CN106866047A - A kind of antistatic inorganic dry powder construction paint and its application - Google Patents
A kind of antistatic inorganic dry powder construction paint and its application Download PDFInfo
- Publication number
- CN106866047A CN106866047A CN201611260927.4A CN201611260927A CN106866047A CN 106866047 A CN106866047 A CN 106866047A CN 201611260927 A CN201611260927 A CN 201611260927A CN 106866047 A CN106866047 A CN 106866047A
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- CN
- China
- Prior art keywords
- dry powder
- antistatic
- inorganic dry
- construction paint
- antistatic inorganic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/90—Electrical properties
- C04B2111/905—Anti-static materials
Abstract
The invention provides a kind of antistatic inorganic dry powder construction paint and its application.The antistatic inorganic dry powder construction paint includes following components by weight ratio：15~160 parts of inorganic coagulation materials, 60~170 parts of re-dispersible glue powders, 40~400 parts of conducting powder functional fillers, 15~120 parts of pigment, 200~550 parts of fillers.The antistatic inorganic dry powder construction paint is suitable to inner wall of building now with using, it is also suitable for terrace, the metope of cosmetic requirement computer floor higher, instrument and meter room and food and medicine industry dust-free workshop, and other are to the place that avoids fire plague grade requirement higher；The antistatic inorganic dry powder construction paint is coated on the coating that metope is formed, and reaches≤1.0 × 105The sheet resistance of Ω, antistatic performance is good, and other performance can reach GB 50,944 2013《Antistatic engineering construction and inspection of quality specification》Requirement；Additionally, also there is the antistatic inorganic dry powder construction paint harmful substances such as the remarkable feature of environmental protection, VOC, benzene homologues, formaldehyde to be not detecting.
Description
Technical field
The present invention relates to a kind of building coating, more particularly to a kind of antistatic inorganic dry powder construction paint and its application.
Background technology
Inorganic dry powder construction paint is a kind of conventional coating, and compared to organic coating, it has following characteristic：(1) no
Combustion property, the physical characteristic with its inorganic matter for being included, its heat-resisting property is especially good, not only will not at a high temperature of 1200 DEG C
Burning, will not typically burn, it is also possible to have fire retardation；(2) gas permeability, the breathing power with water proofing property and height makes stone
The moisture of building interior freely outwards volatilizees；There can be the filtration of alkaline matter simultaneously, coating bubble can be prevented, produced
The shortcomings of heat bursts and plays scale and receive alkali pollution after peeling off and construct；(3) aseptic and liver moss grows, due to its be free of it is organic
Thing, i.e., without organic nutrient substance, so as to prevent mushroom and moss growth, and can have the characteristic of alkali, can kill liver moss
Sporozoite, and the surface of building is kept drying；(4) keep painting color colour-fast, there is the characteristic of inorganic matter because of it, plus
Can be processed by special oxidation modification, it can effectively prevent from fading, therefore its color has stronger weatherability；(5) have
Beneficial to preserving the ecological environment, because it is free of any organic chemistry raw material or solvent, during production and application, will not discharge
Volatile organic matter.
Therefore, inorganic dry powder construction paint is widely used in reality.CN100558834C discloses a kind of environment-friendly dry
Powder coating, is main component by redispersable latex powder and white cement, saves many additives in emulsion paint, reduces and waves
Hair property organic compound；And for example, cement-based powder coating disclosed in CN101230214B, by white cement, redispersable latex powder
Constituted with the additive for making coating play imitative ceramic effect and luminous effect, it has good durability；And for example,
CN102173710A discloses a kind of gypsum base inorganic powder, includes the components such as land plaster, white cement and polyvinyl alcohol micro mist,
By chemical bond and effect, traditional dry powder paint poor durability is solved the problems, such as.However, in actual applications, most of city
The inorganic dry powder construction paint sold is still present the phenomenon of top layer static electrification, and this is unfavorable for the use of inner wall of building, particularly disadvantageous
In terrace, the metope of cosmetic requirement computer floor higher, instrument and meter room and food and medicine industry dust-free workshop, and
There is potential safety hazard to a certain extent to the place that avoids fire plague grade requirement higher in other.
Anti-static coatings are that one kind is applied over body surface, are allowed to certain conduction electric current and eliminate stored charge energy
The functional coating of power.The coating is, using the organic polymer for insulating as main film forming matter, equably to mix conductive filler, profit
The coating with antistatic performance being made of the electric action of conductive filler.Its Antistatic mechanism is that binder resin is filled out with conduction
After material mixing, solidification, conductive filler contacts with each other to form continuous supply chain network structure, and coating is had static electricity resistance.
Although in the prior art in the presence of the technical scheme of some anti-static coatings, for example, CN1460699A discloses one kind
Solvent-free antistatic epoxy floor paint, wherein, by low molecular weight liquid epoxy, reactive diluent, Ricinate A and
B, defoamer, levelling agent, sagging inhibitor, conductive filler, mill base etc. constitute colored paint component；It is with modified cycloaliphatic amine and drier
Curing system.And for example, CN105017933A discloses a kind of preparation method of anti-static coatings, and in particular to one kind has excellent
The composite resin type anti-static coatings and preparation method of electric conductivity and corrosion resisting property；It uses bisphenol A type epoxy resin, end
The combination of epoxy-modified polyurethane resin, the compound resin of polyester resin and electric conductivity potassium titanate crystal whisker and ZnOw.
However, these coating are excessive containing organic principle, composition is more, prepares complicated, is not suitable for inner wall of building now with using.Therefore,
It is one of emphasis of research staff's research of the art to develop a kind of new antistatic inorganic dry powder construction paint.
The content of the invention
In order to make up above-mentioned technological deficiency present in prior art, in order to improve the antistatic of inorganic dry powder construction paint
Performance, the first aspect of the present invention, there is provided a kind of antistatic inorganic dry powder construction paint, it is by weight ratio comprising following
Component：
Wherein, inorganic coagulation material, re-dispersible glue powder are collectively used as binding agent.
Preferably, in above-mentioned antistatic inorganic dry powder construction paint, the inorganic coagulation material be selected from cement, lime,
The mixture of any one or more in gypsum.
Preferably, in above-mentioned antistatic inorganic dry powder construction paint, the re-dispersible glue powder is by polymer emulsion
It is obtained after drying, wherein described polymer is selected from：Monoolefine, alkadienes, acrylic acid, acroleic acid resin, methacrylic acid,
The homopolymers that methacrylate, tertiary carbonic ester, fatty acid ethylene polyisocyanate polyaddition are obtained, or bipolymer or terpolymer
In the mixture of any one or more；Wherein, the formula of the fatty acid vinyl ester is R-CO-O-CH=CH2。
It is further preferred that in above-mentioned antistatic inorganic dry powder construction paint, the general formula R-CO-O-CH=CH2In
R bases be selected from：The alkyl group of C1-C10, the cycloalkyl of C5-C10, the alkenyl of C2-C10.
Preferably, in above-mentioned antistatic inorganic dry powder construction paint, the conducting powder functional filler is selected from conductive titanium
It is any in white powder, conductive potassium titanate, conductive mica powder, conductive barium sulfate, electrically conductive graphite powder, conductive carbon fibre, silver-plated copper powder
One or more of mixture.
Preferably, in above-mentioned antistatic inorganic dry powder construction paint, the pigment is selected from titanium dioxide, iron oxide red, oxygen
Change iron oxide yellow, iron oxide black, lithopone, carbon black, cadmium red, cadmium yellow, lead chromate yellow, chrome oxide green, barba hispanica, zinc oxide, zinc yellow, cobalt blue,
The mixture of any one or more in phthalocyanine pigment, azo pigment, quinacridone-type pigments.
Preferably, in above-mentioned antistatic inorganic dry powder construction paint, described filler is selected from silica, silicate, carbonic acid
Any one or more mixed in salt, carbide, sulfate, sulfide, nitride, metal oxide, metal hydroxides
Compound.
It is further preferred that in above-mentioned antistatic inorganic dry powder construction paint, also including additive, also, each component
Weight it is as follows：
It is further preferred that in above-mentioned antistatic inorganic dry powder construction paint, the additive is selected from defoamer, draws
The mixture of any one or more in gas agent, water reducer, thixotroping rheological agent, thickener, cracking resistance agent.
The second aspect of the present invention, there is provided a kind of antistatic inorganic dry powder construction paint is applied over answering for inner wall of building
With, it is characterised in that by each component of antistatic inorganic dry powder construction paint described according to a first aspect of the present invention it is dry-mixed
Together, before application, scene is added water and stirs, and thin matter decorative coveringn, its sheet resistance are formed in inner wall of building after application
≤1.0×105Ω.Certainly, as a kind of anti-static coatings, antistatic inorganic dry powder construction paint of the present invention can also quilt
Terrace, the metope of cosmetic requirement computer floor higher, instrument and meter room and food and medicine industry dust-free workshop are applied to,
And other are to the place that avoids fire plague grade requirement higher.
Technical scheme provided by the present invention, compared with prior art with advantages below and beneficial effect：It is described anti-quiet
Electric inorganic dry powder construction paint is suitable to the mixing that adds water of dry-mixed rear scene and prepares, and in other words, antistatic inorganic powder building is applied
Material can transport for long-distance in the form of dry powder, significantly save cost of transportation, and be fully compatible for inner wall of building now with using, meanwhile,
Can be also suitably used for cosmetic requirement computer floor higher, the terrace of instrument and meter room and food and medicine industry dust-free workshop,
Metope, and other are to the place that avoids fire plague grade requirement higher；The antistatic inorganic dry powder construction paint is applied
The coating that metope is formed is overlying on ,≤1.0 × 10 are reached5The sheet resistance of Ω, antistatic performance is good, and other performance can reach
To GB 50944-2013《Antistatic engineering construction and inspection of quality specification》Requirement；Additionally, antistatic of the present invention without
Machine Dry Powder Architectural Paint also there is the harmful substances such as the remarkable feature of environmental protection, VOC, benzene homologues, formaldehyde to be do not detect.
Specific embodiment
The first aspect of the present invention, there is provided a kind of antistatic inorganic dry powder construction paint, it is included by weight ratio
Following components：
In a preferred embodiment, the inorganic coagulation material is selected from any one in cement, lime, gypsum or many
The mixture planted.
In a preferred embodiment, the re-dispersible glue powder is obtained after being dried by polymer emulsion, wherein institute
The polymer stated is selected from：Monoolefine, alkadienes, acrylic acid, acroleic acid resin, methacrylic acid, methacrylate, versatic acid
In the homopolymers that ester, fatty acid ethylene polyisocyanate polyaddition are obtained, or bipolymer or terpolymer any one or more
Mixture；Wherein, the formula of the fatty acid vinyl ester is R-CO-O-CH=CH2。
In a further preferred embodiment, the general formula R-CO-O-CH=CH2In R bases be selected from：C1-C10's
Alkyl group, the cycloalkyl of C5-C10, the alkenyl of C2-C10.
In a preferred embodiment, the conducting powder functional filler is selected from conductive titanium dioxide, conductive potassium titanate, conduction
The mixture of any one or more in mica powder, conductive barium sulfate, electrically conductive graphite powder, conductive carbon fibre, silver-plated copper powder.
In a preferred embodiment, the pigment is selected from titanium dioxide, iron oxide red, iron oxide yellow, iron oxide black, vertical moral
Powder, carbon black, cadmium red, cadmium yellow, lead chromate yellow, chrome oxide green, barba hispanica, zinc oxide, zinc yellow, cobalt blue, phthalocyanine pigment, azo face
The mixture of any one or more in material, quinacridone-type pigments.
In a preferred embodiment, described filler is selected from silica, silicate, carbonate, carbide, sulfate, sulphur
The mixture of any one or more in compound, nitride, metal oxide, metal hydroxides.
In a further preferred embodiment, the antistatic inorganic dry powder construction paint also includes additive, and
And, the weight of each component is as follows：
In an embodiment still more preferably, the additive is selected from defoamer, air entraining agent, water reducer, thixotroping
The mixture of any one or more in rheological agent, thickener, cracking resistance agent.
The second aspect of the present invention, there is provided a kind of antistatic inorganic dry powder construction paint is applied over answering for inner wall of building
Be dry mixed for each component of antistatic inorganic dry powder construction paint described according to a first aspect of the present invention by it, is applying
Tu Qian, scene is added water and stirs, and thin matter decorative coveringn, its sheet resistance≤1.0 × 10 are formed in inner wall of building after application5
Ω。
For the technical scheme of antistatic inorganic dry powder construction paint of the present invention, it is made by following examples now
It is explained further and illustrates, but the present invention is not limited to following examples.
Embodiment 1
A kind of antistatic inorganic dry powder construction paint, including：
It is 7.68 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Embodiment 2
A kind of antistatic inorganic dry powder construction paint, including：
It is 8.55 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Embodiment 3
A kind of antistatic inorganic dry powder construction paint, including：
It is 8.64 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Embodiment 4
A kind of antistatic inorganic dry powder construction paint, including：
It is 9.17 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Embodiment 5
A kind of antistatic inorganic dry powder construction paint, including：
It is 7.96 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Embodiment 6
A kind of antistatic inorganic dry powder construction paint, including：
It is 9.09 × 10 to measure its resistance for being coated on inner wall surface using sheet resistance tester4Ω。
Specific embodiment of the invention has been described in detail above, but it is only used as example, and the present invention is not intended to limit
In particular embodiments described above.To those skilled in the art, any equivalent modifications carried out to the practicality and replace
In generation, is also all among scope of the invention.Therefore, the equalization made without departing from the spirit and scope of the invention is converted and repaiied
Change, all should be contained within the scope of the invention.
Claims (10)
1. a kind of antistatic inorganic dry powder construction paint, it is characterised in that by weight ratio comprising following components：
2. antistatic inorganic dry powder construction paint according to claim 1, it is characterised in that the inorganic coagulation material choosing
The mixture of any one or more from cement, lime, gypsum.
3. antistatic inorganic dry powder construction paint according to claim 1, it is characterised in that the re-dispersible glue powder is
It is obtained after being dried by polymer emulsion, wherein described polymer is selected from：Monoolefine, alkadienes, acrylic acid, acrylic acid tree
The homopolymers that ester, methacrylic acid, methacrylate, tertiary carbonic ester, fatty acid ethylene polyisocyanate polyaddition are obtained, or binary copolymerization
The mixture of any one or more in thing or terpolymer；Wherein, the formula of the fatty acid vinyl ester is R-CO-
O-CH=CH2。
4. antistatic inorganic dry powder construction paint according to claim 3, it is characterised in that the general formula R-CO-O-CH
=CH2In R bases be selected from：The alkyl group of C1-C10, the cycloalkyl of C5-C10, the alkenyl of C2-C10.
5. antistatic inorganic dry powder construction paint according to claim 1, it is characterised in that the conducting powder feature is filled out
Material is selected from conductive titanium dioxide, conductive potassium titanate, conductive mica powder, conductive barium sulfate, electrically conductive graphite powder, conductive carbon fibre, silver-plated
The mixture of any one or more in copper powder.
6. antistatic inorganic dry powder construction paint according to claim 1, it is characterised in that the pigment is selected from titanium white
Powder, iron oxide red, iron oxide yellow, iron oxide black, lithopone, carbon black, cadmium red, cadmium yellow, lead chromate yellow, chrome oxide green, barba hispanica, oxidation
The mixture of any one or more in zinc, zinc yellow, cobalt blue, phthalocyanine pigment, azo pigment, quinacridone-type pigments.
7. antistatic inorganic dry powder construction paint according to claim 1, it is characterised in that described filler is selected from oxidation
It is any in silicon, silicate, carbonate, carbide, sulfate, sulfide, nitride, metal oxide, metal hydroxides
One or more of mixture.
8. the antistatic inorganic dry powder construction paint according to any one of claim 1~7, it is characterised in that also include
Additive, also, the weight of each component is as follows：
9. antistatic inorganic dry powder construction paint according to claim 8, it is characterised in that the additive is selected from froth breaking
The mixture of any one or more in agent, air entraining agent, water reducer, thixotroping rheological agent, thickener, cracking resistance agent.
10. a kind of antistatic inorganic dry powder construction paint is applied over the application of inner wall of building, it is characterised in that will be according to right
It is required that each component of the antistatic inorganic dry powder construction paint any one of 1~9 is dry mixed, and before application, scene
Add water and stir, thin matter decorative coveringn, its sheet resistance≤1.0 × 10 are formed in inner wall of building after application5Ω。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611260927.4A CN106866047A (en) | 2016-12-30 | 2016-12-30 | A kind of antistatic inorganic dry powder construction paint and its application |
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| CN201611260927.4A CN106866047A (en) | 2016-12-30 | 2016-12-30 | A kind of antistatic inorganic dry powder construction paint and its application |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109401412A (en) * | 2018-10-23 | 2019-03-01 | 西安航天三沃化学有限公司特种涂料分公司 | A kind of aqueous static conductive putty and preparation method thereof |
| CN114163847A (en) * | 2021-12-02 | 2022-03-11 | 辽宁科大中驰镁建材科技有限公司 | Magnesium phosphate cement-based wall antistatic coating and preparation method thereof |
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| CN104496392A (en) * | 2014-12-31 | 2015-04-08 | 上海墙特节能材料有限公司 | Indoor inorganic dry powder building coating and preparation method thereof |
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Cited By (2)
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| CN109401412A (en) * | 2018-10-23 | 2019-03-01 | 西安航天三沃化学有限公司特种涂料分公司 | A kind of aqueous static conductive putty and preparation method thereof |
| CN114163847A (en) * | 2021-12-02 | 2022-03-11 | 辽宁科大中驰镁建材科技有限公司 | Magnesium phosphate cement-based wall antistatic coating and preparation method thereof |
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