CN102702872A - Environment-friendly type aqueous cloud pattern coating - Google Patents
Environment-friendly type aqueous cloud pattern coating Download PDFInfo
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- CN102702872A CN102702872A CN2012101967817A CN201210196781A CN102702872A CN 102702872 A CN102702872 A CN 102702872A CN 2012101967817 A CN2012101967817 A CN 2012101967817A CN 201210196781 A CN201210196781 A CN 201210196781A CN 102702872 A CN102702872 A CN 102702872A
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Abstract
The invention provides an environment-friendly type aqueous cloud pattern coating which contains the following components in part by weight: 5-30 parts of deionized water, 3-10 parts of film-forming auxiliary agent, 0.1-0.5 part of wetting agent, 2.0-5.0 parts of dispersant, 5-20 parts of filler, 20-50 parts of emulsion or water dispersion resin and 5-25 parts of urea. The aqueous coating provided by the invention has good adhesive force on wood material; the formed lacquer film is full, and has certain hardness, low VOC (volatile organic chemical) content and no heavy metal; and at the same time, while painting, the aqueous coating has the cloud pattern and villiform special effect, and is mild and rich in three-dimension effect.
Description
Technical field
The present invention relates to a kind of water-borne coatings, the aqueous coating that relates in particular to a kind of feature of environmental protection has the coating of cloud effect.
Background technology
Traditional solvent paint (being commonly called as paint) can produce harm to HUMAN HEALTH, environment, and especially when indoor use, it is long that deleterious organic solvents such as benzene class continue the volatilization time, the health and lives safety that directly endangers the people.Can make illnesss such as the people headache occurs, feels sick, throat pain, asthma such as volatile organic compounds (VOC); Free isocyanate (TDI) belongs to the induction type characteristic of concentration and poisons compound by force, can cause bronchitis, asthma even suffocates; Benzene is high malicious carcinogenic substance, mainly influences hemopoietic system, neural system; The plumbous paint that makes has various chromatic colours, and still plumbous harm to human body but can't neglect.The plumbous people of long-term contact trace, accumulative lead can hinder the formation of hemocyte, causes people's intelligence to descend, and study, job performance are low; Can make the people chronic poisoning symptoms such as mental disorder, bad dream, insomnia, headache occur when accumulating to a certain degree; That severe patient also can have is weak, poor appetite, feel sick, abdominal distension, stomachache or diarrhoea etc.Lead also can get into cerebral tissue through blood, and infringement cerebellum and pallium disturb Metabolic activity, makes nutritive substance and oxygen supply not enough, causes the swelling of the little capillary endothelium confluent monolayer cells of brain, and then develops into diffuse brain injuries.
Therefore, the coating of exploitation Environmental Safety is an essential technical problem that solves of considering for health.Disclose a kind of environment friendly antibacterial waterborne paint and preparation method thereof like CN 101486861A, component comprises deionized water, sterilant, film coalescence aid, skimmer, wetting agent, dispersion agent, nano TiO 2, emulsion or water dispersion resin, filler, anti-settling agent, flow agent, thickening material, PH regulator, scratching resistant or slip(ping)agent, pigment or tinting material, special function additive etc.The preparation method comprises: A, preparation aqueous dispersion; In B, the emulsion that add to stir the aqueous dispersion of steps A gained, it is even to add film coalescence aid, flow agent, thickening material, anti-settling agent, PH regulator dispersed with stirring again; C, adding pigment or tinting material; D, moisturizing and when being adjusted to 25 ℃ stormer viscosity be that 65～90KU must this water-borne coatings.
And at present; The innovation of surface effect is constantly pursued in application (promptly referring to metal and nonmetallic surface protective cover or ornament layer) field; Color change, gloss change, multiple match etc. all has appearance; How developing a kind of not only Environmental Safety but also have amazing surperficial layer effect, is a problem that is worth research.
Summary of the invention
It is a kind of good to wood materials sticking power to the object of the present invention is to provide, and paint film is plentiful, have certain degree of hardness, and low VOC, heavy metal free, and the water-borne coatings that has cloud, fine hair shape special-effect during application seem soft and be rich in stereoscopic sensation.The coating result of coating provided by the present invention is unexpected.
Feature of environmental protection water-based cloud paint provided by the present invention, contain following component by weight:
As optimal technical scheme, coating provided by the present invention contains following component by weight:
Because the present invention selects to have added urea; And be water-soluble material, in conjunction with conventional waterborne film-forming material and film coalescence aid, urea volatilization along with water in the construction dissolution process forms the white crystals body; Constitute cloud, villous special-effect, and can show lastingly.
As optimal technical scheme, described film coalescence aid is selected a kind of or its combination of Macrogol 200, Liquid Macrogol, PEG 400, Ucar 35 phenylate PPH, alcohol ester-12 for use.Film coalescence aid is selected the organic cpds of no physiology toxicity, VOC free for use.Film coalescence aid is selected a kind of or its combination of Macrogol 200, Liquid Macrogol, PEG 400, Ucar 35 phenylate PPH, alcohol ester-12 for use.
Wetting agent is used to improve the surface tension and the perviousness of coating on the one hand, makes it can wetting better ground, thereby improves ADHESION OF PAINTS power; Assistance to filler and pigment etc. disperses and assists to prevent to sink to act on the other hand; Can assist powder such as color stuffing in coating, to disperse and assist the coating anti-settling agent follow-up anti-heavy; Open in the anti-settling after rare at coating, the anti-heavy effect that wetting dispersing agent plays is also more important than anti-settling agent far away.So wetting dispersing agent is very important a kind of auxiliary agent in the coating.Water-borne coatings wetting agent commonly used has ethanol, Ucar 35, glycerine, methyl-sulphoxide, and tensio-active agent is like AS, some EPE polyol EPE (this coils class), polyoxyethylene-type surfactant (Tweens) etc.
Dispersion agent can improve and improve the auxiliary agent of solid or liquid material dispersing property.When solid dye grinds, add dispersion agent, help particle to pulverize and stop broken particle aggregation and keep dispersion stable.Water-fast oily liquid can be dispersed into very little liquid pearl under high shear stirs, after stopping stirring, and very fast layering under the effect of IT, and stir after adding dispersion agent, then can form stable emulsion.It mainly acts on is the IT that reduces between liquid-liquid and solid-liquid.Thereby dispersion agent also is a tensio-active agent.Kind has anionic, cationic, non-ionic type, amphoteric and polymer.Should select according to pigment and stopping composition type when selecting the type of dispersion agent.
As optimal technical scheme, described filler is selected a kind of or its combination of ultra-fine fine particle calcium carbonate, talcum powder, process white, silicon calcium powder, Zinic stearas for use.Filler is selected a kind of or its combination of the ultra-fine fine particle calcium carbonate that do not contain heavy metal, talcum powder, process white, silicon calcium powder, Zinic stearas for use.
As optimal technical scheme, described emulsion or water dispersion resin are selected a kind of or its combination of benzene emulsion, organosilicon crylic acid latex, vinyl resin or emulsion, urethane resin or emulsion, aqueous polyester resin or emulsion, epoxy water-base resin or emulsion for use.It is not contain free monomer that emulsion or water dispersion resin are selected for use; Do not contain triphen, a kind of or its combination of the benzene emulsion of content≤65g/L of VOC, organosilicon crylic acid latex, vinyl resin or emulsion, urethane resin or emulsion, aqueous polyester resin or emulsion, epoxy water-base resin or emulsion.
As optimal technical scheme, water-borne coatings provided by the present invention also contains the pigment of 5-10 part, the skimmer of 0.5-1.5 part, the thickening material of 1.0-3.0 part, the sanitas of 0.02-0.1 part.
As optimal technical scheme, described pigment is selected a kind of or its combination of pigment dyestuff, dyestuff, transparent ferric oxide, peace crust powder pigment for use.Pigment can be chosen interpolation wantonly.
As optimal technical scheme, described skimmer can select for use in mineral oils, the organopolysiloxane class one or both compound.Coating by produce, canned, transportation, construction all have mechanical force to forming the whole process of paint film at last; Must a large amount of air be brought in the latex system, a large amount of foams can make the production operation difficulty, and plant factor is not enough; It is insufficient to cause pigment and stopping composition to disperse, even can't produce down.It is to stay many defectives to filming that a large amount of foams brings graver results in the time of can giving construction, like shrinkage cavity, and paint film disadvantages such as pin hole, crater.An effective skimmer acts on quite important in coating system.
Foam can be regarded as a quite a large amount of insoluble gas and is dispersed in the dispersion-s in the small amount of liquid, is under the effect of mechanical force, could to form.Foam is unsettled in itself, sometimes because the effect of the thermal motion of liquid own is enough to make it to vanish.It is generally acknowledged that froth breaking mechanism can be divided into following four processes: 1, skimmer is adsorbed onto the foamy surface; 2, skimmer is penetrated into the foamy surface; 3, skimmer spreads on foam surface, and the adsorption surface promoting agent; 4, foam tension imbalance-broken bubble.
Can be known that by froth breaking mechanism skimmer is the liquid of low surface tension, generally should have following characteristic: 1, the surface tension of skimmer is less than the surface tension that needs froth breaking liquid self; 2, the solubleness in needing the liquid of froth breaking is as far as possible little; 3, good dispersiveness to be arranged.4, can not react with the liquid of want froth breaking, can not influence the force of cohesion of pigment in the coating and the stability of emulsion.5, stronger diffusive force to be arranged.6, can not influence the performance of finished product rubber-emulsion paint.7, unpleasant odor can not be arranged.
As optimal technical scheme, what described thickening material was selected for use is the nonionic polyurethane compounds.Coating and viscosity are closely related.It has a very important characteristic is exactly thixotropy.Thixotropic being characterised in that has when static certain very weak reticulated structure to form, and forms physical crosslinking like the hydrogen bond between polymkeric substance; With the pigment particles is that bridge all shows as thickening by " crosslinked " that its polar adsorption forms between the polymkeric substance.Viscosity and shearing force then show as thixotropy, have applied viscosity degradation after the shearing force, and promptly reticulated structure is destroyed; In case the shearing force of removing, reticulated structure progressively recovers, and viscosity rises again.It is a pseudo-plasticity phenomenon relevant with time and shearing force.When coating ideal state promptly is storage, higher viscosity is arranged to stablize whole system better; During coating application, need lower viscosity to obtain to construct preferably leveling characteristics.This thixotropy needs to rely on an ideal rheology thickened systems just can reach, it well this quiet one moving viscosity of balance change, thixotropy is preferably promptly arranged.
As optimal technical scheme, described sanitas is 1,2-benzisothiazole-3-1 and verivate thereof.Sanitas can suppress the mould-growth in the coating, makes coating keep steady quality.
The preparation method of coating provided by the present invention is with being prepared from according to mixing to stir according to formula materials provided by the present invention, mixes stir about 1 hour to evenly, mixes churning time and can adjust according to practical situation.
Water-borne coatings provided by the present invention not only has low VOC, heavy metal free, and the water-borne coatings that has cloud, fine hair shape special-effect during application, seems soft and is rich in stereoscopic sensation.Coating provided by the present invention has purposes widely, can be used for children's wooden articles, also can be used for wooden furniture, wooden office appliance and all goods relevant with timber, also can be used for fields such as metal, plastics, coating for internal and external wall.
Embodiment
For ease of understanding the present invention, it is following that the present invention enumerates embodiment.Those skilled in the art should understand, and said embodiment only is used for helping to understand the present invention, should not be regarded as concrete restriction of the present invention.
Specify like nothing, various raw materials of the present invention all can obtain through commercially available; Or prepare according to the ordinary method of this area.Only if definition or explanation are arranged in addition, the same meaning that all specialties used herein and scientific words and those skilled in the art are familiar with.Any in addition with the institute similar content of putting down in writing or the equalization method and material all can be applicable in the inventive method.
The experimental technique of unreceipted actual conditions in the following example is measured according to national standard usually.If there is not a corresponding national standards, then carry out according to general international standard, normal condition or according to the condition that manufacturer advises.Unless otherwise indicated, otherwise all umbers are weight part, and all per-cents are weight percentage, and described polymericular weight is a number-average molecular weight.
Only if definition or explanation are arranged in addition, the same meaning that all specialties used herein and scientific words and those skilled in the art are familiar with.Any in addition with the institute similar content of putting down in writing or the equalization method and material all can be applicable in the inventive method.
The water-base resin that the present invention adopts is benzene emulsion, organosilicon crylic acid latex, vinyl resin or emulsion, urethane resin or emulsion, aqueous polyester resin or emulsion, epoxy water-base resin or emulsion etc., require resin not contain free monomer, do not contain triphen, VOC low (≤65g/L).Film coalescence aid in the water-borne coatings is selected organic cpds such as Macrogol 200, Liquid Macrogol or PEG 400, Ucar 35 phenylate PPH, alcohol ester-12 of no physiology toxicity, VOC free etc. for use.Pigment or tinting material are selected pigment dyestuff, dyestuff, transparent ferric oxide and An Ba powder pigment etc. for use in the coating, and pigment is used for solid color enamel (not appearing the application of wood grain); Dyestuff, transparent ferric oxide and An Ba powder are used for colored varnish (appearing the application of wood grain).Avoid mineral dye, because wherein contain a certain amount of heavy metal, if heavy metal meets the hygienic safety standard and can adopt in the mineral dye as far as possible.Filler generally is used in aqueous putty or the solid color enamel, selects for use to meet ultra-fine fine particle calcium carbonate, talcum powder, process white, silicon calcium powder and the Zinic stearas that hygienic requirements does not contain heavy metal.Other auxiliary agent such as dispersion agent, thickening material, skimmer etc. are close with common coating, select zero or low VOC, do not contain the product of APE.
Embodiment 1:
Embodiment 2:
Embodiment 3:
Embodiment 4
The preparation method for coating of embodiment 1 ~ 4 adopts preparation method or the conventional preparation method for coating of providing of the present invention.
Comparative Examples is respectively the embodiment 1,2,3 among the CN 101486861A.
The method for testing performance of the water-borne coatings of water-borne coatings of the present invention and Comparative Examples:
(1) water-borne coatings package stability testing method: sample places in the constant temperature oven (temperature is controlled at 50 ± 2 ℃) to place 30 days, or normal temperature left standstill 90 days, observes loose colour, deposition whether to occur or divide water etc., as does not have above-mentioned phenomenon and be chosen as outstanding.
(2) water-borne coatings volatile organic matter (VOC) and determining heavy metals are carried out according to " interior decoration finishing material limits of harmful substances " GB 18582-2007 standard.
(3) other performance of water-borne coatings is identical with the aqueous woodware paint method for testing performance.
Three embodiment of the present invention and prepared water-borne coatings performance of Comparative Examples such as following table 1.
Table 1 performance test results
Embodiments of the invention and Comparative Examples all do not detect heavy metal.But when using the coating brushing of coating of the present invention and Comparative Examples, can see the coating result that coating provided by the present invention has cloud or villous beauty, and Comparative Examples is not seen.
Applicant's statement; The present invention explains detailed process equipment of the present invention and technical process through the foregoing description; But the present invention is not limited to above-mentioned detailed process equipment and technical process, does not mean that promptly the present invention must rely on above-mentioned detailed process equipment and technical process could be implemented.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. an environment-friendly type aqueous cloud paint is characterized in that, contains following component by weight:
2. water-borne coatings as claimed in claim 1 is characterized in that, contains following component by weight:
3. according to claim 1 or claim 2 water-borne coatings is characterized in that described film coalescence aid is selected a kind of or its combination of Macrogol 200, Liquid Macrogol, PEG 400, Ucar 35 phenylate PPH, alcohol ester-12 for use.
4. according to claim 1 or claim 2 water-borne coatings is characterized in that described filler is selected a kind of or its combination of ultra-fine fine particle calcium carbonate, talcum powder, process white, silicon calcium powder, Zinic stearas for use.
5. according to claim 1 or claim 2 water-borne coatings; It is characterized in that described emulsion or water dispersion resin are selected a kind of or its combination of benzene emulsion, organosilicon crylic acid latex, vinyl resin or emulsion, urethane resin or emulsion, aqueous polyester resin or emulsion, epoxy water-base resin or emulsion for use.
6. according to claim 1 or claim 2 water-borne coatings is characterized in that, also contains the pigment of 5-10 part, the skimmer of 0.5-1.5 part, the thickening material of 1.0-3.0 part, the sanitas of 0.02-0.1 part.
7. water-borne coatings as claimed in claim 6 is characterized in that, described pigment is selected a kind of or its combination of pigment dyestuff, dyestuff, transparent ferric oxide, peace crust powder pigment for use.
8. water-borne coatings as claimed in claim 6 is characterized in that, described skimmer can select for use in mineral oils, the organopolysiloxane class one or both compound.
9. water-borne coatings as claimed in claim 6 is characterized in that, what described thickening material was selected for use is the nonionic polyurethane compounds.
10. water-borne coatings as claimed in claim 6 is characterized in that, described sanitas is 1,2-benzisothiazole-3-1 and verivate thereof.
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| CN2012101967817A CN102702872A (en) | 2012-06-14 | 2012-06-14 | Environment-friendly type aqueous cloud pattern coating |
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| CN2012101967817A CN102702872A (en) | 2012-06-14 | 2012-06-14 | Environment-friendly type aqueous cloud pattern coating |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214887A (en) * | 2013-02-20 | 2013-07-24 | 江苏吉福新材料有限公司 | Water-resistant paint |
| CN103450751A (en) * | 2013-08-22 | 2013-12-18 | 吴江市物华五金制品有限公司 | Antibacterial wet-wiping-resistant interior wall coating |
| CN103709812A (en) * | 2012-10-05 | 2014-04-09 | 魏诰辰 | Wall cancer prevention and treatment coating |
| CN103980773A (en) * | 2013-08-18 | 2014-08-13 | 全椒县泰峰新材料销售有限公司 | Flame retardant coating for exterior wall |
| CN105219222A (en) * | 2015-10-28 | 2016-01-06 | 苏州赛斯德工程设备有限公司 | A kind of heat insulation water-borne coatings and preparation method thereof |
| CN105219221A (en) * | 2015-10-28 | 2016-01-06 | 苏州赛斯德工程设备有限公司 | A kind of outer wall water-based coating and preparation method thereof |
| CN106087557A (en) * | 2016-06-16 | 2016-11-09 | 铜陵锋帆彩色印务有限公司 | Waterproof honeycomb Packaging Box and preparation method thereof |
| CN106700778A (en) * | 2016-12-15 | 2017-05-24 | 江门市联益精细化工有限公司 | Water-based textured paint and preparation method thereof |
| CN106928845A (en) * | 2017-03-22 | 2017-07-07 | 合肥浦尔菲电线科技有限公司 | A kind of environment-friendly type floor paint and preparation method thereof |
| CN107082999A (en) * | 2017-05-26 | 2017-08-22 | 刘文齐 | A kind of multifunctional aqueous binding resin and preparation method thereof |
| CN107903744A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田科技服务有限公司 | A kind of environment friendly emulsion paint |
| CN108753049A (en) * | 2018-06-25 | 2018-11-06 | 无锡万博涂料化工有限公司 | A kind of aqueous rubber coating and preparation method thereof |
| CN113861824A (en) * | 2021-10-15 | 2021-12-31 | 亚士创能科技(上海)股份有限公司 | Artistic coating and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
| CN101550292A (en) * | 2009-05-19 | 2009-10-07 | 天津市现代人再就业服务有限公司 | Environment protecting water-based paint |
| CN101747692A (en) * | 2008-12-22 | 2010-06-23 | 怀懋企业有限公司 | Components of waterborne paint |
| CN102140287A (en) * | 2011-03-25 | 2011-08-03 | 章太平 | Water-based cloud coating |
-
2012
- 2012-06-14 CN CN2012101967817A patent/CN102702872A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
| CN101747692A (en) * | 2008-12-22 | 2010-06-23 | 怀懋企业有限公司 | Components of waterborne paint |
| CN101550292A (en) * | 2009-05-19 | 2009-10-07 | 天津市现代人再就业服务有限公司 | Environment protecting water-based paint |
| CN102140287A (en) * | 2011-03-25 | 2011-08-03 | 章太平 | Water-based cloud coating |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709812A (en) * | 2012-10-05 | 2014-04-09 | 魏诰辰 | Wall cancer prevention and treatment coating |
| CN103214887A (en) * | 2013-02-20 | 2013-07-24 | 江苏吉福新材料有限公司 | Water-resistant paint |
| CN103980773A (en) * | 2013-08-18 | 2014-08-13 | 全椒县泰峰新材料销售有限公司 | Flame retardant coating for exterior wall |
| CN103450751A (en) * | 2013-08-22 | 2013-12-18 | 吴江市物华五金制品有限公司 | Antibacterial wet-wiping-resistant interior wall coating |
| CN105219222A (en) * | 2015-10-28 | 2016-01-06 | 苏州赛斯德工程设备有限公司 | A kind of heat insulation water-borne coatings and preparation method thereof |
| CN105219221A (en) * | 2015-10-28 | 2016-01-06 | 苏州赛斯德工程设备有限公司 | A kind of outer wall water-based coating and preparation method thereof |
| CN106087557A (en) * | 2016-06-16 | 2016-11-09 | 铜陵锋帆彩色印务有限公司 | Waterproof honeycomb Packaging Box and preparation method thereof |
| CN106700778A (en) * | 2016-12-15 | 2017-05-24 | 江门市联益精细化工有限公司 | Water-based textured paint and preparation method thereof |
| CN106700778B (en) * | 2016-12-15 | 2020-08-28 | 江门市联益精细化工有限公司 | Water-based reticulate paint |
| CN106928845A (en) * | 2017-03-22 | 2017-07-07 | 合肥浦尔菲电线科技有限公司 | A kind of environment-friendly type floor paint and preparation method thereof |
| CN107082999A (en) * | 2017-05-26 | 2017-08-22 | 刘文齐 | A kind of multifunctional aqueous binding resin and preparation method thereof |
| CN107903744A (en) * | 2017-12-12 | 2018-04-13 | 佛山早稻田科技服务有限公司 | A kind of environment friendly emulsion paint |
| CN108753049A (en) * | 2018-06-25 | 2018-11-06 | 无锡万博涂料化工有限公司 | A kind of aqueous rubber coating and preparation method thereof |
| CN113861824A (en) * | 2021-10-15 | 2021-12-31 | 亚士创能科技(上海)股份有限公司 | Artistic coating and preparation method and application thereof |
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Application publication date: 20121003 |