CN108753049A - A kind of aqueous rubber coating and preparation method thereof - Google Patents
A kind of aqueous rubber coating and preparation method thereof Download PDFInfo
- Publication number
- CN108753049A CN108753049A CN201810660123.6A CN201810660123A CN108753049A CN 108753049 A CN108753049 A CN 108753049A CN 201810660123 A CN201810660123 A CN 201810660123A CN 108753049 A CN108753049 A CN 108753049A
- Authority
- CN
- China
- Prior art keywords
- rubber
- aqueous
- lotion
- agent
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D107/00—Coating compositions based on natural rubber
- C09D107/02—Latex
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
- C09D171/03—Polyepihalohydrins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of aqueous rubber coating, by following compositions according to mass percentage composition：Water：5~35%, aqueous rubber lotion：30~80%, resin aqueous emulsion：0~55%, color stuffing：0~60%, auxiliary agent：0.1~25%.The present invention also provides a kind of preparation method of aqueous rubber coating, the specific steps are：Water, aqueous rubber lotion, resin aqueous emulsion, auxiliary agent are configured to raw material by step 1 according to mass percent；Step 2 stirs 1~5 hour, 50~200 revs/min of rotating speed；Step 3 is packed after crossing 40 mesh sieve.The aqueous rubber coating advantage of the present invention is：It is aqueous, environmentally friendly, do not peel；Fast drying, easily construction are easily repaired, good weatherability；Keep it is color properties it is good, anti-pollution is good, easy to clean；The advantages that moisture proof is good, salt fog resistance is good, mould proof good, overcomes the defect of the various physics of coating, chemistry, form of construction work etc. on the base materials such as metal, cement, concrete, stone material, plastics, plastic cement, glass, ceramic tile, timber, film, paper, leather.
Description
Technical field
The present invention relates to rubber coating technical fields, and in particular to a kind of aqueous rubber coating and preparation method thereof.
Background technology
There are many floor coatings, water-repellent paint, coating for internal and external wall, road paint currently on the market, is lacked there is prodigious
Point, 1, containing solvent not environmentally, poor adhesive force easily peel, 2, dry slow, construction is not easy, is not easily repaired, weatherability is poor, antiultraviolet
Difference；3, acidproof alkaline error, solvent resistant are poor, oil resistant is poor, poor water resistance, intolerant to animal excrements；4, cold resistance is poor, high temperature and humidity resistance
Difference, ozone-resistant is poor, ageing-resistant difference；6, keep it is color properties it is poor, anti-pollution is poor, not easy to clean；7, do not have elasticity, impact-resisting wear-resisting
It is poor, not anti-skidding；8, moisture proof is poor, salt fog resistance is poor, mould proof difference.
Invention content：
The invention aims to solve any of the above-described technical problem in the presence of the prior art, and provide a kind of aqueous rubber
Glue coating and its preparation.
In order to achieve the above object, the present invention adopts the following technical scheme that：
A kind of aqueous rubber coating, rubber coating is by following compositions according to mass percentage composition：Water：5~35%, it is aqueous
Rubber latex：30~80%, resin aqueous emulsion：0~55%, color stuffing：0~60%, auxiliary agent：0.1~25%.
Preferably, the water is distilled water, one kind in deionized water or arbitrary composition.
Preferably, rubber coating by following compositions according to mass percentage composition：Water：5~30%, aqueous rubber lotion：
40~80%, resin aqueous emulsion：0~45%, color stuffing：0~45%, auxiliary agent：0.1~15%.
Preferably, rubber coating by following compositions according to mass percentage composition：Water：5~30%, aqueous rubber lotion：
40~80%, resin aqueous emulsion：0~35%, color stuffing：0~30%, auxiliary agent：0.1~10%.
Preferably, the aqueous rubber lotion is that rubber is dispersed in the lotion in water.
Preferably, the aqueous rubber lotion is prepared in accordance with the following steps：
S1, rubber powder component is crossed to 40 mesh sieve；
S2, following raw material is prepared according to mass percent：Rubber powder after being sieved in step S1：30~60%, water：30~
65%, dispersant：1~15%, emulsifier：1~15%；
S3, disperseed after mixing each raw material powder in step S2, emulsified, 1000~8000 revs/min, incorporation time
It is 1~8 hour；
S4, the mixture after disperseing in step S3, emulsifying uniformly is crossed into 40 mesh filter screens up to aqueous rubber lotion.
Preferably, when preparing aqueous rubber lotion, dispersant uses anionic, cationic, amphoteric or macromolecule
The surfactant of type.
Preferably, rubber is natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, neoprene, determines base rubber, fourth
The poly- second of nitrile rubber, hydrogenated nitrile-butadiene rubber, EP rubbers, silicon rubber, fluorubber, polyurethane rubber, acrylic rubber, chlorosulfonation
Alkene rubber, epichlorohydrin rubber, chlorinated polyethylene rubber or one kind in chlorine vinegar rubber or the arbitrary composition in rubber.
Preferably, the rubber is new rubber or recycles the mixture of rubber or new rubber and recycling rubber.
Preferably, resin aqueous emulsion is water-based acrylic resin lotion, aqueous polyurethane resin emulsion, water-base epoxy tree
Fat liquor, aqueous polyester resin lotion, aqueous alkide resin emulsion resin, aqueous polyethylene acetate resin lotion, aqueous phenylpropyl alcohol
Resin emulsion, aqueous rosin resin lotion, aqueous terpene resin emulsion, aqueous petroleum resin emulsion, resol resins lotion,
Waterborne organic silicon resin emulsion, one kind in water-based fluorocarbon resin emulsion or the arbitrary composition in resin aqueous emulsion.
Preferably, color stuffing is mountain flour, building stones, titanium white, barium sulfate, calcium carbonate, talcum powder, kaolin, lithopone, antimony
In vain, zirconium dioxide, lead silicate, montmorillonite, dolomite, white lead, tribasic lead sulfate, lead sulfate, zinc oxide, aluminium oxide, silicon ash
Stone, trbasic zinc phosphate, aluminium dihydrogen tripolyphosphate, zinc molybdate, zinc borate, aluminium powder, copper powder, zinc powder, copper zinc powder, baryta yellow, strontium chromate.Chromium
Huang, cadmium yellow, iron oxide yellow, transparent yellow, yellow lead, titanium yellow, calcium Huang, praseodymium yellow, strontium calcium yellow, iron oxide red, transparent iron oxide red, day
Right iron oxide red, red lead, cinnabar, antimony trisulfide, cadmium red, chrome tin pink, iron oxide brown, Chinese blue, cobalt blue, Tie Lan, ultramarine, basic copper carbonate,
Chrome oxide green, chrome green, carbon black, iron oxide black, oxidation cobalt black, copper oxide, white carbon, mica, mica titanium, pigment yellow, it is organic it is middle it is yellow,
Organic Lemon Huang, the everbright fast yellow of resistance to alcohol, solvent yellow, pigment orange, toluidine red, permanent red, naphthol reds, quinacridone be red, paratonere,
Bronze red, rose-red, pigment violet, quinacridone violet, permanent violet, everbright fast violet lake, pigment blue, phthalocyanine blue, naphthol green, alkalinity
Light green color lake, sun-proof emerald green color lake, plastics ancestor, one kind in phthalocyanine green or the arbitrary composition in color stuffing.
Preferably, auxiliary agent be dispersant, levelling agent, antifoaming agent, emulsifier, thickener, anti-settling agent, anti-fouling agent, preservative,
Mould inhibitor, algaecide, conductive agent, antistatic agent, delustering agent, slip agent, scratching resistant, antilubricant, anti-wear agent, coupling agent, light
Stabilizer, heat stabilizer, adhesion promoter, fire retardant, antifreezing agent, hydrophobing agent, mallear stria agent, eliminating smell agent, anionic additive
In one kind or the arbitrary composition in auxiliary agent.
The present invention also provides a kind of preparation methods of aqueous rubber coating, specifically comprise the following steps：
Step 1, raw material mixing：Water, aqueous rubber lotion, water are weighed according to the mass percent range in claim 1
Property resin emulsion, auxiliary agent, and mix；
Step 2 stirs evenly：By the mixture of step 1 in 50~200 revs/min, stir 1~5 hour；
Step 3, sieving packaging：Mixture after step 2 is stirred packs after crossing 40 mesh sieve.
The beneficial effects of the present invention are：
1, aqueous, environmentally friendly, do not peel, 2, fast drying, easily, easily reparation, good weatherability, antiultraviolet are good for construction；3, acidproof
Alkali is good, solvent resistant is good, oil resistant is good, water-tolerant, resistance to animal excrements；4, cold resistance is good, high temperature and humidity resistance is good, ozone-resistant
It is good, it is ageing-resistant good；6, keep it is color properties it is good, anti-pollution is good, easy to clean；7, with elastic, impact-resisting wear-resisting is good, skid resistance is good；8,
The advantages that moisture proof is good, salt fog resistance is good, mould proof good, overcomes in metal, cement, concrete, stone material, plastics, plastic cement, glass
The defect of the various physics of coating, chemistry, form of construction work etc. on the base materials such as glass, ceramic tile, timber, film, paper, leather；
9, this programme environmental protection and energy saving and effectively reduces production cost using new rubber or recycling rubber system for aqueous rubber coating.
Description of the drawings
Fig. 1 is the preparation technology flow chart of the aqueous rubber coating of the present invention.
Specific implementation mode
The selected embodiment that the present invention is illustrated referring now to Figure of description, it will be understood by a person skilled in the art that arriving, this hair
The explanation of bright embodiment is merely exemplary, the scheme being not meant to limit the present invention.
Embodiment 1
1, aqueous rubber lotion is prepared：
Natural rubber powder is crossed into 40 mesh sieve, and each raw material component, wherein natural rubber are prepared according to mass percent：
30%, dispersant B YK-2155：2%, emulsifier is Japanese emulsifier Co., Ltd. Newcol-293：3%, distilled water：65%,
1000 revs/min of rotating speed, high speed dispersion, emulsification 8 hours cross 40 mesh filter screens after dispersion, emulsification uniformly and aqueous rubber lotion are made
A。
2, aqueous rubber coating is prepared：
Following each component, distilled water are prepared according to mass percent：10%, aqueous rubber latex A：65%, aqueous acrylamide
Yogurt liquid：20%, carbon black：3%, dispersant B YK-2155：1%, antifoaming agent BYK-011：1%, after above-mentioned raw materials are mixed, turn
50 revs/min of speed, stirring are crossed 40 mesh sieve, are packed after 2 hours.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on totally dry board surface, is placed in temperature
Degree is more than 10 DEG C, under conditions of humidity light rain 65%, is detected from after doing 8 hours, 200 microns of average dry film thickness.
After testing, which has 24 hours good elasticity, adhesive force good (> 4B), concentrated sulfuric acid resistant (5wt%) unchanged, resistance to sodium hydroxides
The advantages that (5wt%) 24 hours unchanged, water-tolerant (24 hours ne-leakages).
Embodiment 2
1, aqueous rubber lotion is prepared：
Butadiene rubber powder is crossed into 40 mesh sieve, and each component, butadiene rubber are prepared according to mass percent：44%, dispersion
Agent BYK-2155：15%, emulsifier：Japanese emulsifier Co., Ltd. Newcol-297：1%, deionized water：40%, high speed point
Dissipate, emulsification 5 hours, 3000 revs/min of rotating speed, dispersion, emulsification uniformly after cross 40 mesh filter screens aqueous rubber lotion B is made.
2, aqueous rubber coating is prepared：
Following each raw material component, deionized water are prepared according to mass percent：10%, aqueous rubber lotion B：45%, water
Property polyaminoester emulsion：15%, titanium dioxide：14%, mountain flour：4%；Building stones：10%, dispersant B YK-2155：1%, antifoaming agent
BYK-011：1%, it stirs 5 hours, 200 revs/min of rotating speed, 40 mesh sieve, packaging is crossed after stirring.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on clean smooth cement plate, temperature is placed in
Degree is more than 10 DEG C, under the conditions of humidity light rain 65%, from 12 hours dry, 100 microns of average dry film thickness.After testing, the painting
Material have the good, adhesive force good (> 4B) of elasticity, concentrated sulfuric acid resistant (5wt%, 24 hours unchanged), resistance to sodium hydroxide (5wt%, 24
It is hour unchanged), water-tolerant (24 hours ne-leakages), good weatherability (QUV not dusting in 720 hours), the advantages that self-cleaning is good.
Embodiment 3
1, aqueous rubber lotion is prepared：
Natural rubber, isoprene rubber, butadiene rubber powder are crossed into 40 mesh sieve, and each raw material group is prepared according to mass percent
Point, natural rubber 20%, isoprene rubber 30%, butadiene rubber：10%, dispersant B YK-9076：2%, emulsifier：Japan's emulsification
Agent Co., Ltd. Newcol-291-M：3%, Newcol-297：5%, deionized water：30%, high speed dispersion, emulsification 1 hour turn
8000 revs/min of speed crosses 40 mesh filter screens after dispersion, emulsification uniformly and aqueous rubber lotion C is made.
2, aqueous rubber coating is prepared：
Following each raw material component, distilled water are prepared according to mass percent：5%, aqueous rubber lotion C：80%, aqueous fluorine
Carbon resin lotion 13%, levelling agent BYK-333：1%, antifoaming agent BYK-024：1%, it stirs 2 hours, 120 revs/min of rotating speed,
40 mesh sieve, packaging are crossed after stirring.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on galvanized sheet, temperature is placed in and is more than 10
DEG C, under the conditions of humidity light rain 65%, from 12 hours dry, 50 microns of average dry film thickness.After testing, which has elasticity
Good, impact resistance good (> 9J), adhesive force good (> 4B), concentrated sulfuric acid resistant (5wt%, 24 hours unchanged), resistance to sodium hydroxide
(5wt%, 24 hours unchanged), water-tolerant (24 hours ne-leakages), good weatherability (QUV not dusting in 960 hours), gloss retention
Good (0 grade of loss of gloss), the advantages that self-cleaning is good.
Embodiment 4
1, aqueous rubber lotion is prepared：
Silicone rubber powder is crossed into 40 mesh sieve, and is prepared according to mass percent, silicon rubber：40%, dispersant B YK-9076：
2%, emulsifier：Japanese emulsifier Co., Ltd. Newcol-291-M：8%, Newcol-297：7%, deionized water：43%, it is high
Speed dispersion, emulsification 6 hours, 6000 revs/min of rotating speed cross 40 mesh filter screens after dispersion, emulsification uniformly and aqueous rubber lotion D are made.
2, aqueous rubber coating is prepared：
Following components is prepared according to mass percent, distilled water：20%, aqueous rubber lotion D：65%, it is aqueous organic
Resin emulsion 13%, levelling agent：BYK-333：1%, antifoaming agent BYK-024：1%, it stirs 3 hours, 150 revs/min of rotating speed,
40 mesh sieve, packaging are crossed after stirring.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on paper, temperature is placed in and is more than 10 DEG C,
Under the conditions of humidity light rain 65%, from 12 hours dry, 5 microns of average dry film thickness.After testing, which has flexibility
It gets well, smoothness is good, water-tolerant (24 hours ne-leakages), good weatherability (QUV not dusting in 960 hours), the good (loss of gloss 0 of gloss retention
Grade), the advantages that pollution resistance is good, self-cleaning is good.
Embodiment 5
1, aqueous rubber lotion is prepared：
Aqueous rubber lotion is prepared using the neoprene, hydrogenated nitrile-butadiene rubber, EP rubbers of recycling in the present embodiment 5,
The neoprene, hydrogenated nitrile-butadiene rubber, EP rubbers of recycling are crossed to 40 mesh sieve respectively, and each raw material is prepared according to mass percent
Component, wherein the neoprene 15% recycled, hydrogenated nitrile-butadiene rubber 5%, EP rubbers 20%, dispersant B YK-9076：5%,
Emulsifier：Japanese emulsifier Co., Ltd. Newcol-291-M：5%, Newcol-297：5%, deionized water：45%, rotating speed
5000 revs/min, high speed dispersion, emulsification 3 hours cross 40 mesh filter screens after dispersion, emulsification uniformly and aqueous rubber lotion E are made.
2, aqueous rubber coating is prepared：
Following components is prepared according to mass percent, distilled water：20%, aqueous rubber lotion E：60%, aqueous phenylpropyl alcohol
Resin emulsion 18%, levelling agent：BYK-333：1%, antifoaming agent BYK-024：1%, it stirs 4 hours, 200 revs/min of rotating speed stirs
40 mesh sieve is crossed after mixing, and is packed.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on clean smooth concrete slab surface, is set
In temperature more than 10 DEG C, under the conditions of humidity light rain 65%, from 12 hours dry, 100 microns of average dry film thickness.After testing,
The coating is with flexibility is good, smoothness is good, water-tolerant (24 hours ne-leakages), adhesive force good (> 4B), concentrated sulfuric acid resistant
(5wt%, 24 hours unchanged), resistance to sodium hydroxide (5wt%, 24 hours unchanged), the advantages that pollution resistance is good, self-cleaning is good.
Embodiment 6
1, aqueous rubber lotion is prepared：
Aqueous rubber lotion is prepared using the acrylic rubber of recycling, epichlorohydrin rubber in the present embodiment 5, by the third of recycling
Olefin(e) acid ester rubber, epichlorohydrin rubber cross 40 mesh sieve respectively, and prepare each raw material component according to mass percent, wherein the propylene recycled
Acid esters rubber 20%, epichlorohydrin rubber 20%, dispersant B YK-9076：5%, emulsifier：Japanese emulsifier Co., Ltd. Newcol-
291-M：5%, Newcol-297：5%, deionized water：45%, 6000 revs/min of rotating speed, high speed dispersion, emulsification 4 hours, point
It dissipates, uniformly aqueous rubber lotion F is made in rear 40 mesh filter screens of crossing for emulsification.
2, aqueous rubber coating is prepared：
Following components is prepared according to mass percent, distilled water：30%, aqueous rubber lotion E：45%, aqueous poly- second
Alkene acetate resin lotion 23%, levelling agent：BYK-333：1%, antifoaming agent BYK-024：1%, it stirs 4 hours, 200 turns of rotating speed/
Minute, 40 mesh sieve is crossed after stirring, is packed.
3, experiment detection：The aqueous rubber coating for preparing gained in 2 is coated on clean smooth stone surface, is placed in temperature
Degree is more than 10 DEG C, under the conditions of humidity light rain 65%, from 12 hours dry, 50 microns of average dry film thickness.After testing, the coating
With flexibility good, water-tolerant (24 hours ne-leakages), good weatherability (QUV not dusting in 720 hours) adhesive force good (> 4B),
The advantages that pollution resistance is good, self-cleaning is good.
Finally it should be noted that above example is merely to illustrate the technical solution of the application rather than to its protection domain
Limitation, although the application is described in detail with reference to above-described embodiment, the those of ordinary skill in the field should
Understand：Those skilled in the art read the specific implementation mode of application can still be carried out after the application various changes, modification or
Equivalent replacement, but the above change, modification or equivalent replacement, the application wait authorizing or the claim of issued for approval protects model
Within enclosing.
Claims (10)
1. a kind of aqueous rubber coating, which is characterized in that the rubber coating is by following compositions according to mass percentage composition：
Water：5~35%, aqueous rubber lotion：30~80%, resin aqueous emulsion：0~55%, color stuffing：0~60%, auxiliary agent：0.1
~25%.
2. a kind of aqueous rubber coating according to claim 1, which is characterized in that the water is distilled water, deionization
The arbitrary composition in one kind or the water in water.
3. a kind of aqueous rubber coating according to claim 1, which is characterized in that the aqueous rubber lotion is rubber
The lotion being dispersed in water.
4. according to a kind of described in claim 3 aqueous rubber coating, which is characterized in that the aqueous rubber lotion is according to such as
It is prepared by lower step：
S1, rubber powder component is crossed to 40 mesh sieve；
S2, following raw material is prepared according to mass percent：Rubber powder after being sieved in step S1：30~60%, water：30~
65%, dispersant：1~15%, emulsifier：1~15%；
S3, disperseed after mixing each raw material powder in step S2, emulsified, 1000~8000 revs/min, incorporation time 1
~8 hours；
S4, the mixture after disperseing in step S3, emulsifying uniformly is crossed into 40 mesh filter screens up to aqueous rubber lotion.
5. a kind of aqueous rubber coating according to claim 1, which is characterized in that the rubber is natural rubber, butylbenzene
Rubber, isoprene rubber, neoprene, determines base rubber, nitrile rubber, hydrogenated nitrile-butadiene rubber, EP rubbers, silicon rubber at butadiene rubber
Glue, fluorubber, polyurethane rubber, acrylic rubber, chlorosulfonated polyethylene rubber, epichlorohydrin rubber, chlorinated polyethylene rubber or
The arbitrary composition in one kind or the rubber in chlorine vinegar rubber.
6. a kind of aqueous rubber coating according to claim 5, which is characterized in that the rubber is new rubber or recycling rubber
The mixture of glue or new rubber and recycling rubber.
7. a kind of aqueous rubber coating according to claim 1, which is characterized in that the resin aqueous emulsion is aqueous
Emulsion acrylic resin, aqueous polyurethane resin emulsion, aqueous epoxy resin emulsion, aqueous polyester resin lotion, water alcohol acid
Resin emulsion resin, aqueous polyethylene acetate resin lotion, aqueous styrene-acrylic resin lotion, aqueous rosin resin lotion, aqueous terpene
Olefine resin lotion, aqueous petroleum resin emulsion, resol resins lotion, waterborne organic silicon resin emulsion, water-based fluorocarbon resin
The arbitrary composition in one kind or the resin aqueous emulsion in lotion.
8. a kind of aqueous rubber coating according to claim 1, which is characterized in that the color stuffing be mountain flour, building stones,
Titanium white, barium sulfate, calcium carbonate, talcum powder, kaolin, lithopone, stibium trioxide, zirconium dioxide, lead silicate, montmorillonite, dolomite, lead
In vain, tribasic lead sulfate, lead sulfate, zinc oxide, aluminium oxide, wollastonite, trbasic zinc phosphate, aluminium dihydrogen tripolyphosphate, zinc molybdate, boric acid
Zinc, aluminium powder, copper powder, zinc powder, copper zinc powder, baryta yellow, strontium chromate.Chrome yellow, cadmium yellow, iron oxide yellow, transparent yellow, yellow lead, titanium yellow, calcium
Huang, praseodymium yellow, strontium calcium yellow, iron oxide red, transparent iron oxide red, natural iron oxide red, red lead, cinnabar, antimony trisulfide, cadmium red, chrome tin pink, oxygen
Change cologne earth, Chinese blue, cobalt blue, Tie Lan, ultramarine, basic copper carbonate, chrome oxide green, chrome green, carbon black, iron oxide black, oxidation cobalt black, oxidation
Copper, white carbon, mica, mica titanium, pigment yellow, organic middle Huang, Organic Lemon Huang, the everbright fast yellow of resistance to alcohol, solvent yellow, pigment orange, first
Aniline red, permanent red, naphthol reds, quinacridone are red, paratonere, bronze red, rose-red, pigment violet, quinacridone violet, consolidate forever
Purple, everbright fast violet lake, pigment blue, phthalocyanine blue, naphthol green, alkalescent light green color lake, sun-proof emerald green color lake, plastics ancestor, phthalocyanine green
In one kind or the arbitrary composition in the color stuffing.
9. a kind of aqueous rubber coating according to claim 1, which is characterized in that the auxiliary agent is dispersant, levelling
Agent, emulsifier, thickener, anti-settling agent, anti-fouling agent, preservative, mould inhibitor, algaecide, conductive agent, antistatic agent, disappears at antifoaming agent
It is photo etching, slip agent, scratching resistant, antilubricant, anti-wear agent, coupling agent, light stabilizer, heat stabilizer, adhesion promoter, fire-retardant
Agent, antifreezing agent, hydrophobing agent, mallear stria agent, eliminating smell agent, one kind in anionic additive or the arbitrary composition in the auxiliary agent.
10. a kind of preparation method of aqueous rubber coating according to any one of claims 1 to 9, which is characterized in that including such as
Lower step：
Step 1, raw material mixing：Water, aqueous rubber lotion, water are weighed according to the mass percent range described in claim 1
Property resin emulsion, auxiliary agent, and mix；
Step 2 stirs evenly：By the mixture of step 1 in 50~200 revs/min, stir 1~5 hour；
Step 3, sieving packaging：Mixture after step 2 is stirred packs after crossing 40 mesh sieve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810660123.6A CN108753049A (en) | 2018-06-25 | 2018-06-25 | A kind of aqueous rubber coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810660123.6A CN108753049A (en) | 2018-06-25 | 2018-06-25 | A kind of aqueous rubber coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108753049A true CN108753049A (en) | 2018-11-06 |
Family
ID=63977237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810660123.6A Pending CN108753049A (en) | 2018-06-25 | 2018-06-25 | A kind of aqueous rubber coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108753049A (en) |
Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535854A (en) * | 2018-11-27 | 2019-03-29 | 徐州力奥新能源设备有限公司 | A kind of formula of the emulsion paint of new energy equipment |
| CN110591456A (en) * | 2019-09-18 | 2019-12-20 | 王廷龙 | Modified natural rubber waterproof emulsion and preparation method thereof |
| CN111100507A (en) * | 2019-12-26 | 2020-05-05 | 江苏晶华新材料科技有限公司 | Rubber adhesive tape primer, preparation method and application thereof |
| CN111138943A (en) * | 2020-01-06 | 2020-05-12 | 常州工程职业技术学院 | Preparation method of waterproof leakage-repairing coating |
| CN111253821A (en) * | 2019-10-31 | 2020-06-09 | 浙江省海洋开发研究院 | High-solid-content copper-free linear self-polishing marine antifouling paint |
| CN111334052A (en) * | 2020-04-28 | 2020-06-26 | 四川景文材料科技有限公司 | Multifunctional antibacterial weather-resistant composite material composition and preparation method thereof |
| CN111851070A (en) * | 2020-07-07 | 2020-10-30 | 巩义市泛锐熠辉复合材料有限公司 | Heat-insulating flame-retardant sheet and preparation method thereof |
| CN112063302A (en) * | 2020-09-23 | 2020-12-11 | 何志强 | Environment-friendly woodware paint and preparation method thereof |
| CN112175451A (en) * | 2020-09-30 | 2021-01-05 | 广东美的制冷设备有限公司 | Styrene butadiene rubber-based three-proofing paint and preparation method and use method thereof |
| CN112266639A (en) * | 2020-09-23 | 2021-01-26 | 河南中科国械新材料有限公司 | Environment-friendly moxa powder coating |
| CN112300654A (en) * | 2019-07-26 | 2021-02-02 | 西牛皮防水科技有限公司 | Water-based rubber high-molecular waterproof coating and preparation method thereof |
| CN112552821A (en) * | 2020-12-07 | 2021-03-26 | 王志文 | Anticorrosive bactericidal waterproof coating |
| CN112662265A (en) * | 2020-11-03 | 2021-04-16 | 湖南林特新材料科技有限责任公司 | Exposed high-elasticity color waterproof coating and preparation process thereof |
| CN113372775A (en) * | 2021-06-28 | 2021-09-10 | 哈尔滨市雪鹰工程材料有限公司 | High-cold-resistant anticorrosive paint |
| CN113736366A (en) * | 2021-09-26 | 2021-12-03 | 深圳市深赛尔股份有限公司 | Water-based environment-friendly coating with self-repairing function and preparation method thereof |
| CN113773719A (en) * | 2021-09-06 | 2021-12-10 | 徐州江众建筑材料有限公司 | Water-based epoxy floor coating and preparation process thereof |
| CN113897154A (en) * | 2021-11-25 | 2022-01-07 | 广东兆盈合成新材有限公司 | Novel water-based emulsified glue and preparation method thereof |
| CN113913120A (en) * | 2021-11-25 | 2022-01-11 | 广东兆盈合成新材有限公司 | Novel flexible decorative material and preparation method thereof |
| CN114958099A (en) * | 2022-05-27 | 2022-08-30 | 临沂嘉莱乐装饰材料有限公司 | High-elasticity waterproof coating based on functional modified rubber and preparation method and application thereof |
| CN115403965A (en) * | 2022-08-23 | 2022-11-29 | 河北艾科赛林新材料科技有限公司 | Preparation method of water-based acrylic epoxy resin high-elasticity particle glue |
| CN115491024A (en) * | 2022-10-28 | 2022-12-20 | 广东中星体育设施有限公司 | Preparation method of water-based environment-friendly silicon PU material with strong ultraviolet resistance |
| CN115521696A (en) * | 2022-09-30 | 2022-12-27 | 李承杰 | Wear-resistant polyurethane coating and preparation method thereof |
| CN115926549A (en) * | 2022-12-12 | 2023-04-07 | 瑞航(江苏)新材料科技发展有限公司 | Lost foam coating for cast iron and preparation method thereof |
| CN116063915A (en) * | 2022-09-13 | 2023-05-05 | 隽秀新材料科技(苏州)有限公司 | Preparation method of low-temperature-resistant and crack-resistant water-based paint |
| CN116426172A (en) * | 2023-04-12 | 2023-07-14 | 广东吉美帮新材料有限公司 | Corrosion-resistant acid-alkali-resistant water-based rubber coating and preparation method thereof |
| US20230392023A1 (en) * | 2021-12-16 | 2023-12-07 | Qingdao University | Tire anti-tarnish protective solution and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1488684A (en) * | 2002-10-11 | 2004-04-14 | 中国科学院金属研究所 | Nano composite latex paint and preparing method thereof |
| CN102504694A (en) * | 2011-12-19 | 2012-06-20 | 大连理工大学 | Water-based naon-sized pre-coated coil top coating and preparation method thereof |
| CN102702866A (en) * | 2012-06-13 | 2012-10-03 | 天长市银狐漆业有限公司 | Environmental-friendly thermal insulation waterproof nanometer water-based coating |
| CN102702872A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Environment-friendly type aqueous cloud pattern coating |
| CN103320001A (en) * | 2013-06-24 | 2013-09-25 | 丹阳市佳美化工有限公司 | Two-component PU (Polyurethane) paint |
| CN104673038A (en) * | 2015-03-17 | 2015-06-03 | 北京建筑材料科学研究总院有限公司 | Colored solar heat reflection and heat-insulation coating, as well as preparation method thereof |
| CN105062344A (en) * | 2015-08-14 | 2015-11-18 | 兰州科天环保节能科技有限公司 | Interior wall reflection and heat insulation coating and preparation method thereof |
| CN106221536A (en) * | 2016-08-09 | 2016-12-14 | 深圳市永盛辉实业有限公司 | A kind of aqueous polyurethane elastic coating |
| CN106867392A (en) * | 2017-01-18 | 2017-06-20 | 大禹伟业(北京)国际科技有限公司 | A kind of aqueous polyurethane water-repellent paint and its preparation and construction method |
-
2018
- 2018-06-25 CN CN201810660123.6A patent/CN108753049A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1488684A (en) * | 2002-10-11 | 2004-04-14 | 中国科学院金属研究所 | Nano composite latex paint and preparing method thereof |
| CN102504694A (en) * | 2011-12-19 | 2012-06-20 | 大连理工大学 | Water-based naon-sized pre-coated coil top coating and preparation method thereof |
| CN102702866A (en) * | 2012-06-13 | 2012-10-03 | 天长市银狐漆业有限公司 | Environmental-friendly thermal insulation waterproof nanometer water-based coating |
| CN102702872A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Environment-friendly type aqueous cloud pattern coating |
| CN103320001A (en) * | 2013-06-24 | 2013-09-25 | 丹阳市佳美化工有限公司 | Two-component PU (Polyurethane) paint |
| CN104673038A (en) * | 2015-03-17 | 2015-06-03 | 北京建筑材料科学研究总院有限公司 | Colored solar heat reflection and heat-insulation coating, as well as preparation method thereof |
| CN105062344A (en) * | 2015-08-14 | 2015-11-18 | 兰州科天环保节能科技有限公司 | Interior wall reflection and heat insulation coating and preparation method thereof |
| CN106221536A (en) * | 2016-08-09 | 2016-12-14 | 深圳市永盛辉实业有限公司 | A kind of aqueous polyurethane elastic coating |
| CN106867392A (en) * | 2017-01-18 | 2017-06-20 | 大禹伟业(北京)国际科技有限公司 | A kind of aqueous polyurethane water-repellent paint and its preparation and construction method |
Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535854A (en) * | 2018-11-27 | 2019-03-29 | 徐州力奥新能源设备有限公司 | A kind of formula of the emulsion paint of new energy equipment |
| CN112300654B (en) * | 2019-07-26 | 2022-01-28 | 西牛皮防水科技有限公司 | Water-based rubber high-molecular waterproof coating and preparation method thereof |
| CN112300654A (en) * | 2019-07-26 | 2021-02-02 | 西牛皮防水科技有限公司 | Water-based rubber high-molecular waterproof coating and preparation method thereof |
| CN110591456A (en) * | 2019-09-18 | 2019-12-20 | 王廷龙 | Modified natural rubber waterproof emulsion and preparation method thereof |
| CN111253821A (en) * | 2019-10-31 | 2020-06-09 | 浙江省海洋开发研究院 | High-solid-content copper-free linear self-polishing marine antifouling paint |
| CN111253821B (en) * | 2019-10-31 | 2022-03-22 | 浙江省海洋开发研究院 | High-solid-content copper-free linear self-polishing marine antifouling paint |
| CN111100507A (en) * | 2019-12-26 | 2020-05-05 | 江苏晶华新材料科技有限公司 | Rubber adhesive tape primer, preparation method and application thereof |
| CN111138943A (en) * | 2020-01-06 | 2020-05-12 | 常州工程职业技术学院 | Preparation method of waterproof leakage-repairing coating |
| CN111334052A (en) * | 2020-04-28 | 2020-06-26 | 四川景文材料科技有限公司 | Multifunctional antibacterial weather-resistant composite material composition and preparation method thereof |
| CN111851070A (en) * | 2020-07-07 | 2020-10-30 | 巩义市泛锐熠辉复合材料有限公司 | Heat-insulating flame-retardant sheet and preparation method thereof |
| CN112063302A (en) * | 2020-09-23 | 2020-12-11 | 何志强 | Environment-friendly woodware paint and preparation method thereof |
| CN112266639A (en) * | 2020-09-23 | 2021-01-26 | 河南中科国械新材料有限公司 | Environment-friendly moxa powder coating |
| CN112175451A (en) * | 2020-09-30 | 2021-01-05 | 广东美的制冷设备有限公司 | Styrene butadiene rubber-based three-proofing paint and preparation method and use method thereof |
| CN112175451B (en) * | 2020-09-30 | 2022-02-11 | 广东美的制冷设备有限公司 | Styrene butadiene rubber-based three-proofing paint and preparation method and use method thereof |
| CN112662265A (en) * | 2020-11-03 | 2021-04-16 | 湖南林特新材料科技有限责任公司 | Exposed high-elasticity color waterproof coating and preparation process thereof |
| CN112552821A (en) * | 2020-12-07 | 2021-03-26 | 王志文 | Anticorrosive bactericidal waterproof coating |
| CN113372775A (en) * | 2021-06-28 | 2021-09-10 | 哈尔滨市雪鹰工程材料有限公司 | High-cold-resistant anticorrosive paint |
| CN113773719A (en) * | 2021-09-06 | 2021-12-10 | 徐州江众建筑材料有限公司 | Water-based epoxy floor coating and preparation process thereof |
| CN113736366A (en) * | 2021-09-26 | 2021-12-03 | 深圳市深赛尔股份有限公司 | Water-based environment-friendly coating with self-repairing function and preparation method thereof |
| CN113913120A (en) * | 2021-11-25 | 2022-01-11 | 广东兆盈合成新材有限公司 | Novel flexible decorative material and preparation method thereof |
| CN113897154A (en) * | 2021-11-25 | 2022-01-07 | 广东兆盈合成新材有限公司 | Novel water-based emulsified glue and preparation method thereof |
| US20230392023A1 (en) * | 2021-12-16 | 2023-12-07 | Qingdao University | Tire anti-tarnish protective solution and preparation method thereof |
| US11912893B2 (en) * | 2021-12-16 | 2024-02-27 | Qingdao University | Tire anti-tarnish protective solution and preparation method thereof |
| CN114958099A (en) * | 2022-05-27 | 2022-08-30 | 临沂嘉莱乐装饰材料有限公司 | High-elasticity waterproof coating based on functional modified rubber and preparation method and application thereof |
| CN115403965A (en) * | 2022-08-23 | 2022-11-29 | 河北艾科赛林新材料科技有限公司 | Preparation method of water-based acrylic epoxy resin high-elasticity particle glue |
| CN116063915A (en) * | 2022-09-13 | 2023-05-05 | 隽秀新材料科技(苏州)有限公司 | Preparation method of low-temperature-resistant and crack-resistant water-based paint |
| CN115521696A (en) * | 2022-09-30 | 2022-12-27 | 李承杰 | Wear-resistant polyurethane coating and preparation method thereof |
| CN115491024A (en) * | 2022-10-28 | 2022-12-20 | 广东中星体育设施有限公司 | Preparation method of water-based environment-friendly silicon PU material with strong ultraviolet resistance |
| CN115926549A (en) * | 2022-12-12 | 2023-04-07 | 瑞航(江苏)新材料科技发展有限公司 | Lost foam coating for cast iron and preparation method thereof |
| CN116426172A (en) * | 2023-04-12 | 2023-07-14 | 广东吉美帮新材料有限公司 | Corrosion-resistant acid-alkali-resistant water-based rubber coating and preparation method thereof |
| CN116426172B (en) * | 2023-04-12 | 2024-01-12 | 广东吉美帮新材料有限公司 | Corrosion-resistant acid-alkali-resistant water-based rubber coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108753049A (en) | A kind of aqueous rubber coating and preparation method thereof | |
| CN104591598B (en) | A kind of true mineral varnish and preparation method thereof, construction method | |
| CA2825001C (en) | Inorganic dry powder building coating and preparing method therefor | |
| CN108003713B (en) | Water-based marking paint and preparation method and construction method thereof | |
| CN105694550B (en) | The single-component water-based inorganic floor coatings formula of one kind and manufacturing technology | |
| CN104673038A (en) | Colored solar heat reflection and heat-insulation coating, as well as preparation method thereof | |
| CN101679796B (en) | Method for applying corrosion protection coatings to metal surfaces | |
| CN104046189A (en) | Water-based multicolor granite-like paint and preparation method thereof | |
| CN102433050B (en) | Nanometer multifunctional substrate coating and preparation method thereof | |
| CN101328389A (en) | Nanometer grade environment-friendly type color aqueous waterproof coating material | |
| CN109294383A (en) | A kind of fireproof coating and preparation method thereof | |
| CN102585633B (en) | Coating composition with ceramic imitation effect | |
| CN102617103B (en) | Not containing inorganic dry powder construction paint and the production method thereof of solidifying agent | |
| KR101916410B1 (en) | water soluble paint compositions for surface sign of paved road | |
| CN105800998A (en) | Ultra-nanometer color concrete seal solidification agent | |
| CN203905339U (en) | Facing structure of inorganic dry powder wall paper | |
| CN110357490A (en) | Waterborne polymeric binding material, colored sealing mixture and preparation method thereof | |
| CN108003734A (en) | A kind of water-based inner-outer wall anti-cracking waterproof primary coat and preparation method | |
| CN104494226B (en) | A kind of waterproof thermal-insulated fireproof level material and construction technology thereof | |
| CN104745023A (en) | Inorganic dry powder solid color prime coat and application thereof | |
| CN106866047A (en) | A kind of antistatic inorganic dry powder construction paint and its application | |
| US11098199B2 (en) | Method for manufacturing bismuth based pigment having an improved alkaline resistance by encapsulating said pigment with a chelating agent | |
| CN107083134A (en) | A kind of anti-speck rainprint pure acrylate elastic coating and preparation method thereof | |
| JP2011184896A (en) | Waterproof material and method for repairing waterproof layer | |
| CN105176279A (en) | Paint for external wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181106 |