CN105969122A - Polyester powder furniture coating and preparation method thereof - Google Patents
Polyester powder furniture coating and preparation method thereof Download PDFInfo
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- CN105969122A CN105969122A CN201610187082.4A CN201610187082A CN105969122A CN 105969122 A CN105969122 A CN 105969122A CN 201610187082 A CN201610187082 A CN 201610187082A CN 105969122 A CN105969122 A CN 105969122A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Macromonomer-Based Addition Polymer (AREA)
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Abstract
The invention discloses a polyester powder furniture coating, which is composed of the following raw materials (by weight): 0.4-14 parts of lecithin, 0.1-0.2 part of 1,2-epoxy-4-vinylcyclohexane, 1-2 parts of polybenzimidazole, 0.7-1 part of triethanolamine oleate, 2-3 parts of diacetone alcohol, 10-12 parts of tung oil, 0.06-0.07 part of sodium hydroxide, 3-4 parts of methanol, 0.1-0.2 part of perfluorosulfonate resin, 6-8 parts of acetic acid, 10-15 parts of 26-30% hydrogen peroxide, 10-17 parts of tetraethyl orthosilicate, 0.1-0.2 parts of Y-chloropropyltrimethoxysilane, 70-80 parts of unsaturated polyester resin, 0.6-1 part of methylethyl ketone peroxide, 0.1-0.2 part of aminoethylpiperazine, 10-14 parts of calsite powder, 0.6-1 part of formamide, 2-4 parts of tetrabutyl titanate and 3-4 parts of calcium aluminate.
Description
Technical field
The present invention relates to coatings for furniture technical field, particularly relate to a kind of polyester powder coatings for furniture and preparation method thereof.
Background technology
Saturated polyester resin is to prepare one of conventional film-forming resin of coating, but use unsaturated polyester resins for general purpose to there is the shortcomings such as resistance to water, solvent resistance, thermostability and poor mechanical property when preparing coating, need unsaturated polyester resin is modified to improve its combination property and currently mainly utilize polyurethane or base polyurethane prepolymer for use as, acrylic resin, epoxy resin, organosilicon, nano material and vegetable oil etc. unsaturated polyester resin to be modified to improving performance when it prepares coating.Wherein, plant oil modified unsaturated polyester vinegar resin is increasingly paid attention to by people.Vegetable oil is incorporated in unsaturated polyester resin by chemical reaction, easily cause the polyreaction of vegetable oil self, make the limited vegetable oil of modified effect also due to both poor compatibility, modification can be caused by the method modified unsaturated polyester resin being blended to fall flat.Therefore, after vegetable oil derivatization, improve the compatibility of vegetable oil and unsaturated polyester resin, be the important channel of plant oil modified unsaturated polyester resin.
In crude vegetal, Oleum Verniciae fordii is more special, and its main component is eleostearic acid glyceride, has conjugated triene structures, can be used alone in oil-based paint, it is also possible to neutralize other semi-drying oils at synthetic resin coating, non-drying oil is used in mixed way.Oleum Verniciae fordii also has good water proofing property, is widely used in building, paints, prints aspects such as (ink).
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of polyester powder coatings for furniture and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of polyester powder coatings for furniture, it is made up of the raw material of following weight parts:
Lecithin 0.4-1, 4 vinyl epoxy cyclohexane 0.1-0.2, polybenzimidazoles 1-2, single triethanolamine oleate ester 0.7-1, DAA 2-3, Oleum Verniciae fordii 10-12, sodium hydroxide 0.06-0.07, methanol 3-4, perfluorinated sulfonic resin 0.1-0.2, acetic acid 6-8, the hydrogen peroxide 10-15 of 26-30%, tetraethyl orthosilicate 10-17, Y-r-chloropropyl trimethoxyl silane 0.1-0.2, unsaturated polyester resin 70-80, methyl ethyl ketone peroxide 0.6-1, aminoethyl piperazine 0.1-0.2, calcite in powder 10-14, Methanamide 0.6-1, butyl titanate 2-4, calcium aluminate 3-4.
The preparation method of a kind of described polyester powder coatings for furniture, comprises the following steps:
(1) joining in Oleum Verniciae fordii by above-mentioned methanol, add sodium hydroxide, react 70-80 minute at 37-40 DEG C under stirring condition, distill methanol removal, stratification, the supernatant liquid of collection first with sulfuric acid scrubbing, the washing of reusable heat water, distillation dehydration, obtains methyl eleostearate；
(2) 50-60% of above-mentioned methyl eleostearate, perfluorinated sulfonic resin, above-mentioned acetic acid weight is mixed, rise high-temperature and be 60-68 DEG C, the hydrogen peroxide of above-mentioned 26-30% is dripped under stirring condition, insulation reaction 3-4 hour after dropping, filter, filtrate is neutralized with alkali, washing, it is vacuum dried 3-4 hour at 50-60 DEG C, obtains epoxidation methyl eleostearate；
(3) being joined by above-mentioned polybenzimidazoles in the dehydrated alcohol of its weight 6-10 times, add Y-r-chloropropyl trimethoxyl silane, 500-600 rev/min is stirred 10-17 minute, obtains silanol liquid；
(4) above-mentioned butyl titanate is joined in the deionized water of its weight 10-16 times, stir, add Methanamide, lecithin, insulated and stirred 20-30 minute at 50-60 DEG C, dropping concentration is the ammonia of 20-23%, regulation pH is 10-13, warming temperature is 70-80 DEG C, insulation reaction 30-40 minute, obtains titanium colloidal sol；
(5) by above-mentioned tetraethyl orthosilicate, the mixing of epoxidation methyl eleostearate, warming temperature is 36-40 DEG C, add remaining acetic acid, insulated and stirred 10-20 minute, drip the deionized water of above-mentioned mixed system weight 60-70%, add silanol liquid after dropping, at 76-80 DEG C, be incubated 6-7 hour, obtain silica sol modified epoxidation methyl eleostearate；
(6) above-mentioned silica sol modified epoxidation methyl eleostearate is joined in above-mentioned titanium colloidal sol, stir, add 4 vinyl epoxy cyclohexane, 100-200 rev/min is stirred 7-10 minute, add single triethanolamine oleate ester, DAA, insulated and stirred 20-30 minute at 80-90 DEG C, is cooled to room temperature, must premix ester material；
(7) above-mentioned premix ester material is mixed with remaining each raw material, melt extruded by extruder, after then tabletting is broken, then through pulverizing, sieving, to obtain final product.
The invention have the advantage that in the epoxidation methyl eleostearate molecular structure of the present invention and contain epoxy bond and double bond simultaneously, with the carboxyl in unsaturated polyester resin, hydroxyl and double bond, oxidation cross-linked reaction can occur, improve the crosslink density of film, improve filming performance, thus improve the hot strength of film, also improve hardness and the shock resistance of film to a certain extent simultaneously；
Containing hydrophobic fatty acid Long carbon chain in the epoxidation methyl eleostearate of the present invention, when Oleum Verniciae fordii derivant is dispersed in film forming in unsaturated polyester resin, these hydrophobic aliphatic hydrocarbyl groups are at film surface enrichment, film is made to be in a kind of low-surface-energy state, reduce the combination energy on surface and hydrone, thus reduce the water absorption rate of unsaturated polyester resin film, improve unsaturated polyester resin water resistance；
The epoxidation methyl eleostearate of the present invention contains conjugated double bond, and conjugated double bond, in the film forming later stage, occurs oxidation cross-linked, forming network polymers, so that it is tightr to be combined with each other between molecule, the density of film increases, solvent molecule slows down at the permeating speed of film coated surface, thus solvent resistance strengthens；
The epoxidation methyl eleostearate of the present invention has aliphatic long-chain hydrocarbon, and long chain hydrocarbon can play the effect of plasticising in resin, it is possible to strengthen the flexility of unsaturated polyester resin.
Detailed description of the invention
A kind of polyester powder coatings for furniture, it is made up of the raw material of following weight parts:
Lecithin 0.4,4 vinyl epoxy cyclohexane 0.1, polybenzimidazoles 1, single triethanolamine oleate ester 0.7, DAA 2, Oleum Verniciae fordii 10, sodium hydroxide 0.06, methanol 3, perfluorinated sulfonic resin 0.1, the hydrogen peroxide 10 of acetic acid 6,26%, tetraethyl orthosilicate 10, Y r-chloropropyl trimethoxyl silane 0.1, unsaturated polyester resin 70, methyl ethyl ketone peroxide 0.6, aminoethyl piperazine 0.1, calcite in powder 10, Methanamide 0.6, butyl titanate 2, calcium aluminate 3.
The preparation method of a kind of described polyester powder coatings for furniture, comprises the following steps:
(1) joining in Oleum Verniciae fordii by above-mentioned methanol, add sodium hydroxide, react 70 minutes at 37 DEG C under stirring condition, distill methanol removal, stratification, the supernatant liquid of collection first with sulfuric acid scrubbing, the washing of reusable heat water, distillation dehydration, obtains methyl eleostearate；
(2) by above-mentioned methyl eleostearate, perfluorinated sulfonic resin, 50% mixing of above-mentioned acetic acid weight, rising high-temperature is 60 DEG C, the hydrogen peroxide of above-mentioned 26% is dripped under stirring condition, insulation reaction 3 hours after dropping, filter, filtrate is neutralized with alkali, washing, it is vacuum dried 3 hours at 50 DEG C, obtains epoxidation methyl eleostearate；
(3) being joined by above-mentioned polybenzimidazoles in the dehydrated alcohol of its weight 6 times, add Y r-chloropropyl trimethoxyl silane, 500 revs/min are stirred 10 minutes, obtain silanol liquid；
(4) above-mentioned butyl titanate is joined in the deionized water of its weight 10 times, stir, add Methanamide, lecithin, insulated and stirred 20 minutes at 50 DEG C, dropping concentration is the ammonia of 20%, and regulation pH is 10, warming temperature is 70 DEG C, insulation reaction 30 minutes, obtains titanium colloidal sol；
(5) by above-mentioned tetraethyl orthosilicate, the mixing of epoxidation methyl eleostearate, warming temperature is 36 DEG C, add remaining acetic acid, insulated and stirred 10 minutes, drip the deionized water of above-mentioned mixed system weight 60%, add silanol liquid after dropping, at 76 DEG C, be incubated 6 hours, obtain silica sol modified epoxidation methyl eleostearate；
(6) above-mentioned silica sol modified epoxidation methyl eleostearate is joined in above-mentioned titanium colloidal sol, stir, add 4 vinyl epoxy cyclohexanes, 100 revs/min are stirred 7 minutes, add single triethanolamine oleate ester, DAA, insulated and stirred 20 minutes at 80 DEG C, it is cooled to room temperature, ester material must be premixed；
(7) above-mentioned premix ester material is mixed with remaining each raw material, melt extruded by extruder, after then tabletting is broken, then through pulverizing, sieving, to obtain final product.
Performance test:
Impact resistance: >=50kg/cm；
Hardness: 2H.
Claims (2)
1. a polyester powder coatings for furniture, it is characterised in that it is made up of the raw material of following weight parts:
Lecithin 0.4-1, 4 vinyl epoxy cyclohexane 0.1-0.2, polybenzimidazoles 1-2, single triethanolamine oleate ester 0.7-1, DAA 2-3, Oleum Verniciae fordii 10-12, sodium hydroxide 0.06-0.07, methanol 3-4, perfluorinated sulfonic resin 0.1-0.2, acetic acid 6-8, the hydrogen peroxide 10-15 of 26-30%, tetraethyl orthosilicate 10-17, Y-r-chloropropyl trimethoxyl silane 0.1-0.2, unsaturated polyester resin 70-80, methyl ethyl ketone peroxide 0.6-1, aminoethyl piperazine 0.1-0.2, calcite in powder 10-14, Methanamide 0.6-1, butyl titanate 2-4, calcium aluminate 3-4.
2. the preparation method of a polyester powder coatings for furniture as claimed in claim 1, it is characterised in that comprise the following steps:
(1) joining in Oleum Verniciae fordii by above-mentioned methanol, add sodium hydroxide, react 70-80 minute at 37-40 DEG C under stirring condition, distill methanol removal, stratification, the supernatant liquid of collection first with sulfuric acid scrubbing, the washing of reusable heat water, distillation dehydration, obtains methyl eleostearate；
(2) 50-60% of above-mentioned methyl eleostearate, perfluorinated sulfonic resin, above-mentioned acetic acid weight is mixed, rise high-temperature and be 60-68 DEG C, the hydrogen peroxide of above-mentioned 26-30% is dripped under stirring condition, insulation reaction 3-4 hour after dropping, filter, filtrate is neutralized with alkali, washing, it is vacuum dried 3-4 hour at 50-60 DEG C, obtains epoxidation methyl eleostearate；
(3) being joined by above-mentioned polybenzimidazoles in the dehydrated alcohol of its weight 6-10 times, add Y-r-chloropropyl trimethoxyl silane, 500-600 rev/min is stirred 10-17 minute, obtains silanol liquid；
(4) above-mentioned butyl titanate is joined in the deionized water of its weight 10-16 times, stir, add Methanamide, lecithin, insulated and stirred 20-30 minute at 50-60 DEG C, dropping concentration is the ammonia of 20-23%, regulation pH is 10-13, warming temperature is 70-80 DEG C, insulation reaction 30-40 minute, obtains titanium colloidal sol；
(5) by above-mentioned tetraethyl orthosilicate, the mixing of epoxidation methyl eleostearate, warming temperature is 36-40 DEG C, add remaining acetic acid, insulated and stirred 10-20 minute, drip the deionized water of above-mentioned mixed system weight 60-70%, add silanol liquid after dropping, at 76-80 DEG C, be incubated 6-7 hour, obtain silica sol modified epoxidation methyl eleostearate；
(6) above-mentioned silica sol modified epoxidation methyl eleostearate is joined in above-mentioned titanium colloidal sol, stir, add 4 vinyl epoxy cyclohexane, 100-200 rev/min is stirred 7-10 minute, add single triethanolamine oleate ester, DAA, insulated and stirred 20-30 minute at 80-90 DEG C, is cooled to room temperature, must premix ester material；
(7) above-mentioned premix ester material is mixed with remaining each raw material, melt extruded by extruder, after then tabletting is broken, then through pulverizing, sieving, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610187082.4A CN105969122A (en) | 2016-03-28 | 2016-03-28 | Polyester powder furniture coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610187082.4A CN105969122A (en) | 2016-03-28 | 2016-03-28 | Polyester powder furniture coating and preparation method thereof |
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| CN105969122A true CN105969122A (en) | 2016-09-28 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590369A (en) * | 2016-12-05 | 2017-04-26 | 安徽永川电气设备有限公司 | Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material |
| CN106590370A (en) * | 2016-12-05 | 2017-04-26 | 安徽永川电气设备有限公司 | Carbon nanometer tube enhanced bacteriostatic powder paint for electric power switch cabinet and preparation method thereof |
| CN106700856A (en) * | 2016-12-05 | 2017-05-24 | 安徽永川电气设备有限公司 | Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating |
| CN106752781A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet hydrophobic antibacterial powdery paints of silicon substrate and preparation method thereof |
| CN106752780A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints and preparation method thereof |
| CN106752779A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof |
| CN106854427A (en) * | 2016-12-05 | 2017-06-16 | 安徽永川电气设备有限公司 | A kind of power switch cabinet nylon is combined antibacterial powdery paints and preparation method thereof |
| CN106854426A (en) * | 2016-12-05 | 2017-06-16 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial polyester resin powder coating and preparation method thereof |
| CN115109499A (en) * | 2022-08-10 | 2022-09-27 | 肇庆市高要区阿美加涂料有限责任公司 | Epoxy resin water-textured coating and preparation method thereof |
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| CN103881341A (en) * | 2014-04-04 | 2014-06-25 | 中南林业科技大学 | Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof |
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2016
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Patent Citations (3)
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| CN102993921A (en) * | 2012-10-24 | 2013-03-27 | 宿迁市英杰装饰材料有限公司 | Powder coating with low-temperature curing function |
| CN103601703A (en) * | 2013-07-11 | 2014-02-26 | 中南林业科技大学 | Method for preparing epoxy methyl eleostearate from tung oil |
| CN103881341A (en) * | 2014-04-04 | 2014-06-25 | 中南林业科技大学 | Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590369A (en) * | 2016-12-05 | 2017-04-26 | 安徽永川电气设备有限公司 | Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material |
| CN106590370A (en) * | 2016-12-05 | 2017-04-26 | 安徽永川电气设备有限公司 | Carbon nanometer tube enhanced bacteriostatic powder paint for electric power switch cabinet and preparation method thereof |
| CN106700856A (en) * | 2016-12-05 | 2017-05-24 | 安徽永川电气设备有限公司 | Antibacterial anti-oxidation powder coating for electric switch cabinet and preparation method of antibacterial anti-oxidation powder coating |
| CN106752781A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet hydrophobic antibacterial powdery paints of silicon substrate and preparation method thereof |
| CN106752780A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints and preparation method thereof |
| CN106752779A (en) * | 2016-12-05 | 2017-05-31 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial powdery paints of uvioresistant and preparation method thereof |
| CN106854427A (en) * | 2016-12-05 | 2017-06-16 | 安徽永川电气设备有限公司 | A kind of power switch cabinet nylon is combined antibacterial powdery paints and preparation method thereof |
| CN106854426A (en) * | 2016-12-05 | 2017-06-16 | 安徽永川电气设备有限公司 | A kind of power switch cabinet antibacterial polyester resin powder coating and preparation method thereof |
| CN115109499A (en) * | 2022-08-10 | 2022-09-27 | 肇庆市高要区阿美加涂料有限责任公司 | Epoxy resin water-textured coating and preparation method thereof |
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Application publication date: 20160928 |