CN108866442B - 超高碳钢的热处理方法及制品 - Google Patents
超高碳钢的热处理方法及制品 Download PDFInfo
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- CN108866442B CN108866442B CN201810794236.5A CN201810794236A CN108866442B CN 108866442 B CN108866442 B CN 108866442B CN 201810794236 A CN201810794236 A CN 201810794236A CN 108866442 B CN108866442 B CN 108866442B
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- carbon steel
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- 229910000621 Ultra-high-carbon steel Inorganic materials 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims abstract description 54
- 238000010438 heat treatment Methods 0.000 title claims abstract description 28
- 238000010791 quenching Methods 0.000 claims abstract description 29
- 238000001816 cooling Methods 0.000 claims abstract description 28
- 230000000171 quenching effect Effects 0.000 claims abstract description 27
- 229910001562 pearlite Inorganic materials 0.000 claims abstract description 16
- 238000000137 annealing Methods 0.000 claims abstract description 15
- 238000009792 diffusion process Methods 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 239000011651 chromium Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001566 austenite Inorganic materials 0.000 abstract description 35
- 230000008569 process Effects 0.000 description 25
- 229910000734 martensite Inorganic materials 0.000 description 19
- 230000000052 comparative effect Effects 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 239000011572 manganese Substances 0.000 description 9
- 238000005496 tempering Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 230000009466 transformation Effects 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 230000000717 retained effect Effects 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229910001567 cementite Inorganic materials 0.000 description 3
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical class [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/004—Heat treatment of ferrous alloys containing Cr and Ni
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
Abstract
Description
Claims (7)
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CN108866442A CN108866442A (zh) | 2018-11-23 |
CN108866442B true CN108866442B (zh) | 2020-04-10 |
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CN112147737A (zh) * | 2020-09-24 | 2020-12-29 | 南京邮电大学 | 一种耐高温光纤布拉格光栅制作方法 |
CN115216593B (zh) * | 2022-07-07 | 2023-07-28 | 郑州大学 | 一种提高超高碳钢强度的热处理方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1715436A (zh) * | 2004-06-28 | 2006-01-04 | 宝山钢铁股份有限公司 | 一种超高碳钢的生产工艺 |
CN102039314A (zh) * | 2010-11-23 | 2011-05-04 | 唐山大方铸造有限公司 | 一种高碳半钢复合辊环及制造方法 |
CN102383041A (zh) * | 2010-09-03 | 2012-03-21 | 天津职业大学 | 一种高耐磨性超高碳钢及其制备方法 |
CN103122433A (zh) * | 2013-01-31 | 2013-05-29 | 西安交通大学 | 一种超高碳型轴承钢 |
CN103334060A (zh) * | 2013-07-18 | 2013-10-02 | 邢台精诚轧辊有限公司 | 金属压延用石墨工具钢及其制造方法 |
CN105925915A (zh) * | 2016-05-10 | 2016-09-07 | 天津立鑫晟科技有限公司 | 一种超高碳钢及其铸造工艺 |
CN106555131A (zh) * | 2016-12-02 | 2017-04-05 | 机械科学研究总院青岛分院 | 一种超高碳型轴承钢的热处理方法 |
-
2018
- 2018-07-19 CN CN201810794236.5A patent/CN108866442B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1715436A (zh) * | 2004-06-28 | 2006-01-04 | 宝山钢铁股份有限公司 | 一种超高碳钢的生产工艺 |
CN102383041A (zh) * | 2010-09-03 | 2012-03-21 | 天津职业大学 | 一种高耐磨性超高碳钢及其制备方法 |
CN102039314A (zh) * | 2010-11-23 | 2011-05-04 | 唐山大方铸造有限公司 | 一种高碳半钢复合辊环及制造方法 |
CN103122433A (zh) * | 2013-01-31 | 2013-05-29 | 西安交通大学 | 一种超高碳型轴承钢 |
CN103334060A (zh) * | 2013-07-18 | 2013-10-02 | 邢台精诚轧辊有限公司 | 金属压延用石墨工具钢及其制造方法 |
CN105925915A (zh) * | 2016-05-10 | 2016-09-07 | 天津立鑫晟科技有限公司 | 一种超高碳钢及其铸造工艺 |
CN106555131A (zh) * | 2016-12-02 | 2017-04-05 | 机械科学研究总院青岛分院 | 一种超高碳型轴承钢的热处理方法 |
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Effective date of registration: 20220414 Address after: 410000 No. 393, section 3, Jinxing North Road, Wangcheng economic and Technological Development Zone, Changsha City, Hunan Province Patentee after: HUNAN CHANGGAO HIGH VOLTAGE SWITCHGEAR GROUP Co.,Ltd. Address before: 410600 Hunan Hengli Heavy Industry Machinery Co., Ltd., Zhanqian Road, economic development zone, Ningxiang County, Changsha City, Hunan Province Patentee before: HUNAN CHANGGAO NEW MATERIAL Co.,Ltd. Patentee before: HUNAN CHANGGAO HIGH VOLTAGE SWITCHGEAR GROUP Co.,Ltd. |
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Address after: No. 393, Section 3, Jinxing North Road, Wangcheng Economic and Technological Development Zone, Changsha, Hunan 410219 Patentee after: Chang Hi-Tech New Technology Co.,Ltd. Country or region after: China Address before: 410000 No. 393, section 3, Jinxing North Road, Wangcheng economic and Technological Development Zone, Changsha City, Hunan Province Patentee before: HUNAN CHANGGAO HIGH VOLTAGE SWITCHGEAR GROUP Co.,Ltd. Country or region before: China |