CN101037296A - Ferric titanium dull kiln star spot variable composite color material and star spot glaze - Google Patents
Ferric titanium dull kiln star spot variable composite color material and star spot glaze Download PDFInfo
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- CN101037296A CN101037296A CN 200710014374 CN200710014374A CN101037296A CN 101037296 A CN101037296 A CN 101037296A CN 200710014374 CN200710014374 CN 200710014374 CN 200710014374 A CN200710014374 A CN 200710014374A CN 101037296 A CN101037296 A CN 101037296A
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- glaze
- starred
- ferrotitanium
- transmutation
- unglazed
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Abstract
The invention relates to starred composite pigment material and a starred glaze in a ferrotitanium dark kiln with a composition of composite pigment material by wt.% is: Fe2O3 30-60%, Al2O3 5-20%, TiO2 10-30% and ZnO 5-20%; a composition of material of the starred glaze by wt.% is: albite 30-60%, quartz 5-15%, stalactite 5-15%, alumina 5-15%, barium carbonate 5-20%, zinc oxide 5-15%, SuZhou soil 1-5%, talcum 3-8%, and composite pigment 5-20%. The invention produces the pigment by co-reacting the ferric oxidepigment and titanium oxide and other materials with a low cost. The advantages of pigment are that chemical activity is great and the colour generation is stable. The starred glaze product is made by conventional ceramic glazing system with a good quality and a nice decoration effect. The starred is naturally formed by co-reacting of a seeding agent and other flux material in a high temperature and is baked under the oxidation atmosphere by tunnel kiln so it is simple-produced and simple-controlled.
Description
Technical field
The present invention relates to a kind of ferrotitanium compound colorant of unglazed transmutation asterism and starred glaze, belong to the ceramic technology field.
Background technology
The ceramic decoration art, the same with Production of Ceramics of long standing and well established, be an important component part of beautifying ceramic, along with the raising of people's living standard, also more and more higher to the decoration requirement of ceramic product.
Starred glaze product on the market all is to adopt specking or particle method to carry out glazing production, and technology is loaded down with trivial details, and production efficiency is low, and the rare close degree of asterism is indefinite, and appearance effect is difficult consistent.
The transmutation glaze product in an ancient unit of weight kiln, Ruyao etc. mostly is reducing atmosphere and burns till, and burns till to require height, and the control difficulty is big, is difficult to satisfy the requirement of domestic ceramic product scale operation.
Summary of the invention
The object of the present invention is to provide a kind of ferrotitanium compound colorant of unglazed transmutation asterism and starred glaze, preparation, control are easy, constant product quality, and good decorating effect is fit to scale operation.
Ferrotitanium of the present invention the is unglazed compound colorant of transmutation asterism, its ingredients by weight percentage composition is:
Fe
2O
330～60%, Al
2O
35～20%, TiO
210～30% and ZnO 5～20%.
The same with common colorant preparation technology, after high-temperature calcination, make, 1250～1300 ℃ of calcining temperatures, by high-temperature calcination synthetic spinel colorant, color and luster is good, stable performance, good decorating effect.
Ferrotitanium is unglazed transmutation starred glaze, the compound colorant of being made up of 5～20% weight percent and the parent glaze of surplus are made, and wherein the glaze formula of parent glaze is:
With SiO in the glaze formula of parent glaze
2/ Al
2O
3Be controlled at 3～6, can obtain unglazed overglaze and set off effect.
Its ingredients by weight percentage composition is:
Albite 30～60%, quartz 5～15%, Stalactitum 5～15%, aluminum oxide 5～15%, barium carbonate 2～10%, zinc oxide 5～15%, Suzhou soil 1～5%, talcum 3～8% and compound colorant 5～20%.
Ferrotitanium of the present invention is unglazed transmutation starred glaze can adopt traditional ceramic enamel frit makeing, glazing process to prepare the starred glaze product, and preparation, control are easy, are burnt till by tunnel furnace oxidizing atmosphere, and 1190～1210 ℃ of firing temperatures are fit to scale operation.
Ferric oxide and titanium oxide are two kinds of traditional ceramic glaze raw materials, price is low, be widely used, but all be to use both at home and abroad in the Production of Ceramics as general raw material, the present invention then is by ferric oxide and titanium oxide and the common reaction of other raw material are made colorant, colorant have chemically reactive big, be colour-stable characteristics, prepare glaze then, the asterism effect of seed content and other flux raw material acting in conjunction at high temperature, formation nature.Constant product quality, good decorating effect.
Embodiment
The invention will be further described below in conjunction with embodiment.
Test raw materials used composition and see Table 1.
Table 1, the raw materials used chemical weight percentage composition of test:
Remarks: the ferric oxide that uses in the compound colorant, aluminum oxide, titanium oxide, zinc oxide are technical pure chemical industry raw material.
Embodiment 1
Ferrotitanium of the present invention is unglazed, and compound colorant ingredients by weight percentage composition of transmutation asterism and the situation of burning till see Table 2.
Table 2, the percentage composition of compound colorant ingredients by weight and burn till information slip
| Specimen coding | Proportioning raw materials (weight percent) | Calcining temperature | Firing atmosphere | |||
| Fe 2O 3 | TiO 2 | Al 2O 3 | ZnO | |||
| A1 | 55％ | 25％ | 8％ | 12％ | 1260℃ | Oxidation |
The same with common colorant preparation, after high-temperature calcination, make, preparation process is as follows:
(1) grog preparation:
Ball milling: material: ballstone: water=1: 2: 1.5;
Fineness: 250 mesh sieves tail over less than 0.08%;
Oven dry: use iron drying baker, duty to stir, avoid sintering;
Burn till: oxidizing atmosphere, shuttle kiln, 1260 ℃ of top temperatures.
(2) grog fine grinding:
Ball milling: grog: ballstone: water=1: 2: 1;
Fineness: 250 mesh sieves tail over less than 0.05%;
Oven dry: use iron drying baker, duty to stir, avoid sintering, finished product colorant moisture is no more than 1%.
The compound colorant that ferrotitanium of the present invention is unglazed transmutation starred glaze is made up of 10% weight percent and the parent glaze of surplus are made, and wherein the glaze formula of parent glaze is:
Concrete ingredients by weight percentage composition sees Table 3.
Table 3, ferrotitanium of the present invention is unglazed transmutation starred glaze ingredients by weight percentage composition table
| Raw material | Albite | Quartzy | Stalactitum | Aluminum oxide | Barium carbonate | Zinc oxide | Suzhou soil | Talcum | Compound colorant |
| Content | 45％ | 3％ | 12％ | 5％ | 16％ | 3％ | 3％ | 3％ | 10％ |
The glaze preparation:
Ball milling: material: ballstone: water=1: 2: 0.8;
Fineness: 250 mesh sieves tail over less than 0.09%;
Burn till after the glazing: small cross-section tunnel furnace, oxidizing atmosphere, firing temperature: 1200 ℃.
The glaze that burns till the back product is simple and elegant iron oxide red, and asterism is a milk yellow.
Embodiment 2
Compound colorant ingredients by weight of the present invention percentage composition and the situation of burning till see Table 4.
Table 4, the percentage composition of compound colorant ingredients by weight and burn till information slip
| Specimen coding | Proportioning raw materials (weight percent) | Calcining temperature | Firing atmosphere | |||
| Fe 2O 3 | TiO 2 | Al 2O 3 | ZnO | |||
| B3 | 50％ | 30％ | 10％ | 10％ | 1280℃ | Oxidation |
The compound colorant that ferrotitanium of the present invention is unglazed transmutation starred glaze is made up of 8% weight percent and the parent glaze of surplus are made, and wherein the glaze formula of parent glaze is:
Ferrotitanium of the present invention is unglazed, and the percentage composition of transmutation starred glaze ingredients by weight sees Table 5.
Table 5, ferrotitanium of the present invention is unglazed transmutation starred glaze ingredients by weight percentage composition table
| Raw material | Albite | Quartzy | Stalactitum | Aluminum oxide | Barium carbonate | Zinc oxide | Suzhou soil | Talcum | Compound colorant |
| Content | 40％ | 12％ | 8％ | 10％ | 5％ | 8％ | 3％ | 6％ | 8％ |
Colorant and glaze preparation technology are with embodiment 1, and the firing temperature of starred glaze is 1190 ℃.
The glaze that burns till the back product is shallow brown, and asterism is pale yellow and be broken needle shape.
Embodiment 3
The present invention's compound colorant ingredients by weight percentage composition and the situation of burning till see Table 6.
Table 6: compound colorant ingredients by weight percentage composition and burn till information slip
| Specimen coding | Proportioning raw materials (weight percent) | Calcining temperature | Firing atmosphere | |||
| Fe 2O 3 | TiO 2 | Al 2O 3 | ZnO | |||
| D5 | 40％ | 40％ | 12％ | 8％ | 1300℃ | Oxidation |
The compound colorant that ferrotitanium of the present invention is unglazed transmutation starred glaze is made up of 12% weight percent and the parent glaze of surplus are made, and wherein the glaze formula of parent glaze is:
Ferrotitanium of the present invention is unglazed, and the percentage composition of transmutation starred glaze ingredients by weight sees Table 7.
Table 7, ferrotitanium of the present invention is unglazed transmutation starred glaze ingredients by weight percentage composition table
| Raw material | Albite | Quartzy | Stalactitum | Aluminum oxide | Barium carbonate | Zinc oxide | Suzhou soil | Talcum | Compound colorant |
| Content | 42％ | 12％ | 6％ | 10％ | 4％ | 8％ | 3％ | 3％ | 12％ |
Colorant and glaze preparation technology are with embodiment 1, and the firing temperature of starred glaze is 1210 ℃.
The glaze that burns till the back product is chocolate, and asterism is faint yellow.
Embodiment 4
Ferrotitanium of the present invention the is unglazed compound colorant of transmutation asterism, the ingredients by weight percentage composition is:
Fe
2O
335%, Al
2O
320%, TiO
230% and ZnO 15%.
Ferrotitanium is unglazed transmutation starred glaze, the ingredients by weight percentage composition is:
Albite 33%, quartz 10%, Stalactitum 8%, aluminum oxide 9%, barium carbonate 8%, zinc oxide 10%, Suzhou soil 2%, talcum 5% and compound colorant 15%.
Other is with embodiment 1.
Embodiment 5
Ferrotitanium of the present invention the is unglazed compound colorant of transmutation asterism, the ingredients by weight percentage composition is:
Fe
2O
358%, Al
2O
318%, TiO
211% and ZnO 13%.
Ferrotitanium is unglazed transmutation starred glaze, the ingredients by weight percentage composition is:
Albite 37%, quartz 8%, Stalactitum 12%, aluminum oxide 10%, barium carbonate 10%, zinc oxide 5%, Suzhou soil 5%, talcum 5% and compound colorant 8%.
Other is with embodiment 1.
Embodiment 6
Ferrotitanium of the present invention the is unglazed compound colorant of transmutation asterism, the ingredients by weight percentage composition is:
Fe
2O
349%, Al
2O
317%, TiO
216% and ZnO 18%.
Ferrotitanium is unglazed transmutation starred glaze, the ingredients by weight percentage composition is:
Albite 45%, quartz 12%, Stalactitum 8%, aluminum oxide 8%, barium carbonate 5%, zinc oxide 6%, Suzhou soil 3%, talcum 3% and compound colorant 10%.
Other is with embodiment 1.
Claims (4)
1, the compound colorant of the unglazed transmutation asterism of a kind of ferrotitanium is characterized in that the ingredients by weight percentage composition is:
Fe
2O
330～60%, Al
2O
35～20%, TiO
210～30% and ZnO 5～20%.
2, the unglazed transmutation starred glaze of a kind of ferrotitanium is characterized in that the compound colorant be made up of the 5-20% weight percent and the parent glaze of surplus make, and wherein the glaze formula of parent glaze is:
3, the unglazed transmutation starred glaze of ferrotitanium according to claim 2 is characterized in that SiO in the glaze formula of parent glaze
2/ Al
2O
3=3～6.
4,, it is characterized in that its ingredients by weight percentage composition is according to claim 2 or the unglazed transmutation starred glaze of 3 described ferrotitaniums:
Albite 30～60%, quartz 5～15%, Stalactitum 5～15%, aluminum oxide 5～15%, barium carbonate 5～20%, zinc oxide 5～15%, Suzhou soil 1～5%, talcum 3～8% and compound colorant 5～20%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710014374A CN100594192C (en) | 2007-04-25 | 2007-04-25 | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710014374A CN100594192C (en) | 2007-04-25 | 2007-04-25 | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101037296A true CN101037296A (en) | 2007-09-19 |
| CN100594192C CN100594192C (en) | 2010-03-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710014374A Expired - Fee Related CN100594192C (en) | 2007-04-25 | 2007-04-25 | Ferric titanium dull kiln star spot variable composite color material and star spot glaze |
Country Status (1)
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|---|---|
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617187A (en) * | 2012-03-16 | 2012-08-01 | 湖南港鹏实业有限公司 | Process for producing black pigment ceramic at high temperature |
| CN102617189A (en) * | 2012-03-31 | 2012-08-01 | 山东万乔集团有限公司 | Enameled brick for oven door of coke oven |
| CN103553715A (en) * | 2013-10-08 | 2014-02-05 | 东莞市高诚陶瓷制品有限公司 | Oxidation reaction glaze material |
| CN105330147A (en) * | 2015-10-27 | 2016-02-17 | 唐山工业职业技术学院 | Preparation method of zinc silicate crystal glaze for bone china |
| CN108529878A (en) * | 2018-06-14 | 2018-09-14 | 江西嘉顺瓷业有限公司 | A kind of low bulk sesame point glaze and preparation method thereof |
| CN113480168A (en) * | 2021-07-01 | 2021-10-08 | 醴陵陶润实业发展有限公司 | Practical decorative particles and preparation method thereof |
-
2007
- 2007-04-25 CN CN200710014374A patent/CN100594192C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617187A (en) * | 2012-03-16 | 2012-08-01 | 湖南港鹏实业有限公司 | Process for producing black pigment ceramic at high temperature |
| CN102617187B (en) * | 2012-03-16 | 2014-04-09 | 湖南港鹏实业有限公司 | Process for producing black pigment ceramic at high temperature |
| CN102617189A (en) * | 2012-03-31 | 2012-08-01 | 山东万乔集团有限公司 | Enameled brick for oven door of coke oven |
| CN103553715A (en) * | 2013-10-08 | 2014-02-05 | 东莞市高诚陶瓷制品有限公司 | Oxidation reaction glaze material |
| CN105330147A (en) * | 2015-10-27 | 2016-02-17 | 唐山工业职业技术学院 | Preparation method of zinc silicate crystal glaze for bone china |
| CN105330147B (en) * | 2015-10-27 | 2019-02-12 | 唐山工业职业技术学院 | A kind of preparation method of Bone China zinc silicate crystalline glaze material |
| CN108529878A (en) * | 2018-06-14 | 2018-09-14 | 江西嘉顺瓷业有限公司 | A kind of low bulk sesame point glaze and preparation method thereof |
| CN113480168A (en) * | 2021-07-01 | 2021-10-08 | 醴陵陶润实业发展有限公司 | Practical decorative particles and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100594192C (en) | 2010-03-17 |
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Granted publication date: 20100317 Termination date: 20120425 |