CN108770328A - 一种mof衍生的复合微波吸收剂及其制备方法 - Google Patents
一种mof衍生的复合微波吸收剂及其制备方法 Download PDFInfo
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- CN108770328A CN108770328A CN201810774536.7A CN201810774536A CN108770328A CN 108770328 A CN108770328 A CN 108770328A CN 201810774536 A CN201810774536 A CN 201810774536A CN 108770328 A CN108770328 A CN 108770328A
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- 230000002745 absorbent Effects 0.000 title claims abstract description 52
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- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 238000000197 pyrolysis Methods 0.000 claims abstract description 36
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims abstract description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 165
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 51
- 239000000243 solution Substances 0.000 claims description 46
- 239000010949 copper Substances 0.000 claims description 33
- 229910052799 carbon Inorganic materials 0.000 claims description 22
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical class [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 20
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 15
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 15
- 238000013019 agitation Methods 0.000 claims description 14
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 10
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- 229910002804 graphite Inorganic materials 0.000 claims description 4
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- 239000000047 product Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Inorganic materials [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 238000009777 vacuum freeze-drying Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 235000013339 cereals Nutrition 0.000 claims 1
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- 238000010521 absorption reaction Methods 0.000 abstract description 13
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- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000012621 metal-organic framework Substances 0.000 abstract 5
- BICXKAQZWLCDDX-UHFFFAOYSA-N copper dinitrate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O BICXKAQZWLCDDX-UHFFFAOYSA-N 0.000 abstract 1
- 229910021389 graphene Inorganic materials 0.000 description 26
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- 239000013354 porous framework Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- -1 Graphite alkene Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0073—Shielding materials
- H05K9/0081—Electromagnetic shielding materials, e.g. EMI, RFI shielding
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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Abstract
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109659571A (zh) * | 2019-01-29 | 2019-04-19 | 东华大学 | 一种二氧化碳电化学还原催化剂及在零距离反应器中的应用 |
CN109652013A (zh) * | 2019-01-28 | 2019-04-19 | 安徽大学 | 一种复合微波吸收剂 |
CN110156120A (zh) * | 2019-06-26 | 2019-08-23 | 中南大学 | 污水处理装置及处理方法 |
CN111137874A (zh) * | 2020-01-10 | 2020-05-12 | 南昌航空大学 | 一种以hkust-1为模板制备复合吸波材料的方法 |
CN113415796A (zh) * | 2021-06-02 | 2021-09-21 | 山东大学 | 一种Cu/C复合材料作为电磁波吸收材料的应用 |
CN113747777A (zh) * | 2021-09-08 | 2021-12-03 | 济南市中恒光机电技术中心 | 一种电磁波屏蔽材料 |
CN115347174A (zh) * | 2022-08-31 | 2022-11-15 | 华南理工大学 | 一种多孔Cu-MOF、硒化铜衍生物及其制备方法与应用 |
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CN103305184A (zh) * | 2013-06-08 | 2013-09-18 | 西北工业大学 | 还原氧化石墨烯/Cu2O/Cu量子点三元吸波材料的制备方法 |
CN103432997A (zh) * | 2013-08-30 | 2013-12-11 | 华南理工大学 | Cu基有机骨架-氧化石墨烯复合多孔材料及其制备方法 |
CN103877951A (zh) * | 2012-12-21 | 2014-06-25 | 中国科学院大连化学物理研究所 | 石墨氧化物和含铜配位聚合物纳米粒子复合材料及其制备 |
CN104645940A (zh) * | 2015-03-13 | 2015-05-27 | 桂林电子科技大学 | 一种氧化石墨烯和含铜配位聚合物复合材料及其微波合成方法 |
CN104745149A (zh) * | 2015-03-05 | 2015-07-01 | 北京科技大学 | 一种含碳材料金属有机骨架基复合相变材料的制备方法 |
CN105688867A (zh) * | 2016-03-10 | 2016-06-22 | 商丘师范学院 | 一种六棱柱型石墨烯-金属有机框架复合材料及其制备方法 |
CN106622151A (zh) * | 2015-11-03 | 2017-05-10 | 中国石油化工股份有限公司 | 含有金属有机骨架材料的复合材料及其制备方法与应用 |
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2018
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CN103877951A (zh) * | 2012-12-21 | 2014-06-25 | 中国科学院大连化学物理研究所 | 石墨氧化物和含铜配位聚合物纳米粒子复合材料及其制备 |
CN103305184A (zh) * | 2013-06-08 | 2013-09-18 | 西北工业大学 | 还原氧化石墨烯/Cu2O/Cu量子点三元吸波材料的制备方法 |
CN103432997A (zh) * | 2013-08-30 | 2013-12-11 | 华南理工大学 | Cu基有机骨架-氧化石墨烯复合多孔材料及其制备方法 |
CN104745149A (zh) * | 2015-03-05 | 2015-07-01 | 北京科技大学 | 一种含碳材料金属有机骨架基复合相变材料的制备方法 |
CN104645940A (zh) * | 2015-03-13 | 2015-05-27 | 桂林电子科技大学 | 一种氧化石墨烯和含铜配位聚合物复合材料及其微波合成方法 |
CN106622151A (zh) * | 2015-11-03 | 2017-05-10 | 中国石油化工股份有限公司 | 含有金属有机骨架材料的复合材料及其制备方法与应用 |
CN105688867A (zh) * | 2016-03-10 | 2016-06-22 | 商丘师范学院 | 一种六棱柱型石墨烯-金属有机框架复合材料及其制备方法 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109652013A (zh) * | 2019-01-28 | 2019-04-19 | 安徽大学 | 一种复合微波吸收剂 |
CN109652013B (zh) * | 2019-01-28 | 2021-11-16 | 安徽璜峪电磁技术有限公司 | 一种复合微波吸收剂 |
CN109659571A (zh) * | 2019-01-29 | 2019-04-19 | 东华大学 | 一种二氧化碳电化学还原催化剂及在零距离反应器中的应用 |
CN109659571B (zh) * | 2019-01-29 | 2022-02-01 | 东华大学 | 一种二氧化碳电化学还原催化剂及在零距离反应器中的应用 |
CN110156120A (zh) * | 2019-06-26 | 2019-08-23 | 中南大学 | 污水处理装置及处理方法 |
CN110156120B (zh) * | 2019-06-26 | 2023-04-25 | 中南大学 | 污水处理装置及处理方法 |
CN111137874A (zh) * | 2020-01-10 | 2020-05-12 | 南昌航空大学 | 一种以hkust-1为模板制备复合吸波材料的方法 |
CN111137874B (zh) * | 2020-01-10 | 2023-03-31 | 南昌航空大学 | 一种以hkust-1为模板制备复合吸波材料的方法 |
CN113415796A (zh) * | 2021-06-02 | 2021-09-21 | 山东大学 | 一种Cu/C复合材料作为电磁波吸收材料的应用 |
CN113747777A (zh) * | 2021-09-08 | 2021-12-03 | 济南市中恒光机电技术中心 | 一种电磁波屏蔽材料 |
CN113747777B (zh) * | 2021-09-08 | 2022-04-08 | 北京伊斯普电子技术有限公司 | 一种电磁波屏蔽材料 |
CN115347174A (zh) * | 2022-08-31 | 2022-11-15 | 华南理工大学 | 一种多孔Cu-MOF、硒化铜衍生物及其制备方法与应用 |
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Effective date of registration: 20210514 Address after: 235299 Building 2, Xiaoxian high tech park, Zhangjiang, Shunhe Road, Longcheng Town, Xiaoxian County, Suzhou City, Anhui Province Patentee after: Anhui Huangyu Electromagnetic Technology Co.,Ltd. Address before: No. 111, Kowloon Road, Hefei, Anhui, Anhui Patentee before: ANHUI University |
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