CN110106698A - Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof - Google Patents

Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof Download PDF

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CN110106698A
CN110106698A CN201910439029.2A CN201910439029A CN110106698A CN 110106698 A CN110106698 A CN 110106698A CN 201910439029 A CN201910439029 A CN 201910439029A CN 110106698 A CN110106698 A CN 110106698A
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fabric
preparation
moisture conductivity
sweat
agent
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刘群英
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

Abstract

The invention discloses a kind of Sweat Exhaust & Moisture Conductivity fabrics and preparation method thereof, and the preparation method comprises the following steps: a, preparing Nano silver solution;B, Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water are mixed, obtains absorbable and breathable finishing liquid;C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying, baked after drying to get.Nano silver solution prepared by the present invention, the nano silver size of synthesis is smaller, epigranular, can be stabilized in system, fabric after arrangement carries out wearability, functional test, and properties are excellent, and antibiotic property, Sweat Exhaust & Moisture Conductivity are good, the sweat that human body generates can be vapored away quickly, increase the comfort level of dress, is suitble to the clothes such as preparation open air and movement, adapts to the variation of market and people's demand, it improves product specification, increase added value of product, there is very big commercial value.

Description

Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof
Technical field
The present invention relates to a kind of fabrics, and in particular to a kind of Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof.
Background technique
With the quickening of human civilization process, the progress of science and technology and the transformation of people's consumption idea, the need of garment material It asks and has been not limited solely to simply cover body, the solid endurable and practicabilities such as warming, and gradually to fashion, aesthetics, comfortable Property propose higher requirement.
In summer, since a large amount of sweat can be generated when weather is overheated and moved, for the Ms to like to be beautiful, summer institute Habited quality seems with snugness of fit to be even more important, so clothes made from high wet fiber is in summer very by Ms's Like, in the field, wet fiber, which has begun, to be applied in most dress ornament, including female outerwear.Ms is excellent for fabric The demands such as matter is comfortable, refrigerant dry and comfortable, convenience promote the opening of wetness guiding perspiration discharging textile markets.Although man is not as Ms one Sample is so high to comfort, the Functional Requirement of clothes, but man is mainly long with shirt, Western-style clothes, shirt, western clothes throughout the year Based on trousers, and the exercise intensity of comparatively man is bigger, from the point of view of the dressing feature and amount of exercise of man, more needs height Wet guilding fabric.
With the more and more outdoor activities of people's participation and duration is elongated, and people are to outdoor activity dress ornament Demand is growing day by day, is pursued and welcomes by numerous consuming public.Leisure and a basic demand of sportswear are comfortable Property, it in addition to this, and requires in the case where perspiring, clothes will not paste skin and generate clammy sense.Modern textiles Positive direction frivolous, of fine quality, that added value is high is developed, and the new concept of the modern life is embodied --- and green leads wet row with comfortably Sweat fabric is increasingly taken seriously, and already becomes the research hotspot of current textile industry.
Wetness guiding perspiration discharging function refers to the reasonable fabric construction of design and fiber method for modifying, makes suction of the fabric to moisture It is wet, mobile, the properties such as perspire and change, while possessing water imbibition and quick-drying.During exercise, sweat is shifted people by fabric To atmosphere, there are mainly two types of approach: first is that skin surface sweat is directly contacted with fabric, and the wet fabric in the form of liquid water Inside to be absorbed by fabric, since there are a large amount of apertures between yarn or fiber, capillary effect can be formed, finally knitted Sweat in object is just transmitted to the outside of fabric by means of capillary effect, is dispersed into atmosphere;Second is that the sweat of skin surface Steam is flashed to, these steam are absorbed by the fiber surface in fabric, and liquid water is condensed on the inside of fabric, are finally dispersed into In atmosphere.It can be seen from both the above mode fabric complete wetness guiding perspiration discharging process it is obvious that be exactly in simple terms soak, Moisture absorption, diffusion, evaporation are specifically using the capillary effect in fabric, and the sweat that human body is discharged is absorbed, is turned The modes such as shifting, diffusion are quickly transmitted to fabric surface evaporation, so that fabric be made to have wetness guiding perspiration discharging effect.
It is well known that bacterium can be proliferated rapidly in more wet environments, and people's various textiles used in everyday are all thin The suitable place that bacterium breeds procreation and propagates.If textile, which has the function of to kill, inhibits germ, can not only it prevent bacterium in fabric Upper breeding to prevent disease, and can be reduced transmission.The exploitation of functional fabric and application oneself become fabric row One research hotspot of industry.And a kind of fabric is made by complex function arrangement while there is two or more functional characteristic, Can preferably meet the needs of people.
201611051901.9 Chinese patents of application number disclose a kind of silk and lead wet antibacterial fabric and preparation method thereof, The fabric includes following raw material: silk, carbon fiber, polyethylene amino ethyl ester, polyvinyl resin, ethyl acetate, lemon-grass essential oil, Poly- propyl alcohol front three acid esters, sorbierite butyl ester, silver nano solution, cetyl ester, glycerol, allantoin, cetostearyl alcohol.Preparation Method: silk and carbon fiber are immersed in silver nano solution, are placed in 5-9 DEG C 1-2 hours, are taken out, and the first of spray drying is mixed Close object;By polyethylene amino ethyl ester, polyvinyl resin, ethyl acetate, poly- propyl alcohol front three acid esters, sorbierite butyl ester, octanoic acid 16 After alkyl ester, glycerol, allantoin, cetostearyl alcohol Hybrid Heating are melted, the first mixture is added and after lemon-grass essential oil stirs evenly Single fiber is extruded into investment spinneret;Fiber is compiled into fabric.The fabric wet guilding is good, and sterilizing ability is strong, antibacterial It is of long duration.
201310627035.3 Chinese patents of application number disclose a kind of waterproof wet cloth production technology, including as follows Step: 1) being added 60-65g/L moisture absorbing and sweat releasing auxiliary agent in forming machine immersion liquid slot, reacts 5 minutes at 45-50 DEG C;Setting temperature is 160-165 DEG C, speed is 20-25 ms/min, and the reaction time is 1 minute in drying chamber of being formed, and forms one layer of moisture absorption in design on fabric surface Perspire film;2) 110-120g/L waterproofing agent, 6-8g/L foaming agent, 5-7g/L foam stabilizer are added into foaming machine, in 15-20 minutes It feeds intake and finishes, through 10 minutes high-speed stirreds at fine and smooth foam, then foaming agent is coated uniformly on moisture absorption by coating machine and is arranged Another surface of single jersey material forms one layer of waterproof membrane;3) use 185-190 DEG C of temperature with 20 ms/min of rate on forming machine Drying and shaping is carried out to cloth cover, the reaction time in drying chamber is 2 minutes.The invention makes have one layer of moisture absorbing and sweat releasing film inside fabric With one layer of waterproof layer, to be provided simultaneously with waterproof and wetness guiding perspiration discharging function.
The finishing agents for fabric finishing functions various in recent years, including anti-bacteium deodorization finishing agent, anti-mite finishing agent, insect prevention Finishing agent, anti-ultraviolet finishing agent, anionic finishing agent, far infrared finishing agent, antiflaming finishing agent, sweat absorption and flash drying finishing agent, The research and application of perfumed finishing agent, soil-releasing finishing agent, skin care finishing agent and formaldehyde-free crease-proofing finishing agent etc. are opened as fabric The hot spot of hair.Multifunctional composite finishing is by two or more function and service in a kind of finishing technique of textile, to mention The class and added value of high product.It selects composite functional finishing agent while assigning knitted fabric multiple functions, and is able to maintain Its original wearability, it has also become an important research direction.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof, has to perspire and lead Wet performance, while there is anti-microbial property.
The object of the invention is achieved by the following technical programs:
A kind of preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, Nano silver solution is prepared;
B, Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water are mixed, obtains perspiring whole Manage liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying, baked after drying to get.
A kind of preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.01-0.06mol/L silver nitrate solution is made by silver nitrate is soluble in water, polypropylene is added to silver nitrate solution Amide to its mass concentration is 0.5-1%, and it in temperature is 30-40 that add citric acid to its mass concentration, which be 0.01-0.05%, DEG C with revolving speed be 200-600r/min stir 30-60min, then with 0.05-0.15mol/L sodium hydrate aqueous solution adjusting pH to 8- 8.5 temperature be 90-100 DEG C with revolving speed be 200-600r/min stirring 1-3h, then be added silane coupling agent it is dense to its quality Degree is that 0.1-0.5% is ultrasonically treated 1-3h, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: (0.005-0.015): (0.001-0.005): (0.001-0.005): (0.5-1.5) is that 200-600r/min stirs 5- with revolving speed 20min obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying, baked after drying to get.
The silane coupling agent is 3- chloropropyl triethoxysilane or 3- mercaptopropyltriethoxysilane.
Preferably, the silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 200-500W, supersonic frequency 25-45kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.Polyamide polyether organosilicon In ternary polymerization type hydrophilic finishing agent molecular structure exist rigidity polyamide segment, hydrophilic polyoxyethylene ether segment and Polymethyl siloxane segment flexible, remaining polyester fiber molecular unit structure is similar, divides during high-temperature heating with terylene The effect of co-melting cocrystallization occurs for son, using preferred hexamethylene diamine, adipic acid, Carboxylic-terminated Polyethylene Glycol and double-end amino polyethers Silicone oil proportion allows hydrophilic finishing agent is permanent to be retained in above fabric, and hydrophilic polyoxyethylene ether segment and PolydimethylsiloxaneChain Chain Duan Ze flexible is aligned on the surface of fabric, is changed while assigning fabric good hydrophilicity The feel of fabric has been apt to it, water resistance and antistatic property have good improvement, and hand feeling quality is more excellent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is at least one of vinyl modified polyvinyl alcohol, carboxy-modified polyvinyl alcohol.
Preferably, the modified polyvinylalcohol by vinyl modified polyvinyl alcohol, carboxy-modified polyvinyl alcohol in mass ratio For 1:(1.5-2.5) composition.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:(10-20).
The temperature of the dipping is 30-40 DEG C, time 10-20min.
The temperature of the drying is 90-100 DEG C, drying time 5-10min.
It is 1-2min that the temperature baked, which is 140-155 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
The present invention provides a kind of Sweat Exhaust & Moisture Conductivity fabrics, are prepared by the preparation method of above-mentioned Sweat Exhaust & Moisture Conductivity fabric.
Silver is a kind of relatively conventional also relatively inexpensive noble metal, due to its excellent physico-chemical property, becomes physics, changes The hot spot of the scientific domains research such as, material, while being also widely used.The main application fields of silver have antibacterial material Material, medical material, photosensitive material, silver alloy such as disclose at the fields.The either equal Shortcomings of silver ion or simple substance silver antibacterial agent Place.For example, silver ion has water solubility, it is easy to be lost in the solution, to reduce its local concentration;Secondly, silver-ionized It is more active to learn property, Yi Fasheng oxidation reaction sensitive to light and heat also causes its anti-microbial property to decline.Silver-colored simple substance antibacterial agent is easy Reunite, the rate for discharging silver is slower, and antibacterial effect is not so good as silver ion antimicrobial agent.Nano silver is between solid and molecule " Jie's state ", specific surface area is very big, has skin effect, small-size effect and macroscopical tunnel-effect, has superpower antibacterial ability It is a kind of ideal anti-biotic material with higher safety.Nanometer silver antimicrobial composite coating simple process, low in cost, utilization Bacterium and pollutant can be catalytically decomposed in natural light, have high catalytic activity, good chemical stability and thermal stability, without two Secondary pollution, it is nonirritant the features such as.
The beneficial effects of the present invention are:
Sweat Exhaust & Moisture Conductivity fabric of the present invention and preparation method thereof, the Nano silver solution of preparation, the nano silver size of synthesis is smaller, Epigranular can be stabilized in system, and the fabric after arrangement carries out wearability, functional test, and properties are excellent, Antibiotic property, Sweat Exhaust & Moisture Conductivity are good, and the sweat that human body generates can be vapored away quickly, increase the comfort level of dress, are suitble to preparation family The clothes such as outer and movement, adapt to the variation of market and people's demand, improve product specification, increase added value of product, are to increase A kind of effective way of product diversity is the important method improved properties of product, expand its use scope, has very big quotient Industry value.
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these illustrative embodiments and Purpose is only used to enumerate the present invention, not constitutes any type of any restriction to real protection scope of the invention, more non-to incite somebody to action Protection scope of the present invention is confined to this.
It is as follows using disclosure: polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent according to application No. is 201610048201.8 Chinese patent in the preparation of method shown in embodiment one.Imine modified block silicone softening agent is according to Shen It please be number for the preparation of method shown in embodiment 1 in 201810096689.0 Chinese patent.Vinyl modified polyvinyl alcohol is according to Shen It please be number for the preparation of method shown in embodiment 2 in 201210387854.0 Chinese patent.3- mercaptopropyltriethoxysilane according to Application No. is the preparations of method shown in embodiment 1 in 201310396681.3 Chinese patent.Carboxy-modified polyvinyl alcohol is according to Shen It please be number for the preparation of method shown in embodiment 1 in 201110086949.4 Chinese patent.Fabric is polyester-cotton blend fabric, by Jinzhou City honor Rise textile mills' offer, ingredient and content: 90% washs 10% cotton, density: 110*76, yarn count: 45*45, grammes per square metre: 100g/ ㎡, width It is wide: 160cm, fabric tissue: plain weave.
Embodiment 1
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, it is 0.2% ultrasonic treatment 1.5h that silane coupling agent to its mass concentration, which is then added, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- chloropropyl triethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is carboxy-modified polyvinyl alcohol.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 2
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, it is 0.2% ultrasonic treatment 1.5h that silane coupling agent to its mass concentration, which is then added, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is carboxy-modified polyvinyl alcohol.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 3
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, Nano silver solution is obtained;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is carboxy-modified polyvinyl alcohol.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 4
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, with 0.1mol/L sodium hydrate aqueous solution tune Section pH to 8 temperature be 95 DEG C with revolving speed be 300r/min stirring 1.5h, then be added silane coupling agent to its mass concentration be 0.2% ultrasonic treatment 1.5h, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is carboxy-modified polyvinyl alcohol.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 5
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, it is 0.2% ultrasonic treatment 1.5h that silane coupling agent to its mass concentration, which is then added, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is vinyl modified polyvinyl alcohol.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 6
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, it is 0.2% ultrasonic treatment 1.5h that silane coupling agent to its mass concentration, which is then added, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, polyvinyl alcohol 1788, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Embodiment 7
The preparation method of Sweat Exhaust & Moisture Conductivity fabric, comprising the following steps:
A, 0.05mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution To its mass concentration be 0.7%, add citric acid to its mass concentration be 0.02% temperature be 35 DEG C with revolving speed for 300r/ Min stir 40min, then with 0.1mol/L sodium hydrate aqueous solution adjust pH to 8 temperature be 95 DEG C with revolving speed for 300r/min 1.5h is stirred, it is 0.2% ultrasonic treatment 1.5h that silane coupling agent to its mass concentration, which is then added, obtains Nano silver solution;
B, in mass ratio it is 1 by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water: 0.01:0.003:0.002:1 is that 300r/min stirs 10min with revolving speed, obtains absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying is baked after drying to get Sweat Exhaust & Moisture Conductivity fabric.
The silane coupling agent is 3- mercaptopropyltriethoxysilane.
The ultrasonic power of the ultrasonic treatment is 300W, supersonic frequency 40kHz.
The hydrophilic finishing agent is polyamide polyether organosilicon ternary polymerization type hydrophilic finishing agent.
The silicone softening agent is imine modified block silicone softening agent.
The modified polyvinylalcohol is mixed in mass ratio for 1:2 by vinyl modified polyvinyl alcohol, carboxy-modified polyvinyl alcohol It closes.
The fabric, absorbable and breathable finishing liquid mass ratio be 1:15.
The temperature of the dipping is 35 DEG C, time 15min.
The temperature of the drying is 95 DEG C, drying time 8min.
It is 1.5min that the temperature baked, which is 150 DEG C, bakes the time.
The fabric is polyester-cotton blend fabric.
Test case 1
The Sweat Exhaust & Moisture Conductivity fabric of embodiment is subjected to hydrophilic aptitude tests.Concrete outcome is shown in Table 1.
Hydrophily measurement: it is indicated with wetting time.Referring to AATCC79 " absorbability of white goods is tested " test.It is washable Property measurement: according to GB/T8629-2001 washing standard the fabric of arrangement is washed, measurement washing 30 times after Sweat Exhaust & Moisture Conductivity face The wetting time of material.
Each sample test 5 times, is averaged.
Table 1: hydrophilic aptitude tests result table
Test case 2
The Sweat Exhaust & Moisture Conductivity fabric of embodiment is subjected to anti-microbial property test.Concrete outcome is shown in Table 2.
Anti-microbial property assessment: referring to FZ/T73023-2006 standard, sample strain is staphylococcus aureus ATCC6538. The fabric of arrangement is washed according to GB/T8629-2001 washing standard, perspires the anti-of wet cloth after measurement washing 10 times Bacterium rate.
Each sample test 5 times, is averaged.
Table 2: anti-microbial property test result table
Sweat Exhaust & Moisture Conductivity fabric of the present invention and preparation method thereof, the Nano silver solution of preparation, the nano silver size of synthesis is smaller, Epigranular can be stabilized in system, and the fabric after arrangement carries out wearability, functional test, and properties are excellent, Antibiotic property, Sweat Exhaust & Moisture Conductivity are good, and the sweat that human body generates can be vapored away quickly, increase the comfort level of dress, are suitble to preparation family The clothes such as outer and movement, adapt to the variation of market and people's demand, improve product specification, increase added value of product, are to increase A kind of effective way of product diversity is the important method improved properties of product, expand its use scope, has very big quotient Industry value.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to the technology of invention Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all be covered in power of the invention In sharp claimed range.

Claims (10)

1. a kind of preparation method of Sweat Exhaust & Moisture Conductivity fabric, which comprises the following steps:
A, Nano silver solution is prepared;
B, Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water are mixed, obtains absorbable and breathable finishing Liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying, baked after drying to get.
2. a kind of preparation method of Sweat Exhaust & Moisture Conductivity fabric, which comprises the following steps:
A, 0.01-0.06mol/L silver nitrate solution is made by silver nitrate is soluble in water, polyacrylamide is added to silver nitrate solution Be 0.5-1% to its mass concentration, add citric acid to its mass concentration be 0.01-0.05% temperature be 30-40 DEG C with Revolving speed is that 200-600r/min stirs 30-60min, then adjusts pH to 8-8.5 with 0.05-0.15mol/L sodium hydrate aqueous solution Temperature be 90-100 DEG C with revolving speed be 200-600r/min stirring 1-3h, then be added silane coupling agent to its mass concentration be 0.1-0.5% is ultrasonically treated 1-3h, obtains Nano silver solution;
It b, is in mass ratio 1:(0.005- by Nano silver solution, hydrophilic finishing agent, modified polyvinylalcohol, silicone softening agent, water 0.015): (0.001-0.005): (0.001-0.005): (0.5-1.5) is that 200-600r/min stirs 5-20min with revolving speed, Obtain absorbable and breathable finishing liquid;
C, fabric is placed in absorbable and breathable finishing liquid and is impregnated, dewatered drying, baked after drying to get.
3. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the silane coupling agent is 3- chlorine Propyl-triethoxysilicane or 3- mercaptopropyltriethoxysilane.
4. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 3, which is characterized in that the silane coupling agent is 3- mercapto Propyl-triethoxysilicane.
5. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the ultrasonic function of the ultrasonic treatment Rate is 200-500W, supersonic frequency 25-45kHz.
6. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the hydrophilic finishing agent is polyamides Amine polyether silicones ternary polymerization type hydrophilic finishing agent;The silicone softening agent is imine modified block silicone softening agent.
7. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the modified polyvinylalcohol is second At least one of alkenyl modified polyvinylalcohol, carboxy-modified polyvinyl alcohol.
8. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the fabric, absorbable and breathable finishing liquid Mass ratio be 1:(10-20);The temperature of the dipping is 30-40 DEG C, time 10-20min;The temperature of the drying is 90-100 DEG C, drying time 5-10min;It is 1-2min that the temperature baked, which is 140-155 DEG C, bakes the time.
9. the preparation method of Sweat Exhaust & Moisture Conductivity fabric according to claim 2, which is characterized in that the fabric is polyester-cotton blend fabric.
10. a kind of Sweat Exhaust & Moisture Conductivity fabric, which is characterized in that using Sweat Exhaust & Moisture Conductivity fabric described in any one of claim 1-9 Preparation method is prepared.
CN201910439029.2A 2019-05-24 2019-05-24 Sweat Exhaust & Moisture Conductivity fabric and preparation method thereof Pending CN110106698A (en)

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Application publication date: 20190809