CN106811972A - A kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent - Google Patents
A kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent Download PDFInfo
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- CN106811972A CN106811972A CN201611265433.5A CN201611265433A CN106811972A CN 106811972 A CN106811972 A CN 106811972A CN 201611265433 A CN201611265433 A CN 201611265433A CN 106811972 A CN106811972 A CN 106811972A
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- finishing agent
- permanent seal
- seal cooling
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent, belong to textile finishing technical field.The present invention is with wool as raw material, after cleaning wool keratin solution is made after alkali soluble desolventing technology, again with sodium cellulose glycolate as template, nano silicon is made the loose structure nano silicon of good dispersion, recycle loose structure absorption octadecyl ammonium chloride, antiseptic is made, finally with the wool keratin solution complex antimicrobials and silicone oil for preparing, permanent seal cooling fabric antimicrobial finishing agent is obtained.Permanent seal cooling fabric antimicrobial finishing agent prepared by the present invention is by preparing loose structure nano silicon; using its specific surface area it is big the characteristics of load quaternary ammonium salt antiseptic; recycle wool keratin solution cladding antiseptic; and it is covered in fabric face; diaphragm is formed, the antibacterial endurance quality of fabric is significantly improved.
Description
Technical field
The present invention relates to a kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent, belong to textile finishing technical field.
Background technology
For a long time, the development of China's textile industry relies primarily on low value-added, traditional, the universal fiber species of production,
With the development of technological progress and the social demand of industry, the market challenges that traditional low value-added textile product is faced
It is growing day by day with survival pressure.Country implement industrial upgrading overall background under, exploitation high technology content, health, it is green
The fabric that colour circle is protected has turned into the important component of weaving adjustment of agricultural stracture.Wherein, develop a kind of new, efficient
Textile fabric antiseptic, the economic value added to improving China's textile product as early as possible has great importance.
It is well known that quaternary ammonium salt antibacterial finishing agent has benefited from, its is nontoxic, harmless, safely and efficiently characteristic, extensively should
For textile industry.Conventional quaternary ammonium salt antibacterial finishing agent is with high costs mostly from external import at present, causes textile enterprise to be given birth to
The antibacterial fabric cost of product is raised.Research and the antibacterial finishing agent of production high-quality low-cost, have emphatically in actual production
Want meaning.In recent years, quaternary ammonium salt antiseptic is always the focus of researcher's concern, and the cation positive charge of its band can be with
The negative electricity carried with bacterial cell membrane surface is combined, and upsets the physiological function of bacterial cell membrane, damages breathing, transmission of bacterium etc.
Function, or even the cell membrane of bacterium is directly dissolved, the RNA in cell liquid etc. is revealed, bacterium is directly killed, but due to sun
Quaternary ammonium salts it is water-soluble high, antibiotic fabric is washed to cause anti-microbial property drastically to decline afterwards for several times, cause antibacterial
Endurance quality is undesirable.
The content of the invention
The technical problems to be solved by the invention：For water-soluble high, the antibiotic fabric quilt due to cation quaternary ammonium salt
Washing can cause anti-microbial property drastically to decline afterwards for several times, the problem for causing antibacterial endurance quality undesirable, the invention provides
A kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent, it is of the invention with wool as raw material, after cleaning after alkali soluble desolventing technology
Wool keratin solution is made, then with sodium cellulose glycolate as template, nano silicon is made many of good dispersion
Pore structure nano silicon, recycles loose structure absorption octadecyl ammonium chloride, antiseptic is made, finally with the sheep for preparing
The solution combined antiseptic of feather keratin and silicone oil, are obtained permanent seal cooling fabric antimicrobial finishing agent.Permanent seal cooling fabric prepared by the present invention
Antibacterial finishing agent by preparing loose structure nano silicon, using its specific surface area it is big the characteristics of load quaternary ammonium salt antibacterial
Agent, recycles wool keratin solution cladding antiseptic, and is covered in fabric face, forms diaphragm, significantly improves fabric
Antibacterial endurance quality.
In order to solve the above technical problems, the technical solution adopted by the present invention is：
（1）1~2kg wools are weighed, 2~3 times are washed with deionized and are fitted into baking oven afterwards, 2~3h is dried at 50~55 DEG C,
It is transferred to again in pulverizer and is crushed to broken section of 2~5mm, it is 2% NaOH that broken section of wool is added into 10~20L mass fractions
In solution, under 80~90 DEG C of waters bath with thermostatic control, 3~5h is dissolved, add 10~20g activated carbons, stirred with 500~600r/min
1~2h, then filtering, collects filtrate, obtains wool keratin solution, standby；
（2）4~6g sodium cellulose glycolates are weighed, 4~6g dodecyl sodium sulfates, 5~10g nano silicons add 600
In~800mL deionized waters, then disperse 15~20min with 300W ultrasonic echographies, obtain mixed liquor, be then placed in very mixed liquor
In vacuum freecing-dry case, vacuum is evacuated to for 1~10Pa, 20~30h of freeze-drying in the case where 50 DEG C of 60~﹣ of ﹣, then by desciccate
It is placed in resistance furnace, 1000~1200 DEG C is warming up to 5~10 DEG C/min, keeping temperature calcines 3~4h, naturally cools to room temperature
After take out, obtain porous nano silica；
（3）3~5g octadecyl ammonium chlorides are weighed, in addition 1~2L deionized waters, with 300~400r/ at 50~60 DEG C
Min stirs 1~2h, and standing and defoaming processes 1~2h in then continuing at vacuum drying chamber, adds the above-mentioned porous nanos two of 3~5g
Silica, stirs 20~30min, then filtering with 500~600r/min, collects filter residue, filter residue is placed in drying box, 60
2~3h is dried at~70 DEG C, silicon dioxide carried quaternary ammonium salt antiseptic is obtained；
（4）Measure 300~500mL steps（1）The wool keratin solution of preparation, adds 3~5g above-mentioned silicon dioxide carried seasons
Ammonium salt antimicrobial, under 40~50 DEG C of waters bath with thermostatic control, 30~40min is stirred with 300~400r/min, adds 100~200mL
Silicone oil, continues to stir 1~2h, is discharged after being cooled to room temperature, obtains permanent seal cooling fabric antimicrobial finishing agent.
Application process of the invention is：In mass ratio 100：1~120：1, the permanent seal cooling fabric that water is prepared with the present invention
Antibacterial finishing agent is uniformly mixed, and obtains finish solution, then fabric is immersed in finish solution, at 80~90 DEG C
30~40min for the treatment of, then takes out after fabric pricks dry excessive moisture and dries.After testing, the durable of present invention preparation is used
Type fabric antimicrobial finishing agent, antibacterial fabric endurance quality improves 40~50%, and pliability is high, good hand touch.
The method have the benefit that：
（1）Permanent seal cooling fabric antimicrobial finishing agent antibacterial excellent in durability prepared by the present invention；
（2）Permanent seal cooling fabric antimicrobial finishing agent prepared by the present invention, the feel of fabric is not interfered with not only, also improves fabric
Flexibility.
Specific embodiment
1~2kg wools are weighed, 2~3 times is washed with deionized and is fitted into baking oven afterwards, dry 2 at 50~55 DEG C~
3h, then be transferred in pulverizer and be crushed to broken section of 2~5mm, it is 2% hydroxide that broken section of wool is added into 10~20L mass fractions
In sodium solution, under 80~90 DEG C of waters bath with thermostatic control, 3~5h is dissolved, add 10~20g activated carbons, stirred with 500~600r/min
1~2h is mixed, then filtering, collect filtrate, obtain wool keratin solution, it is standby；Weigh 4~6g sodium cellulose glycolates, 4~6g
Dodecyl sodium sulfate, 5~10g nano silicons in addition 600~800mL deionized waters, then use 300W ultrasonic echographies
15~20min of dispersion, obtains mixed liquor, and then mixed liquor is placed in vacuum freezing drying oven, is evacuated to vacuum for 1~10Pa,
20~30h of freeze-drying in the case where 50 DEG C of 60~﹣ of ﹣, then desciccate is placed in resistance furnace, it is warming up to 5~10 DEG C/min
1000~1200 DEG C, keeping temperature calcines 3~4h, is taken out after naturally cooling to room temperature, obtains porous nano silica；Weigh 3
~5g octadecyl ammonium chlorides, are added in 1~2L deionized waters, and 1~2h is stirred with 300~400r/min at 50~60 DEG C,
Then continue at standing and defoaming in vacuum drying chamber and process 1~2h, add the above-mentioned porous nano silicas of 3~5g, with 500~
600r/min stirs 20~30min, then filtering, collects filter residue, and filter residue is placed in drying box, and 2 are dried at 60~70 DEG C
~3h, obtains silicon dioxide carried quaternary ammonium salt antiseptic；Measure 300~500mL steps（1）The wool keratin solution of preparation, plus
Enter the above-mentioned silicon dioxide carried quaternary ammonium salt antiseptics of 3~5g, under 40~50 DEG C of waters bath with thermostatic control, stirred with 300~400r/min
30~40min, adds 100~200mL silicone oil, continues to stir 1~2h, is discharged after being cooled to room temperature, obtains permanent seal cooling fabric and resists
Bacterium finishing agent.
Example 1
1kg wools are weighed, 2 times is washed with deionized and is fitted into baking oven afterwards, 2h is dried at 50 DEG C, then be transferred to pulverizer
In be crushed to broken section of 2mm, in adding 10L mass fractions to be 2% sodium hydroxide solution broken section of wool, under 80 DEG C of waters bath with thermostatic control,
Dissolving 3h, adds 10g activated carbons, stirs 1h with 500r/min, then filtering, collects filtrate, obtains wool keratin solution, standby
With；Weigh 4g sodium cellulose glycolates, 4g dodecyl sodium sulfates, 5g nano silicons, in adding 600mL deionized waters,
Disperse 15min with 300W ultrasonic echographies again, obtain mixed liquor, then mixed liquor is placed in vacuum freezing drying oven, be evacuated to true
Reciprocal of duty cycle is 1Pa, the freeze-drying 20h in the case where 50 DEG C of ﹣, then desciccate is placed in resistance furnace, and 1000 are warming up to 5 DEG C/min
DEG C, keeping temperature calcining 3h takes out after naturally cooling to room temperature, obtains porous nano silica；Weigh 3g octadecyl chlorinations
Ammonium, is added in 1L deionized waters, and 1h is stirred with 300r/min at 50 DEG C, then continues at standing and defoaming treatment in vacuum drying chamber
1h, adds the above-mentioned porous nano silicas of 3g, stirs 20min with 500r/min, then filtering, filter residue is collected, by filter residue
It is placed in drying box, 2h is dried at 60 DEG C, obtains silicon dioxide carried quaternary ammonium salt antiseptic；Measure 300mL steps（1）Prepare
Wool keratin solution, adds the above-mentioned silicon dioxide carried quaternary ammonium salt antiseptics of 3g, under 40 DEG C of waters bath with thermostatic control, with 300r/min
Stirring 30min, adds 100mL silicone oil, continues to stir 1h, is discharged after being cooled to room temperature, obtains permanent seal cooling fabric antimicrobial finishing agent.
Application process of the invention is：In mass ratio 120：1, the permanent seal cooling antibiotic finish of the fabric that water is prepared with the present invention
Agent is uniformly mixed, and obtains finish solution, then fabric is immersed in finish solution, 30min is processed at 80 DEG C, so
Take out afterwards after fabric pricks dry excessive moisture and dry.After testing, the permanent seal cooling fabric antimicrobial finishing agent for being prepared using the present invention,
Antibacterial fabric endurance quality improves 40%, and pliability is high, good hand touch.
Example 2
1.5kg wools are weighed, 2 times is washed with deionized and is fitted into baking oven afterwards, 2h is dried at 52 DEG C, then be transferred to crushing
Broken section of 3mm is crushed in machine, in adding 12L mass fractions to be 2% sodium hydroxide solution broken section of wool, in 85 DEG C of waters bath with thermostatic control
Under, 4h is dissolved, 15g activated carbons are added, 1.5h is stirred with 560r/min, then filtering, filtrate is collected, obtain wool keratin molten
Liquid, it is standby；5g sodium cellulose glycolates are weighed, 5g dodecyl sodium sulfates, 8g nano silicons add 700mL deionizations
In water, then disperse 18min with 300W ultrasonic echographies, obtain mixed liquor, then mixed liquor is placed in vacuum freezing drying oven, take out
It is 6Pa, the freeze-drying 25h in the case where 55 DEG C of ﹣ to vacuum, then desciccate is placed in resistance furnace, is warming up to 10 DEG C/min
1100 DEG C, keeping temperature calcining 3.5h takes out after naturally cooling to room temperature, obtains porous nano silica；Weigh 4g octadecanes
Ammonium chloride, is added in 1.5L deionized waters, and 1.2h is stirred with 350r/min at 55 DEG C, is then continued at quiet in vacuum drying chamber
Deaeration treatment 1.2h is put, the above-mentioned porous nano silicas of 4g are added, 25min is stirred with 550r/min, then filtering, collected
Filter residue, filter residue is placed in drying box, and 2.3h is dried at 65 DEG C, obtains silicon dioxide carried quaternary ammonium salt antiseptic；Measure 400mL
Step（1）The wool keratin solution of preparation, adds the above-mentioned silicon dioxide carried quaternary ammonium salt antiseptics of 4g, in 45 DEG C of waters bath with thermostatic control
Under, 35min is stirred with 350r/min, 160mL silicone oil is added, continue to stir 1.2h, discharged after being cooled to room temperature, obtain permanent seal cooling
Fabric antimicrobial finishing agent.
Application process of the invention is：In mass ratio 110：1, the permanent seal cooling antibiotic finish of the fabric that water is prepared with the present invention
Agent is uniformly mixed, and obtains finish solution, then fabric is immersed in finish solution, 35min is processed at 85 DEG C, so
Take out afterwards after fabric pricks dry excessive moisture and dry.After testing, the permanent seal cooling fabric antimicrobial finishing agent for being prepared using the present invention,
Antibacterial fabric endurance quality improves 43%, and pliability is high, good hand touch.
Example 3
2kg wools are weighed, 3 times is washed with deionized and is fitted into baking oven afterwards, 3h is dried at 55 DEG C, then be transferred to pulverizer
In be crushed to broken section of 5mm, in adding 20L mass fractions to be 2% sodium hydroxide solution broken section of wool, under 90 DEG C of waters bath with thermostatic control,
Dissolving 5h, adds 20g activated carbons, stirs 2h with 600r/min, then filtering, collects filtrate, obtains wool keratin solution, standby
With；Weigh 6g sodium cellulose glycolates, 6g dodecyl sodium sulfates, 10g nano silicons, in adding 800mL deionized waters,
Disperse 20min with 300W ultrasonic echographies again, obtain mixed liquor, then mixed liquor is placed in vacuum freezing drying oven, be evacuated to true
Reciprocal of duty cycle is 10Pa, the freeze-drying 30h in the case where 60 DEG C of ﹣, then desciccate is placed in resistance furnace, and 1200 are warming up to 10 DEG C/min
DEG C, keeping temperature calcining 4h takes out after naturally cooling to room temperature, obtains porous nano silica；Weigh 5g octadecyl chlorinations
Ammonium, is added in 2L deionized waters, and 2h is stirred with 400r/min at 60 DEG C, then continues at standing and defoaming treatment in vacuum drying chamber
2h, adds the above-mentioned porous nano silicas of 5g, stirs 30min with 600r/min, then filtering, filter residue is collected, by filter residue
It is placed in drying box, 3h is dried at 70 DEG C, obtains silicon dioxide carried quaternary ammonium salt antiseptic；Measure 500mL steps（1）Prepare
Wool keratin solution, adds the above-mentioned silicon dioxide carried quaternary ammonium salt antiseptics of 5g, under 50 DEG C of waters bath with thermostatic control, with 400r/min
Stirring 40min, adds 200mL silicone oil, continues to stir 2h, is discharged after being cooled to room temperature, obtains permanent seal cooling fabric antimicrobial finishing agent.
Application process of the invention is：In mass ratio 100：1, the permanent seal cooling antibiotic finish of the fabric that water is prepared with the present invention
Agent is uniformly mixed, and obtains finish solution, then fabric is immersed in finish solution, 40min is processed at 90 DEG C, so
Take out afterwards after fabric pricks dry excessive moisture and dry.After testing, the permanent seal cooling fabric antimicrobial finishing agent for being prepared using the present invention,
Antibacterial fabric endurance quality improves 50%, and pliability is high, good hand touch.
Claims (1)
1. a kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent, it is characterised in that specific preparation process is：
（1）1~2kg wools are weighed, 2~3 times are washed with deionized and are fitted into baking oven afterwards, 2~3h is dried at 50~55 DEG C,
It is transferred to again in pulverizer and is crushed to broken section of 2~5mm, it is 2% NaOH that broken section of wool is added into 10~20L mass fractions
In solution, under 80~90 DEG C of waters bath with thermostatic control, 3~5h is dissolved, add 10~20g activated carbons, stirred with 500~600r/min
1~2h, then filtering, collects filtrate, obtains wool keratin solution, standby；
（2）4~6g sodium cellulose glycolates are weighed, 4~6g dodecyl sodium sulfates, 5~10g nano silicons add 600
In~800mL deionized waters, then disperse 15~20min with 300W ultrasonic echographies, obtain mixed liquor, be then placed in very mixed liquor
In vacuum freecing-dry case, vacuum is evacuated to for 1~10Pa, 20~30h of freeze-drying in the case where 50 DEG C of 60~﹣ of ﹣, then by desciccate
It is placed in resistance furnace, 1000~1200 DEG C is warming up to 5~10 DEG C/min, keeping temperature calcines 3~4h, naturally cools to room temperature
After take out, obtain porous nano silica；
（3）3~5g octadecyl ammonium chlorides are weighed, in addition 1~2L deionized waters, with 300~400r/ at 50~60 DEG C
Min stirs 1~2h, and standing and defoaming processes 1~2h in then continuing at vacuum drying chamber, adds the above-mentioned porous nanos two of 3~5g
Silica, stirs 20~30min, then filtering with 500~600r/min, collects filter residue, filter residue is placed in drying box, 60
2~3h is dried at~70 DEG C, silicon dioxide carried quaternary ammonium salt antiseptic is obtained；
（4）Measure 300~500mL steps（1）The wool keratin solution of preparation, adds 3~5g above-mentioned silicon dioxide carried seasons
Ammonium salt antimicrobial, under 40~50 DEG C of waters bath with thermostatic control, 30~40min is stirred with 300~400r/min, adds 100~200mL
Silicone oil, continues to stir 1~2h, is discharged after being cooled to room temperature, obtains permanent seal cooling fabric antimicrobial finishing agent.
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| CN201611265433.5A CN106811972A (en) | 2016-12-30 | 2016-12-30 | A kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent |
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| CN201611265433.5A CN106811972A (en) | 2016-12-30 | 2016-12-30 | A kind of preparation method of permanent seal cooling fabric antimicrobial finishing agent |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108642768A (en) * | 2018-06-15 | 2018-10-12 | 中原工学院 | A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon |
| CN108729229A (en) * | 2018-06-15 | 2018-11-02 | 中原工学院 | Application and its preparation of the easy desizing type slurry of low temperature in Quality Pure Cotton Yarn Production or polyester cotton scribbled |
| CN108998978A (en) * | 2018-06-15 | 2018-12-14 | 中原工学院 | Application and preparation method of the protein size in botany, viscose glue and hair/viscosity mixed yarn |
| CN109023944A (en) * | 2018-06-15 | 2018-12-18 | 中原工学院 | Application and its preparation of the antistatic slurry in terylene, aramid fiber and acid fiber by polylactic |
| CN111317318A (en) * | 2020-03-23 | 2020-06-23 | 浙江宏都寝具有限公司 | Antibacterial washable polylactic acid fiber quilt and manufacturing process thereof |
| CN112853765A (en) * | 2021-02-03 | 2021-05-28 | 百事基材料（青岛）股份有限公司 | Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108642768A (en) * | 2018-06-15 | 2018-10-12 | 中原工学院 | A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon |
| CN108729229A (en) * | 2018-06-15 | 2018-11-02 | 中原工学院 | Application and its preparation of the easy desizing type slurry of low temperature in Quality Pure Cotton Yarn Production or polyester cotton scribbled |
| CN108998978A (en) * | 2018-06-15 | 2018-12-14 | 中原工学院 | Application and preparation method of the protein size in botany, viscose glue and hair/viscosity mixed yarn |
| CN109023944A (en) * | 2018-06-15 | 2018-12-18 | 中原工学院 | Application and its preparation of the antistatic slurry in terylene, aramid fiber and acid fiber by polylactic |
| CN108998978B (en) * | 2018-06-15 | 2021-09-24 | 中原工学院 | Application of protein slurry in worsted wool yarn, viscose and wool/viscose blended yarn and preparation method |
| CN109023944B (en) * | 2018-06-15 | 2021-09-24 | 中原工学院 | Application of antistatic slurry in terylene, aramid fiber and polylactic acid fiber and preparation thereof |
| CN111317318A (en) * | 2020-03-23 | 2020-06-23 | 浙江宏都寝具有限公司 | Antibacterial washable polylactic acid fiber quilt and manufacturing process thereof |
| CN112853765A (en) * | 2021-02-03 | 2021-05-28 | 百事基材料（青岛）股份有限公司 | Down feather macrofiber containing active ingredients of tangerine peel, orange and pomelo and preparation method thereof |
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