CN106590369A - Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material - Google Patents
Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a bacteriostatic and flame-retardant powdery coating material for power switch cabinets. The bacteriostatic and flame-retardant powdery coating material is prepared from the following raw materials in parts by weight: 1-2 parts of antimony trioxide, 0.5-1 part of 8-oxine copper, 0.08-0.2 part of lanthanum oxide, 2-4 parts of sodium m-hydroxy benzoate, 5-7 parts of 8-hydroxyquinoline, 10-14 parts of polyethylene glycol octylphenyl ether, 36-40 parts of tetrabutyl titanate, 20-25 parts of cyclohexanol, 100-120 parts of unsaturated polyester resin, 1-2 parts of ammonium polyphosphate, 3-4 parts of zinc borate hydrate, 0.1-0.4 part of hexachlorocyclotriphosphazene, 10-12 parts of expanded perlite, 2-4 parts of glyceryl caprylate-caprate, 0.6-1 part of hexamethylphosphoric triamide, 0.4-1 part of calcium acetylacetonate, 0.6-1 part of aluminum potassium sulfate and 1-2 parts of sodium polyacrylate. The finished coating material disclosed by the invention is good in flame retardance and high in safety.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of power switch cabinet antibacterial Flame Retardant Powder Coatings and its system
Preparation Method.
Background technology
With social development, the demand of anti-biotic material will constitute huge market, and the production of antiseptic and its product will be into
For important new industry field.Substantially, temperature tolerance is poor, service life is short for organic antiseptic short-term bactericidal effect；Mineral-type
Antiseptic working life is long, and high temperature resistant has side effect.And complex antimicrobials greatly improve antibacterial rationally using both advantages
Agent performance and the scope of application, overcome the limitation of single antibacterial antiplaque agent spectrum.Composite antibacterial material will be that from now on anti-biotic material is sent out
The direction of exhibition application and main points；
M-hydroxybenzoic acid has active anticancer by suppressing xanthine oxidase, and 8-hydroxyquinoline also has certain antibacterial
Activity.Rare earth-septichen -8-hydroxyquinoline ternary complex is synthesized, rare earth-P-hydroxybenzoic acid -8- hydroxyls
Quinoline ternary complex has also been synthesized.But, the synthesis of rare earth-m-hydroxybenzoic acid -8-hydroxyquinoline ternary complex,
Structure and property research are not reported so far, the synthesis and the antibacterial that have a m-hydroxybenzoic acid phenanthroline complex of rarely seen report
Property Quality Research, but this complex is only higher in concentration（>500ppm）When just show bacteriostasis property.Rare earth ion due to
Its special electron structure, the metabolic process that can make mushroom stops, with extensive antibacterial action.Zuo Yuping et al. is proved
In excessive earth solution, Niger's aspergillus fungi can be combined rapidly with rare earth ion, make breathing and the grape of fungal cell
Utilizing for sugar reduces, until stopping.Rare earth ion has anti-inflammatory, sterilization, anticancer, anticoagulation, analgesic activity again simultaneously.Due to dilute
Native ion to be formed and can strengthen its fungistatic effect after complex, therefore in recent years, this field progressively causes the attention of people and pass
Note.Lin Feng, what water sample, Wang Liufang have been respectively synthesized different rare earth compoundings and have made bacteriostatic experiment, it was demonstrated that complex it is antibacterial
Ability is better than independent part and corresponding rare earth ion.In addition, China is the abundant country of rare earth resources, rare earth resources are developed
It is the long-term fundamental state policy of one, China.The research application of Rare Earth Functional Materials has important economic implications and social effect.Cause
This, study on the synthesis has the rare earth compounding of good bacteriostasis property, develops new application, explores rational production procedure etc.
With important theoretical and realistic meaning.
Antibacterial powder paint refers to that film has antibiotic property made by powdery paints, can kill or suppress to attach on film
Bacterium.Powdery paints is widely used in goods showing cabinet, refrigerator, water dispenser, bed product, furniture of steel, kitchen utensils, food work
Industry equipment, hospital facility etc..These be all people often in contact with utensil.Therefore, the development and Application of antibacterial powder paint has
Important social effect.Since the nineties, the western developed country such as Japan has developed antimicrobial form powdery paints in succession, and
China is still in this respect the starting stage.With people's living standard continuous improvement and environmental protection consciousness not
Disconnected to strengthen, antimicrobial form powdery paints is the new approaches that powdery paints application opens a health.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of power switch cabinet is with antibacterial fire-retardant powder
Coating and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of antibacterial Flame Retardant Powder Coatings of power switch cabinet, it is made up of the raw material of following weight parts：
Antimony oxide 1-2, copper 8-quinolinolate 0.5-1, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8- hydroxyl
Quinoline 5-7, Triton X-100 10-14, butyl titanate 36-40, cyclohexanol 20-25, unsaturated polyester resin
100-120, APP 1-2, water and Firebrake ZB 3-4, hexachlorocyclotriph,sphazene 0.1-0.4, expanded perlite 10-12, pungent capric acid
Glyceride 2-4, HMPA 0.6-1, calcium acetylacetonate 0.4-1, alum 0.6-1, Sodium Polyacrylate 1-2.
A kind of described power switch cabinet preparation method of antibacterial Flame Retardant Powder Coatings, comprises the following steps：
（1）Above-mentioned APP, water and Firebrake ZB, m-hydroxybenzoic acid sodium are mixed, compound weight 27-30 times is added to
In deionized water, stir, obtain the fire-retardant aqueous solution；
（2）Above-mentioned lanthana is added in its weight 47-50 times, 30-40% hydrochloric acid solution, is stirred, obtain chlorination dilute
Native solution；
（3）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add the above-mentioned fire-retardant aqueous solution, obtain premix dispersion liquid；
（4）Above-mentioned copper 8-quinolinolate is added in the absolute ethyl alcohol of its weight 14-20 times, it is 60-65 DEG C to rise high-temperature, is protected
Temperature stirring 3-6 minutes, above-mentioned butyl titanate is added, it is 70-78 DEG C to rise high-temperature, insulated and stirred 10-20 minute, is added above-mentioned
Calcium acetylacetonate, stirs to normal temperature, obtains metatitanic acid ester alcohol liquid；
（5）By above-mentioned re chloride, premix dispersion liquid mixing, stir, above-mentioned Sodium Polyacrylate is added, in 47-50
Insulated and stirred 6-10 minute at DEG C, secure satisfactory grades sub- solution；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned macromolecule
Solution, ultrasonic 3-5 minutes, adds above-mentioned metatitanic acid ester alcohol liquid, stirs 3-4 hours, centrifugation, by precipitation acetone, anhydrous second
Alcohol, deionized water are washed 3-4 time successively, in being placed on drying box, 6-7 hours are dried at 100-110 DEG C, obtain antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in sending into extruder, melting extrusion, cooling,
Sieve, obtain final product the powdery paints.
It is an advantage of the invention that：
The 8-hydroxyquinoline of the present invention can suppress the formation of bacterial cell membrane, m-hydroxybenzoic acid that also there is certain antibacterial to make
With；After forming nano-antibacterial complex, because the carboxyl on complex and cellular phospholipid and peptide chain has stronger affinity, can be steady
It is scheduled on cell membrane and lysosome membrane, so as to suppress lysosome to discharge anti-inflammatory agent, on the one hand can be with the transfer ribose of bacterium
Phosphoryl bonding in nucleic acid, it is suppressed that the activity of its nuclease and function, so that the growth of bacterium is suppressed：The opposing party
Face, due to formed complex after, the molecular weight and conjugation of complex all strengthen, and fat-soluble enhancing is penetrated to cell membrane
Or damage capability strengthens, the key component that making biology growing and metabolism needs is lost in, and causes organism to complete normally
Operating.Rare earth ion has an effect of the intracellular Ca2+ of antagonism, and Ca2+ be maintain cell normal physiological activity from
Son, it is interfered to bacterial cell normal activities, causes bacterial death；
The present invention adds titanium dioxide prepared by tetra-n-butyl titanate to have certain anti-microbial property because of its photocatalytic activity, enters
One step improves the biocidal property of composite and polyacrylic compatibility, improves the stability and antiseptic property of finished product；
Antimony oxide, APP, water and Firebrake ZB, hexachlorocyclotriph,sphazene that the present invention is added etc., can effectively improve
The anti-flammability of finished product coating, improves safety in utilization.
Specific embodiment
A kind of antibacterial Flame Retardant Powder Coatings of power switch cabinet, it is made up of the raw material of following weight parts：
Antimony oxide 1, copper 8-quinolinolate 0.5, lanthana 0.0.8, m-hydroxybenzoic acid sodium 2,8 oxyquinolines 5, poly- second two
Alcohol octyl phenyl ether 10, butyl titanate 36, cyclohexanol 20, unsaturated polyester resin 100, APP 1, water and Firebrake ZB 3,
Hexachlorocyclotriph,sphazene 0.1, expanded perlite 10, Glycerin, mixed triester with caprylic acid capric acid 2, HMPA 0.6, calcium acetylacetonate 0.4, sulphur
Sour aluminium potassium 0.6, Sodium Polyacrylate 1.
A kind of described power switch cabinet preparation method of antibacterial Flame Retardant Powder Coatings, comprises the following steps：
（1）Above-mentioned APP, water and Firebrake ZB, m-hydroxybenzoic acid sodium are mixed, going for 27 times of compound weight is added to
In ionized water, stir, obtain the fire-retardant aqueous solution；
（2）Above-mentioned lanthana is added in 47 times of its weight, 30% hydrochloric acid solution, is stirred, obtain rare earth chloride molten
Liquid；
（3）30%, the 25% of cyclohexanol weight of above-mentioned Triton X-100 weight is taken, mixing stirs, in addition
8 oxyquinolines are stated, is stirred, add the above-mentioned fire-retardant aqueous solution, obtain premix dispersion liquid；
（4）Above-mentioned 8 copper quinolinate is added in the absolute ethyl alcohol of 14 times of its weight, it is 60 DEG C to rise high-temperature, insulated and stirred 3
Minute, above-mentioned butyl titanate is added, it is 70 DEG C to rise high-temperature, and insulated and stirred 10 minutes adds above-mentioned calcium acetylacetonate, stirring
To normal temperature, metatitanic acid ester alcohol liquid is obtained；
（5）By above-mentioned re chloride, premix dispersion liquid mixing, stir, above-mentioned Sodium Polyacrylate is added, at 47 DEG C
Insulated and stirred 6 minutes, secure satisfactory grades sub- solution；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned macromolecule
Solution, ultrasound 3 minutes adds above-mentioned metatitanic acid ester alcohol liquid, stirs 3 hours, and centrifugation by precipitation acetone, absolute ethyl alcohol, is gone
Ionized water is washed successively 3 times, in being placed on drying box, is dried 6 hours at 100 DEG C, obtains antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in sending into extruder, melting extrusion, cooling,
Sieve, obtain final product the powdery paints.
Performance test：
Impact resistance：≥50kg/cm；
Hardness：2H.
Claims (2)
1. antibacterial Flame Retardant Powder Coatings of a kind of power switch cabinet, it is characterised in that it is made up of the raw material of following weight parts
's：
Antimony oxide 1-2, copper 8-quinolinolate 0.5-1, lanthana 0.0.8-0.2, m-hydroxybenzoic acid sodium 2-4,8- hydroxyl
Quinoline 5-7, Triton X-100 10-14, butyl titanate 36-40, cyclohexanol 20-25, unsaturated polyester resin
100-120, APP 1-2, water and Firebrake ZB 3-4, hexachlorocyclotriph,sphazene 0.1-0.4, expanded perlite 10-12, pungent capric acid
Glyceride 2-4, HMPA 0.6-1, calcium acetylacetonate 0.4-1, alum 0.6-1, Sodium Polyacrylate 1-2.
2. a kind of power switch cabinet as claimed in claim 1 preparation method of antibacterial Flame Retardant Powder Coatings, it is characterised in that
Comprise the following steps：
（1）Above-mentioned APP, water and Firebrake ZB, m-hydroxybenzoic acid sodium are mixed, compound weight 27-30 times is added to
In deionized water, stir, obtain the fire-retardant aqueous solution；
（2）Above-mentioned lanthana is added in its weight 47-50 times, 30-40% hydrochloric acid solution, is stirred, obtain chlorination dilute
Native solution；
（3）30-40%, the 25-30% of cyclohexanol weight of above-mentioned Triton X-100 weight are taken, are mixed, stirred,
Above-mentioned 8-hydroxyquinoline is added, is stirred, add the above-mentioned fire-retardant aqueous solution, obtain premix dispersion liquid；
（4）Above-mentioned copper 8-quinolinolate is added in the absolute ethyl alcohol of its weight 14-20 times, it is 60-65 DEG C to rise high-temperature, is protected
Temperature stirring 3-6 minutes, above-mentioned butyl titanate is added, it is 70-78 DEG C to rise high-temperature, insulated and stirred 10-20 minute, is added above-mentioned
Calcium acetylacetonate, stirs to normal temperature, obtains metatitanic acid ester alcohol liquid；
（5）By above-mentioned re chloride, premix dispersion liquid mixing, stir, above-mentioned Sodium Polyacrylate is added, in 47-50
Insulated and stirred 6-10 minute at DEG C, secure satisfactory grades sub- solution；
（6）Remaining Triton X-100 is added in remaining cyclohexanol, is stirred, add above-mentioned macromolecule
Solution, ultrasonic 3-5 minutes, adds above-mentioned metatitanic acid ester alcohol liquid, stirs 3-4 hours, centrifugation, by precipitation acetone, anhydrous second
Alcohol, deionized water are washed 3-4 time successively, in being placed on drying box, 6-7 hours are dried at 100-110 DEG C, obtain antibacterial dispersant；
（7）Above-mentioned antibacterial dispersant is mixed with remaining each raw material, is stirred, in sending into extruder, melting extrusion, cooling,
Sieve, obtain final product the powdery paints.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611102639.6A CN106590369A (en) | 2016-12-05 | 2016-12-05 | Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611102639.6A CN106590369A (en) | 2016-12-05 | 2016-12-05 | Bacteriostatic and flame-retardant powdery coating material for power switch cabinets and preparation method for coating material |
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| CN106590369A true CN106590369A (en) | 2017-04-26 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109722138A (en) * | 2018-11-29 | 2019-05-07 | 安徽开林新材料股份有限公司 | A kind of flame-proof antibiotic ultraviolet-curing paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN105950003A (en) * | 2016-07-04 | 2016-09-21 | 铜陵方正塑业科技有限公司 | Bacteriostatic film paint and preparation method thereof |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
| CN106085195A (en) * | 2016-07-13 | 2016-11-09 | 安徽省和翰光电科技有限公司 | A kind of inorganic fire-retarded waterborne polyester coating and preparation method thereof |
-
2016
- 2016-12-05 CN CN201611102639.6A patent/CN106590369A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1704403A (en) * | 2004-05-27 | 2005-12-07 | 上海师范大学 | Nano rare earth m-hydroxy benzoic acid 8-hydroxyquinoline antibacterial agent and method for preparing same |
| CN105969122A (en) * | 2016-03-28 | 2016-09-28 | 刘辉 | Polyester powder furniture coating and preparation method thereof |
| CN105950003A (en) * | 2016-07-04 | 2016-09-21 | 铜陵方正塑业科技有限公司 | Bacteriostatic film paint and preparation method thereof |
| CN106085195A (en) * | 2016-07-13 | 2016-11-09 | 安徽省和翰光电科技有限公司 | A kind of inorganic fire-retarded waterborne polyester coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109722138A (en) * | 2018-11-29 | 2019-05-07 | 安徽开林新材料股份有限公司 | A kind of flame-proof antibiotic ultraviolet-curing paint |
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Application publication date: 20170426 |