CN105671955A - Fabric antioxidant with seaweed extract and method for preparing fabric antioxidant - Google Patents

Fabric antioxidant with seaweed extract and method for preparing fabric antioxidant Download PDF

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Publication number
CN105671955A
CN105671955A CN201610038514.5A CN201610038514A CN105671955A CN 105671955 A CN105671955 A CN 105671955A CN 201610038514 A CN201610038514 A CN 201610038514A CN 105671955 A CN105671955 A CN 105671955A
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chlorella
fabric
extract
antioxidant
seaweed extract
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CN201610038514.5A
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周继东
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Suzhou Insilk Digital Textile Science and Technology Co Ltd
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Suzhou Insilk Digital Textile Science and Technology Co Ltd
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Priority to CN201610038514.5A priority Critical patent/CN105671955A/en
Publication of CN105671955A publication Critical patent/CN105671955A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67358—Halides or oxyhalides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a fabric antioxidant with seaweed extract and a method for preparing the fabric antioxidant.The method includes particular operation steps of (1), washing attachments and sand on the surfaces of chlorella by the aid of filtered seawater, drying the chlorella in the sun at the room temperature, drying the chlorella in a drying oven to remove redundant water and cutting and grinding the chlorella to obtain chlorella powder; (2), carrying out reflux extraction on the chlorella powder prepared at the step (1) in methanol-chloroform mixed solvents twice, combining filter liquid and evaporating the filter liquid to obtain chlorella extract cream; (3), extracting the chlorella extract cream prepared at the step (2) in a supercritical carbon dioxide extraction device to obtain chlorella extract; (4), adding auxiliaries into the chlorella extract prepared at the step (3), heating and uniformly stirring the auxiliaries and the chlorella extract to obtain a mixture, rinsing and filtering the mixture and naturally cooling the mixture until the temperature of the mixture reaches the room temperature so as to obtain the fabric antioxidant with the seaweed extract.The fabric antioxidant and the method have the advantages that the fabric antioxidant with the seaweed extract is extremely high in antioxidant activity, side effects rarely can be realized, and the service range of seaweed can be expanded.

Description

A kind of fabric antioxidant containing Seaweed Extract and its preparation method
Technical field:
The invention belongs to textile materials technical field, it is specifically related to a kind of fabric antioxidant containing Seaweed Extract and its preparation method.
Background technology:
Ultraviolet is the short hertzian wave of a kind of wavelength ratio visible ray, and the ultraviolet of different wave length is also different to the hazard rating of human body, all can be subject to ultraviolet infringement in people's daily life and industrial production in various degree. At present, at field of textiles, the application of antioxidant in the Final finishing and daily nursing of fabric is comparatively general. In the postfinishing process of fabric, in order to make the door width of fabric, gram weight and planeness reach the requirement of finished product, need to be formalized by fabric under the high temperature conditions, and too high setting temperature is to causing that the fiber in fabric is oxidized and yellowing is brittle, then the quality of finished product is affected, at natural dyestuff instantly more and more widely, especially the use of anti ultraviolet agent seems indispensable.
Antioxidant be can play prolong stagnant because being oxidized strong-willed deterioration, become sour or the material of variable color, many use chemosynthesis antioxidants both at home and abroad, such as butylated hydroxytoluene, butylated hydroxy anisole, Tenox PG and tertiarybutylhydroquinone etc., goods can be mended and neutralize free radical, thus dispel the infringement of radical pair material, or can effectively stop or delay the autoxidation process of material, but the antioxidant of these chemosynthesis has certain toxicity and carcinogenesis, it is that synthetized oxidation preventive agent is produced doubt and repels psychology by people.
Natural antioxidants safety non-toxic, meets people to healthy and safe demand. All in nature chain being disturbed in radical chain reaction to cause and propagation process, the compound removing ROS all becomes natural antioxidants. The kind of natural antioxidants is more, water soluble antioxidant and fat-soluble antioxidant it is divided into according to solubility, water soluble antioxidant has vitamins C, gsh, Benzazole compounds, uric acid and catechol etc., and fat-soluble antioxidant has vitamin-E, β-carotene, biological flavone compounds etc.These natural antioxidantss all have application in food, medical treatment, weaving etc.
Marine alga is pure marine plant, it is rich in hydrophilic protein, polysaccharide, foodstuff fibre, vitamin B12, vitamins C and E, vitamin H, niacin agent, inorganic elements and amino acid and lipid acid etc., therefore the resistance of oxidation of marine alga is strong, and the lipid algal oil of extraction from pure natural seaweeds is also rich in linolenic acid, arachidonic acid, timnodonic acid, docosahexenoic acid etc., resisting the ability of autoxidation, resistance of oxidation is strong. A kind of disclosed in Chinese patent CN102877299B (publication date 2013.1.6) suppress the application of composite dose of superoxide-dismutase/trehalose on yarn fabric for yarn fabric ashing reaction; the removing that SOD/ trehalose is mainly used for ashing yarn fabric free radical, reaches the original state of the protection textiles historical relic of nontoxic pollution-free. By above-mentioned prior art it will be seen that the extract of marine alga is used for textiles can play anti-oxidant effect.
Summary of the invention:
The technical problem to be solved in the present invention is to provide a kind of fabric antioxidant containing Seaweed Extract and its preparation method, using chlorella as raw material, combine through chemical extraction and supercritical extraction, obtain extraction yield height, the chlorella extract that content is abundant, again by adding other auxiliary agents, obtain the fabric antioxidant containing Seaweed Extract.
For solving the problems of the technologies described above, the technical scheme of the present invention is:
A kind of fabric antioxidant containing Seaweed Extract, it is characterized in that, main component in the described fabric antioxidant containing Seaweed Extract is chlorella extract, and described chlorella extract contains Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins.
Preferably, the component of the described fabric antioxidant containing Seaweed Extract, by weight, comprising: chlorella extract 25-60 part, auxiliary agent 10-30 part.
The present invention also provides the preparation method of a kind of fabric antioxidant containing Seaweed Extract, it is characterised in that: comprise the following steps:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in baking oven and dry the unnecessary moisture of removal, remove and shred grinding formation chlorella powder;
(2) chlorella powder prepared by step (1) is placed in methyl alcohol chloroform mixed solvent, reflux extraction 2 times, merging filtrate, filtrate evaporation is formed chlorella medicinal extract;
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, extraction obtains chlorella extract;
(4) adding auxiliary agent in chlorella extract step (3) prepared, heated and stirred is even, and rinsing is filtered, and naturally cools to room temperature, obtains the fabric antioxidant containing Seaweed Extract.
Preferred as technique scheme, in described step (1), the temperature of oven dry is 60-70 DEG C.
Preferred as technique scheme, in described step (1), the fineness of chlorella powder is 100-150 order.
Preferred as technique scheme, in described step (2), the mass ratio of chlorella powder and methyl alcohol chloroform mixed solvent is 1:5-10.
Preferred as technique scheme, in described step (2), in methyl alcohol chloroform mixed solvent, the volume ratio of methyl alcohol and chloroform is 1:0.5-2.
Preferred as technique scheme, in described step (3), the processing condition of extraction are: temperature 35-45 DEG C, pressure 30-50MPa, extraction time 3-4h.
Preferred as technique scheme, in described step (3), main containing Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins in chlorella extract.
Preferred as technique scheme, in described step (4), containing calcium chloride, citric acid and deionized water in auxiliary agent.
Compared with prior art, the present invention has following useful effect:
(1) main component in the fabric antioxidant containing Seaweed Extract that prepared by the present invention is chlorella extract, wherein chlorella extract contains Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins, these materials all also have very strong anti-oxidant activity, and possess that active function is strong, feature that complex structure, side effect are low, can give yarn fabric good antioxidant property.
(2) main component in the fabric antioxidant containing Seaweed Extract that prepared by the present invention is chlorella extract, has widened the range of application of marine organisms, it is to increase the economic benefit of marine alga crop.
(3) main component in the fabric antioxidant containing Seaweed Extract that prepared by the present invention is chlorella extract, compared with the antioxidant of traditional chemical reagent synthesis, nontoxic pollution-free, to environment no pressure, and compare than the natural antioxidants used at present, oxidation-resistance is strong, good stability, antioxidant working mechanism is complicated, not easily loses efficacy.
(4) the fabric antioxidant containing Seaweed Extract that prepared by the present invention can act on fabric face, the free radical of fabric face can be removed, the free radical that will be formed by fabric face or formed reverses as original biomacromolecule, and high-efficiency antioxidant, effective acting time is long.
(5) the fabric antioxidant containing Seaweed Extract that prepared by the present invention may be used for the setting process of textile technology, anti-oxidant arrangement, it is also possible to is added in dyestuff, increases the antioxidant property of dyestuff.
Embodiment:
Below in conjunction with specific embodiment, the present invention being described in detail, illustrative examples and explanation in this present invention are used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 60 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 100 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 5 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:0.5, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 35 DEG C and 30MPa, extraction 3h obtains chlorella extract.
(4) by weight, adding the deionized water of the calcium chloride of 3 parts, the citric acid of 3 parts and 4 parts in the chlorella extract steps of 25 parts (3) prepared, heated and stirred is even, and rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
Embodiment 2:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 70 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 150 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 10 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:2, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 45 DEG C and 50MPa, extraction 4h obtains chlorella extract.
(4) by weight, are added in the chlorella extract that the steps of 60 parts (3) are prepared the deionized water of the calcium chloride of 10 parts, the citric acid of 10 parts and 10 parts, heated and stirred is even, rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
Embodiment 3:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 65 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 120 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 8 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:1, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 40 DEG C and 40MPa, extraction 3.5h obtains chlorella extract.
(4) by weight, adding the deionized water of the calcium chloride of 15 parts, the citric acid of 5 parts and 2 parts in the chlorella extract steps of 40 parts (3) prepared, heated and stirred is even, and rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
Embodiment 4:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 70 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 100 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 6 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:1.2, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 35 DEG C and 35MPa, extraction 3.5h obtains chlorella extract.
(4) by weight, adding the deionized water of the calcium chloride of 10 parts, the citric acid of 10 parts and 5 parts in the chlorella extract steps of 50 parts (3) prepared, heated and stirred is even, and rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
Embodiment 5:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 60 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 150 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 8 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:2, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 45 DEG C and 45MPa, extraction 3h obtains chlorella extract.
(4) by weight, adding the deionized water of the calcium chloride of 12 parts, the citric acid of 7 parts and 10 parts in the chlorella extract steps of 35 parts (3) prepared, heated and stirred is even, and rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
Embodiment 6:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in 65 DEG C of baking ovens and dry the unnecessary moisture of removal, remove and shred grinding formation 130 object chlorella powders.
(2) by weight, the methyl alcohol chloroform mixed solvent that chlorella powder prepared by the step of 1 part (1) is placed in 5 parts, wherein the volume ratio of methyl alcohol and chloroform is 1:0.5, reflux extraction 2 times, merging filtrate, forms chlorella medicinal extract by filtrate evaporation.
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, when 45 DEG C and 45MPa, extraction 3.5h obtains chlorella extract.
(4) by weight, adding the deionized water of the calcium chloride of 7 parts, the citric acid of 10 parts and 10 parts in the chlorella extract steps of 45 parts (3) prepared, heated and stirred is even, and rinsing is filtered, naturally cool to room temperature, obtain the fabric antioxidant containing Seaweed Extract.
After testing, in the chlorella extract that prepared by embodiment 1-6, the degree (%) of Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins is as shown in the table:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Sargassum polysaccharides 12.4 16.1 13.0 12.9 13.7 15.7
Polyphenol 8.16 9.07 8.34 8.59 8.74 8.61
Superoxide-dismutase 10.4 12.7 11.6 10.9 11.5 12.0
Unsaturated fatty acids 8.4 10.6 9.2 10.1 8.7 9.6
Ox acid 5.2 7.9 6.2 5.9 7.2 6.5
Vitamins 3.1 6.2 5.0 4.9 5.3 6.1
After testing, the result containing the antioxidant property of the fabric antioxidant of Seaweed Extract that prepared by embodiment 1-6 is as follows:
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Free radical scavenging activity (%) 77.9 83.6 80.9 79.2 75.4 80.7
Inhibiting rate (%) 29.5 40.1 38.2 36.8 35.1 30.4
As seen from the above table, the antioxidant component in the fabric antioxidant containing Seaweed Extract prepared by the present invention is many, and antioxidant property is excellent.
Above-described embodiment is the principle of illustrative the present invention and effect thereof only, but not for limiting the present invention. Above-described embodiment all under the spirit not running counter to the present invention and category, can be modified or change by any person skilled in the art scholar. Therefore, in art, tool usually intellectual, not departing under disclosed spirit and technological thought all the equivalence modifications completed or change, must be contained by the claim of the present invention such as.

Claims (10)

1. the fabric antioxidant containing Seaweed Extract, it is characterized in that, main component in the described fabric antioxidant containing Seaweed Extract is chlorella extract, and described chlorella extract contains Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins.
2. a kind of fabric antioxidant containing Seaweed Extract according to claim 1, it is characterised in that, the component of the described fabric antioxidant containing Seaweed Extract, by weight, comprising: chlorella extract 25-60 part, auxiliary agent 10-30 part.
3. the preparation method containing the fabric antioxidant of Seaweed Extract, it is characterised in that: comprise the following steps:
(1) seawater that chlorella is filtered is cleaned surperficial dirt settling and the grains of sand, at room temperature dry, be placed in baking oven and dry the unnecessary moisture of removal, remove and shred grinding formation chlorella powder;
(2) chlorella powder prepared by step (1) is placed in methyl alcohol chloroform mixed solvent, reflux extraction 2 times, merging filtrate, filtrate evaporation is formed chlorella medicinal extract;
(3) chlorella medicinal extract prepared by step (2) being placed in supercritical carbon dioxide extraction apparatus, extraction obtains chlorella extract;
(4) adding auxiliary agent in chlorella extract step (3) prepared, heated and stirred is even, and rinsing is filtered, and naturally cools to room temperature, obtains the fabric antioxidant containing Seaweed Extract.
4. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (1), the temperature of oven dry is 60-70 DEG C.
5. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (1), the fineness of chlorella powder is 100-150 order.
6. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (2), the mass ratio of chlorella powder and methyl alcohol chloroform mixed solvent is 1:5-10.
7. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (2), in methyl alcohol chloroform mixed solvent, the volume ratio of methyl alcohol and chloroform is 1:0.5-2.
8. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (3), the processing condition of extraction are: temperature 35-45 DEG C, pressure 30-50MPa, extraction time 3-4h.
9. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterized in that: in described step (3), main containing Sargassum polysaccharides, polyphenol, superoxide-dismutase, unsaturated fatty acids, ox acid, vitamins in chlorella extract.
10. the preparation method of a kind of fabric antioxidant containing Seaweed Extract according to claim 3, it is characterised in that: in described step (4), containing calcium chloride, citric acid and deionized water in auxiliary agent.
CN201610038514.5A 2016-01-21 2016-01-21 Fabric antioxidant with seaweed extract and method for preparing fabric antioxidant Pending CN105671955A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108642911A (en) * 2018-03-27 2018-10-12 武汉纺织大学 Improve the ecological antioxidant of natural dye dying fibre photooxidation resistant performance
CN108635324A (en) * 2018-05-14 2018-10-12 深圳市仙迪化妆品有限公司 Antioxidant and the preparation method and application thereof, antioxidant and preparation method thereof
CN110575680A (en) * 2019-09-19 2019-12-17 福建启元堂生物技术有限公司 Method for double super-extraction of marine nutrients
CN112281514A (en) * 2020-09-25 2021-01-29 嘉兴景和环保科技有限公司 Method for dyeing chemical fiber textile fabric by using complex enzyme
CN114657768A (en) * 2022-03-25 2022-06-24 杭州永前布业有限公司 Preparation process of anti-ultraviolet bag fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1559647A (en) * 2004-03-11 2005-01-05 南京农业大学 Preparation method of seaweed antioxidation active component
CN102877299A (en) * 2012-10-22 2013-01-16 中国科学技术大学 Application of superoxide dismutase and trehalose mixture for textile ashing reaction inhibitor to textiles
KR20130010571A (en) * 2011-07-19 2013-01-29 (주)월드코스텍 Method for adhering powder of chamaecyparis obtusa and pad adhered powder of chamaecyparis obtusa using thereof
CN102976992A (en) * 2012-12-14 2013-03-20 国家海洋局第三海洋研究所 Method for extracting lutein from chlorella

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1559647A (en) * 2004-03-11 2005-01-05 南京农业大学 Preparation method of seaweed antioxidation active component
KR20130010571A (en) * 2011-07-19 2013-01-29 (주)월드코스텍 Method for adhering powder of chamaecyparis obtusa and pad adhered powder of chamaecyparis obtusa using thereof
CN102877299A (en) * 2012-10-22 2013-01-16 中国科学技术大学 Application of superoxide dismutase and trehalose mixture for textile ashing reaction inhibitor to textiles
CN102976992A (en) * 2012-12-14 2013-03-20 国家海洋局第三海洋研究所 Method for extracting lutein from chlorella

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108642911A (en) * 2018-03-27 2018-10-12 武汉纺织大学 Improve the ecological antioxidant of natural dye dying fibre photooxidation resistant performance
CN108635324A (en) * 2018-05-14 2018-10-12 深圳市仙迪化妆品有限公司 Antioxidant and the preparation method and application thereof, antioxidant and preparation method thereof
CN110575680A (en) * 2019-09-19 2019-12-17 福建启元堂生物技术有限公司 Method for double super-extraction of marine nutrients
CN112281514A (en) * 2020-09-25 2021-01-29 嘉兴景和环保科技有限公司 Method for dyeing chemical fiber textile fabric by using complex enzyme
CN114657768A (en) * 2022-03-25 2022-06-24 杭州永前布业有限公司 Preparation process of anti-ultraviolet bag fabric

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