CN105330147B - A kind of preparation method of Bone China zinc silicate crystalline glaze material - Google Patents
A kind of preparation method of Bone China zinc silicate crystalline glaze material Download PDFInfo
- Publication number
- CN105330147B CN105330147B CN201510702105.6A CN201510702105A CN105330147B CN 105330147 B CN105330147 B CN 105330147B CN 201510702105 A CN201510702105 A CN 201510702105A CN 105330147 B CN105330147 B CN 105330147B
- Authority
- CN
- China
- Prior art keywords
- glaze
- bone
- bone china
- base
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The present invention relates to a kind of Bone China preparation methods of zinc silicate crystalline glaze material, belong to Bone China production technical field.Technical solution is: in Bone China base glaze, suitable SiO is added2, suitable seed content ZnO, TiO is added2, suitable colour former metal oxide is added.Each component raw material is weighed into mixing according to the proportion, ball milling, cross 250 meshes, tail over < 0.3%, the glaze that will be sieved again is imposed on spare plain bone base by the method for leaching glaze or leaching glaze, and then, the glazing element bone base after drying is placed in kiln, it is fired according to specific sintering curve, obtains Bone China Products of Crystalline Glaze.The beneficial effects are mainly reflected as follows: innovatively propose a kind of preparation method of Bone China crystalline glaze material, brilliant glaze paint whole, that color is beautiful of using up is formd on Bone China, it is combined with the feature of Bone China light transmission, exquisiteness, smoothness, reach strong artistic effect, meets the new demand in market.
Description
Technical field
The present invention relates to a kind of Bone China preparation methods of zinc silicate crystalline glaze material, belong to Bone China production technology neck
Domain.
Background technique
Bone China abbreviation china, scientific name bone china is with the bone black of animal, clay, feldspar and quartz for base stock, warp
Cross a kind of porcelain made of high temperature biscuiting and low temperature sinter are fired twice.Bone China is because it is good with translucency, whiteness is high, porcelain
Fine and smooth, the features such as glaze paint is smooth, become popular among consumers high-grade porcelain, for a long time always various countries noble porcelain.But
Bone China porcelain crisp fritter, hardness and toughness are poor, and which limits application of some decoration techniques on Bone China.Crystalline glaze is
One kind having gorgeous color, and the artistic glaze of different flavor, the patent in relation to crystalline glaze is relatively more, but not yet finds Bone China at present
The report of upper crystalline glaze, therefore the crystalline glaze studied on Bone China is very necessary, it will the shape of prosperity and brand to Bone China
At playing booster action.
Summary of the invention
The purpose of the present invention is intended to provide a kind of preparation method of Bone China zinc silicate crystalline glaze material, the shape on Bone China
The complete zinc silicate crystalline glaze of Cheng Jinghua increases a kind of new trailing for Bone China.
The technical scheme is that a kind of preparation method of Bone China with zinc silicate crystalline glaze material, on Bone China basis
In glaze, suitable SiO2 is added, suitable seed content ZnO, TiO2 is added, suitable colour former metal oxide is added, respectively
Weight percentages of components are as follows: SiO2 10~30%, ZnO 10~30%, TiO2 1~5%, colour former 1~5%, remaining is base
Plinth glaze.Glaze is mixed, ball milling crosses 250 meshes, tails over < 0.3%, then the glaze that will be sieved is applied by the method for leaching glaze or leaching glaze
In on plain bone base；Sintering curve are as follows: kiln temperature is at the uniform velocity risen to 1230 DEG C of 5~20min of holding in 3~8h by room temperature, then
Drop to 1080 DEG C in 20min and keep 30~180min, then drop quickly in 15~20min 850 DEG C keep 10~
30min, last cooled to room temperature.
Plain bone base preparation process are as follows: Bone China moulded pottery not yet put in a kiln to bake is burnt at 850~1000 DEG C, is kept 30min, is obtained plain bone base, standby
With.
Glaze preparation process are as follows: weigh raw material respectively according to formula, make to expect: ball: the ratio 1:1.5:0.8 of water, then
The ball milling in planetary ball mill, Ball-milling Time are 20~60min, cross 250 meshes, tail over < 0.3%, the concentration for adjusting glaze slip is
50~70 Baume degrees.
Glazing process are as follows: impose on the crystalline glaze material prepared on plain bone base with leaching glaze or glaze pouring method, glazed thickness is
0.5~2mm, naturally dry.
Sintering curve are as follows: the glazing element bone base after drying is placed in kiln and is burnt into, kiln temperature is in 3~8h by room temperature
1230 DEG C of 5~20min of holding are at the uniform velocity risen to, 1080 DEG C are then dropped in 20min and keep 30~180min, then 15~
850 DEG C of 10~30min of holding are dropped quickly in 20min, last cooled to room temperature obtains product.
The present invention provides three requirements that zinc silicate crystalline glaze is formed on Bone China: one is suitable for crystalline glaze
The plain bone base firing temperature of glazing；Second is that there is the excessive ZnO that hypersaturated state is presented under maximum sintering temperature in glaze；Three
It is the cooling insulating process for thering is suitable nucleus to be formed with growth and development in calcining system.Therefore, corresponding critical process is: unique
Bone China crystalline glaze material formula and specific calcining system, the control of especially cooling and insulating process.
The beneficial effects of the present invention are: a kind of preparation method of Bone China zinc silicate crystalline glaze material is provided, in sclerotin
Crystalline substance is formd on porcelain and spends complete zinc silicate crystalline glaze, meets the new demand of Bone China decoration.
Detailed description of the invention
Fig. 1 is the appearance diagram of the embodiment of the present invention.
Specific embodiment
With reference to the accompanying drawing, by embodiment, the present invention will be further described.
A kind of Bone China preparation method of zinc silicate crystalline glaze material, comprises the following steps:
1, ingredient
It selects traditional Chinese medicines to analyze pure SiO2, analyzes pure ZnO, the pure TiO2 of analysis, analyze pure CuO, be added in Bone China base glaze,
Specific mass percent are as follows: SiO2 20%, ZnO 20%, TiO2 1%, CuO 1.5%, base glaze 57.5%.
2, preparation method
1) glaze slip preparation process are as follows: weigh raw material respectively according to formula, make to expect: ball: the ratio of water is equal to 1:1.5:0.8,
Then the ball milling in planetary ball mill, Ball-milling Time 30min cross 250 meshes, tail over < 0.3%, the concentration for adjusting glaze slip is
53 Baume degrees.
2) glazing process are as follows: moulded pottery not yet put in a kiln to bake biscuiting temperature is 950 DEG C, is imposed on glaze slip on plain bone base with leaching glaze or waterfall process, glaze
Layer is burnt into after natural drying with a thickness of 1.5mm.
3) sintering curve are as follows: the glazing element bone base after drying is placed in kiln, at the uniform velocity rises to 1230 by room temperature in 5h
DEG C, 10min is kept, then chilling 10min, makes temperature drop to 1080 DEG C and keeps 120min, last cooled to room temperature,
Obtain product.
The present invention is suitble to Bone China glaze decorating, and crystalline glaze is creatively applied to Bone China production, enriches sclerotin
The form of expression of porcelain；The smooth soft, novel appearance of sclerotin porcelain products glaze paint produced by the invention, best in quality, market prospects are wide
It is wealthy, there is significant economic benefit and social benefit.
Claims (2)
1. a kind of Bone China preparation method of zinc silicate crystalline glaze material, comprises the following steps:
1. Bone China moulded pottery not yet put in a kiln to bake is burnt at 850~1000 DEG C, 30min is kept, plain bone base is obtained, it is spare；
2. suitable SiO is added in Bone China base glaze2, suitable ZnO, TiO is added2As seed content, it is added appropriate
Colour former metal oxide；Wherein weight percentage of each component are as follows: SiO210~30%, ZnO 10~30%, TiO21~
5%, colour former 1~5%, the base glaze in conjunction with surplus is absolutely；Above-mentioned material is mixed into ball in planetary ball mill
Mill, Ball-milling Time are 20~60min, cross 250 meshes, tail over < 0.3%；It is 50~70 Baume degrees by the Concentration Modulation of glaze slip；
3. the glaze that will be sieved is imposed on plain bone base by the method for leaching glaze or leaching glaze, glazed thickness is 0.5~2mm, naturally dry；
It is burnt into 4. the glazing element bone base after drying is placed in kiln, sintering curve are as follows:
A. kiln temperature is at the uniform velocity risen to 1230 DEG C in 3~8h by room temperature, and keeps 5~20min；
B. 1080 DEG C are then dropped in 20min, and keep 30~180min；
C. 850 DEG C are dropped quickly in 15~20min again, keeps 10~30min；Last cooled to room temperature, is produced
Product.
2. the Bone China according to claim 1 preparation method of zinc silicate crystalline glaze material, it is characterised in that: raw material carries out
When ball milling, in material: ball: the proportion that the ratio of water is 1:1.5:0.8 carries out ball milling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510702105.6A CN105330147B (en) | 2015-10-27 | 2015-10-27 | A kind of preparation method of Bone China zinc silicate crystalline glaze material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510702105.6A CN105330147B (en) | 2015-10-27 | 2015-10-27 | A kind of preparation method of Bone China zinc silicate crystalline glaze material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105330147A CN105330147A (en) | 2016-02-17 |
| CN105330147B true CN105330147B (en) | 2019-02-12 |
Family
ID=55280950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510702105.6A Active CN105330147B (en) | 2015-10-27 | 2015-10-27 | A kind of preparation method of Bone China zinc silicate crystalline glaze material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105330147B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107500538A (en) * | 2017-10-16 | 2017-12-22 | 齐齐哈尔大学 | The method that crystalline glaze is prepared with Yian kaolin |
| CN111606702A (en) * | 2020-04-28 | 2020-09-01 | 潮州市长城世家瓷业有限公司 | High-stability zinc silicate positioning crystalline ceramic and manufacturing process thereof |
| CN114956560B (en) * | 2022-06-17 | 2023-11-03 | 景德镇欧神诺陶瓷有限公司 | Crystal glaze, preparation method thereof and crystal glaze ceramic product |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101037296A (en) * | 2007-04-25 | 2007-09-19 | 山东茂华硅工有限公司 | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
-
2015
- 2015-10-27 CN CN201510702105.6A patent/CN105330147B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101037296A (en) * | 2007-04-25 | 2007-09-19 | 山东茂华硅工有限公司 | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
Non-Patent Citations (1)
| Title |
|---|
| 辊道窑快烧结晶釉的制备与晶体形貌分析;朱小平等;《中国陶瓷》;20050630;第41卷(第3期);第21-24页，第71页， |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105330147A (en) | 2016-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109455933B (en) | Crystalline glaze and ceramic tile prepared from same | |
| CN109231824B (en) | Method for manufacturing black golden fancy glaze ceramic | |
| CN105294088B (en) | The preparation process of mud Xing Juntao | |
| CN103588507B (en) | White-dotted stereoscopic decorative glazed ceramic product and preparation method thereof | |
| CN105753322A (en) | Medium-temperature plum green glaze and medium-temperature plum green Longquan celadon | |
| CN103232225B (en) | Method for preparing colorful leaf-temmoku porcelain and product prepared from colorful leaf-temmoku porcelain | |
| CN106396638B (en) | Low temperature lightweight lime gradual change glaze ceramics and its manufacture craft | |
| CN105776866B (en) | Longquan celadon jasper green glaze, the green Longquan celadon of jasper and preparation method thereof | |
| CN102249654A (en) | Ancient blue and white porcelain and production method thereof | |
| CN109455934B (en) | Ceramic tile with stream color decoration effect and preparation method thereof | |
| CN103601534A (en) | High-whiteness under-glaze colorful low-temperature ceramic and preparation method thereof | |
| CN113773118B (en) | Jun porcelain overglaze color drawing process | |
| CN103332966A (en) | Preparation method of composite opaque glaze | |
| CN105330147B (en) | A kind of preparation method of Bone China zinc silicate crystalline glaze material | |
| CN106565094A (en) | Flambe furry tiger skin fancy glaze, ceramic product and preparation method thereof | |
| CN106219976B (en) | A kind of combined decoration metallic Ceramic Tiles and its manufacturing method | |
| CN107793031A (en) | High temperature burr glaze and preparation method thereof | |
| CN107382067B (en) | Rust glaze, rust glaze ceramic product prepared from rust glaze and preparation method of rust glaze ceramic product | |
| CN106396618B (en) | A kind of reducing atmosphere fires the manufacturing method of high temperature matt Zijin vitreous enamel | |
| CN104987137A (en) | Method for applying rabbit-hair-like glaze on ceramic body | |
| CN104876442B (en) | Turquoise glaze for colored pottery products | |
| CN107586038B (en) | Process for preparing jun porcelain from green and white glaze for jun porcelain | |
| CN104446344A (en) | Preparation method of slim mirror-plane artistic porcelain painting and product prepared by preparation method | |
| CN110342823B (en) | Fertilizer Bai Youtao porcelain and preparation method thereof | |
| CN108129028B (en) | Glittering and translucent thick-glaze ceramic product and manufacturing process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |