CN106436024A - Novel far-infrared mask base cloth - Google Patents

Novel far-infrared mask base cloth Download PDF

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Publication number
CN106436024A
CN106436024A CN201610843026.1A CN201610843026A CN106436024A CN 106436024 A CN106436024 A CN 106436024A CN 201610843026 A CN201610843026 A CN 201610843026A CN 106436024 A CN106436024 A CN 106436024A
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Prior art keywords
fiber
graphene
far
loycell
mask substrate
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CN201610843026.1A
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CN106436024B (en
Inventor
康卫民
范兰兰
程博闻
庄旭品
李晓捷
邓南平
鞠敬鸽
马晓敏
赵义侠
李磊
何宏升
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Tianjin Polytechnic University
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Tianjin Polytechnic University
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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08Composition of the spinning solution or the bath
    • D01F2/10Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather

Abstract

The invention discloses far-infrared mask base cloth and a preparation method thereof. The far-infrared mask base cloth is prepared from, by mass, 25%-50% of graphene modified Loycell fibers and 50%-75% of Loycell fibers; the graphene content in the graphene modified Loycell fibers accounts for 0.5%-5% of the mass of the fibers. The preparation method of the far-infrared mask base cloth is characterized by comprising the steps of 1, preparation of the graphene modified Loycell fibers; 2, spunlace forming of the far-infrared mask base cloth. The far-infrared characteristic of graphene and the biocompatibility and biodegradability characteristics of the Loycell fibers are utilized, the Loycell fiber mask base cloth with a far-infrared function is developed, and the mask base cloth is harmless to the human body and the environment and meets the national environmental protection requirements.

Description

A kind of new far infrared mask substrate
Technical field
The present invention relates to a kind of mask substrate, and in particular to a kind of preparation method of far infrared mask substrate.
Background technology
Far infrared is a kind of black light, is the abbreviation of remote infrared line, and which all can to gene, cell, blood vessel, nerve etc. Produce impact.The skin of the deep enough human body of far-infrared engergy and subcutaneous tissue, expand blood circulation promoting so as to capillary vessel, can Metabolic obstacle cleaning is would interfere with, brings back to life tissue again.Far material can be produced to be had a lot, the most frequently used just It is carbons product (charcoal, carbon fiber etc.).With the tempo increase of human lives, and the popularization of electronic product, daily all Can be among electron radiation, in the course of time, easily injury be produced to the skin of people.
At present, far facial film has been occurred in that on market.Patent CN 204499797U discloses a kind of Far-infrared Heating Facial film, is that Far infrared electric backing is positioned between surface layer and zone of heating, then by electric heating piece and terminals parallel connection, terminals Connection temp control switch, and several placing troughs are evenly arranged with that surface of zone of heating away from surface layer.The dress Put and the heat energy for being sent on far-infrared electric diaphragm can uniformly be distributed so that the blood circulation cup band of whole face Dynamic, promote the absorption of facial film effective ingredient, while this device can coordinate the additional unit such as cucumber slice, lemon tablet by placing trough Element, increases the using effect of facial film.
Patent CN 105169564A discloses a kind of Far infrared heating face mask, and it is disposably that carbon fiber paper is multiple which passes through carrier Integrator;Carbon fiber paper is located at the intermediate layer of carrier, and the both ends of the surface of carbon fiber paper are by electrode and power electric connection.Using whole The carbon fiber paper of piece, after energising, temperature is relatively uniform and area is big;Achieve and voltage, temperature are regulated and controled, can be according to each one The adaptedness difference of temperature is adjusted.Produced far infrared wavelength is close to human body wavelength, so as to reach health-care physiotherapeutic Effect;Can also use as the companion of other facial films, make human body face more effectively absorb nutrition.
Far infrared facial film obtained by said method is realized on the basis of having firing equipment, and which is in the process for using Middle possibility produces certain danger, and service life is likely to be affected.One of member of Graphene Shi Tan family, which is compared with one As carbon fiber stable and service life is longer.And Lyocell fiber is a kind of biodegradable cellulose fibre, its source Extensively, sucting wet air permeability is good, soft, smooth, is a kind of good mask substrate raw material.The present invention be based on the remote of Graphene Infrared property, which is combined with common Lyocell fiber, the mask substrate for being prepared using the method for spun lacing.The mask substrate More convenient when using, as long as can just launch far-infrared light under the irradiation for having thermal light source (sunlight etc.), on the one hand Can with active cell, promote essence absorption, on the other hand enhance metabolism, can will residual face cosmetics from Skin and sweat gland are discharged, and reduce kidney burden.
Content of the invention
The present invention relates to the present invention using Graphene have far infrared and Loycell fiber bio-compatible and can be biological Degradation characteristic, develops the Lyocell fiber mask substrate with far-infrared functional, and the mask substrate is to human body and environment no Evil, meets national requirements for environmental protection.
The present invention solves the technical scheme of described far infrared mask substrate technical problem:Design a kind of far infrared facial film Base, its mass percent group is divided into:
Graphene modification Loycell fiber:20%~50%,
Loycell fiber:50%~80%;
In the Graphene modification Loycell fiber, Graphene content accounts for the 0.5-5% of fiber quality.
While the preparation method of the far infrared mask substrate of design, it is characterised in that comprise the steps:
(1) prepared by modified Lyocell fiber:By modified for dodecyl sodium sulfate Graphene and cellulose/N- methyl Quinoline-N- oxide (NNMO) solution carries out wet spinning after being blended, and obtains with emitting far-infrared Graphene modification Lyocell fiber, the Graphene is 0.5-5% with cellulose mass percent;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are pressed a definite proportion Example mixing, mixing ratio is to reinforce to make surface density for 30g/m 1: 1-4: 1, through fiber opening, combing and spun lacing2Non-weaving cloth, It is 1.5MPa that the spun lacing reinforces the liquid drugs injection pressure that liquid drugs injection pressure is first, and the liquid drugs injection pressure of second spun lacing is 4.5MPa, The liquid drugs injection pressure of the 3rd road spun lacing is 5MPa, can be prepared by described far infrared mask substrate after drying.
In far infrared mask substrate preparation method of the present invention, Graphene is through surfactant sodium dodecyl base sodium sulfonate In the modified solution for being uniformly dispersed in NNMO, the dispersion liquid of stable and uniform is formed, to obtain Graphene evenly Modified Lyocell fiber.It is, Lyocell fiber has good using the purpose of modified and unmodified fibers mixing ratio Hydrophilic, after adhering to Graphene there is the possibility for declining in its hydrophilic, and mixing Lyocell fiber can improve its hydrophilic, Again can reduces cost.The content difference of Graphene, the far effect difference of its facial film, according to people's body constitution difference, Ke Yixuan Select the facial film of different Graphene contents, the far infrared transmissivity scope of far infrared mask substrate of the present invention 78%~ 86% (output value embodiment 1-4).One maximum advantage of spun-laced nonwoven fabric is exactly that flexibility is good, more can skin-proximal, give people more Good comfort;Additionally, Lyocell fiber has excellent biocompatibility and biodegradable performance, to human body and environment Harmless, meet national requirements for environmental protection.Preparation method wet spinning of the present invention and spun lacing technology are all known technologies, with technique letter Singly, it is not necessary to special installation, the features such as industrializing implementation is easy.
Specific embodiment
The present embodiments relate to wherein several groups embodiments are carried out by a kind of new far infrared mask substrate below respectively Describe in detail.
Embodiment 1:
(1) preparation of modified Lyocell fiber:Dodecylbenzene sodium sulfonate using 5% and Graphene blending, room temperature surpasses Sound 1h, washing, dry.To stir under aqueous solution high temperature of the Graphene that dries with NMMO, moisture is removed, the content of Graphene is 0.5%.By cellulose pulp with the blending of above-mentioned product until spinning after cellulose dissolution, obtains with emitting far-infrared modification Lyocell fiber;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are mixed, mixing Than for 1: 1, the fiber lay down of mixing being set as net using cross lapping, the surface density of fibre web is 30g/m2, recycle high-pressure water-jet The fiber for mixing is reinforced by technique, and it is 1.5MPa that its liquid drugs injection pressure is first of liquid drugs injection pressure, second spun lacing Liquid drugs injection pressure is 4.5MPa, and the liquid drugs injection pressure of the 3rd road spun lacing is 5MPa, obtains surface density for 30g/m2Non-weaving cloth, through dry Described far infrared mask substrate is can be prepared by after dry.
Using far infrared tester, far infrared test is carried out to the mask substrate, its far emissivity is 78%.
Embodiment 2:
(1) preparation of modified Lyocell fiber:Dodecylbenzene sodium sulfonate using 5% and Graphene blending, room temperature surpasses Sound 1h, washing, dry.To stir under aqueous solution high temperature of the Graphene that dries with NMMO, moisture is removed, the content of Graphene is 1%.By cellulose pulp with the blending of above-mentioned product until spinning after cellulose dissolution, obtains with emitting far-infrared modified Lyocell fiber;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are mixed, mixing Than for 2: 1, the fiber lay down of mixing being set as net using cross lapping, high-pressure water-jet technique is recycled to carry out the fiber for mixing Reinforce, it is 1.5MPa that its liquid drugs injection pressure is first of liquid drugs injection pressure, the liquid drugs injection pressure of second spun lacing is 4.5MPa, the 3rd road The liquid drugs injection pressure of spun lacing is 5MPa, obtains surface density for 30g/m2Non-weaving cloth, can be prepared by after drying described far red Outer mask substrate.
Using far infrared tester, far infrared test is carried out to the mask substrate, its far emissivity is 80%.
Embodiment 3:
(1) preparation of modified Lyocell fiber:Dodecylbenzene sodium sulfonate using 5% and Graphene blending, room temperature surpasses Sound 1h, washing, dry.To stir under aqueous solution high temperature of the Graphene that dries with NMMO, moisture is removed, the content of Graphene is 2%.By cellulose pulp with the blending of above-mentioned product until spinning after cellulose dissolution, obtains with emitting far-infrared modified Lyocell fiber;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are mixed, mixing Than for 3: 1, the fiber lay down of mixing being set as net using cross lapping, high-pressure water-jet technique is recycled to carry out the fiber for mixing Reinforce, it is 1.5MPa that its liquid drugs injection pressure is first of liquid drugs injection pressure, the liquid drugs injection pressure of second spun lacing is 4.5MPa, the 3rd road The liquid drugs injection pressure of spun lacing is 5MPa, obtains surface density for 30g/m2Non-weaving cloth, can be prepared by after drying described far red Outer mask substrate.
Using far infrared tester, far infrared test is carried out to the mask substrate, its far emissivity is 84%.
Embodiment 4:
(1) preparation of modified Lyocell fiber:Dodecylbenzene sodium sulfonate using 5% and Graphene blending, room temperature surpasses Sound 1h, washing, dry.To stir under aqueous solution high temperature of the Graphene that dries with NMMO, moisture is removed, the content of Graphene is 4%.By cellulose pulp with the blending of above-mentioned product until spinning after cellulose dissolution, obtains with emitting far-infrared modified Lyocell fiber;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are mixed, mixing Than for 4: 1, the fiber lay down of mixing being set as net using cross lapping, high-pressure water-jet technique is recycled to carry out the fiber for mixing Reinforce, it is 1.5MPa that its liquid drugs injection pressure is first of liquid drugs injection pressure, the liquid drugs injection pressure of second spun lacing is 4.5MPa, the 3rd road The liquid drugs injection pressure of spun lacing is 5MPa, obtains surface density for 30g/m2Non-weaving cloth, can be prepared by after drying described far red Outer mask substrate.
Using far infrared tester, far infrared test is carried out to the mask substrate, its far emissivity is 86%.

Claims (2)

1. a kind of far infrared mask substrate, its mass percent group is divided into:
Graphene modification Loycell fiber:20%~50%,
Loycell fiber:50%~80%;
In the Graphene modification Loycell fiber, Graphene content accounts for the 0.5-5% of fiber quality.
2. the preparation method of far infrared mask substrate according to claim 1, it is characterised in that comprise the following steps:
(1) prepared by modified Lyocell fiber:By modified for dodecyl sodium sulfate surfactant Graphene and cellulose/N- Methyhnorpholine-N-oxide solution carries out wet spinning after being blended, and obtains with emitting far-infrared Graphene modification Lyocell fiber, the Graphene is 0.5-5% with cellulose mass percent;
(2) far infrared mask substrate spun lacing molding:Modified Lyocell fiber and common Lyocell fiber are mixed by a certain percentage Close, mixing ratio is to reinforce to make surface density for 30g/m 1: 1-4: 1, through fiber opening, combing and spun lacing2Non-weaving cloth, described Spun lacing reinforces liquid drugs injection pressure, and first of liquid drugs injection pressure is 1.5MPa, and the liquid drugs injection pressure of second spun lacing is 4.5MPa, and the 3rd The liquid drugs injection pressure of road spun lacing is 5MPa, can be prepared by described far infrared mask substrate after drying.
CN201610843026.1A 2016-09-21 2016-09-21 A kind of preparation method of far infrared mask substrate Active CN106436024B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107399119A (en) * 2017-08-11 2017-11-28 恒天嘉华非织造有限公司 A kind of high-end hygienic material of graphene-based fiber and its preparation technology
CN107399118A (en) * 2017-08-11 2017-11-28 恒天嘉华非织造有限公司 A kind of high-end medical material of graphene-based fiber and its preparation technology
CN107955984A (en) * 2017-12-01 2018-04-24 山东英利实业有限公司 A kind of graphene polysaccharide graft Lyocell fiber and preparation method thereof
CN108294977A (en) * 2018-01-26 2018-07-20 湖南御茯堂健康管理咨询有限公司 A kind of graphene black jade facial mask
CN108396462A (en) * 2018-03-12 2018-08-14 东纶科技实业有限公司 A kind of graphene fiber non-woven material and preparation method thereof
CN108866816A (en) * 2017-05-08 2018-11-23 山东圣泉新材料股份有限公司 A kind of bacteriostatic non-woven cloth and its preparation method and application
CN108892814A (en) * 2018-07-12 2018-11-27 高昕文 A kind of preparation method being retained mask substrate

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CN101338487A (en) * 2008-08-05 2009-01-07 无锡双象超纤材料股份有限公司 Degradable superfine fiber nonwoven
WO2009036481A1 (en) * 2007-09-18 2009-03-26 Lenzing Aktiengesellschaft Lyocell fiber
CN102159764A (en) * 2008-09-22 2011-08-17 连津格股份公司 Use of lyocell fibers and items comprising lyocell fibers
KR20120082287A (en) * 2011-01-13 2012-07-23 경북대학교 산학협력단 Precursor including lyocell/graphene nanocomposite and carbon-fiber by using the same and method of manufacturing the same
CN103556248A (en) * 2013-10-28 2014-02-05 山东英利实业有限公司 Bamboo charcoal Lyocell fiber and preparation process thereof
CN104244997A (en) * 2012-02-28 2014-12-24 澜星股份公司 Hygiene product
CN205474200U (en) * 2016-01-18 2016-08-17 上海奥领纺织新材料有限公司 Multi -functional yarn of graphene fiber blending

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Publication number Priority date Publication date Assignee Title
WO2009036481A1 (en) * 2007-09-18 2009-03-26 Lenzing Aktiengesellschaft Lyocell fiber
CN101338487A (en) * 2008-08-05 2009-01-07 无锡双象超纤材料股份有限公司 Degradable superfine fiber nonwoven
CN102159764A (en) * 2008-09-22 2011-08-17 连津格股份公司 Use of lyocell fibers and items comprising lyocell fibers
KR20120082287A (en) * 2011-01-13 2012-07-23 경북대학교 산학협력단 Precursor including lyocell/graphene nanocomposite and carbon-fiber by using the same and method of manufacturing the same
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108866816A (en) * 2017-05-08 2018-11-23 山东圣泉新材料股份有限公司 A kind of bacteriostatic non-woven cloth and its preparation method and application
CN107399119A (en) * 2017-08-11 2017-11-28 恒天嘉华非织造有限公司 A kind of high-end hygienic material of graphene-based fiber and its preparation technology
CN107399118A (en) * 2017-08-11 2017-11-28 恒天嘉华非织造有限公司 A kind of high-end medical material of graphene-based fiber and its preparation technology
CN107955984A (en) * 2017-12-01 2018-04-24 山东英利实业有限公司 A kind of graphene polysaccharide graft Lyocell fiber and preparation method thereof
CN108294977A (en) * 2018-01-26 2018-07-20 湖南御茯堂健康管理咨询有限公司 A kind of graphene black jade facial mask
CN108396462A (en) * 2018-03-12 2018-08-14 东纶科技实业有限公司 A kind of graphene fiber non-woven material and preparation method thereof
CN108892814A (en) * 2018-07-12 2018-11-27 高昕文 A kind of preparation method being retained mask substrate

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