CN1939982A - Multiple white pigment with titanium dioxide as main material - Google Patents
Multiple white pigment with titanium dioxide as main material Download PDFInfo
- Publication number
- CN1939982A CN1939982A CN 200510021798 CN200510021798A CN1939982A CN 1939982 A CN1939982 A CN 1939982A CN 200510021798 CN200510021798 CN 200510021798 CN 200510021798 A CN200510021798 A CN 200510021798A CN 1939982 A CN1939982 A CN 1939982A
- Authority
- CN
- China
- Prior art keywords
- titanium dioxide
- proportion
- aluminium silicate
- pure aluminium
- white pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 18
- 239000012463 white pigment Substances 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 title claims description 8
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 claims abstract description 8
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 13
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 13
- 235000012211 aluminium silicate Nutrition 0.000 claims description 13
- 239000004615 ingredient Substances 0.000 claims description 8
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 3
- 239000012634 fragment Substances 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 239000004033 plastic Substances 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000005060 rubber Substances 0.000 abstract description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052918 calcium silicate Inorganic materials 0.000 abstract 1
- 239000000378 calcium silicate Substances 0.000 abstract 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 235000013799 ultramarine blue Nutrition 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 description 11
- 239000000049 pigment Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
Abstract
A polybasic white pigment with titanium dioxide as main raw material consists of titanium dioxide 8-120 proportion, antimony trioxide 0.5-60 proportion, stearic acid 0.5-40 proportion, barium metaborate 0.5-60 proportion, aluminum silicate 1-70 proportion, calcium silicate 1-120 proportion, manganese violet 0.01-5 proportion and ultra marine blue 0.1-5 proportion. The process is carried out by hydrolyzing, drying, breaking, adding into aluminum silicate, mixing and crushing. It can be used for coating, rubber and paper-making, plastic windows and doors and mechanical equipments. It has excellent light resistance, heat resistance, weather resistance, anti-rusting and corrosion-resisting functions.
Description
Technical field
The invention belongs to the pigment technology field.
Background technology
The prior art titanium white powder pigment is widely used in fields such as coating, plastics, rubber, papermaking and machinofacture.Its weak point is that photostabilization is poor, flavescence easily, and efflorescence easily influences result of use.
Summary of the invention
Technical problem to be solved provide a kind of inhibited from yellowing, to be difficult for atomizing be the multiple white pigment of major ingredient with titanium dioxide.
The technical scheme that solves its technical problem is as follows: be the multiple white pigment of major ingredient with titanium dioxide, its moiety comprises titanium dioxide, antimonous oxide, stearic acid, barium metaborate, pure aluminium silicate, lime carbonate, manganese violet and ultramarine.
The weight proportion of each moiety is as follows: titanium dioxide 8-120: antimonous oxide 0.5-60: stearic acid 0.5-40: barium metaborate 0.5-60: pure aluminium silicate 1-70: lime carbonate 1-120: manganese violet 0.01-5: ultramarine 0.1-5.
The polynary preparation method from pigment who with titanium dioxide is major ingredient is as follows:
A. hydrolysis: stearic acid 0.5-40 and barium metaborate 0.5-60 are dissolved in in the moiety gross weight 100-200 water doubly, be warming up to 60 ℃, add all the other moietys except that pure aluminium silicate that prepare according to weight proportion while stirring, be warming up to 105 °-130 ℃, kept constant temperature 1 hour;
B. oven dry: with the thick shape mixed solution of operation a gained in drying shed, with 120 ° of-220 ℃ of temperature oven dry;
C. broken: as, to be the fragment that is not more than 5mm with crusher in crushing with the material of operation b gained;
D. adding pure aluminium silicate mixes: with the material of operation c gained, under 20 ° of-30 ℃ of temperature of room temperature, add pure aluminium silicate 1-70 and mix;
E. pulverize:, pulverize and be 500-1200 order powder the material of operation d gained.
Beneficial effect: the present invention is applied to fields such as various coating, rubber and papermaking, for example at the bottom of exterior coating, plastic color master material, the sports shoes, plastic door-window, automobile and mechanical means etc. be as tinting pigment.Beneficial effect is to have good fast light, heat-resisting weather to change performance, inhibited from yellowing, be difficult for efflorescence, bulk article outward appearance form and aspect high conformity, have functions such as fire-retardant, fire prevention, mildew-resistant and sterilization when being used for, have antirust, etch-proof function when being used for as the steel part topcoating as coating.
Embodiment
Three embodiment of each moiety weight ratio prescription of multiple white pigment that make major ingredient with titanium dioxide are as follows:
Embodiment one: titanium dioxide 20: antimonous oxide 2: stearic acid 0.73: barium metaborate 0.5: pure aluminium silicate 17: lime carbonate 30: manganese violet 0.02: ultramarine 0.2.
Embodiment two: titanium dioxide 60: antimonous oxide 2: stearic acid 0.73: barium metaborate 0.5: pure aluminium silicate 5.9: lime carbonate 8.5: manganese violet 0.02: ultramarine 0.2.
Embodiment three: titanium dioxide 80: antimonous oxide 2: stearic acid 0.73: barium metaborate 0.5: pure aluminium silicate 3: lime carbonate 1.5: manganese violet 0.02: ultramarine 0.2.
Claims (3)
1. be the multiple white pigment of major ingredient with titanium dioxide, it is characterized in that its moiety comprises titanium dioxide, antimonous oxide, stearic acid, barium metaborate, pure aluminium silicate, lime carbonate, manganese violet and ultramarine.
2. described according to claim 1 is the multiple white pigment of major ingredient with titanium dioxide, it is characterized in that the weight proportion of each moiety is as follows:
Titanium dioxide 8-120: antimonous oxide 0.5-60: stearic acid 0.5-40: barium metaborate 0.5-60: pure aluminium silicate 1-70: lime carbonate 1-120: manganese violet 0.01-5: ultramarine 0.1-5.
3. be the preparation method of the multiple white pigment of major ingredient with titanium dioxide, it is characterized in that comprising following operation:
A. hydrolysis: stearic acid 0.5-40 and barium metaborate 0.5-60 are dissolved in in the moiety gross weight 100-200 water doubly, heat to 60 ℃, add all the other moietys except that pure aluminium silicate that prepare according to weight proportion while stirring, heat, kept constant temperature 1 hour to 105 °-130 ℃;
B. oven dry: with the thick shape mixed solution of operation a gained, in drying shed, with 120 ° of-220 ℃ of temperature oven dry;
C. broken: as, to be the fragment that is not more than 5mm with crusher in crushing with the material of operation b gained;
D. adding pure aluminium silicate mixes: with the material of operation c gained, under 20 ° of-30 ℃ of temperature of room temperature, add pure aluminium silicate 1-70, mix;
F. pulverize:, pulverize and be 500-1200 order powder the material of operation d gained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100217989A CN100455628C (en) | 2005-09-28 | 2005-09-28 | Multiple white pigment with titanium dioxide as main material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100217989A CN100455628C (en) | 2005-09-28 | 2005-09-28 | Multiple white pigment with titanium dioxide as main material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1939982A true CN1939982A (en) | 2007-04-04 |
| CN100455628C CN100455628C (en) | 2009-01-28 |
Family
ID=37958518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100217989A Active CN100455628C (en) | 2005-09-28 | 2005-09-28 | Multiple white pigment with titanium dioxide as main material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100455628C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159997A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Protective clothing material with self-repairing function in sports field and preparation method thereof |
| CN103159996A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Multifunctional protective clothing material in sports field and preparation method thereof |
| CN103160057A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Composite functional pad material for sporting goods and preparation method thereof |
| CN103205037A (en) * | 2012-01-17 | 2013-07-17 | 贾振勇 | Multifunctional protector material in field of sports, and preparation method thereof |
| CN104231356A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of protective clothing material with self-repairing function in sports field |
| CN104231357A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of multifunctional protective clothing material used in sports field |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340387A (en) * | 1992-02-24 | 1994-08-23 | Smith Donald A | Color transforming art medium compositions |
| US6312510B1 (en) * | 1997-02-13 | 2001-11-06 | Mitsubishi Pencil Kabushiki Kaisha | Water-base white pigment ink for ballpoints |
| CN1312237C (en) * | 2004-02-11 | 2007-04-25 | 范斌远 | Lithopone |
-
2005
- 2005-09-28 CN CNB2005100217989A patent/CN100455628C/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159997A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Protective clothing material with self-repairing function in sports field and preparation method thereof |
| CN103159996A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Multifunctional protective clothing material in sports field and preparation method thereof |
| CN103160057A (en) * | 2011-12-16 | 2013-06-19 | 李胜春 | Composite functional pad material for sporting goods and preparation method thereof |
| CN104231356A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of protective clothing material with self-repairing function in sports field |
| CN104231357A (en) * | 2011-12-16 | 2014-12-24 | 李胜春 | Preparation method of multifunctional protective clothing material used in sports field |
| CN103205037A (en) * | 2012-01-17 | 2013-07-17 | 贾振勇 | Multifunctional protector material in field of sports, and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100455628C (en) | 2009-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100455628C (en) | Multiple white pigment with titanium dioxide as main material | |
| CN104151970B (en) | Hydrate colour transparent heat insulating dope and preparation method and using method | |
| CN103013298B (en) | A kind of powder coating containing modified Nano carbon and preparation method thereof | |
| KR960029233A (en) | Method for producing anatase titanium dioxide | |
| CN101864242B (en) | Method for preparing yellowing resistant water-borne coating | |
| CN103013296A (en) | Powder coating containing modified attapulgite and preparation method of powder coating | |
| CN104861479A (en) | Antibacterial color master batch used for polyethylene glycol terephthalate | |
| CN101701370A (en) | Antibacterial polyester fibre | |
| CN106752106B (en) | Anti-aging functional filler nano-calcium carbonate of bright white uvioresistant and its preparation method and application | |
| CN107915933B (en) | Preparation method of special toughening type nano calcium carbonate for PVC (polyvinyl chloride) plastics | |
| CN101709190B (en) | Far infrared interior wall painting | |
| CN104194048A (en) | Antibacterial and ozone-resistant modified calcium carbonate and preparation method thereof | |
| CN102086310B (en) | Preparation method of weather-resistance environmental-friendly synthetic mica pearlescent pigment | |
| CN109836734A (en) | A kind of method of modifying of uvioresistant PVC composite material | |
| CN103849047A (en) | Polyethylene color master batches with antibacterial function | |
| CN106745233A (en) | For the preparation method of the calcining seeds of rutile titanium white powder production | |
| CN101864235B (en) | Method for preparing exterior wall coating | |
| CN104356543A (en) | Filler for plastic door window and preparation method of filler | |
| CN104292706A (en) | Flame retardant PVC plastic door and window filler and preparation method thereof | |
| CN103540108B (en) | A kind of manufacture craft of crystallization nanometer PET | |
| CN104311885A (en) | Plastic door and window filler containing nanometer corundum powder and preparation method of plastic door and window filler | |
| CN108727917A (en) | A kind of Sun-proof Powder Paint for Automobile and preparation method thereof | |
| CN106366511A (en) | Light degradable PVC sheet containing anhydrous sodium sulphate and making method thereof | |
| CN1590470A (en) | Water environmentel protection type inner and external well mineral varnish paint and its prepqration method | |
| CN101397378A (en) | Polychloroethylene ultraviolet light stabilizer, light resistant polychloroethylene and preparation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| DD01 | Delivery of document by public notice | ||
| DD01 | Delivery of document by public notice |
Addressee: Fan Binyuan Document name: payment instructions |
|
| DD01 | Delivery of document by public notice |
Addressee: Fan Binyuan Document name: Notice of Termination of Patent Rights |