（5）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned chlorination dilute
Native solution, stirs, and mixes with above-mentioned premix dispersion liquid, stirs, and adds above-mentioned butyl titanate, alcohol dispersion liquid, stirs
Mix 3-4 hours, precipitation acetone, absolute ethyl alcohol, deionized water are washed 3-4 times in centrifugation successively, are placed in drying box,
Dried at 100-110 DEG C 6-7 hours, obtain antibacterial dispersant；
（6）Above-mentioned polyvinyl alcohol is taken, is sent in 90-96 DEG C of water bath with thermostatic control, insulated and stirred 10-20 minutes, discharging, in addition
Antibacterial dispersant, HBCD are stated, it is ultrasonic 20-30 minutes, obtain antibacterial dispersion alcohol liquid；
（7）Above-mentioned antibacterial dispersion alcohol liquid is mixed with remaining each raw material, is stirred, in feeding extruder, melting extrusion is cold
But, sieve, obtain final product the powdery paints.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611102358.0A CN106700856A (en) | 2016-12-05 | 2016-12-05 | Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611102358.0A CN106700856A (en) | 2016-12-05 | 2016-12-05 | Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116355506A (en) * | 2023-04-19 | 2023-06-30 | 山东科技大学 | Antibacterial and mildew-proof aluminum profile powder coating and preparation method thereof |
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|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN105885612A (en) * | 2016-06-12 | 2016-08-24 | 合肥和安机械制造有限公司 | Rust-proof anti-corrosion metal copper coating and preparation method thereof |
| CN105968513A (en) * | 2016-06-30 | 2016-09-28 | 安徽杰奥玛克合成材料科技有限公司 | Flame-retardant oxidation-resistant geogrid and preparation method thereof |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
-
2016
- 2016-12-05 CN CN201611102358.0A patent/CN106700856A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
| CN105885612A (en) * | 2016-06-12 | 2016-08-24 | 合肥和安机械制造有限公司 | Rust-proof anti-corrosion metal copper coating and preparation method thereof |
| CN105968513A (en) * | 2016-06-30 | 2016-09-28 | 安徽杰奥玛克合成材料科技有限公司 | Flame-retardant oxidation-resistant geogrid and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116355506A (en) * | 2023-04-19 | 2023-06-30 | 山东科技大学 | Antibacterial and mildew-proof aluminum profile powder coating and preparation method thereof |
| CN116355506B (en) * | 2023-04-19 | 2023-09-22 | 山东科技大学 | Antibacterial and mildew-proof aluminum profile powder coating and preparation method thereof |
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Application publication date: 20170524 |
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