CN107399119A - A kind of high-end hygienic material of graphene-based fiber and its preparation technology - Google Patents
A kind of high-end hygienic material of graphene-based fiber and its preparation technology Download PDFInfo
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- CN107399119A CN107399119A CN201710683242.9A CN201710683242A CN107399119A CN 107399119 A CN107399119 A CN 107399119A CN 201710683242 A CN201710683242 A CN 201710683242A CN 107399119 A CN107399119 A CN 107399119A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 83
- 239000000835 fiber Substances 0.000 title claims abstract description 82
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000005516 engineering process Methods 0.000 title claims abstract description 16
- 239000002390 adhesive tape Substances 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 16
- 102000008186 Collagen Human genes 0.000 claims abstract description 14
- 108010035532 Collagen Proteins 0.000 claims abstract description 14
- 230000037314 wound repair Effects 0.000 claims abstract description 14
- 230000000249 desinfective effect Effects 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 230000008030 elimination Effects 0.000 claims description 9
- 238000003379 elimination reaction Methods 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 9
- 238000009960 carding Methods 0.000 claims description 6
- 238000009940 knitting Methods 0.000 claims description 6
- 230000007246 mechanism Effects 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 4
- 239000010439 graphite Substances 0.000 claims description 4
- 229920001661 Chitosan Polymers 0.000 claims description 3
- 108010081750 Reticulin Proteins 0.000 claims description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 230000000774 hypoallergenic effect Effects 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 239000012528 membrane Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229920001436 collagen Polymers 0.000 claims 1
- 238000012856 packing Methods 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000035876 healing Effects 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000006855 networking Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
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- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
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- B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
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- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
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- A—HUMAN NECESSITIES
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- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/32—Proteins, polypeptides; Degradation products or derivatives thereof, e.g. albumin, collagen, fibrin, gelatin
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- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
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- A61L15/42—Use of materials characterised by their function or physical properties
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- A—HUMAN NECESSITIES
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- A61L15/44—Medicaments
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- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
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- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/30—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
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- B32B2307/51—Elastic
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/582—Tearability
- B32B2307/5825—Tear resistant
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- B32B2535/00—Medical equipment, e.g. bandage, prostheses or catheter
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Abstract
The invention discloses a kind of high-end hygienic material of graphene-based fiber and its preparation technology of grapheme material technical field,Including graphene fiber substrate,Breathable adhesive tape layer is connected with the top of the graphene fiber substrate,The top of the breathable adhesive tape layer is provided with collagen protein sponge layer,The top of the collagen protein sponge layer is provided with sanitary disinfecting layer,The sanitary disinfecting layer includes the wound repair film for being arranged on its surface,The surface place placed in the middle of the wound repair film is additionally provided with wound surface dressing layer,The present invention on graphene-based bottom by setting breathable adhesive tape,On the basis of air permeability is ensured,There is provided and collagen protein sponge layer easily connected mode,Utilize the good elastic substrate with rigidity as wound surface hygienic material of graphene fiber,The tear-proof degree of hygienic material can be increased,And beneficial to the ventilative of wound when being pasted onto wound surface,Promote the healing of wound surface.
Description
Technical field
The present invention relates to grapheme material technical field, the high-end hygienic material of specially a kind of graphene-based fiber and its system
Standby technique.
Background technology
Graphene is a kind of cellular flat film formed by carbon atom with sp2 hybrid forms, is a kind of only one
The quasi- two-dimensional material of atomic layer level thickness, monoatomic layer graphite is done so being called.Univ Manchester UK physicist An De
Lie Gaimu and Constantine's Nuo Woxiao loves, graphene is isolated from graphite with micromechanics stripping method success, therefore altogether
With acquisition Nobel Prize in physics in 2010.The method of the common power production of graphene be mechanical stripping method, oxidation-reduction method,
SiC epitaxial growth methods, film production method are chemical vapour deposition technique (CVD).Due to its very good intensity, it is flexible, lead
Electricity, heat conduction, optical characteristics, it is obtained in fields such as physics, materialogy, electronic information, computer, Aero-Space considerable
Development.Nano level graphene oxide sheet can be spun into macroscopical graphene fiber up to several meters.Prepared fiber is not only
Intensity is high, and good toughness, can break into knot or be woven into the mat of conduction.But graphene fiber material is facing applying
The scope of bed medically is narrow, because graphene fiber has good elasticity and rigidity, can answer graphene fiber material
In the recovery for using clinical wound surface.Therefore, we have proposed a kind of high-end hygienic material of graphene-based fiber and its preparation
Technique comes into operation, to solve the above problems.
The content of the invention
It is an object of the invention to provide a kind of high-end hygienic material of graphene-based fiber and its preparation technology, with solution
State the problem of being proposed in background technology.
To achieve the above object, the present invention provides following technical scheme:A kind of high-end hygienic material of graphene-based fiber, bag
Graphene fiber substrate is included, breathable adhesive tape layer, the top of the breathable adhesive tape layer are connected with the top of the graphene fiber substrate
Portion is provided with collagen protein sponge layer, and the top of the collagen protein sponge layer is provided with sanitary disinfecting layer, the sanitary disinfecting layer bag
The wound repair film for being arranged on its surface is included, the surface place placed in the middle of the wound repair film is additionally provided with wound surface dressing layer.
Preferably, the graphene fiber substrate includes two layers of graphene fiber layer, and above and below two layers of graphene fiber layer
Superposition is set.
Preferably, the breathable adhesive tape layer is medical no sensitive tape layer, and the bottom of breathable adhesive tape layer passes through knitting
It is fixed in graphene fiber substrate.
Preferably, the wound repair film is medical chitosan wound repair gel, and the wound surface dressing layer is served as reasons
The surface of the medical adhesive elastic body of sodium carboxymethylcellulose particle, hypoallergenic and plasticizer composition is semipermeable more with one layer
Poly film structure.
Preferably, a kind of preparation technology of the high-end hygienic material of graphene-based fiber, the graphene-based fiber are high-end medical
The preparation technology's of material comprises the following steps that:
S1:Graphene-based fibrous raw material is sent into opener by feeding mechanism and carries out impurity elimination processing;
S2:Graphene-based fibrous raw material after shredding impurity elimination processing is sent into carding machine, by graphene-based fiber
Raw material becomes reticular fiber structure;
S3:Graphene fibre web is sent into lapping machine, utilizes moving back and forth fibre web laying to networking for lower net guide
On curtain;
S4:The graphene-based fibre web of the second layer is prepared using above-mentioned same step, and two layers of fibre web is superimposed, after compacting
It is sent into roller drafting mechanism and carries out drawing-off processing;
S5:Graphene fibre web after drawing-off is handled carries out spun lacing processing, and the fibre web of motion is entered using High-Pressure Water
The continuous injection of row, makes the graphene fiber in fibre web tangle, so that fibre web is reinforced;
S6:Fibre web is sent into dryer, after the drying of the moisture on its surface, by pre-processed sanitary disinfecting layer and
Collagen protein sponge layer is pasted onto on breathable adhesive tape layer, and breathable adhesive tape layer is fixed on into graphene fibre web by the technique of knitting
On;
S7:Graphene hygienic material is sent into metal detector and detected, is batched after qualified, and cuts and beats
Bag.
Preferably, in the step S1, graphene-based fibrous raw material is sent to smart shredding again after being handled first by thick shredding
Carry out impurity elimination processing.
Preferably, in the step S2, the cylinder of carding machine and doffer are hollow cylinder structure, and cylinder and doffer
Surface is coated with pin cloth, and the wherein rotating speed of cylinder is 360~520r/min, and the rotating speed of doffer is 20~40r/min.
Preferably, in the step S3, lapping machine is double curtain sandwich crosslapping machines, and its lapping speed is 40~60m/min.
Preferably, in the step S6, drying temperature is 100~120 DEG C, the control of regain after drying 4~6% it
Between.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention on graphene-based bottom by setting ventilative glue
Band, on the basis of air permeability is ensured, there is provided with collagen protein sponge layer easily connected mode, utilize the good of graphene fiber
Good elasticity and substrate of the rigidity as wound surface hygienic material, by increasing capacitance it is possible to increase the tear-proof degree of hygienic material, and paste
In wound surface beneficial to the ventilative of wound, promote the healing of wound surface, preparation method of the present invention is simple, efficiency high, and property
Can be stable.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention;
Fig. 2 is sanitary disinfecting Rotating fields schematic diagram of the present invention;
Fig. 3 is workflow diagram of the present invention.
In figure:1 graphene fiber substrate, 2 breathable adhesive tape layers, 3 collagen protein sponge layers, 4 sanitary disinfecting layers, 41 surface of a wound are repaiied
Laminating adhesive, 42 wound surface dressing layers.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made
Embodiment, belong to the scope of protection of the invention.
Fig. 1-3 are referred to, the present invention provides a kind of technical scheme:A kind of high-end hygienic material of graphene-based fiber, including
Graphene fiber substrate 1, the top of the graphene fiber substrate 1 are connected with breathable adhesive tape layer 2, the breathable adhesive tape layer 2
Top is provided with collagen protein sponge layer 3, and the top of the collagen protein sponge layer 3 is provided with sanitary disinfecting layer 4, the sanitary disinfecting
Layer 4 includes the wound repair film 41 for being arranged on its surface, and the surface place placed in the middle of the wound repair film 41 is additionally provided with wound surface
Dressing layer 42.
Wherein, the graphene fiber substrate 1 includes two layers of graphene fiber layer, and two layers of graphene fiber layer is folded up and down
Add and put, the breathable adhesive tape layer 2 is medical no sensitive tape layer, and the bottom of breathable adhesive tape layer 2 is fixed on by knitting
In graphene fiber substrate 1, the wound repair film 41 is medical chitosan wound repair gel, the wound surface dressing layer
42 be semi-transparent with one layer by the surface that sodium carboxymethylcellulose particle, the medical adhesive elastic body of hypoallergenic and plasticizer form
The poly membrane structure of property.
Present invention also offers a kind of preparation technology of the graphene-based high-end hygienic material of fiber, the graphene-based fiber are high
Hold comprising the following steps that for the preparation technology of hygienic material:
S1:Graphene-based fibrous raw material is sent into opener by feeding mechanism and carries out impurity elimination processing, graphene-based fiber
Raw material is sent to smart shredding and carries out impurity elimination processing again after being handled first by thick shredding;
S2:Graphene-based fibrous raw material after shredding impurity elimination processing is sent into carding machine, by graphene-based fiber
Raw material becomes reticular fiber structure, and the cylinder of carding machine and doffer are hollow cylinder structure, and the surface of cylinder and doffer are equal
Pin cloth is coated with, the wherein rotating speed of cylinder is 360~520r/min, and the rotating speed of doffer is 20~40r/min;
S3:Graphene fibre web is sent into lapping machine, utilizes moving back and forth fibre web laying to networking for lower net guide
On curtain, lapping machine is double curtain sandwich crosslapping machines, and its lapping speed is 40~60m/min;
S4:The graphene-based fibre web of the second layer is prepared using above-mentioned same step, and two layers of fibre web is superimposed, after compacting
It is sent into roller drafting mechanism and carries out drawing-off processing;
S5:Graphene fibre web after drawing-off is handled carries out spun lacing processing, and the fibre web of motion is entered using High-Pressure Water
The continuous injection of row, makes the graphene fiber in fibre web tangle, so that fibre web is reinforced;
S6:Fibre web is sent into dryer, after the moisture drying on its surface, by pre-processed sanitary disinfecting layer 4
It is pasted onto with collagen protein sponge layer 3 on breathable adhesive tape layer 2, and breathable adhesive tape layer 2 is fixed on graphite by the technique of knitting
On alkene fibre web, drying temperature is 100~120 DEG C, and the regain after drying is controlled between 4~6%;
S7:Graphene hygienic material is sent into metal detector and detected, is batched after qualified, and cuts and beats
Bag.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (9)
1. a kind of high-end hygienic material of graphene-based fiber, including graphene fiber substrate (1), it is characterised in that:The graphite
Breathable adhesive tape layer (2) is connected with the top of alkene fibrous substrate (1), the top of the breathable adhesive tape layer (2) is provided with collagen sea
Continuous layer (3), the top of the collagen protein sponge layer (3) are provided with sanitary disinfecting layer (4), and the sanitary disinfecting layer (4) includes setting
The wound repair film (41) on its surface is put, the surface place placed in the middle of the wound repair film (41) is additionally provided with wound surface dressing layer
(42)。
A kind of 2. graphene-based high-end hygienic material of fiber according to claim 1, it is characterised in that:The graphene is fine
Wiki bottom (1) includes two layers of graphene fiber layer, and two layers of graphene fiber layer is superimposed setting up and down.
A kind of 3. graphene-based high-end hygienic material of fiber according to claim 1, it is characterised in that:The breathable adhesive tape
Layer (2) is medical no sensitive tape layer, and the bottom of breathable adhesive tape layer (2) is fixed on graphene fiber substrate by knitting
(1) on.
A kind of 4. graphene-based high-end hygienic material of fiber according to claim 1, it is characterised in that:The wound repair
Film (41) is medical chitosan wound repair gel, the wound surface dressing layer (42) be by sodium carboxymethylcellulose particle,
The surface of the medical adhesive elastic body of hypoallergenic and plasticizer composition has one layer of semipermeable poly membrane structure.
A kind of 5. preparation technology of the high-end hygienic material of graphene-based fiber, it is characterised in that:The graphene-based high-end doctor of fiber
With comprising the following steps that for the preparation technology of material:
S1:Graphene-based fibrous raw material is sent into opener by feeding mechanism and carries out impurity elimination processing;
S2:Graphene-based fibrous raw material after shredding impurity elimination processing is sent into carding machine, by graphene-based fibrous raw material
Become reticular fiber structure;
S3:Graphene fibre web is sent into lapping machine, utilizes moving back and forth fibre web laying on lace curtaining for lower net guide;
S4:The graphene-based fibre web of the second layer is prepared using above-mentioned same step, and two layers of fibre web is superimposed, is sent into after compacting
Drawing-off processing is carried out in roller drafting mechanism;
S5:Graphene fibre web after drawing-off is handled carries out spun lacing processing, and the fibre web of motion is connected using High-Pressure Water
Continuous injection, makes the graphene fiber in fibre web tangle, so that fibre web is reinforced;
S6:Fibre web is sent into dryer, after the drying of the moisture on its surface, by pre-processed sanitary disinfecting layer (4) and
Collagen protein sponge layer (3) is pasted onto on breathable adhesive tape layer (2), and breathable adhesive tape layer (2) is fixed on by the technique of knitting
On graphene fibre web;
S7:Graphene hygienic material is sent into metal detector and detected, is batched after qualified, and cut packing.
A kind of 6. preparation technology of graphene-based high-end hygienic material of fiber according to claim 5, it is characterised in that:Institute
State in step S1, graphene-based fibrous raw material is sent to smart shredding and carries out impurity elimination processing again after being handled first by thick shredding.
A kind of 7. preparation technology of graphene-based high-end hygienic material of fiber according to claim 5, it is characterised in that:Institute
Stating in step S2, the cylinder of carding machine and doffer are hollow cylinder structure, and the surface of cylinder and doffer are coated with pin cloth,
Wherein the rotating speed of cylinder is 360~520r/min, and the rotating speed of doffer is 20~40r/min.
A kind of 8. preparation technology of graphene-based high-end hygienic material of fiber according to claim 5, it is characterised in that:Institute
State in step S3, lapping machine is double curtain sandwich crosslapping machines, and its lapping speed is 40~60m/min.
A kind of 9. preparation technology of graphene-based high-end hygienic material of fiber according to claim 5, it is characterised in that:Institute
State in step S6, drying temperature is 100~120 DEG C, and the regain after drying is controlled between 4~6%.
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