CN108914558A - 一种复合型纳米抗静电纤维面料的制备方法 - Google Patents
一种复合型纳米抗静电纤维面料的制备方法 Download PDFInfo
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Abstract
发明公开了一种复合型纳米抗静电纤维面料的制备方法,以抗氧剂1010、硬脂酸锌、碳纳米管等为原料,并引入凹凸棒土‑ZIF‑67/TiO2复合材料,通过超声处理、浸渍、物理复配等方法制备了一种复合型纳米抗静电纤维面料。本发明制备的复合型纳米抗静电纤维面料具有优异的抗静电性能,并且面料柔软舒适,绿色安全。
Description
技术领域
本发明属于纺织材料技术领域,具体涉及一种复合型纳米抗静电纤维面料。
背景技术
随着国民经济的发展,我国合成纤维的产量迅速剧增,纺织静电问题就日益尖锐起来。在我国北方秋冬季节等一些比较干燥的地区,存在的静电问题特别突出,静电危害较大,更可能对人们的生活造成重大影响。静电在人体的积累可能影响到各个脏器,尤其是心脏的正常工作,从而引发心率异常和心脏早搏;身体上的静电还可能诱发老、幼、病、孕人群的各种疾病。例如,静电可使孕妇激素水平下降,继而引发流产或早产;在儿童体内积累的静电可能影响中枢神经及机体的生理平衡。基于日渐旺盛的市场需求,如何制备高性能的抗静电纤维面料,避免合成纤维的静电危害成为学术界十分关注的话题。
现有的抗静电纤维的主要有两类:(1)非永久性抗静电纤维;(2)永久性导电/抗静电纤维。采用填充无机、金属或金属氧化物等导电填料制备永久性导电/抗静电纤维,该纤维具有持久抗静电性和优良的抗静电效果。添加长链烷烃的两亲性抗静电剂,使用共混纺丝技术制备抗静电纤维是工业上较为普遍的方法之一,两亲性物质在聚合物纤维吸附水膜,实现聚合物纤维的抗静电效果。在20世纪60年代,杜邦公司和东丽公司采用聚乙二醇等高分子抗静电剂,成功的将共混型抗静电聚合物纤维工业化。由于该纤维具有优秀的抗静电效果以及良好的可染色性能,因此成为工业上制备抗静电复合纤维最为普遍的方法。本发明以抗氧剂1010、硬脂酸锌、碳纳米管等为原料,并引入凹凸棒土- ZIF-67/TiO2复合材料,制备了一种抗静电性能优异的复合型纳米抗静电纤维面料。
发明内容
本发明的目的在于提供一种复合型纳米抗静电,绿色安全的纺织面料及其制备方法。
一种复合型纳米抗静电纤维面料的制备方法,其特征在于该方法包括以下步骤:
1)称取12重量份抗氧剂1010、25重量份抗氧剂DLTP、7重量份硬脂酸锌、16重量份碳纳米管于反应釜中,加入90重量份无水乙醇,磁力搅拌2h,混合均匀后在磁场作用下通入氩气吹扫1~2h,升温至65~70℃,在350W功率下超声波处理30min,将得到的溶液过滤,取其滤液,备用;
2)取58~98重量份上述步骤1)中得到的滤液,加入12~52重量份凹凸棒土- ZIF-67/TiO2复合材料,20重量份无水乙醇,磁力搅拌2h后得到抗静电处理液,取15份腈纶纤维浸渍于上述抗静电处理液中,65℃超声振荡2h,反应结束后挤去多余的处理液,使得处理液和腈纶纤维的总重为30份,置于烘箱中102℃下烘干2h,得到复合型纳米抗静电纤维面料。
有益效果:本发明提供一种复合型纳米抗静电纤维面料的制备方法,制备过程中引入凹凸棒土- ZIF-67/TiO2复合材料,经过其处理的纤维面料比电阻可大大减小,且与硬脂酸锌、金属有机骨架ZIF-67粉末等材料复配使用可有效提高面料的导电性能,防止静电产生,且该面料制备过程环保节能,面料柔软舒适,绿色安全。
具体实施方式
实施例1
1)称取12重量份抗氧剂1010、25重量份抗氧剂DLTP、7重量份硬脂酸锌、16重量份碳纳米管于反应釜中,加入90重量份无水乙醇,磁力搅拌2h,混合均匀后在磁场作用下通入氩气吹扫1~2h,升温至65~70℃,在350W功率下超声波处理30min,将得到的溶液过滤,取其滤液,备用;
2)取83重量份上述步骤1)中得到的滤液,加入27重量份凹凸棒土- ZIF-67/TiO2复合材料,20重量份无水乙醇,磁力搅拌2h后得到抗静电处理液,取15份腈纶纤维浸渍于上述抗静电处理液中,65℃超声振荡2h,反应结束后挤去多余的处理液,使得处理液和腈纶纤维的总重为30份,置于烘箱中102℃下烘干2h,得到复合型纳米抗静电纤维面料。
上述凹凸棒土- ZIF-67/TiO2复合材料制备方法如下:
称取27重量份三油酸甘油酯置于三口烧瓶中,加入60重量份异丙醇,磁力搅拌4h后升温至80℃时,用滴液漏斗向三口烧瓶内缓慢滴加120重量份质量分数为16%的氯乙酸钠溶液,用氢氧化钠调节反应体系的pH值在7.5~8.5之间,保温反应4h,自然冷却,向烧瓶中加入14重量份纳米级钛白粉、20重量份凹凸棒土、6重量份金属有机骨架ZIF-67粉末,在75℃下恒温反应3h,离心分离后在微波消解仪下140℃微波处理2h,65℃真空干燥12h,冷却,得到凹凸棒土- ZIF-67/TiO2复合材料。
实施例2
与实施例1完全相同,不同在于:加入58重量份滤液,52重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例3
与实施例1完全相同,不同在于:加入63重量份滤液,47重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例4
与实施例1完全相同,不同在于:加入68重量份滤液,42重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例5
与实施例1完全相同,不同在于:加入73重量份滤液,37重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例6
与实施例1完全相同,不同在于:加入78重量份滤液,32重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例7
与实施例1完全相同,不同在于:加入88重量份滤液,60重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例8
与实施例1完全相同,不同在于:加入93重量份滤液,17重量份凹凸棒土- ZIF-67/TiO2复合材料。
实施例9
与实施例1完全相同,不同在于:加入98重量份滤液,12重量份凹凸棒土- ZIF-67/TiO2复合材料。
对比例1
与实施例1完全相同,不同在于:制备抗静电纤维面料时不加入凹凸棒土- ZIF-67/TiO2复合材料。
对比例2
与实施例1完全相同,不同在于:制备抗静电纤维面料时用未经处理的凹凸棒土代替凹凸棒土- ZIF-67/TiO2复合材料。
对比例3
与实施例1完全相同,不同在于:制备复合材料时不加入金属有机骨架ZIF-67粉末。
对比例4
与实施例1完全相同,不同在于:制备凹凸棒土- ZIF-67/TiO2复合材料时不调节pH值。
对比例5
与实施例1完全相同,不同在于:制备复合材料时不加入TiO2。
对比例6
与实施例1完全相同,不同在于:制备该抗静电纤维面料时不加入抗氧剂DLTP。
对比例7
与实施例1完全相同,不同在于:制备该抗静电纤维面料时不加入硬脂酸锌。
对比例8
与实施例1完全相同,不同在于:制备该抗静电纤维面料时不进行超声波处理。
对比例9
与实施例1完全相同,不同在于:制备该抗静电纤维面料时不通入氩气吹扫。
将实施例1~9与对比例1~9制备的抗静电纤维面料,放在恒温恒湿实验室中平衡24h后进行比电阻值的测定,并按下式计算比电阻:
式中,R为测量的电阻(MΩ);f为腈纶的标准填充度,f = 0.27。
抗静电纤维面料性能测试结果
由实施例1~9可以发现,当在实施例1所处于配比环境中,制得的复合型纳米抗静电纤维面料抗静电性能最佳,比电阻仅为1.45MΩ·cm,而是实施例2~9制备的抗静电纤维面料抗静电性能不是特别理想,其比电阻值均在30~70MΩ·cm之间,可见其原料的配比对抗静电纤维面料的抗静电性能有着巨大的影响,实施例1的配比产生了出乎意料的抗静电效果,可见在实施例1所述的原料配比下制备的抗静电纤维面料,提取的滤液与凹凸棒土- ZIF-67/TiO2复合材料等几种物质间结构框架协同性最好, 大幅度提高了抗静电效果,因而得到的抗静电纤维面料抗静电性能最优异。另外对比例1~5说明凹凸棒土- ZIF-67/TiO2复合材料的加入对抗静电纤维面料性能影响较大,对比例6~9说明制备抗静电纤维面料原料及条件的选择对其抗静电性能有突出影响。
Claims (6)
1.一种复合型纳米抗静电纤维面料的制备方法,其特征在于该方法包括以下步骤:
1)称取12重量份抗氧剂1010、25重量份抗氧剂DLTP、7重量份硬脂酸锌、16重量份碳纳米管于反应釜中,加入90重量份无水乙醇,磁力搅拌2h,混合均匀后在磁场作用下通入氩气吹扫1~2h,升温至65~70℃,在350W功率下超声波处理30min,将得到的溶液过滤,取其滤液,备用;
2)取58~98重量份上述步骤1)中得到的滤液,加入12~52重量份凹凸棒土- ZIF-67/TiO2复合材料,20重量份无水乙醇,磁力搅拌2h后得到抗静电处理液,取15份腈纶纤维浸渍于上述抗静电处理液中,65℃超声振荡2h,反应结束后挤去多余的处理液,使得处理液和腈纶纤维的总重为30份,置于烘箱中102℃下烘干2h,得到复合型纳米抗静电纤维面料。
2.根据权利要求1所述一种复合型纳米抗静电纤维面料的制备方法,其特征在于步骤1、2)中搅拌速度为200~300r/min。
3.根据权利要求1所述一种复合型纳米抗静电纤维面料的制备方法,其特征在于步骤2)中超声振荡频率为40kHz。
4.根据权利要求1所述一种复合型纳米抗静电纤维面料的制备方法,其特征在于步骤2)中所述凹凸棒土- ZIF-67/TiO2复合材料制备方法如下:
称取27重量份三油酸甘油酯置于三口烧瓶中,加入60重量份异丙醇,磁力搅拌4h后升温至80℃时,用滴液漏斗向三口烧瓶内缓慢滴加120重量份质量分数为16%的氯乙酸钠溶液,用氢氧化钠调节反应体系的pH值在7.5~8.5之间,保温反应4h,自然冷却,向烧瓶中加入14重量份纳米级钛白粉、20重量份凹凸棒土、6重量份金属有机骨架ZIF-67粉末,在75℃下恒温反应3h,离心分离后在微波消解仪下140℃微波处理2h,65℃真空干燥12h,冷却,得到凹凸棒土- ZIF-67/TiO2复合材料。
5.根据权利要求1~4所述一种复合型纳米抗静电纤维面料的制备方法,其特征在于所述金属有机骨架ZIF-67粉末为600~800目。
6.根据权利要求1~5所述一种复合型纳米抗静电纤维面料的制备方法,其特征在于所述纳米级钛白粉粒径为30~50nm。
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061112A (zh) * | 2010-11-12 | 2011-05-18 | 华东师范大学 | 复合金属有机骨架材料胶体溶液的制备方法及其在光学涂层上的应用 |
CN102464821A (zh) * | 2010-11-18 | 2012-05-23 | 上海杰事杰新材料(集团)股份有限公司 | 一种抗菌耐老化抗静电塑料母料及其制备方法 |
CN102851975A (zh) * | 2012-09-10 | 2013-01-02 | 昆山市周市惠宏服装厂 | 抗静电织物及其制造方法 |
CN104562663A (zh) * | 2014-12-26 | 2015-04-29 | 高俊丽 | 一种制备抗静电面料的方法 |
CN104805694A (zh) * | 2015-04-21 | 2015-07-29 | 常熟市翔鹰特纤有限公司 | 一种抗静电腈纶纤维的制作方法 |
CN105694810A (zh) * | 2016-04-27 | 2016-06-22 | 南京航空航天大学 | 一种以ZIF-67为模板制备CuO/多孔碳复合吸波材料的方法 |
CN107123803A (zh) * | 2017-05-26 | 2017-09-01 | 哈尔滨工业大学 | 一种基于金属有机骨架结构合成二氧化钛和碳复合材料的方法及应用 |
CN107217488A (zh) * | 2017-06-23 | 2017-09-29 | 宁波高新区达康工业科技有限公司 | 一种抗静电抑菌腈纶面料 |
-
2018
- 2018-06-26 CN CN201810666518.7A patent/CN108914558A/zh active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061112A (zh) * | 2010-11-12 | 2011-05-18 | 华东师范大学 | 复合金属有机骨架材料胶体溶液的制备方法及其在光学涂层上的应用 |
CN102464821A (zh) * | 2010-11-18 | 2012-05-23 | 上海杰事杰新材料(集团)股份有限公司 | 一种抗菌耐老化抗静电塑料母料及其制备方法 |
CN102851975A (zh) * | 2012-09-10 | 2013-01-02 | 昆山市周市惠宏服装厂 | 抗静电织物及其制造方法 |
CN104562663A (zh) * | 2014-12-26 | 2015-04-29 | 高俊丽 | 一种制备抗静电面料的方法 |
CN104805694A (zh) * | 2015-04-21 | 2015-07-29 | 常熟市翔鹰特纤有限公司 | 一种抗静电腈纶纤维的制作方法 |
CN105694810A (zh) * | 2016-04-27 | 2016-06-22 | 南京航空航天大学 | 一种以ZIF-67为模板制备CuO/多孔碳复合吸波材料的方法 |
CN107123803A (zh) * | 2017-05-26 | 2017-09-01 | 哈尔滨工业大学 | 一种基于金属有机骨架结构合成二氧化钛和碳复合材料的方法及应用 |
CN107217488A (zh) * | 2017-06-23 | 2017-09-29 | 宁波高新区达康工业科技有限公司 | 一种抗静电抑菌腈纶面料 |
Non-Patent Citations (4)
Title |
---|
丁群等: "《纺织品贸易从业人员必读》", 31 January 2013, 中国纺织出版社 第1版 * |
李一新: "金属有机骨架、二氧化钛复合材料的制备及其在有机物处理中的应用", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
覃小红: "《纳米技术与纳米纺织品》", 31 December 2011, 东华大学出版社 第1版 * |
钱慧丽等: "《预拌砂浆应用技术》", 30 April 2015, 中国建材工业出版社 第1版 * |
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