CN108635324A - Antioxidant and the preparation method and application thereof, antioxidant and preparation method thereof - Google Patents
Antioxidant and the preparation method and application thereof, antioxidant and preparation method thereof Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/99—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from microorganisms other than algae or fungi, e.g. protozoa or bacteria
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9706—Algae
- A61K8/9711—Phaeophycota or Phaeophyta [brown algae], e.g. Fucus
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- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A61K8/9717—Rhodophycota or Rhodophyta [red algae], e.g. Porphyra
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- A61K8/9722—Chlorophycota or Chlorophyta [green algae], e.g. Chlorella
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- A61K2800/522—Antioxidants; Radical scavengers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
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Abstract
The present invention relates to antioxidant technology field, a kind of antioxidant and the preparation method and application thereof, antioxidant and preparation method thereof are provided.A kind of preparation method of antioxidant is extracted from algae using supercritical extract or subcritical abstraction and obtains extract liquor, can be obtained required antioxidant after carrying out decompression precipitation to gained extract liquor.A kind of antioxidant is prepared using the preparation method of above-mentioned antioxidant.The present invention also provides a kind of applications of antioxidant, by above-mentioned antioxidant for making in food, health products or cosmetics.The present invention also provides a kind of preparation methods of antioxidant, provide above-mentioned antioxidant, are isolated purification and obtain algae extract, and the algae extract is dissolved in and can be obtained required antioxidant in grease.A kind of antioxidant is prepared using the preparation method of above-mentioned antioxidant.
Description
Technical field
The present invention relates to antioxidant technology field more particularly to a kind of antioxidant and the preparation method and application thereof, resist
Oxidation additive and preparation method thereof.
Background technology
Antioxidant used for cosmetic at present generally uses food grade antioxidants.The antioxidant of food-grade mainly divides
For two classes, one is for the molten antioxidant of oil based on plant, the second is the water soluble antioxidant based on sausage.Food
The shelf-life of grade vegetable oil is usually a year and a half.And the shelf-life of fragrant sausage products is shorter, and during preservation, generally all
Freezer is needed to preserve.
The shelf-life of cosmetics is usually 3 years or more, and is stored in room temperature, and in the majority with oil water mixture, this just increases again
The risk that cosmetics are oxidized easily is added.Therefore, current food grade antioxidants, it is difficult to meet the requirement of cosmetics.
Invention content
It is an object of the invention to overcome the above-mentioned prior art, provide a kind of antioxidant and preparation method thereof with
Using, antioxidant and preparation method thereof.
In order to solve the above technical problems, invention uses technical solution as described below.A kind of preparation method of antioxidant,
It is extracted from algae using supercritical extract or subcritical abstraction and obtains extract liquor, decompression precipitation is carried out to gained extract liquor
It can be obtained required antioxidant afterwards.
Preferably, it is described use supercritical extract or subcritical abstraction extracted from algae obtain extract liquor for,
By algae algae powder, then algae powder is placed in soak after impregnating, is carried using supercritical extract or subcritical abstraction
Extract liquor is obtained, the soak includes vegetable oil and bleeding agent.
Preferably, the powder diameter of the algae powder is 2-150mm, and the soaking time of the immersion is 10min-5h, is impregnated
Temperature is 35-85 DEG C.
Preferably, the weight ratio of the soak and algae powder is 1-5：1；The weight ratio of the vegetable oil and bleeding agent is 1-
100：1.
Preferably, the vegetable oil is sunflower oil, macadimia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado
The combination of one or more of oil, wheat-germ oil, soya-bean oil, camellia oil or shea butter；The bleeding agent is tocopherol, breast
The combination of one or more of fragrant extract, Rosmarinus officinalis extract, Paeonol, food grade chemical synthetized oxidation preventive agent.
Preferably, the algae be Ovshinsky seaweed, Bo Nate spirulinas, fork coral algae, tip edge bladder-wrack, Codiumfragile(sur.) Hariot.,
Compatibile, light black huge seaweed, blunt sargassum, powder ball fan algae, powder ball fan algae, floating chlorella, starfish branch tube algae, red autumnal leaves algae,
Rhodophyta algae, spirulina maxim, atomic chlorella, bulk kelp, tool are away from helictite algae, Kong Yezao, Robusta red algae, spirulina, green
Algae, wool Marine Red Alga Polysiphonia Urceolata, bladder-wrack, Antarctic Continent clump stalk algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chains algae, worm fork red algae, fur
It is Song Zao, Phaeodactylum tricornutum, China fir leaf caulerpa, coralline algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, the black top algae of withe, small
Ball algae, leaflet seaweed, asterism China fir algae, outstanding wart sargassum, Dunaliella salina, foreign Pseudanabaena sp, haematococcus pluvialis, kappaphycus
The combination of one or more of algae, dulse, Skeletonema Costatum, broom shape sea wing algae, purple ball algae.
A kind of antioxidant is prepared using the preparation method of above-mentioned antioxidant.
A kind of application of antioxidant, by above-mentioned antioxidant for making in food, health products or cosmetics.
A kind of preparation method of antioxidant, provides above-mentioned antioxidant, is isolated purification and obtains algae and carries
Object is taken, the algae extract is dissolved in and can be obtained required antioxidant in grease.
A kind of antioxidant, it is characterised in that：It is prepared using the preparation method of above-mentioned antioxidant.
The beneficial effects of the present invention are：It can be effectively from algae using supercritical extract or subcritical abstraction
Antioxidant is extracted, these methods are simple and practicable, and since algae raw material is natural traditional food plant, abundant raw material
Inexpensive, the product obtained is pollution-free, has no toxic side effect, safe and practical, therefore the method for the present invention has stronger industrialization
Practicability and operability.
Specific implementation mode
To make those skilled in the art that the purpose, technical scheme and advantage of invention be more clearly understood, below
Invention is further elaborated in conjunction with the embodiments.
The present invention provides a kind of preparation methods of antioxidant, are planted from algae using supercritical extract or subcritical abstraction
Extraction obtains extract liquor in object, can be obtained required antioxidant after carrying out decompression precipitation to gained extract liquor.
Preferably, the use supercritical extract or subcritical abstraction extract from algae and obtain algae extracting solution
By algae algae powder, then algae powder to be placed in soak after impregnating, utilizing supercritical extract or subcritical abstraction
Extraction obtains algae extracting solution, and the soak includes vegetable oil and bleeding agent.
Wherein it is preferred to which the algae is Ovshinsky seaweed, Bo Nate spirulinas, fork coral algae, tip edge bladder-wrack, thorn
It is Song Zao, compatibile, light black huge seaweed, blunt sargassum, powder ball fan algae, powder ball fan algae, floating chlorella, starfish branch tube algae, red
Ye Zao, Rhodophyta algae, spirulina maxim, atomic chlorella, bulk kelp, tool are away from helictite algae, Kong Yezao, Robusta red algae, spiral
Algae, green alga, wool Marine Red Alga Polysiphonia Urceolata, bladder-wrack, Antarctic Continent clump stalk algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chain algae, worm fork red algae,
Fur pine algae, Phaeodactylum tricornutum, China fir leaf caulerpa, coralline algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, the black top of withe
Algae, chlorella, leaflet seaweed, asterism China fir algae, outstanding wart sargassum, Dunaliella salina, foreign Pseudanabaena sp, haematococcus pluvialis, the long heart
The combination of one or more of Kappa algae, dulse, Skeletonema Costatum, broom shape sea wing algae, purple ball algae.It is optimal,
The algae is haematococcus pluvialis.
The wherein preparation of algae powder can will be crushed, and be sieved to obtain with pulverizer after algae removing impurity.It is preferred that
The powder diameter on ground, the algae powder is 2-150mm, it is preferred that the powder diameter of the algae powder is 10-120mm, it is optimal to be
90mm.Algae powder, which is placed in soak, to impregnate can be specifically, and steeping tank is added in algae powder, injects vegetable oil and bleeding agent.
Preferably, the vegetable oil is sunflower oil, macadimia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado
The combination of one or more of oil, wheat-germ oil, soya-bean oil, camellia oil or shea butter.It can be effectively from algae
In extract antioxidant.It is preferred that the vegetable oil is sunflower oil, macadimia nut oil, one kind in jojoba oil or several
The combination of kind.Optimal to be, the vegetable oil is sunflower oil, and extraction effect is more preferable.
Preferably, the bleeding agent is tocopherol, Olibanum extract, Rosmarinus officinalis extract, Paeonol, food grade chemical conjunction
At the combination of one or more of antioxidant.Antioxidant can be effectively extracted from algae.It is preferred that
The bleeding agent is the combination of one or more of tocopherol, Olibanum extract, chemical synthesis antioxidant.It is optimal to be, institute
It is Olibanum extract to state bleeding agent, and extraction effect is more preferable.
Preferably, the weight ratio of the soak and algae powder is 1-5：1, product can be efficiently extracted.It is preferred that institute
The weight ratio for stating soak and algae powder is 1-4：1, the optimal weight ratio for the soak and algae powder is 3.5：1.
Preferably, the weight ratio of the vegetable oil and bleeding agent is 1-100：1, product can be efficiently extracted.Preferably
It is that the weight ratio of the vegetable oil and bleeding agent is 10-80：1, the optimal weight ratio for the vegetable oil and bleeding agent is 50：
1。
Usually, according to the difference of the performance of raw material itself, soaking temperature differs greatly.In the present invention, it is preferred to
The soaking temperature of the immersion is 35-85 DEG C, and extraction effect is good.It is preferred that the soaking temperature of the immersion is 45-75 DEG C,
Optimal, the soaking temperature of the immersion is 65 DEG C.Preferably, the soaking time of the immersion is 10min-5h, when immersion
Between preferably 20min-3.5h, it is optimal be 3h.
It is as follows using supercritical extract or subcritical abstraction：Unit is extracted using supercritical carbon dioxide,
Extraction temperature is at 30-75 DEG C, and for pressure under 1.5-90 kilograms of pressure, extractant is carbon dioxide, overcritical to the algae powder of immersion
Or sub-critical extraction.Pressure is preferably 5-80 kilograms, most preferably 50 kilograms.Extraction temperature is more preferably 45-75 DEG C, optimal
It is 65 DEG C.
Below for different vegetable oil and the weight ratio of algae powder, different bleeding agents, different extraction temperatures and different algaes
When class, the yield of the antioxidant obtained illustrates.
1, influence of the weight ratio of vegetable oil algae powder to the yield of the antioxidant obtained
Process conditions：Extracting pressure is 50 kilograms, and algae powder diameter is 70mm, and algae is haematococcus pluvialis, and soaking time is 2 small
When, soaking temperature is 75 DEG C, and bleeding agent is chemically synthesized food antioxidant, and the weight ratio of bleeding agent and vegetable oil is 1：
30.It the results are shown in Table 1.
The yield for the antioxidant that table 1 is obtained when being extracted using the weight ratio of different vegetable oil algae powder
| Vegetable oil | The weight ratio of vegetable oil and algae powder | The yield (%) of antioxidant |
| Jojoba oil | 3.5:1 | 5.8 |
| Rose hip oil | 3.5:1 | 0.2 |
| Avocado oil | 3.5:1 | 10.2 |
| Macadimia nut oil | 3.5:1 | 6.4 |
| Sweet Almond Oil | 3.5:1 | 11.7 |
| Shea butter | 3.5:1 | 1.8 |
| Soya-bean oil | 3.5:1 | 9.9 |
| Wheat-germ oil | 3.5:1 | 12.3 |
| Camellia oil | 3.5:1 | 7.9 |
| Sunflower oil | 3.5:1 | 14.8 |
As shown in Table 1, when vegetable oil selects sunflower oil, the yield highest of antioxidant.
2, influence of the bleeding agent to the yield of the antioxidant obtained
Process conditions：The weight ratio of vegetable oil and algae powder is 3：1, vegetable oil is soya-bean oil, and algae powder powder particle diameter is 70mm, leaching
It is 2.5 hours to steep the time, and extracting pressure is 70 kilograms, and extraction temperature is 50 DEG C.It the results are shown in Table 2.
Table 2 uses the yield of the antioxidant obtained when extraction under different bleeding agents
| Bleeding agent | The weight ratio of bleeding agent and vegetable oil | The yield (%) of antioxidant |
| Olibanum extract | 1：4 | 14.2 |
| Rosmarinus officinalis extract | 1：4 | 9.8 |
| Tocopherol | 1：4 | 6.6 |
| Paeonol | 1：40 | 8.8 |
| TT | 1：40 | 6.5 |
| BHA | 1：40 | 7.2 |
| TBHQ | 1：40 | 9.6 |
As shown in Table 2, when bleeding agent selects Olibanum extract, the yield highest of antioxidant.
3, influence of the extraction temperature to the yield of the antioxidant obtained
Process conditions：The weight ratio of vegetable oil and algae powder is 3：1, algae powder powder particle diameter is 70mm, and soaking time is 3 small
When, extracting pressure is 70 kilograms, and bleeding agent is tocopherol, and the weight ratio of bleeding agent and vegetable oil is 1：4.It the results are shown in Table 3.
Table 3 uses the yield of the antioxidant obtained when extraction under different extraction temperatures
| Extraction temperature (DEG C) | The weight ratio of sunflower oil and chlorella raw material | The yield (%) of antioxidant |
| 30 | 3:1 | 3.5 |
| 35 | 3:1 | 4.2 |
| 40 | 3:1 | 7.8 |
| 45 | 3:1 | 9.0 |
| 50 | 3:1 | 11.5 |
| 55 | 3:1 | 11.9 |
| 60 | 3:1 | 13.5 |
| 65 | 3:1 | 14.8 |
| 70 | 3:1 | 13.0 |
| 75 | 3:1 | 9.8 |
| 80 | 3:1 | 7.0 |
| 85 | 3:1 | 6.2 |
As shown in Table 3, when extraction temperature is 45-75 DEG C, the yield of antioxidant is higher, when extraction temperature is 65 DEG C,
The yield highest of antioxidant.
4, influence of the algae to the yield of the antioxidant obtained
Process conditions：Extracting pressure is 50 kilograms, and algae powder diameter is 55mm, and soaking time is 4.5 hours, and soaking temperature is
75 DEG C, bleeding agent is Olibanum extract, and the ratio of bleeding agent and vegetable oil is 1：30.It the results are shown in Table 4.
The yield for the antioxidant that table 4 is obtained when being extracted using different algae classes
As shown in Table 4, algae class is Codiumfragile(sur.) Hariot., compatibile, light black huge seaweed, blunt sargassum, spirulina, Antarctic Continent clump
Obstruct algae, Europe capsule chain algae, worm fork red algae, fur pine algae, Phaeodactylum tricornutum, China fir leaf caulerpa, coralline algae, haematococcus pluvialis, the long heart
When Kappa algae, dulse, purple ball algae, the yield of antioxidant is higher；When algae class is haematococcus pluvialis, antioxidant
Yield highest.
The present invention also provides a kind of antioxidants, i.e., are prepared using the preparation method of above-mentioned antioxidant.To upper
It states made from method antioxidant and carries out GC-MS analyses, antioxidant Linoleic acid content >=30%, linolenic acid content >=
50%, it is more than 20 carbon unsaturated fatty acids 18%, Vitamin C content >=0.02%, tocopherol content >=0.005%, dimension life
Plain A content >=0.0008%, amino acid content >=5%.
The present invention also provides a kind of applications of antioxidant, and above-mentioned antioxidant is used for food, health products or makeup
In product.The antioxidant can be used as food or health products directly edible after refined, or as additive, be added food,
In health products or cosmetics, anti-oxidant and elimination free radical effect is made it have.
The present invention also provides the preparation methods of antioxidant, provide above-mentioned antioxidant, are isolated and purify
To algae extract, the algae extract is dissolved in and can be obtained required antioxidant in grease.The grease is
Sunflower oil, macadimia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado oil, wheat-germ oil, soya-bean oil, camellia oil,
The combination of one or more of shea butter, lard, butter, house oil, snake oil, sheep oil, fish oil.
The present invention also provides a kind of antioxidants, i.e., are prepared into using the preparation method of above-mentioned antioxidant
It arrives.
Some specific embodiments are provided below
One, the preparation of antioxidant
Embodiment 1
Using intermittent means of supercritical extraction tank group, extracted to impregnating algae powder：Using 100 grams of crushing algae powder as raw material, powder
Particle diameter is 20mm, and batch extractor is added, and injects and impregnates 400 grams of sunflower oil, 2 grams, soaking time 3h of bleeding agent Olibanum extract,
75 DEG C of soaking temperature.To the soak in batch extractor after leaching, supercritical extract, gained algae antioxygen mixture are carried out
410.6 grams, decompression precipitation is carried out, obtains 8.6 grams of algae oil mixture, yield 8.6%.Algae powder is asterism China fir algae.
Embodiment 2
Using intermittent means of supercritical extraction tank group, extracted to impregnating algae powder：Using 100 grams of crushing algae powder as raw material, powder
Particle diameter is 90mm, and batch extractor is added, and injects and impregnates 200 grams of camellia caul-fat, 5 grams, soaking time 20min of bleeding agent tocopherol,
30 DEG C of soaking temperature；To the soak in batch extractor after leaching, supercritical extract, gained algae antioxygen mixture are carried out
214.0 grams, decompression precipitation is carried out, obtains 9 grams of algae oil mixture, yield 9%.Algae powder is red autumnal leaves algae.
Embodiment 3
Using intermittent means of supercritical extraction tank group, extracted to impregnating algae powder：Using 100 grams of crushing algae powder as raw material, powder
Particle diameter is 20mm, and batch extractor is added, and 300 grams of macadimia nut oil, 2 grams of bleeding agent synthetized oxidation preventive agent, when immersion are impregnated in injection
Between 3h, 75 DEG C of soaking temperature.To the soak in batch extractor after leaching, supercritical extract is carried out, gained algae antioxygen closes
310.8 grams of agent, carries out decompression precipitation, obtains 8.8 grams of algae oil mixture, yield 8.8%.Algae powder is haematococcus pluvialis.
Embodiment 4
Using intermittent means of supercritical extraction tank group, extracted to impregnating algae powder：Using 100 grams of crushing algae powder as raw material, powder
Particle diameter is 50mm, and batch extractor is added, and injects and impregnates 200 grams of camellia caul-fat, 5 grams, soaking time 120min of bleeding agent Paeonol,
76 DEG C of soaking temperature；To the soak in batch extractor after leaching, supercritical extract, gained algae antioxygen mixture are carried out
214.0 grams, decompression precipitation is carried out, obtains 9 grams of algae oil mixture, yield 9%.Algae powder is Ovshinsky seaweed.
Embodiment 5-39
Technique is to use intermittent means of supercritical extraction tank group, to impregnating the extraction of algae powder：Using 100 grams of crushing algae powder as raw material,
Powder particle diameter is 20mm, and batch extractor is added, and 400 grams of sunflower oil is impregnated in injection, and pressure is 50 public used by the extracting method
Jin, algae powder diameter are 55mm, and soaking time is 4.5 hours, and soaking temperature is 75 DEG C, and bleeding agent is Olibanum extract, bleeding agent
Ratio with vegetable oil is 1：30.
That difference lies in algae classes is different by embodiment 5-39, algae used be respectively Bo Nate spirulinas, fork coral algae,
Tip edge bladder-wrack, Codiumfragile(sur.) Hariot., compatibile, light black huge seaweed, blunt sargassum, powder ball fan algae, powder ball fan algae, floating chlorella,
Starfish branch tube algae, Rhodophyta algae, spirulina maxim, atomic chlorella, bulk kelp, tool are red away from helictite algae, Kong Yezao, Robusta
Algae, spirulina, green alga, wool Marine Red Alga Polysiphonia Urceolata, bladder-wrack, Antarctic Continent clump stalk algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chains algae, worm
Pitch red algae, fur pine algae, Phaeodactylum tricornutum, China fir leaf caulerpa, coralline algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, thin
The black top algae of branch, chlorella, leaflet seaweed, asterism China fir algae, outstanding wart sargassum, Dunaliella salina, foreign Pseudanabaena sp, kappaphycus
Algae, dulse, Skeletonema Costatum, broom shape sea wing algae, purple ball algae.Gained yield (unit %) is specifically shown in Table 4, herein no longer
It repeats.
Two, the Study of Antioxidation of antioxidant
Embodiment 40-55
Antioxidant obtained by embodiment 1-39 is mixed, 0.2 gram of mixed composite antioxidant, grease 99.8 are taken
Gram.Grease is respectively sunflower oil, macadimia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado oil, wheat embryo
Oil, soya-bean oil, camellia oil, shea butter, lard, butter, house oil, snake oil, sheep oil, fish oil.Oxidation of Fat and Oils is led in oil recovery Switzerland ten thousand
Anti-oxidant stabilization time when the test of steady testing instrument plus composite antioxidant are with 110 DEG C that are not added with composite antioxidant：
Table 5 is not added with composite antioxidant and adds the anti-oxidant stabilization time of each grease of composite antioxidant
Embodiment 56-78
Unialgal antioxidant and the research of the antioxidant antioxygenic property of compound algae, experimental method is the same as embodiment 40-
55。
Single algae is haematococcus pluvialis, floating chlorella, red autumnal leaves algae, Rhodophyta algae, spirulina, chlorella.It must implement
Example 56-61.
Compound algae is Ovshinsky seaweed, Bo Nate spirulinas, fork coral algae, tip edge bladder-wrack, Codiumfragile(sur.) Hariot., compatibile, light
Black huge seaweed, blunt sargassum, powder ball fan algae, powder ball fan algae, floating chlorella, starfish branch tube algae, red autumnal leaves algae, Rhodophyta algae, pole
Spirulina major, atomic chlorella, bulk kelp, tool are away from helictite algae, Kong Yezao, Robusta red algae, spirulina, green alga, wool multitube
Algae, bladder-wrack, Antarctic Continent clump stalk algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chains algae, worm fork red algae, fur pine algae, phaeodactylum tricornutum
Refer to algae, China fir leaf caulerpa, coralline algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, the black top algae of withe, chlorella, leaflet sea
Algae, asterism China fir algae, outstanding wart sargassum, Dunaliella salina, foreign Pseudanabaena sp, haematococcus pluvialis, kappaphycus alvarezi, the red skin of palmate
3-5 kind algae oil mixture compounding is randomly selected in algae, Skeletonema Costatum, broom shape sea wing algae, purple ball algae, obtains embodiment 62-78.
All antioxidant additive amounts are 0.2 gram, and grease is 99.8 grams, and grease is rose hip oil.
Table 6 adds the anti-oxidant stabilization time of unialgal antioxidant and the antioxidant of compound algae
Three, the preparation of antioxidant and antioxygenic property research
Embodiment 79-94
By antioxidant obtained by embodiment 1-39, algae extract is obtained after separating-purifying respectively and is mixed to get compound anti-
Oxidation additive takes 2 grams of mixed compound anti-oxidation additive, 98 grams of grease to obtain antioxidant after mixing.Grease
Respectively sunflower oil, macadimia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado oil, wheat-germ oil, soya-bean oil,
Camellia oil, shea butter, lard, butter, house oil, snake oil, sheep oil, fish oil.Oxidation of Fat and Oils steady testing is led to using Switzerland ten thousand
Anti-oxidant stabilization time when instrument test plus antioxidant are with 110 DEG C that are not added with antioxidant：
Table 7 is not added with compound anti-oxidation additive and adds the anti-oxidant stabilization time of each grease of compound anti-oxidation additive
Embodiment 95-117
By antioxidant obtained by embodiment 56-78, algae extract is obtained after separating-purifying respectively, takes algae extract
0.2 gram, grease is 99.8 grams, and grease is rose hip oil.Namely embodiment 95-100 is unialgal antioxidant, single
Algae is respectively haematococcus pluvialis, floating chlorella, red autumnal leaves algae, Rhodophyta algae, spirulina, chlorella.Embodiment 101-117 is
Compound algae antioxidant, compound algae are Ovshinsky seaweed, Bo Nate spirulinas, fork coral algae, tip edge bladder-wrack, Juniperus formosana
Algae, compatibile, light black huge seaweed, blunt sargassum, powder ball fan algae, powder ball fan algae, floating chlorella, starfish branch tube algae, red autumnal leaves
Algae, Rhodophyta algae, spirulina maxim, atomic chlorella, bulk kelp, tool away from helictite algae, Kong Yezao, Robusta red algae, spirulina,
It is green alga, wool Marine Red Alga Polysiphonia Urceolata, bladder-wrack, Antarctic Continent clump stalk algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chain algae, worm fork red algae, soft
Mao Songzao, Phaeodactylum tricornutum, China fir leaf caulerpa, coralline algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, the black top algae of withe,
Chlorella, leaflet seaweed, asterism China fir algae, outstanding wart sargassum, Dunaliella salina, foreign Pseudanabaena sp, haematococcus pluvialis, kappaphycus
3-5 kind algae oil mixture compounding is randomly selected in algae, dulse, Skeletonema Costatum, broom shape sea wing algae, purple ball algae.It is anti-oxidant
Stabilization time the results are shown in Table 8.
Table 8 adds the anti-oxidant stabilization time of unialgal antioxidant and the antioxidant of compound algae
Four, application of the antioxidant in cosmetics
Embodiment 118-133
In conventional cosmetic formula, content of vegetable oil 0.5-100%, antioxidant 0.05%, use is auspicious
It is anti-oxidant when the test of Shi Wantong Oxidation of Fat and Oils steady testing instrument plus antioxidant are with 110 DEG C that are not added with antioxidant
Stabilization time, wherein embodiment 128-133 are composite plant oil, and vegetable oil used, which is cosmetics, allows the vegetable oil used, multiple
It it is 40 grams with the simple fat content of ratio random distribution, compound grease is 100 grams.Anti-oxidant stabilization time the results are shown in Table 9.
Table 9 is not added with antioxidant and adds the anti-oxidant stabilization time of antioxidant
Claims (10)
1. a kind of preparation method of antioxidant, it is characterised in that：Using supercritical extract or subcritical abstraction from algae
Middle extraction obtains extract liquor, can be obtained required antioxidant after carrying out decompression precipitation to gained extract liquor.
2. the preparation method of antioxidant as described in claim 1, it is characterised in that：Described uses supercritical extract or Asia
It is, by algae algae powder, algae powder to be then placed in soak that critical extraction, which extracts from algae and obtains extract liquor,
After middle immersion, extract to obtain extract liquor using supercritical extract or subcritical abstraction, the soak includes vegetable oil and infiltration
Agent.
3. the preparation method of antioxidant as claimed in claim 2, it is characterised in that：The powder diameter of the algae powder is 2-
The soaking time of 150mm, the immersion are 10min-5h, and soaking temperature is 35-85 DEG C.
4. the preparation method of antioxidant as claimed in claim 2, it is characterised in that：The weight ratio of the soak and algae powder
For 1-5：1；The weight ratio of the vegetable oil and bleeding agent is 1-100：1.
5. the preparation method of antioxidant as claimed in claim 2, it is characterised in that：The vegetable oil is sunflower oil, Australia
In macadamia nut oil, jojoba oil, rose hip oil, Sweet Almond Oil, avocado oil, wheat-germ oil, soya-bean oil, camellia oil or shea butter
One or more of combinations；
The bleeding agent is tocopherol, Olibanum extract, Rosmarinus officinalis extract, Paeonol, food grade chemical synthetized oxidation preventive agent
One or more of combination.
6. the preparation method of the antioxidant as described in claim any one of 1-5, it is characterised in that：The algae is
Ovshinsky seaweed, Bo Nate spirulinas, fork coral algae, tip edge bladder-wrack, Codiumfragile(sur.) Hariot., compatibile, light black huge seaweed, blunt sargassum,
Powder ball fans algae, powder ball fan algae, floating chlorella, starfish branch tube algae, red autumnal leaves algae, Rhodophyta algae, spirulina maxim, atomic bead
Algae, bulk kelp, tool are away from helictite algae, Kong Yezao, Robusta red algae, spirulina, green alga, wool Marine Red Alga Polysiphonia Urceolata, bladder-wrack, Antarctic Continent clump
Obstruct algae, Europe capsule chain algae, yellow tang, Chinese mosla sprout capsule chains algae, worm fork red algae, fur pine algae, Phaeodactylum tricornutum, China fir leaf caulerpa, coral
Algae, the extra large algae of elongation, Sargassum fulvellum, Euglena gracilis, the black top algae of withe, chlorella, leaflet seaweed, asterism China fir algae, outstanding wart horse
Tail algae, Dunaliella salina, foreign Pseudanabaena sp, haematococcus pluvialis, kappaphycus alvarezi, dulse, Skeletonema Costatum, broom shape sea
The combination of one or more of wing algae, purple ball algae.
7. a kind of antioxidant, it is characterised in that：It is prepared using the preparation method of antioxidant described in claim 1.
8. a kind of application of antioxidant, it is characterised in that：By the antioxidant described in claim 7 for food, health products
Or in cosmetics.
9. a kind of preparation method of antioxidant, it is characterised in that：Antioxidant as claimed in claim 7 is provided, it will
Its separating-purifying obtains algae extract, and the algae extract is dissolved in and can be obtained required anti-oxidant addition in grease
Agent.
10. a kind of antioxidant, it is characterised in that：It is prepared using the preparation method of antioxidant described in claim 9
It obtains.
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| CN111214846A (en) * | 2019-11-29 | 2020-06-02 | 云南绿A生物产业园有限公司 | Haematococcus pluvialis extract and preparation method thereof |
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| CN111518615A (en) * | 2020-04-28 | 2020-08-11 | 武汉轻工大学 | Method for preparing shea butter by adopting subcritical propane extraction technology, shea butter and application |
| CN113350235A (en) * | 2021-06-22 | 2021-09-07 | 科丝美诗(中国)化妆品有限公司 | Lip care composition and preparation and application of cosmetics thereof |
| CN115251380A (en) * | 2021-04-30 | 2022-11-01 | 上海其然生物科技有限公司 | Method for preparing antioxidant from arbor tissue by adopting alcohol soaking method and application |
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Address after: 518000, room five, floor 192, 501 Chongqing Road, Heping community, Fuyong street, Baoan District, Guangdong, Shenzhen Patentee after: Shenzhen Xiandi Cosmetics Co., Ltd Address before: 518000, room five, floor 192, 501 Chongqing Road, Heping community, Fuyong street, Baoan District, Guangdong, Shenzhen Patentee before: SHENZHEN SANDA COSMETICS Co.,Ltd. |