CN108642768A - A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon - Google Patents

A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon Download PDF

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Publication number
CN108642768A
CN108642768A CN201810622842.9A CN201810622842A CN108642768A CN 108642768 A CN108642768 A CN 108642768A CN 201810622842 A CN201810622842 A CN 201810622842A CN 108642768 A CN108642768 A CN 108642768A
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preparation
viscose
viscose rayon
shell fabric
perspiring shell
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CN108642768B (en
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刘让同
李亮
刘淑萍
李淑静
别剑龙
胡泽栋
耿长军
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Zhongyuan University of Technology
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B15/00Removing liquids, gases or vapours from textile materials in association with treatment of the materials by liquids, gases or vapours
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to field of textiles, particularly relate to a kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, specifically include following steps:Viscose fabric is placed in a concentration of 30g/L 60g/L of water repellent, rolls processing through two leachings two, pick-up keeps 75%, and 105 DEG C of preliminary dryings are 3min, and 150 DEG C bake 4min;Viscose fabric after water repellent finish is placed in a concentration of 30g/L 60g/L of hydrophilic agent, rolls processing through two leachings two, pick-up keeps 75%, and 40 DEG C of preliminary dryings are 5min, and 60 DEG C bake 10min, obtain the viscose fabric with moisture absorption sweat discharging functions.A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon of the present invention, realizes moisture absorbing and sweat releasing effect of viscose fabric, improves the value-added content of product, enrich thread water absorben perspiring shell fabric.

Description

A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon
Technical field
The present invention relates to field of textiles, and in particular to a kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon.
Background technology
With the fast development of society, the pursuit of quality of the life is continuously improved in the mankind, for the clothes of necessary article, Its color, feel and quality are not only pursued, the wearability of clothes, healthy and safe and individual character fashion-orientation, this phenomenon are more focused on Particularly evident in summer, the clothes that people are more desirable to oneself have the function of moisture absorbing and sweat releasing.Certainly, for getting used to sports and leisure The crowd of life style, the clothes with moisture absorption sweat discharging functions can more meet its pursuit to comfort.Moisture absorption sweat discharging functions Clothes be usually by with good moisture absorption, lead wet fiber or fabric forms, which can pass through fibre by the sweat that human body generates Dimension absorbs, gap dissipates outward between fibrous inside hole or fiber, but can by sweat along fibrous inside hole and fiber it is axial to Outer transfer.
The garment material with moisture absorption sweat discharging functions mainly uses the following aspects to realize at present:One, by composition The fiber of garment material carries out physics or chemical modification processing, improves its moisture absorption and wet transmitting performance, such as:Surface micropore, interface The introducing etc. in different section, surface grooves, hydrophilic radical;Two, the fabric tissue of garment material is rationally designed, is made in fabric With more porosity, capillary effect is formed;Three, the fibre fractionation of reasonably combined garment material keeps water molecule energy effectively fast The outside transmission of speed.Such as:The excellent fiber of moisture pick-up properties and the fiber of moisture pick-up properties difference carry out blended, intertexture, looping etc..
Viscose rayon has excellent moisture pick-up properties, belongs to biology base recyclable materials, but the fiber product perspires, soon Dryness can be poor, if preferable moisture absorbing and sweat releasing ability can be made it have, which can be expanded, it is increased Added value further enriches the type of thread water absorben perspiring shell fabric.
Invention content
The present invention proposes a kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, solves viscose rayon face The moisture absorbing and sweat releasing problem of material.
Realize the technical scheme is that:A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, including Following steps:
(1)Viscose fabric is placed in water repellent, rolls processing through two leachings two, pick-up keeps 75%, 95-105 DEG C of preliminary drying 3min, 130-150 DEG C bakes 4min;
(2)Viscose fabric after water repellent finish is placed in hydrophilic agent, rolls processing through two leachings two, pick-up keeps 75%, 35-45 DEG C preliminary drying 5min, 55-65 DEG C bakes 10min, obtains the viscose fabric with moisture absorption sweat discharging functions.
The water repellent is organic silicon water repellent or organic fluoride class water repellent.
The step(1)A concentration of 30g/L-60g/L of middle water repellent, step(2)A concentration of 30g/L- of middle hydrophilic agent 60g/L。
The preparation method of the hydrophilic agent is:Denaturant urea, surfactant, highly basic and water are hybridly prepared into mixing Waste wool is placed in mixed solution by solution, and 3h is handled in 95-100 DEG C, and vinegar acid for adjusting pH is utilized after processing, molten after adjusting Liquid obtains hydrophilic agent through activated carbon adsorption, suction filtration and spray drying.
The denaturant urea, surfactant, highly basic and water mass ratio be 10:1:4:85.
The surfactant is in dodecyl sodium sulfate, cetyl benzenesulfonic acid sodium or octadecyl benzenesulfonic acid sodium Any one.
The pH value of the mixed solution is 11, and the pH after acetic acid is adjusted is 5.
The technological parameter of the spray drying is:The hot-air that dried medium is 150-160 DEG C, hot blast rate is in 60-70m3/ H, feed rate 0.15-0.25ml/s, 20-30 DEG C of feeding temperature.
Viscose rayon moisture pick-up properties is excellent, but perspiration discharging performance is poor, and reason is fibrous inside hydrophilic radical and water Molecule is formed with Hydrogenbond and combines water, and hydrone is made to be stranded in fibrous inside, and discharge is difficult.The viscose glue handled by water repellent is fine Dimension table face forms effective water repellent layer, and the hydrophilic radical of viscose rayon is effectively coated, and makes the parent of hydrone and viscose rayon Water base group can not form hydrogen bond, and hydrone can only stay in viscose rayon surface, this is conducive to the transmission and evaporation of hydrone.So And the water repellent layer that viscose rayon surface is formed is unfavorable for the wettability power of viscose rayon, therefore carry out hydrophilic treated and be conducive to it The moisture pick-up properties of the holding of wettability power, hydrophilic treated water repellent finish viscose rayon obtains larger improvement, and then realizes viscose glue The moisture absorption sweat discharging functions of fabric lining.
The beneficial effects of the invention are as follows:A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon of the present invention, tool There is preferable moisture absorbing and sweat releasing performance, realizes moisture absorbing and sweat releasing effect of viscose fabric, improve the value-added content of product, enrich Thread water absorben perspiring shell fabric.
Description of the drawings
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technology description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with Obtain other attached drawings according to these attached drawings.
Fig. 1 is viscose fabric water repellent of the present invention and hydrophilic finiss pictorial diagram.
Specific implementation mode
Below in conjunction with the embodiment of the present invention, technical scheme of the present invention is clearly and completely described, it is clear that institute The embodiment of description is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, The every other embodiment that those of ordinary skill in the art are obtained under the premise of not making the creative labor, belongs to this hair The range of bright protection.
Embodiment 1
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
Viscose fabric is placed in a concentration of 30g/L of final concentration water repellent, rolls processing through two leachings two, pick-up holding 75%, 105 DEG C Preliminary drying is 3min, and 150 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in a concentration of 30g/ of hydrolysis egg again L rolls processing through two leachings two, and pick-up keeps 75%, and 40 DEG C of preliminary dryings are 5min, and 60 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose glue Fabric.
1 fabric moisture perspiration discharging performance Specifications of table
Project Vapor transfer rate Water absorption rate Measure wicking height Evaporation rate It drips diffusion time
Common viscose fabric 2557.25g/m2▪d 125% 3.5cm 0.1771g/h 57.8s
Moisture absorbing and sweat releasing viscose fabric 5237.45g/m2▪d 123% 3.8cm 0.2844g/h 49s
Embodiment 2
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
Viscose fabric is placed in a concentration of 40g/L of final concentration water repellent, rolls processing through two leachings two, pick-up holding 75%, 105 DEG C Preliminary drying is 3min, and 150 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in a concentration of 50g/ of hydrolysis egg again L rolls processing through two leachings two, and pick-up keeps 75%, and 40 DEG C of preliminary dryings are 5min, and 60 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose glue Fabric.
Embodiment 3
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
Viscose fabric is placed in a concentration of 50g/L of final concentration water repellent, rolls processing through two leachings two, pick-up holding 75%, 105 DEG C Preliminary drying is 3min, and 150 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in a concentration of 50g/ of hydrolysis egg again L rolls processing through two leachings two, and pick-up keeps 75%, and 40 DEG C of preliminary dryings are 5min, and 60 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose glue Fabric.
Embodiment 4
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
Viscose fabric is placed in a concentration of 60g/L of final concentration water repellent, rolls processing through two leachings two, pick-up holding 75%, 105 DEG C Preliminary drying is 3min, and 150 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in a concentration of 50g/ of hydrolysis egg again L rolls processing through two leachings two, and pick-up keeps 75%, and 40 DEG C of preliminary dryings are 5min, and 60 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose glue Fabric.
Embodiment 5
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
(1)By denaturant urea, cetyl benzenesulfonic acid sodium, sodium hydroxide and water according to mass ratio be 10:1:4:85 mixing are matched Mixed solution is made, waste wool is placed in mixed solution, the pH value of mixed solution is 11,3h is handled in 95 DEG C, after processing It is 5 using vinegar acid for adjusting pH, solution obtains hydrophilic agent through activated carbon adsorption, suction filtration and spray drying after adjusting;
The technological parameter of spray drying is:The hot-air that dried medium is 150 DEG C, hot blast rate is in 60m3/ h, feed rate are 0.15ml/s, 20 DEG C of feeding temperature;
(2)Viscose fabric is placed in final concentration water repellent a concentration of 60g/L, water repellent FG-910, rolls processing through two leachings two, is rolled Remaining rate keeps 75%, and 95 DEG C of preliminary dryings are 3min, and 130 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in again Step(1)In obtained hydrophilic agent, a concentration of 30g/L of hydrophilic agent rolls processing through two leachings two, and pick-up keeps 75%, 35 DEG C of preliminary dryings For 5min, 55 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose fabric.
Embodiment 6
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
(1)By denaturant urea, octadecyl benzenesulfonic acid sodium, sodium hydroxide and water according to mass ratio be 10:1:4:85 mixing are matched Mixed solution is made, waste wool is placed in mixed solution, the pH value of mixed solution is 11,3h is handled in 98 DEG C, after processing It is 5 using vinegar acid for adjusting pH, solution obtains hydrophilic agent through activated carbon adsorption, suction filtration and spray drying after adjusting;
The technological parameter of spray drying is:The hot-air that dried medium is 155 DEG C, hot blast rate is in 65m3/ h, feed rate are 0.20ml/s, 25 DEG C of feeding temperature;
(2)Viscose fabric is placed in a concentration of 60g/L of final concentration water repellent, water repellent is that HA-210 rolls processing through two leachings two, is rolled Remaining rate keeps 75%, and 100 DEG C of preliminary dryings are 3min, and 140 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is set again In step(1)In obtained hydrophilic agent, a concentration of 30-60g/L of hydrophilic agent rolls processing through two leachings two, and pick-up keeps 75%, 40 DEG C preliminary drying is 5min, and 60 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose fabric.
Embodiment 7
A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, includes the following steps:
(1)By denaturant urea, dodecyl sodium sulfate, sodium hydroxide and water according to mass ratio be 10:1:4:85 mixed preparings At mixed solution, waste wool is placed in mixed solution, the pH value of mixed solution is 11, and 3h is handled in 100 DEG C, sharp after processing It is 5 with vinegar acid for adjusting pH, solution obtains hydrophilic agent through activated carbon adsorption, suction filtration and spray drying after adjusting;
The technological parameter of spray drying is:The hot-air that dried medium is 160 DEG C, hot blast rate is in 70m3/ h, feed rate are 0.25ml/s, 30 DEG C of feeding temperature;
(2)Viscose fabric is placed in final concentration water repellent a concentration of 60g/L, water repellent CO, rolls processing, pick-up through two leachings two 75% is kept, 105 DEG C of preliminary dryings are 3min, and 150 DEG C bake 4min.The viscose fabric obtained after above-mentioned water repellent finish is placed in step again Suddenly(1)In obtained hydrophilic agent, a concentration of 60g/L of hydrophilic agent rolls processing through two leachings two, and pick-up keeps 75%, and 45 DEG C of preliminary dryings are 5min, 65 DEG C bake 10min, that is, arrive moisture absorbing and sweat releasing viscose fabric.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.

Claims (8)

1. a kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon, it is characterised in that include the following steps:
(1)Viscose fabric is placed in water repellent, rolls processing through two leachings two, pick-up keeps 75%, 95-105 DEG C of preliminary drying 3min, 130-150 DEG C bakes 4min;
(2)Viscose fabric after water repellent finish is placed in hydrophilic agent, rolls processing through two leachings two, pick-up keeps 75%, 35-45 DEG C preliminary drying 5min, 55-65 DEG C bakes 10min, obtains the viscose fabric with moisture absorption sweat discharging functions.
2. the preparation method of the thread water absorben perspiring shell fabric according to claim 1 based on viscose rayon, it is characterised in that:It is described Water repellent is organic silicon water repellent or organic fluoride class water repellent.
3. the preparation method of the thread water absorben perspiring shell fabric according to claim 1 based on viscose rayon, it is characterised in that:It is described Step(1)A concentration of 30g/L-60g/L of middle water repellent, step(2)A concentration of 30g/L-60g/L of middle hydrophilic agent.
4. the preparation method of the thread water absorben perspiring shell fabric according to claim 1 based on viscose rayon, which is characterized in that described The preparation method of hydrophilic agent is:Denaturant urea, surfactant, highly basic and water are hybridly prepared into mixed solution, will be discarded Wool is placed in mixed solution, is handled 3h in 95-100 DEG C, vinegar acid for adjusting pH is utilized after processing, solution is inhaled through activated carbon after adjusting Attached, suction filtration and spray drying obtain hydrophilic agent.
5. the preparation method of the thread water absorben perspiring shell fabric according to claim 4 based on viscose rayon, it is characterised in that:It is described Denaturant urea, surfactant, highly basic and water mass ratio be 10:1:4:85.
6. the preparation method of the thread water absorben perspiring shell fabric according to claim 4 based on viscose rayon, it is characterised in that:It is described Surfactant is any one in dodecyl sodium sulfate, cetyl benzenesulfonic acid sodium or octadecyl benzenesulfonic acid sodium.
7. the preparation method of the thread water absorben perspiring shell fabric according to claim 4 based on viscose rayon, it is characterised in that:It is described The pH value of mixed solution is 11, and the pH after acetic acid is adjusted is 5.
8. the preparation method of the thread water absorben perspiring shell fabric according to claim 4 based on viscose rayon, it is characterised in that:It is described The technological parameter of spray drying is:The hot-air that dried medium is 150-160 DEG C, hot blast rate is in 60-70m3/ h, feed rate are 0.15-0.25ml/s, 20-30 DEG C of feeding temperature.
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Publication number Priority date Publication date Assignee Title
CN110359282A (en) * 2019-07-02 2019-10-22 东莞德永佳纺织制衣有限公司 A kind of wicking function ameliorative way of viscose glue class fabric
CN110359282B (en) * 2019-07-02 2021-08-31 东莞德永佳纺织制衣有限公司 Method for improving wicking function of viscose fabric

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