CN108033682A - The sheen glaze and glaze noodle producing method of glazed tile - Google Patents

The sheen glaze and glaze noodle producing method of glazed tile Download PDF

Info

Publication number
CN108033682A
CN108033682A CN201711295044.1A CN201711295044A CN108033682A CN 108033682 A CN108033682 A CN 108033682A CN 201711295044 A CN201711295044 A CN 201711295044A CN 108033682 A CN108033682 A CN 108033682A
Authority
CN
China
Prior art keywords
glaze
paint
glazed tile
sheen
glossiness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711295044.1A
Other languages
Chinese (zh)
Inventor
王彦庆
杨春
宋子春
黄中华
李文胜
杨晖
檀瑞超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huida Sanitary Ware Co Ltd
Original Assignee
Huida Sanitary Ware Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huida Sanitary Ware Co Ltd filed Critical Huida Sanitary Ware Co Ltd
Priority to CN201711295044.1A priority Critical patent/CN108033682A/en
Publication of CN108033682A publication Critical patent/CN108033682A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C03C8/20Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses the sheen glaze and glaze noodle producing method of a kind of glazed tile, the chemical composition and mass percentage of its siccative are:SiO248~53%, Al2O311~15%, CaO 6~8%, MgO 0.5~1.5%, K2O 2~5%, Na2O 2~5%, B2O30.2~1%, BaO 5~8%, ZnO 10~13%, ZrO22~3%, Fe2O3≤0.2%、TiO2≤ 0.1%, surplus is impurity.This glaze adds suitable aluminium oxide, zinc oxide, calcic, baric raw material in formula, forms composite matt glaze agent;Zinc-aluminium high temperature forms spinelle, improves glaze paint opacity, adjusts glossiness, adjusts the high temperature levelability of glaze paint so that the more smooth exquisiteness of glaze paint.This glaze introduces suitable kaolin, and aluminium oxide, zinc oxide, adjusts glaze paint chemical composition, to adjust in glaze the mineral compositions such as calcium is unglazed, barium is unglazed and zinc is unglazed, composite matt glaze agent, reach the smooth exquisiteness of glaze paint, the low purpose of glossiness.

Description

The sheen glaze and glaze noodle producing method of glazed tile
Technical field
The present invention relates to a kind of Ceramic glaze and preparation method, prepared by the sheen glaze and glaze paint of especially a kind of glazed tile Method.
Background technology
With the raising of present material and culture level and the popularization of environmental sanitation, requirement of the people to environment of living A part higher and higher, that glazed tile is decorated as living environment, it is moist that people are more desirable to glazed tile surface more smooth, touches Feel, easy cleaning, surface gloss is low, it is not easy to because light damages eyes, therefore, study surfacing exquisiteness light Sliding and low glossiness sheen glaze is the inevitable requirement that people improve the quality of living.
Or existing common matting glaze rough surface glossiness is low, or the smooth glossiness of glaze paint is high, the two must not be simultaneous One.Also there is the sheen glaze newly researched and developed currently on the market, but I develops different from their technique, and effect is also different, he On the basis of former common dumb light glaze paint, by adding soft polissoir, by the soft throwing of glaze paint, although this soft throwing glossiness It is low, but pin hole is more, and production production process is added into, production cost is considerably increased, and less than optimal sheen glaze paint is imitated Fruit.Also there is the sheen glaze that low gloss ink is sprayed in highlighted glaze paint, though this technique is easy to operate, its glossiness also has Between 30~70, gloss is too strong.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of sheen glaze of the high glazed tile of glossiness;The present invention also carries A kind of glaze noodle producing method of glazed tile is supplied.
In order to solve the above technical problems, the technical solution used in the present invention is:The chemical composition and quality hundred of its siccative Point content is:SiO248~53%, Al2O311~15%, CaO 6~8%, MgO 0.5~1.5%, K2O 2~5%, Na2O 2~ 5%、B2O30.2~1%, BaO 5~8%, ZnO 10~13%, ZrO22~3%, Fe2O3≤0.2%、TiO2≤ 0.1%, surplus is Impurity.
The raw material of siccative described in glaze of the present invention is using kaolin, zirconium silicate, aluminium oxide, burning talcum, albite, zinc oxide And frit.
The method of the present invention uses above-mentioned glaze;The siccative adds water to be modulated into glaze slip, and glazing is behind the surface of brick, sintering It can obtain the glaze paint.
325 purpose of glaze slip described in the method for the present invention is tailed over as 0.1~0.4g/100ml, flow velocity for 50 milliliters of current meters 25~ 35 seconds, proportion was 1.85~1.90g/ml.
It is using beneficial effect caused by above-mentioned technical proposal:The present invention added in component suitable aluminium oxide, Zinc oxide, calcium oxide, barium monoxide, form composite matt glaze agent;Zinc-aluminium high temperature forms spinelle, improves glaze paint opacity, adjusts light Damp degree, adjusts the high temperature levelability of glaze paint so that the more smooth exquisiteness of glaze paint.Suitable kaolin, oxygen are introduced in raw material of the present invention Change aluminium, zinc oxide, adjust glaze paint chemical composition, calcium is unglazed, barium is unglazed and zinc is unglazed adjusting in glaze, the mineral such as composite matt glaze agent Composition, reaches the smooth exquisiteness of glaze paint, the low purpose of glossiness.
The method of the present invention products obtained therefrom is compared with the similar product mutually having, its glaze paint is more moist, and glossiness is low, slightly Rugosity is in below 0.7um, and glossiness is between 10~20;Since glaze paint more flat smooth is fine and smooth, glossiness is low, and product glaze paint is high The defects of warm flow leveling is more preferable, more difficult generation pin hole, glossiness is low, injury of the more difficult generation to human eye; Gained sheen glaze product surface is more moist, and glossiness is low, is more suitable for the needs of modern people's consumption.
Embodiment
The present invention will be further described in detail with reference to the specific embodiments.
The sheen glaze of this glazed tile is using kaolin, zirconium silicate, aluminium oxide, burning talcum, albite, zinc oxide and melts Block is configured to siccative, then adds water to be modulated into glaze slip by siccative;Glazing can obtain glaze paint behind the surface of brick, sintering.It is described dry Material is matched by the mass percentage of following chemical compositions:SiO248~53%, Al2O311~15%, CaO 6~8%, MgO 0.5~1.5%, K2O 2~5%, Na2O 2~5%, B2O30.2~1%, BaO 5~8%, ZnO 10~13%, ZrO22~ 3%、Fe2O3≤0.2%、TiO2≤ 0.1%, surplus is impurity.325 purpose of glaze slip is tailed over as 0.1~0.4g/100ml, flow velocity For 50 milliliters of current meters 25~35 seconds, proportion was 1.85~1.90g/ml.
Embodiment 1-7:The sheen glaze and glaze noodle producing method of this glazed tile are using following with when technique.
(1)Composition proportion:It is configured to using kaolin, zirconium silicate, aluminium oxide, burning talcum, albite, zinc oxide and frit Siccative, the composition proportion of siccative is shown in Table 1 in each embodiment.
Table 1:The composition proportion of siccative in each embodiment(wt%)
In table 1, the surplus of each embodiment dry ingredients is impurity.
(2)Modulate glaze slip:Water is added to be modulated into glaze slip above-mentioned siccative.The index of glaze slip is shown in Table 2 obtained by each embodiment.
Table 2:The index of glaze slip obtained by each embodiment
The time that flow velocity described in table 2 flows to end for 50 milliliters of volumetric standards detection glaze slips.
(3)Glaze paint detects:Above-mentioned glaze slip glazing be can obtain into the glaze paint behind the surface of brick, sintering.To gained Glaze paint carries out complete detection analysis and summary, obtains the every overall target of table 3.
Table 3:The Testing index of each embodiment glaze paint
The interpretation of result detected from table 3 goes out:Common matting glaze 1, glaze paint pin hole is less, and glossiness is higher more than 20, roughness It is partially thick in more than 0.7um;Common matting glaze 2, glaze paint pin hole is less, and glossiness is below 20, but roughness is in more than 0.7um It is partially thick.Glaze paint pin hole obtained by this glaze is seldom, is better than common matting glaze, glossiness is between 10~20, while surface roughness In below 0.7um, it is better than common matting glaze;Seldom with glaze paint pin hole, glossiness is low, and surface roughness is low, and glaze paint is smooth thin The features such as greasy.

Claims (4)

1. the sheen glaze of a kind of glazed tile, it is characterised in that the chemical composition and mass percentage of its siccative be:SiO2 48 ~53%, Al2O311~15%, CaO 6~8%, MgO 0.5~1.5%, K2O 2~5%, Na2O 2~5%, B2O30.2~1%, BaO 5~8%, ZnO 10~13%, ZrO22~3%, Fe2O3≤0.2%、TiO2≤ 0.1%, surplus is impurity.
2. the sheen glaze of glazed tile according to claim 1, it is characterised in that:The raw material of the siccative for kaolin, Zirconium silicate, aluminium oxide, burn talcum, albite, zinc oxide and frit.
A kind of 3. glaze noodle producing method of glazed tile, using the glaze described in claim 1 or 2, it is characterised in that:The siccative Water is added to be modulated into glaze slip, glazing can obtain the glaze paint behind the surface of brick, sintering.
4. the glaze noodle producing method of glazed tile according to claim 3, it is characterised in that:325 purpose of glaze slip tails over For 0.1~0.4g/100ml, flow velocity is 50 milliliters of current meters 25~35 seconds, and proportion is 1.85~1.90g/ml.
CN201711295044.1A 2017-12-08 2017-12-08 The sheen glaze and glaze noodle producing method of glazed tile Pending CN108033682A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711295044.1A CN108033682A (en) 2017-12-08 2017-12-08 The sheen glaze and glaze noodle producing method of glazed tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711295044.1A CN108033682A (en) 2017-12-08 2017-12-08 The sheen glaze and glaze noodle producing method of glazed tile

Publications (1)

Publication Number Publication Date
CN108033682A true CN108033682A (en) 2018-05-15

Family

ID=62101482

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711295044.1A Pending CN108033682A (en) 2017-12-08 2017-12-08 The sheen glaze and glaze noodle producing method of glazed tile

Country Status (1)

Country Link
CN (1) CN108033682A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947251A (en) * 2018-09-02 2018-12-07 张家港市沐和新材料技术开发有限公司 A kind of glaze formula with antibiotic property
CN109231837A (en) * 2018-11-22 2019-01-18 东莞市唯美陶瓷工业园有限公司 A kind of surface enameling method of Ceramic Tiles and its Ceramic Tiles of preparation
CN111875415A (en) * 2020-08-11 2020-11-03 佛山市三水新明珠建陶工业有限公司 Method for manufacturing soft glazed ceramic chip
CN113387579A (en) * 2021-07-14 2021-09-14 福建省德化县帝窑陶瓷有限公司 Formula and manufacturing process of self-stretching high-smoothness transparent glaze slip

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02228485A (en) * 1989-02-28 1990-09-11 Ejiri Horo Kk Production of enameled cooker
CN101921136A (en) * 2010-04-13 2010-12-22 张垠 Raw material matting glaze
CN102491791A (en) * 2011-11-25 2012-06-13 广东道氏技术股份有限公司 Antique matte glaze with delicate texture and using method thereof
CN102557749A (en) * 2011-12-14 2012-07-11 谢健城 Formula of high-grade pottery matt glaze

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02228485A (en) * 1989-02-28 1990-09-11 Ejiri Horo Kk Production of enameled cooker
CN101921136A (en) * 2010-04-13 2010-12-22 张垠 Raw material matting glaze
CN102491791A (en) * 2011-11-25 2012-06-13 广东道氏技术股份有限公司 Antique matte glaze with delicate texture and using method thereof
CN102557749A (en) * 2011-12-14 2012-07-11 谢健城 Formula of high-grade pottery matt glaze

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108947251A (en) * 2018-09-02 2018-12-07 张家港市沐和新材料技术开发有限公司 A kind of glaze formula with antibiotic property
CN109231837A (en) * 2018-11-22 2019-01-18 东莞市唯美陶瓷工业园有限公司 A kind of surface enameling method of Ceramic Tiles and its Ceramic Tiles of preparation
CN109231837B (en) * 2018-11-22 2021-07-20 东莞市唯美陶瓷工业园有限公司 Surface glazing method of ceramic tile and ceramic tile prepared by same
CN111875415A (en) * 2020-08-11 2020-11-03 佛山市三水新明珠建陶工业有限公司 Method for manufacturing soft glazed ceramic chip
CN111875415B (en) * 2020-08-11 2022-11-11 佛山市三水新明珠建陶工业有限公司 Method for manufacturing soft glazed ceramic chip
CN113387579A (en) * 2021-07-14 2021-09-14 福建省德化县帝窑陶瓷有限公司 Formula and manufacturing process of self-stretching high-smoothness transparent glaze slip

Similar Documents

Publication Publication Date Title
CN108033682A (en) The sheen glaze and glaze noodle producing method of glazed tile
CN104140297B (en) The glaze of embossment phantom ornamental brick and preparation
CN101870593B (en) High-hardness self-cleaning glaze and preparation method thereof
CN109970342B (en) Matte high-antifouling glaze, ceramic tile and preparation method thereof
CN108395101A (en) A kind of low light exquisiteness glaze, glaze slip preparation method, glazed tile and preparation method
CN103964900B (en) A kind of sky blue furnace transmutation glaze formula and preparation method thereof
CN111848223B (en) Highly-antibacterial functional glazed brick and preparation method thereof
CN107857475A (en) A kind of ceramic whiteware glaze
CN106495742B (en) Anti- wax stone bonding glaze, anti-wax stone bonding ceramics and its preparation process
CN106830689A (en) A kind of preparation method of Sub-shine glaze sanitary ceramics
CN109133640A (en) A kind of wear-resisting dry granular and soft face antique porcelain brick of the soft face brick of waxy luster texture
CN105016787A (en) Matte background and glossy pattern glazed tile manufactured by using polished slag and preparation method of matte background and glossy pattern glazed tile
WO2015054805A1 (en) High whiteness underglaze multicolored low-temperature porcelain and preparation method
CN108726883A (en) A kind of preparation method of high abrasion domestic ceramics glaze
CN107344814A (en) A kind of sheen brick cover-coat enamel and sheen brick
CN107651938A (en) A kind of pottery and preparation method thereof
CN109384389A (en) A kind of manufacturing method of Antique Imitation Tiles clear frit
CN107573017A (en) A kind of technique for manufacturing stealthy decorative pattern ceramic
CN107352797A (en) Scagliola glaze and ceramic and preparation method with Scagliola glaze
CN107244908A (en) A kind of high white jade stone polished brick adobe and its ceramic tile preparation method
CN106517779A (en) Red glaze and preparation method thereof
US7037868B2 (en) Transparent tile glaze
CN105776863A (en) Mild satin glaze and manufacturing method thereof
CN108558442A (en) A kind of satin glaze and its preparation method and application
CN105330147B (en) A kind of preparation method of Bone China zinc silicate crystalline glaze material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180515