CN108913403A - Detergent and preparation method thereof - Google Patents
Detergent and preparation method thereof Download PDFInfo
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- CN108913403A CN108913403A CN201810984886.6A CN201810984886A CN108913403A CN 108913403 A CN108913403 A CN 108913403A CN 201810984886 A CN201810984886 A CN 201810984886A CN 108913403 A CN108913403 A CN 108913403A
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Abstract
The invention discloses a kind of detergents and preparation method thereof, and preparation method includes the following steps：One, fresh camellia oleifera fruit peel off acquisition 20~50 parts of fresh fruit shell, fresh tea seed squeezing after 30~60 parts of cake slag, 1~10 part of fresh ginger, 10~20 parts of fresh mint leaf, 5~10 parts of fresh rosemary leave, co-grinding, slurrying, filtering, obtain slurries；Two, it takes the resulting slurries of step 1 to be concentrated into every milliliter of concentrate and contains 0.15~0.19 gram of active matter；Three, 25-60 parts of the concentrate for taking step 2 to obtain, 40~70 parts of electrolysis water, 5~15 parts of sodium bicarbonate, 2~5 parts of sea salt, 1~3 part of bentonite；Filtering is mixed, obtains detergent.Its stability is high, and without adding preservative, bactericidal effect is good, dirt-removing power is strong, and biological degradability is high, does not hurt hands mildly, low bubble, water-saving.
Description
Technical field
The present invention relates to a kind of articles for washing and preparation method thereof, especially a kind of detergent and preparation method thereof.
Background technique
The cleaning supplies industry in China is started in 1958, and by the development in year many years, it is Clean- that China has entered the world
Product big producer ranks, product form and product variety become increasingly abundant, and specialization, functionalization, personalized product continue to bring out, shape
At personal cleanliness's nursing materials, household cleaning nursing materials, industry and the big category system of communal facility cleaning supplies three.Have
There is certain scale, become one of the pillar industry of China's light industry, currently, China's cleaning supplies industry has synthetic detergent
Factory 100,2,900,000 tons of annual production capacity.
Family daily necessity cleaning agent is various in style, wherein having the cleaning furniture for aiming at room, floor, wall, door and window glass
The hard surface cleaner of glass has the special purpose detergent of cleaning glass vessel, plastic items, jewelry accessories, has culinary clear
Wash up, kitchen range, kitchen ventilator and ceramic tile special purpose detergent, there are also lavatory defend dedicated bathtub, urinal detergent and deodorant with
And carpet cleaner etc..The main component of dish washing liquid for kitchen use is a variety of surfactants and builder, including alkyl benzene sulphonate
Sodium, fatty alcohol polyoxyethylene ether, coconut oil diethanol amine and triethanolamine etc., there are also special cleaning bathtubs, refrigerator, ceramic tile, head
The various detergent of decorations, cooking stove etc., component prescription substantially take off not open the range of above-mentioned several substances.
But chemical synthesis cleaning product is used for a long time causes pachylosis dry and cracked not only to the stimulation of skin, and
Not exclusively, residual causes to endanger body, while because being not easily decomposed, quite serious to the pollution of ambient soil and water body for cleaning.
Summary of the invention
A kind of preparation method of detergent is provided the purpose of the present invention is overcoming the above-mentioned insufficient of the prior art, technique
Simply, raw material is common, cheap；By the detergent that it makes, stability is high, and bactericidal effect is good, detergent power is strong, biology drop
Solution degree is high, mildly feel well hand, low bubble, water-saving；It is non-toxic, nonirritant, without anaphylaxis, can be used as in people's daily life and cleans
The ideal safety and environmental protection washing product such as food Work tool, tableware and veterinary antibiotics.
The technical scheme is that：A kind of preparation method of detergent comprising following processing step：
One, slurries are produced
Raw material is weighed by following proportion by weight：Fresh camellia oleifera fruit is peeled off 20~50 parts of fresh fruit shell, the fresh tea seed of acquisition
5~10 parts of 10~20 parts of 1~10 part of 30~60 parts of cake slag, fresh ginger, fresh mint leaf after squeezing, fresh rosemary leave,
Co-grinding adds the water of granular mass 30-60%, stirs evenly, squeezed by juice extractor at 5-10 mm granules, filters, obtains
Obtain slurries；
Two, concentrate is produced
The resulting slurries of step 1 are taken, water-bath, which is concentrated into every milliliter of concentrate, in 93~97 DEG C of water temperature contains 0.2~0.3
Gram dry matter；
Three, detergent is produced
Raw material is weighed by following proportion by weight：25-60 parts of the concentrate for taking step 2 to obtain, 40~70 parts of electrolysis water, little Su
5~15 parts, 2~5 parts of sea salt, 1~3 part of bentonite are played, after electrolysis water is heated to 50~70 DEG C, then successively by sodium bicarbonate, dense
Contracting liquid, sea salt, bentonite are added in electrolysis water, stir evenly and are completely dissolved well filter, be down to room temperature, obtain detergent.
Preferably, the raw material of step 1 passes through pulverizer respectively and is crushed；Pulverizer screen-aperture is 7-10mm.
Preferably, the juice extractor extrusion spiral of step 1 uses backpitch structure, and material adds the water of 30-60%, and liquid squeezes out
Interspace 2-3mm.
Preferably, the filtering of step 1 uses decanter centrifuge.
Preferably, the bentonite is sodium bentonite.
Preferably, the electrolysis water ph value is 9-10.
The primary symbols and name resolving that the present invention uses are as follows：
~：Numberical range, such as 1~5 expression 1 to 5.
The primary raw material that the present invention uses is described as follows：
Camellia oleifera fruit：The fruit of tea oil tree knot, seed benevolence obtains tea oil after squeezing, extract technology extract in fruit.Camellia oleifera fruit contains
Vitamin E and antioxidant content, it can protect the skin of people, can especially prevent skin injury and aging, and skin is made to have light
Pool, delicacy.In addition, keep hair pitch-black shinny if being used to wash my hair can also prevent hair loss, but it is more luxurious.And natural table
Face activating agent Tea Saponin has very strong detergency ability.
Tea seed：Gained after fresh camellia oleifera fruit shelling.
Electrolysis water：By clean water by electrolysis, it is rich in the electrolysis water of-OH, pH9-12 is not hurt hands mildly.
Sodium bicarbonate：White powder or monoclinic crystal crystalline powder, it is odorless, taste is salty, soluble easily in water, but than sodium carbonate in water
In solubility it is small, do not dissolve in ethyl alcohol, aqueous solution be in alkalescence.It is heated easily to decompose.It is slowly decomposed in humid air.About 50
DEG C start to lose carbon dioxide, becomes sodium carbonate in 100 DEG C of wholes.It is decomposed rapidly in weak acid, aqueous solution is opened at 20 DEG C
Beginning splits the carbon dioxide off and sodium carbonate, all decomposes when to boiling point.It is dissolved in 10 parts of water at 25 DEG C, about 18 DEG C of whens are dissolved in 12 parts
Water does not dissolve in ethyl alcohol.The solution not stirred made of its cold water is only in alkalescence reaction to phenolphthalein test paper, places or increase
Temperature, alkalinity increase.The 0.1mol/L pH value of water solution of 25 DEG C of Fresh is 8.3, shows alkalinity, but be free of OH ﹣, does not belong to
In alkali, belong to acid carbonate (bicarbonate).Storage:It is dry, it is protected from light, is sealed.Purposes:Analytical reagent.Organic synthesis.
Pharmacy（Treat hyperhydrochloria）.Leavening（Roasting cake）.Extinguishing chemical（Foam or dry powder）.
Sea salt:From salt marsh, sea salt contains trace mineral, such as calcium, magnesium, potassium, bromide and other various micro members
Element.The mollusk (insect) that slug, snail, leech one kind have mucus can be killed.
Bentonite：Also bentonite, bentonite or amargosite are.China's exploitation use is bentonitic with a long history, originally only
As a kind of detergent.(just having opencut before the centuries of Sichuan Renshou area, local people's bentonite is referred to as native powder).It is really wide
It is general to use but only hundred coming year history.Colonial is the discovery that in the ancient stratum of the Wyoming State, in the clay of yellow green, adds water
Expansion just all clays for having this property, is referred to as bentonite at paste, later people afterwards.It is in fact bentonitic main
Mineralogical composition is montmorillonite, and content in 85-90%, bentonitic properties is determined by montmorillonite.Montmorillonite can
, yellowish-white, grey, white etc. for example yellowish green in various colors.It can also be able to be loose earthy, be rubbed with the hands and ground with finger at compact massive
When have a sliding sense, it is in suspension, when water is few in the pasty state that small blocks add volume after water to swell several times to 20-30 times in water.Montmorillonite
Property it is related with internal structure with its chemical component.
Ginger：There is the effects of warm, excited, sweating, preventing or arresting vomiting, removing toxic substances, warm lung cough-relieving, especially for ichthyophagy crab poison, the tuber of pinellia, day
The drug poisoning such as Southern Star have detoxication.Suitable for affection of exogenous wind-cold, headache, phlegm retention, cough, gastrofrigid vomiting;By ice and snow, water
It is anxious that it is drunk with ginger decoction after wet, cold invasion, blood can be promoted, disperse cold-evil.
Peppermint：The general name of Labiatae (Labiatae) Mentha (Mentha Linn) plant is perennial root grass
This.Europe and Mediterranean are originated in, there is cultivation all over the world now, its cauline leaf is mainly used to extract essential oil as natural perfume
Material.Peppermint is also edible with all herbal medicine, is mainly used to refine peppermint oil and menthol, the two are the masters that peppermint plays a role
Ingredient is wanted, the foundation of different peppermint kinds is also to discriminate between.Peppermint can be used for toothpaste and dental care product, food, cigarette, wine,
The flavoring of cold drink, cosmetics and perfumed soap.In medicine, it is widely used in the medicines such as wind-dispelling, anti-corrosion, anti-inflammatory, antipruritic
In product, such as cooling ointment, rheumatic oil.
Rosemary：（Classification system：Rosmarinus officinalis）Labiatae shrub.Property happiness temperature climate, originate in
The northern Mediterranean of European Region and Africa.China is just once introduced a fine variety in period far away from Caowei Kingdom.Occasionally there is application in present gardens.From fan
Repeatedly antioxidant and Rosemary Oil with excellent anti-oxidation characteristics can be extracted in fragrant flower and leaf.Rosemary antioxidant.
Medicine, fried food, rich oil food and the fresh-keeping of each quasi-grease is widely used in guarantee the quality；And rosemary essence is then used for fragrance, sky
The daily-use chemical industries industry such as gas freshener, driving ants and sterilization, desinsection.
Usage and dosage of the present invention:
Detergent of the invention adds the tablewares such as appropriate instillation dish, then is cleaned with rag, and then clear water washes down；Or directly pour into water
Middle stirring, immersion after being washed with rag, then are rinsed with clear water.
The present invention has following features compared with prior art：
1. detergent of the invention is prepared using plant and induction biosynthesis raw material, biological degradability and stability are high.
2. detergent of the invention is after use, hand feels mildly refreshing hand.
3. detergent of the invention has detergent power strong, low bubble, water-saving advantage.
5. detergent of the invention is without obvious animal toxicity, harmless, safety.
6. detergent sterilizing ability of the invention is strong, nonirritant, no anaphylaxis, environmental protection.
In order to illustrate more clearly of the present invention, following embodiment and detection test situation, but its range to invention are enumerated
It is without any restrictions.
Specific embodiment
Bentonite is sodium bentonite in embodiment.
Following example 1-6, slurries preparation method used in comparative example 1 are as follows：Fresh camellia oleifera fruit is peeled off the fresh fruit of acquisition
40 kilograms of cake slag, 5 kilograms of fresh ginger after 30 kilograms of shell, the squeezing of fresh tea seed, 15 kilograms of fresh mint leaf, fresh fan change
8 kilograms of spiceleaf, co-grinding is added 35 kilograms of water, stirs evenly at 5-10 mm granules, is squeezed by juice extractor and obtains tea
Seed slurries, filtering obtain slurries.
Slurries preparation method used used in comparative example 2 is as follows：Fresh camellia oleifera fruit is peeled off 30 kilograms of the fresh fruit shell, new of acquisition
40 kilograms of cake slag, 15 kilograms of fresh mint leaf, 8 kilograms of fresh rosemary leave after the squeezing of fresh fried flour seed, co-grinding is at 5-10
Mm granules are added 35 kilograms of water, stir evenly, and are squeezed by juice extractor and obtain tea seed slurries, and filtering obtains slurries.
Embodiment 1
A kind of preparation method of detergent, mainly comprises the technical steps that：By gained slurries, the water-bath in 95 DEG C of water temperature
It is concentrated into every milliliter of concentrate containing 0.25 gram of dry matter, obtains concentrate；Raw material is weighed by following proportion by weight：It takes
40 kilograms of concentrate, 60 kilograms of electrolysis water, 10 kilograms of sodium bicarbonate, 3 kilograms of sea salt, 2 kilograms of bentonite, electrolysis water is heated to
After 60-65 DEG C, then successively will sodium bicarbonate, concentrate, sea salt, bentonite be added electrolysis water in, stir evenly be completely dissolved it is well
Filter, is down to room temperature, obtains detergent.
Embodiment 2-6
Raw material used in embodiment 2-6 and quality are as shown in Table 1 below, and preparation method is same as Example 1；Following
Table 1 shows specific raw material and quality used in embodiment 1-6.
Table 1, unit are kilogram
。
Comparative example 1 eliminates bentonite on the basis of embodiment 6, and sea salt becomes 5 parts, other same as Example 6；It is right
It is other same as Example 6 without addition ginger in the slurries of ratio 2.
Detection and test
The detergent of various embodiments of the present invention is sent to the detection and test that special detection mechanism has carried out system by applicant, master
It is as follows to detect test result.
One, is by the resulting detergent of the above various embodiments, by examining pH（GB 9985-2000 detection）Deng obtaining following
Testing result shown in table 2：
Table 2
。
From the above table 2 it can be seen that the detergent of various embodiments of the present invention has the advantages that safety, health, comparative example 1 are bright
Aobvious detection heavy metal, microorganism；Comparative example 2 detects microorganism.Various embodiments of the present invention control in bacterial action better than comparison
Example 1 and 2.
Two, cleaning action detects
Purpose：Take the various embodiments of the present invention of identical grams and the detergent of comparative example and step 2 concentrate, electrolysis water, little Su
It beats, standard detergent, tests its cleaning capacity.
Method：The detergent of various embodiments of the present invention and comparative example, step 2 concentrate, electrolysis water, sodium bicarbonate, standard are washed
Agent is washed, identical grams is taken, measures cleaning capacity with the method for national standard GB9985-2000.
As a result：It see the table below shown in 3.
The contrasting detection result (N=6, %) of 3. cleaning action of table
。
Conclusion：As can be seen from Table 3, the cleaning force of the detergent of various embodiments of the present invention is concentrated better than step 2
Liquid, electrolysis water, sodium bicarbonate, standard detergent, this absolutely proves that each raw material component of the detergent of various embodiments of the present invention exists
Be in cleaning force form synergistic effect, if each component of the detergent of various embodiments of the present invention does not form collaboration
Effect is cleaned in de-sludging, then the cleaning capacity of each component mixture of same quality can be lower than highest cleaning capacity in each component
The cleaning capacity of the electrolysis water of same quality, i.e., present invention produces unexpected cleaning capacities.It is penetrated into for efficacy factor
Enter skin preparation.
Three, antibacterial action detects
1. antibacterial range detects（The measurement of inhibition zone diameter size）
Purpose：With the detergent and step 2 concentrate, electrolysis water, little Su of agar diffusion method detection various embodiments of the present invention
Beat that wide, resistance is strong, the pathogenic bacteria of food spoilage, food poisoning, pyogenic infection can be caused to have antibacterial to being distributed in environment
Effect, specifies its antibacterial range.
Method：Diameter 12cm plate is taken, culture medium 15ml is poured into, is dipped with the cotton swab of sterilizing for prescribed limit after condensation
The test organisms bacterium solution of the logarithmic growth phase of density, is uniformly coated on media surface.Then sterilizing Oxford is clamped with aseptic nipper
Cup is put in plate, the detergent 200ul of various embodiments of the present invention is added in each Oxford cup, and carry out parallel test three times.
It is taken out behind 24 hours of 37 DEG C of cultures, surveys inhibition zone diameter, and find out the average value of parallel test inhibition zone diameter three times.With same
The method of sample uses two concentrates of the step of same concentrations, electrolysis water, saleratus solution to compare detection test.
As a result：Contrasting detection result see the table below shown in 4:
4. antibacterium range of table contrasting detection result (mm,±s)
。
2. antimicrobial levels detect（MIC；The measurement of MBC）
Purpose：With liquid dilution method detection various embodiments of the present invention detergent and with step 2 concentrate, electrolysis water, small
Wide, resistance is strong, can cause food spoilage, food poisoning, suppurative to being distributed in environment for 3, soda or more various concentration points
The pathogenic bacteria antimicrobial levels of infection detect minimum inhibitory concentration（MIC）And minimum bactericidal concentration（MBC）, specify its antimicrobial levels.
Method：Take sterile test tube several, after the detergent with fluid nutrient medium equimultiple dilution various embodiments of the present invention,
Each pipe plus 0.1ml set culture medium control tube and bacterium solution control tube for trying bacterium solution, 37 DEG C of cultures take out afterwards for 24 hours see as a result,
In the case that control tube meets the requirements, each developmental tube is observed one by one, is with the solution highest dilution that test organisms can be inhibited to grow
Minimum inhibitory concentration（MIC）, and the culture in the test tube of each asepsis growth is forwarded on the agar plate of corresponding culture medium,
37 DEG C of cultures take out observation afterwards for 24 hours as a result, dilute to kill the solution highest of the various embodiments of the present invention of 99.9% test organisms thallus
Degree of releasing is minimum bactericidal concentration（MBC）.The step of using same concentrations with same method two concentrates, electrolysis water, sodium bicarbonate
Solution compares detection test.
As a result：It see the table below shown in 5：
The contrasting detection result (mg/mL) of 5. antibacterium degree of table
。
Conclusion：From table 4,5 as can be seen that the antibacterial and bactericidal effect of the detergent of various embodiments of the present invention is better than comparison
Example 2, step 2 concentrate, electrolysis water, sodium bicarbonate.That is the detergent of various embodiments of the present invention is main former relative to it
Material step 2 concentrate, electrolysis water, sodium bicarbonate have improved bactericidal effect, and the detergent of various embodiments of the present invention is than independent
Use step 2 concentrate, electrolysis water, sodium bicarbonate more preferable as nursing antiseptic property.
Five, animal toxicity test
Purpose：Observation rabbit intact skin and damaged skin contact tested material in a short time（The detergent of the embodiment of the present invention）Afterwards
Generated toxic reaction provides safety foundation for the detergent of the embodiment of the present invention.
Method：White New Zealand rabbits 12 are selected, is randomly divided into 3 groups, every group 4.A group:Intact skin group, B group:It is broken
Damage skin group, C group:Blank control group.Experiment position is skin of back, and control group is to distilled water, and tested material group is to of the invention
The detergent of each embodiment, is coated directly on intact skin and damaged skin, and Tu Houfu is fixed with polyethylene film, then gauze,
Guarantee itself and skin contact 24 hours, after applying examination 24 hours, is not poisoned to death such as, can be gone with warm water or other nonirritant solvents
Tested material（The detergent of various embodiments of the present invention）.Be observed continuously 7 days, observe and record daily to after tested material animal it is complete
Body poisoning manifestations and death condition, the variation including the weight of animals, skin, hair, eyes and mucous membrane, breathing, circulation, maincenter mind
Variation through system, four limbs activity etc..
As a result：White New Zealand rabbits are given and have no systemic toxicity profiles performance and dead after the detergents of various embodiments of the present invention
Situation, the weight of animals increases, on breathing, circulation, central nervous system, four limbs activity etc. without influence.To the non-show of damaged skin
Spot, oedema.
Conclusion：The detergent of various embodiments of the present invention is to white New Zealand rabbits intact skin and damaged skin non-toxic reaction.
Six, skin irritation test
Purpose：Detect various embodiments of the present invention detergent skin irritation reaction, for clinical application provide safety according to
According to.
Method：According to《Skin irritation test and skin allergy test guideline》In related requirement carry out.Family
Rabbit skin gives the detergent of various embodiments of the present invention, chemical dish washing liquid, distilled water, observation skin irritation reaction.
As a result：After family's rabbit skin gives the detergent of various embodiments of the present invention, not to intact skin and damaged skin
The skin wound repairs such as show spot, oedema.After family's rabbit skin gives chemical dish washing liquid, erythema, oedema are showed no to intact skin
Equal skin wound repairs, are shown in the skin wound repairs such as obvious erythema, oedema to damaged skin.
Conclusion：The detergent percutaneous drug delivery of various embodiments of the present invention, it is stingless to complete normal skin and damaged skin
Swash property.And chemical dish washing liquid, irritation is generated to damaged skin.
Seven, skin allergy test
Purpose：The allergic reaction for detecting the intact skin of the detergent of various embodiments of the present invention, provides peace for clinical application
Full property foundation.
Method：According to《Skin irritation test and skin allergy test guideline》In related requirement carry out, globefish
Mouse sensitization contact and excitation contact detect the detergent of various embodiments of the present invention, distilled water and positive control medicine 2,4- bis-
Nitro-chlorobenzene, observation skin hypersensitivity reaction.
As a result：After cavy gives the detergent of detection various embodiments of the present invention, the local skin of tested cavy is not found
There are the allergic reactions such as erythema, oedema in skin.
Conclusion：The detergent of various embodiments of the present invention without anaphylaxis.
Eight, Detection of Stability
1, it is tested 1 year under room temperature, the detergent of various embodiments of the present invention is without lamination.
2,24 h are placed into subzero 10 DEG C of refrigerator in subzero 3 DEG C, are observed when taking out recovery to room temperature, it is of the invention
The detergent nodeless mesh of each embodiment, no precipitating；24 h are placed in the incubator of (40 scholar I) DEG C, taking-up is observed immediately, this
The detergent of each embodiment of invention is not stratified, haze-free, free from extraneous odour.
Nine, biological degradability
According to GB/T15818 surfactant biodegradation test method, the detergent gross activity of various embodiments of the present invention
The biological degradability of object reaches 99% or more.
Claims (8)
1. a kind of preparation method of detergent, it is characterized in that：It is comprised the technical steps that：
One, slurries are produced
Fresh camellia oleifera fruit peel off acquisition 20~50 parts of fresh fruit shell, fresh tea seed squeezing after 30~60 parts of cake slag, fresh life
1~10 part of ginger, 10~20 parts of fresh mint leaf, 5~10 parts of fresh rosemary leave, co-grinding is at 5-10 mm granules, addition
The water of granular mass 30-60%, stirs evenly, and is squeezed by juice extractor, and filtering obtains slurries；
Two, concentrate is produced
The resulting slurries of step 1 are taken, water-bath, which is concentrated into every milliliter of concentrate, in 93~97 DEG C of water temperature contains 0.2~0.3
Gram dry matter；
Three, detergent is produced
Raw material is weighed by following proportion by weight：25-60 parts of the concentrate for taking step 2 to obtain, 40~70 parts of electrolysis water, little Su
Play 5~15 parts, 2~5 parts of sea salt, 1~3 part of bentonite；After electrolysis water is heated to 50~70 DEG C, then successively by sodium bicarbonate, dense
Contracting liquid, sea salt, bentonite are added in electrolysis water, stir evenly and are completely dissolved well filter, be down to room temperature, obtain detergent.
2. the preparation method of detergent according to claim 1, it is characterized in that：The raw material of step 1 pass through respectively pulverizer into
Row crushes；Crusher sifting screen distance is 7-10mm.
3. the preparation method of detergent according to claim 1, it is characterized in that：The juice extractor extrusion spiral of step 1 is using anti-
Helical structure, material add the water of 30-60%, and liquid squeezes interspace 2-3mm out.
4. the preparation method of detergent according to claim 1, it is characterized in that：The filtering of step 1 uses decanter centrifuge.
5. the preparation method of detergent according to claim 1, it is characterized in that：Step 2 be concentrated in high-efficiency evaporator into
Row.
6. the preparation method of detergent according to claim 1, it is characterized in that the bentonite is sodium bentonite.
7. the preparation method of detergent according to claim 1, it is characterized in that：The electrolysis water pH value of step 3 is 9-12.
8. a kind of detergent, it is characterized in that：It is as made from the preparation method of detergent as claimed in claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810984886.6A CN108913403A (en) | 2018-08-28 | 2018-08-28 | Detergent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810984886.6A CN108913403A (en) | 2018-08-28 | 2018-08-28 | Detergent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108913403A true CN108913403A (en) | 2018-11-30 |
Family
ID=64407141
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810984886.6A Pending CN108913403A (en) | 2018-08-28 | 2018-08-28 | Detergent and preparation method thereof |
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| CN (1) | CN108913403A (en) |
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| CN102517170A (en) * | 2011-12-07 | 2012-06-27 | 王爽 | Natural plant environment-friendly washing product |
| CN103451032A (en) * | 2013-08-30 | 2013-12-18 | 湖南大三湘油茶科技有限公司 | Safe and environment-friendly tea seed washing powder and preparation method thereof |
| CN103555480A (en) * | 2013-09-29 | 2014-02-05 | 青岛叁鼎卫生制品有限公司 | Liquid detergent for fruits and vegetables |
| CN103451036B (en) * | 2013-08-30 | 2014-07-23 | 湖南大三湘油茶科技有限公司 | Safe and environment-friendly tea seed washing liquid and preparation method thereof |
| CN104178379A (en) * | 2014-08-08 | 2014-12-03 | 福州喜自然生物科技有限公司 | Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity |
| CN107245382A (en) * | 2017-06-16 | 2017-10-13 | 中原工学院 | A kind of fruits and vegetables washing salt based on the potent removal residues of pesticides of the de- function double-unit system of suction |
| CN107699394A (en) * | 2017-10-09 | 2018-02-16 | 彭旗 | A kind of tea seed washes clean rapidly dissolving tablet and its preparation method and application |
| CN107828563A (en) * | 2017-11-07 | 2018-03-23 | 重庆市盐业（集团）有限公司 | One kind cleaning salt and its preparation and application |
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Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102517170A (en) * | 2011-12-07 | 2012-06-27 | 王爽 | Natural plant environment-friendly washing product |
| CN103451032A (en) * | 2013-08-30 | 2013-12-18 | 湖南大三湘油茶科技有限公司 | Safe and environment-friendly tea seed washing powder and preparation method thereof |
| CN103451036B (en) * | 2013-08-30 | 2014-07-23 | 湖南大三湘油茶科技有限公司 | Safe and environment-friendly tea seed washing liquid and preparation method thereof |
| CN103555480A (en) * | 2013-09-29 | 2014-02-05 | 青岛叁鼎卫生制品有限公司 | Liquid detergent for fruits and vegetables |
| CN104178379A (en) * | 2014-08-08 | 2014-12-03 | 福州喜自然生物科技有限公司 | Natural washing product with strong oil and dirt removal capacity and preparation method of natural washing product with strong oil and dirt removal capacity |
| CN107245382A (en) * | 2017-06-16 | 2017-10-13 | 中原工学院 | A kind of fruits and vegetables washing salt based on the potent removal residues of pesticides of the de- function double-unit system of suction |
| CN107699394A (en) * | 2017-10-09 | 2018-02-16 | 彭旗 | A kind of tea seed washes clean rapidly dissolving tablet and its preparation method and application |
| CN107828563A (en) * | 2017-11-07 | 2018-03-23 | 重庆市盐业（集团）有限公司 | One kind cleaning salt and its preparation and application |
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