CN108587644A - A kind of Acid Paddy Soils modifying agent - Google Patents

A kind of Acid Paddy Soils modifying agent Download PDF

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Publication number
CN108587644A
CN108587644A CN201810732507.4A CN201810732507A CN108587644A CN 108587644 A CN108587644 A CN 108587644A CN 201810732507 A CN201810732507 A CN 201810732507A CN 108587644 A CN108587644 A CN 108587644A
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China
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parts
soil
modifying agent
acid
paddy soils
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乔保建
夏祥华
任代胜
付锡江
陶元平
彭冲
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Anhui Yuan Liang Rice Industry Co Ltd
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Anhui Yuan Liang Rice Industry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of Acid Paddy Soils modifying agents, the formula of the medicament is by a certain proportion of biomass black wood charcoal, dolomite, sepiolite, lime stone, zeolite, vermiculite, bentonite, flyash, polyacrylamide, bush mycorrhizal fungi preparation, the decomposed object of pig manure, super absorbent resin composition.The present invention can improve Acid Paddy Soils, improve soil pH value, increase soil texture stability, reduce the dissolution of heavy metal-polluted soil, promote Nutrient Elements in Soil content, facilitation is played to the growth and volume increase of rice, lays the first stone, has broad application prospects for the southern Acid Paddy Soils of extensive improvement.

Description

A kind of Acid Paddy Soils modifying agent
Technical field
The present invention relates to technical field of agriculture science, more particularly to a kind of Acid Paddy Soils modifying agent.
Background technology
Soil acidification refers to that soil receives to input H therein+Afterwards, one side H+With the slag cation on soil colloid Occur exchange reaction to and be attracted to grogs surface, the slag cation to be got off by exchange and then with percolating water leaching loss; On the other hand, the aluminium that the H+ on grogs surface can be spontaneously with mineral lattice surface reacts, and is quickly converted to exchangeable aluminum.By It is an importance in soil weathering soil-forming process in soil acidification, it will lead to pH decreased, form acid soil After earth, influence activity biological in soil, change the form of nutrient in soil, reduce nutrient availability, promote free manganese, The poisoning metal elements such as aluminium ion dissolve in the soil liquid, to generate toxic action to crop.
The reason of soil acidification usually promising natural cause and artificial origin, the soil acidification process of natural cause it is very slow Slowly, the pH for reducing by 1 unit at least wanted for 50100 years under field conditions (factors).Result of study show mainly to have two it is big it is artificial because Element accelerates soil acidification, and one is acid deposition caused by atmosphere pollution, another is then whole system caused by agricultural production Imbalance.For in worldwide, industrial pollution has significantly speeded up the process of soil acidification, and especially acid deposition is led The environmental acidification of cause, the three big Acid Rain Zones of North America, northwest Europe and China as most serious in the world, the acidification of these Soils In The Regions become Gesture is fairly obvious.And all there is acid soil in worldwide, be primarily present in acid soil as a type in soil In tropical and subtropical region and Temperate Region in China, the subtropical and tropical zones in China, widely distributed various red or yellow Acid soil, the acid soil of Temperate Region in China is mainly distributed on Northern Europe, North America, based on acid podzolic soil.In recent decades, China's rapid industrial development, a large amount of sour gas are discharged into air, and acid deposition makes environment by immense pressure, causes China southern The frequency and intensity of the acid deposition in side area all obviously increase.Europe and North America are always two big Acid Rain Zones in the world, China Southern red-yellow soil area becomes the 3rd big Acid Rain Zone of the world behind this two big Acid Rain Zone, currently, on the south China the Changjiang river extensively Ground is dispersed with the acid soil of large area, is concentrated mainly on Zhejiang, Fujian, Jiangxi, Guangdong, Yunnan, Guangxi, Hainan and Guizhou etc. Southern province, about 200,000,000 hm of the gross area2, the pH value of most of acid soil is less than 5.5, wherein being greatly less than 5.0, very To lower, with the further development of Chinese society economy, China's acid soil area and acidizing degree, which also have, to be further increased Trend.
China the Changjiang river areas to the south is also important Rice Cropping region, and the soil of high-yield rice is mostly subacidity to neutrality (pH value 6.0~7.0), soil of the pH value less than 5.5 may make rice plant growth's depauperation, lead to the underproduction even total crop failure, So influence of the soil acidification to Rice Cropping is also increasing.
For a long time due to intrinsic ideal effect, scientists pay close attention to the influence of Acid Rain on Soil mostly, and new hair Now but expose a serious defect using nitrogen fertilizer:It makes the acidity of soil dramatically increase, and this can be in length The ability of their support life is reduced after time.From the research of the Farmland in China changes of pH to the past over more than 20 years It was found that different degrees of acidification phenomenon occurs for up to 90% or so agricultural land soil, soil pH value averagely declines about 0.5 list Position, is equivalent to soil acid amount and increases 2.2 times on the original basis.And the pH value of soil is most important to plant growth, because Most of crops all adapt to grow in neutral or slightly sour soil, once pH decreased (acidity enhancing), caused Pest and disease damage will hinder the growth of plant, and strong acid environment can also activate the activity of toxic metals, accelerate filtering out for toxic metals.
These situations show that China is needing further to be reinforced to the research of acid soil, especially for acidified Soil, need to take effective measures improvement and improvement.An importance direct shadow of the soil acidification as soil degradation It rings and arrives soil quality.In recent years, the various unreasonable mankind's activities such as acid rain depositions are continuously increased, ammonium fertilizer largely uses are led Soil acidification aggravation, arable land acid soil area is caused to show a rising trend.The acidification of soil directly affects physics, the chemistry of soil And biological property, not only cause Soil Mineral Nutrition element to be largely lost, nutrient active reduces, soil microbial activities are suppressed The harm such as system, toxic heavy metal activation, and soil and water ecological setting are endangered, seriously constrain the sustainable of agricultural Development.Therefore, effective acid soil improving agent is studied, soil quality is improved, there is important meaning for agricultural sustainable development Justice.
Invention content
The technical problems to be solved by the invention:Mineral nutrient element caused by being acidified for current paddy soil is a large amount of It is lost in, nutrient active reduces, soil microbial activities are suppressed, toxic heavy metal activates and endanger soil and water ecological setting The problem of, the present invention, which can play, is obviously improved soil pH value, improves soil nutrient, reduces heavy metal in soil content, and activation is micro- The soil improvement action of biology.
In order to solve the above technical problems, the present invention provides technical solution below:
The present invention provides a kind of Acid Paddy Soils modifying agent, includes the component of following parts by weight:Biomass black wood charcoal, white clouds Stone, sepiolite, lime stone, zeolite, vermiculite, bentonite, flyash, polyacrylamide, bush mycorrhizal fungi preparation, pig manure are decomposed Object, super absorbent resin.
Preferably, a kind of Acid Paddy Soils modifying agent, includes the component of following parts by weight:Biomass black wood charcoal, dolomite, sea The decomposed object of afrodite, lime stone, zeolite, vermiculite, bentonite, flyash, polyacrylamide, bush mycorrhizal fungi preparation, pig manure, height Water-absorbing resins.
Preferably, the bush mycorrhizal fungi preparation includes Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould At least one of, preparation method is as follows:
(1) substrate preparation:By careless carbon:Vermiculite:Perlite:Zeolite (volume ratio) is 1:1:2:1 ratio mixing, high pressure are steamed Vapour sterilizing is spare;
(2) will contain respectively Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould three kinds of mycorrhizal fungal spores, Mycelial Inoculant first mixes, and spore density >=25 of each strain/gram, the Inoculant being mixed with then is layered on base again In matter, total Inoculant dosage is the 7% of matrix volume, then covers the matrix of one layer of 4 cm thick;
(3) clover and onion are uniformly sowed in the matrix of inoculated fungi, cultivation temperature is 25~35 DEG C, relative humidity 50%~80%, 15000 lux of intensity of illumination, normal management and fertilising;
(4) plant strain growth removes aerial part after 17~18 weeks, scrapes 3 ㎝ matrix of surface layer, underlying substrate is connected to plant Root system dries, and is crushed to the particle less than 6 millimeters.
Preferably, the flyash is bitumeniferous alkaline coal ash, and the molecular weight of the polyacrylamide is 15,000,000 ~2,000 ten thousand, the specification of the vermiculite is 4~10mm, and the zeolite is zeolite powder, the mesh of 150 mesh of grain size~250.
Preferably, the preparation method of the decomposed object of the pig manure is as follows:
(1) use mechanical dehydration by pig manure water content be down to 60~80% hereinafter, incorporation crush after drying crop material, Stalk is 1 with pig manure weight ratio:1~3:1, control waits for that the water content of fermentation materials 50%~60%, is adjusted with calcium superphosphate PH to 6.5~7.5;
(2) it will wait for that fermentation materials heap enters in fermentation tank, throwing is turned over after adding microbial bacterial agent, winter, every four days stirrings were primary, Summer, every 2 days stirrings were primary, and fermentation time is 25 days winters, 20 days summers;
(3) the decomposed object of pig manure is transported into fermentation tank, continues to bank up 10 days.
It is further preferred that described be used as stalk at least one of rape stalk, wheat stalk, rice straw, it is long Degree is less than 5cm, and the additive amount of the microbial bacterial agent is 2~5 ‰.
The advantageous effect that the present invention obtains:
The present invention is by the alkaline modifying agent of application and changes the improvement of the measures to acid soil such as modifying agent method of administration Effect can play and be obviously improved soil pH value, improve soil nutrient, reduce heavy metal in soil content, activate the soil of microorganism Earth improving effect.To reduce soil acid evil, the yield of crops and the quality of agricultural product are improved, is not only ensureing farmland quality There is certain realistic meaning with crop production safety and environmental protection aspect, while being also further to recognize soil acidification Feature and its mechanism, the reasonable application of modifying agent and further investigation etc. provide theoretical foundation.
Specific implementation mode
Below by the description to embodiment, specific embodiments of the present invention will be described in further detail, with side Those skilled in the art is helped to have more complete, accurate and deep understanding to the inventive concept of the present invention, technical solution.
Embodiment 1:Soil conditioner is prepared as follows
The group of soil conditioner is divided into:
3 parts of biomass black wood charcoal, 5 parts of dolomite, 10 parts of sepiolite, 15 parts of lime stone, 6 parts of 200 mesh powdered zeolite, 4~ The polyacrylamide 20 of 10 parts of 10mm vermiculites, 5 parts of bentonite, 40 parts of the flyash of the pitch containing 2%wt, average molecular weight 17,500,000 Part, 30 parts of bush mycorrhizal fungi preparation, 22 parts of the decomposed object of pig manure, 3 parts of super absorbent resin.
Preparation method:
(1) preparation of bush mycorrhizal fungi preparation:
(A) substrate preparation:By careless carbon:Vermiculite:Perlite:Zeolite (volume ratio) is 2:2:2:1 ratio mixing, high pressure are steamed Vapour sterilizing is spare;
(B) will contain respectively Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould three kinds of mycorrhizal fungal spores, Mycelial Inoculant first mixes, then the Inoculant being mixed with is layered on matrix by 65/gram of spore density of each strain again On, total Inoculant dosage is the 12% of matrix volume, then covers the matrix of one layer of 4 cm thick;
(C) clover and onion are uniformly sowed in the matrix of inoculated fungi, cultivation temperature is 25~35 DEG C, relative humidity 65%, 12500 lux of intensity of illumination, normal management and fertilising;
(D) plant strain growth removes aerial part after 15 weeks, scrapes 3 ㎝ matrix of surface layer, underlying substrate is connected to root system of plant It dries, is crushed to the particle of 3.5 millimeters of grain size.
(2) preparation method of the decomposed object of pig manure is as follows:
(A) use mechanical dehydration that pig manure water content is down to 70%, drying rape stalk, wheat stalk after incorporation crushing Or rice straw, 3 centimetres of stalk length, stalk are 2 with pig manure weight ratio:1, control waits for the water content of fermentation materials 55%, PH to 7.0 is adjusted with calcium superphosphate;
(B) it will wait for that fermentation materials heap enters in fermentation tank, and turn over throwing after adding 3.5 ‰ wt microbial bacterial agents, every four days of winter was turned over Material is primary, and summer, every 2 days stirrings were primary, and fermentation time is 25 days winters, 20 days summers;
(C) the decomposed object of pig manure is transported into fermentation tank, continues to bank up 10 days.
(3) it puts into pestsides synthesis machine and is sufficiently mixed after weighing except the other components of super absorbent resin, mixture is close Envelope preserves.
(4) it is used after being sufficiently mixed using preceding addition super absorbent resin.
Embodiment 2:Soil conditioner is prepared as follows
1 part of biomass black wood charcoal, 1 part of dolomite, 5 parts of sepiolite, 10 parts of lime stone, 2 parts of 150 mesh powdered zeolite, 4mm vermiculites 5 parts, 10 part, clump the branch bacterium of polyacrylamide of 2 parts of bentonite, 30 parts of the flyash of the pitch containing 1%wt, average molecular weight 15,000,000 10 parts of mycorrhiza fungi microbial inoculum, 15 parts of the decomposed object of pig manure, 1 part of super absorbent resin.
Preparation method:
(1) preparation of bush mycorrhizal fungi preparation:
(A) substrate preparation:By careless carbon:Vermiculite:Perlite:Zeolite (volume ratio) is 2:2:2:1 ratio mixing, high pressure are steamed Vapour sterilizing is spare;
(B) will contain respectively Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould three kinds of mycorrhizal fungal spores, Mycelial Inoculant first mixes, then the Inoculant being mixed with is layered on matrix by 30/gram of spore density of each strain again On, total Inoculant dosage is the 8% of matrix volume, then covers the matrix of one layer of 3.5 cm thick;
(C) clover and onion are uniformly sowed in the matrix of inoculated fungi, cultivation temperature is 25~35 DEG C, relative humidity 50%, 10000 lux of intensity of illumination, normal management and fertilising;
(D) plant strain growth removes aerial part after 14 weeks, scrapes surface layer 2cm matrix, underlying substrate is connected to root system of plant It dries, is crushed to the particle of 3.5 millimeters of grain size.
(2) preparation method of the decomposed object of pig manure is as follows:
(A) use mechanical dehydration that pig manure water content is down to 60%, drying rape stalk, wheat stalk after incorporation crushing Or rice straw, 2 centimetres of stalk length, stalk are 1 with pig manure weight ratio:1, control waits for the water content of fermentation materials 50%, PH to 6.5 is adjusted with calcium superphosphate;
(B) it will wait for that fermentation materials heap enters in fermentation tank, throwing, winter every four days stirrings are turned over after adding 2 ‰ wt microbial bacterial agents Once, summer every 2 days stirrings are primary, and fermentation time is 25 days winters, 20 days summers;
(C) the decomposed object of pig manure is transported into fermentation tank, continues to bank up 10 days.
(3) it puts into pestsides synthesis machine and is sufficiently mixed after weighing except the other components of super absorbent resin, mixture is close Envelope preserves.
(4) it is used after being sufficiently mixed using preceding addition super absorbent resin.
Embodiment 3:Soil conditioner is prepared as follows
5 parts of biomass black wood charcoal, 10 parts of dolomite, 15 parts of sepiolite, 20 parts of lime stone, 10 parts of 250 mesh powdered zeolite, 10mm 15 parts of vermiculite, 8 parts of bentonite, 50 parts of the flyash of the pitch containing 3%wt, average molecular weight 20,000,000 30 parts of polyacrylamide, 50 parts of bush mycorrhizal fungi preparation, 30 parts of the decomposed object of pig manure, 5 parts of super absorbent resin.
Preparation method:
(1) preparation of bush mycorrhizal fungi preparation:
(A) substrate preparation:By careless carbon:Vermiculite:Perlite:Zeolite (volume ratio) is 2:2:2:1 ratio mixing, high pressure are steamed Vapour sterilizing is spare;
(B) will contain respectively Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould three kinds of mycorrhizal fungal spores, Mycelial Inoculant first mixes, then the Inoculant being mixed with is layered on base by 100/gram of spore density of each strain again In matter, total Inoculant dosage is the 15% of matrix volume, then covers the matrix of one layer of 5.5 cm thick;
(C) clover and onion are uniformly sowed in the matrix of inoculated fungi, cultivation temperature is 25~35 DEG C, relative humidity 80%, 15000 lux of intensity of illumination, normal management and fertilising;
(D) plant strain growth removes aerial part after 16 weeks, scrapes surface layer 4cm matrix, underlying substrate is connected to root system of plant It dries, is crushed to the particle of 5 millimeters of grain size.
(2) preparation method of the decomposed object of pig manure is as follows:
(A) use mechanical dehydration that pig manure water content is down to 80%, drying rape stalk, wheat stalk after incorporation crushing Or rice straw, 4 centimetres of stalk length, stalk are 3 with pig manure weight ratio:1, control waits for the water content of fermentation materials 60%, PH to 7.5 is adjusted with calcium superphosphate;
(B) it will wait for that fermentation materials heap enters in fermentation tank, throwing, winter every four days stirrings are turned over after adding 5 ‰ wt microbial bacterial agents Once, summer every 2 days stirrings are primary, and fermentation time is 25 days winters, 20 days summers;
(C) the decomposed object of pig manure is transported into fermentation tank, continues to bank up 10 days.
(3) it puts into pestsides synthesis machine and is sufficiently mixed after weighing except the other components of super absorbent resin, mixture is close Envelope preserves.
(4) it is used after being sufficiently mixed using preceding addition super absorbent resin.
The Acid Paddy Soils modifying agent of the present invention is as follows to the improvement test of rice soil and result:
(1) Acid Paddy Soils are the yellow mud field of plate shale development, pH value 5.0~5.5.
(2) it uses quick lime as a contrast, sets 3 processing altogether, respectively:(a) CK does not add any substance;(b) life is applied Lime 1.38g/kg soil;(c) modifying agent in embodiment 1-3,1.38g/kg soil are applied.Each processing is all provided with 12 weights It is multiple.
(3) each processing weigh 6.5kg cover sieved soil in bottom diameter 20cm, bore 26cm, high 19cm polypots in, will (modifying agent mixes well dress alms bowl with soil) is added in soil sample by set amount in different modifying agents, and fills it up with common irrigate in farmland and use Water, and ensure that the depth of waterflooding in each basin alms bowl is consistent (being higher by 2~3cm of soil layer), to prevent the influence of rainwater, taken with light-transmissive film Canopy blocks.
(4) culture experiment taken at regular intervals soil sample, in laboratory measurement soil pH value, and before experiment is carried out and end Afterwards, mixed soil sample, the analysis soil organism, alkali-hydrolyzable nitrogen, available phosphorus, exchangeable calcium, exchangeable magnesium, exchangeability are acquired respectively Aluminium, exchangeable potassium, exchangeable sodium, Soil exchangeable Al total ion concentration, cation exchange capacity (CEC) (CEC), good fortune, lead, water stability group The indexs such as kernel structure.
(5) indices are all made of conventional method analysis.Soil pH value uses soil ratio for 1:1, it weighs l1g and passes through 1mm The air-dried soil sample of sieve is placed in 25ml beakers, adds deionized water 10ml, is stirred 5 minutes, with corrected after standing 25 minutes The mode of pH meter measures;Available phosphorus extracts an anti-colorimetric method of aluminium antimony with sodium bicarbonate;Exchangeable calcium, magnesium NH4OAc extractions one are former Sub- absorptiometry;Rock picker, manganese are using People's Republic of China's forestry industry standard-forest soil extraction Property iron, aluminium, manganese, silicon, Carbon analysis (LY/T1257-1999);The measurement of organic matter uses potassium bichromate titrimetric method (external heat Method);Alkali-hydrolyzable nitrogen is measured using alkaline hydrolysis diffusion method;Exchangeable potassium, sodium extract a flame spectrometry using acetic acid money;Soil exchangeable Alkali total amount uses NH4OAc neutralization titrations;Pb in Soil, good fortune are extracted using potassium iodide monomethyl isobutyl ketone (KI-MIBK) Atomic absorption spectrophotometry;Cation Exchange Capacity in Soils is measured using one sulfuric acid process of barium chloride;Water-stable granular structure Using dry sieve method and wet screening.
Influence statistic analysis result of 1 different soils modifying agent of the table processing to rice soil pH
Processing 0d 21d 35d 49d 63d
CK 5.36±0.04 5.37±0.04 5.39±0.02 5.48±0.04 5.50±0.04
Quick lime 5.34±0.06 5.93±0.06 6.02±0.04 6.10±0.04 6.19±0.06
Embodiment 1 5.38±0.06 5.89±0.06 6.05±0.06 6.16±0.04 6.33±0.06
Embodiment 2 5.40±0.06 5.68±0.06 5.83±0.04 5.98±0.04 6.05±0.06
Embodiment 3 5.36±0.06 5.83±0.06 6.00±0.06 6.04±0.06 6.12±0.04
Note:0d is the soil before processing.
Can there be different degrees of promotion to the pH of Acid Paddy Soils using quick lime and modifying agent, and compare CK group ratios Compared with quick lime and modifying agent can reach 0.5 unit or more in different times to the promotion of pH, be promoted to the pH of acid soil There is remarkable effect.
It is operated by soil improvements in 3 months, the chemical properties variation such as following table of Acid Paddy Soils:
Influence of 2 different soils modifying agent of the table processing to soil nutrient content
CK Quick lime Embodiment 1 Embodiment 2 Embodiment 3
Alkali-hydrolyzable nitrogen 320 271 364 329 349
Available phosphorus 16.3 18.1 22.3 18.6 20.1
Organic matter 41300 40500 49300 43300 47300
CEC 11.2 11.4 10.8 10.80 11.1
Exchangeable sodium 48.3 55.2 57.2 48.3 55.6
Exchangeable potassium 140.4 152.1 175.3 156.0 165.5
Exchangeable calcium 714 1202 1349 1156 1296
Exchangeable magnesium 110.4 121.2 109.1 127.88 119.8
Alkali total amount 5.06 7.65 7.99 7.14 7.77
Ca/Mg 6.4674 9.9175 12.3690 9.0400 10.8180
Degree of base saturation 45.18 67.11 74.2 66.1 69.9
Note:Wherein exchangeable base total amount and CEC units be cmol/kg, degree of base saturation %, in addition to Ca/Mg remaining Index unit is mg/kg;Numerical value is the average value of corresponding index in table.
Degree of base saturation (BS)=exchangeable base total amount * 100%/CEC
Ca/Mg reflects the variation of soil ecological process and the biological effectiveness of calcium and magnesium, can also be to other nutrients in soil such as The biological effectiveness of the elements such as sodium potassium produces a very large impact, and the Ca/Mg ratios of embodiment 1-3 are high than control as shown in Table 2, Illustrate that the biological effectiveness of soil calcium ions and magnesium ions is greatly improved;Compared with the control group, quick lime so that alkaline hydrolysis nitrogen content is aobvious Writing reduces, and embodiment 1-3 so that alkali-hydrolyzable nitrogen, available phosphorus content significantly increase, exchangeable potassium content significantly increases, and alkali is full Have with degree and significantly promoted, effectively improves the acid buffer capacity of Acid Paddy Soils, and the soil physico-chemical property of embodiment 1-3 is improved Effect is close or is significantly better than quick lime group.
The calculation formula of soil agreegate destructive rate is:Aggregate destructive rate=(it is big to be more than 0.25mm dry screens aggregate one In 0.25mm wet screenings aggregate)/it is more than 0.25mm dry screen aggregate × 100%
3 different soils modifying agent of table is formed to soil agreegate and the influence of destructive rate
The aggregate that wet screening obtains is the water stability performance in soil, and water stability performance is destroyed with aggregate Rate reflects the stability of soil texture, and the water stability performance total amount of > 0.25mm is minimum in control treatment, destructive rate highest, Wherein CK processing destructive rates are significantly higher than quick lime and embodiment 1-3, show that quick lime and embodiment 1-3 can improve rice soil Aggregate stability, and embodiment 1 and 3 it is with obvious effects be better than quick lime group, efficiently promoted soil texture stability.
Influence of the 4 different soils modifying agent of table to rock picker and content of beary metal
Processing Exchangeable aluminum (mg/kg) Total lead (mg/kg) Total cadmium (mg/kg)
CK 67.4 44.4 0.535
Quick lime 35.1 43.6 0.342
Embodiment 1 30.8 29.1 0.222
Embodiment 2 34.9 38.8 0.351
Embodiment 3 32.4 35.3 0.299
Heavy metal is extremely firmly adsorbed on soil with ionic forms and exchanged on point and firewood soil particle in the soil, soil acid Degree, which increases, can be such that they are split away off from soil exchange point and firewood soil particle, i.e. the dissolution of heavy metal-polluted soil, an a large amount of huge sum of money Plant growth can be generated toxic action by belonging to Ion release, and people has eaten the cereal containing heavy metal and also will produce poisoning instead It answers, it is unhealthful.
From table 4, it can be seen that embodiment 1-3 can significantly reduce exchangeable aluminum in acid soil, total lead and total cadmium Content reduces the toxicity of heavy metal, improves soil, is conducive to the growth of crops, improves the quality of cereal, reduces heavy metal intake Risk.
Test and result of the Acid Paddy Soils modifying agent of the present invention in terms of rice yield raising are as follows:
Implementation steps are as follows:
It applies modifying agent processing experiment and sets 5 processing, respectively:(1) CK does not add any substance, plants conventional seedling water Rice;(2) it applies quick lime 1.38g/kg soil ten and plants conventional Raised Seedling Rice;(3-5) applies embodiment 1-3,1.38g/kg soil+cultivation The conventional Raised Seedling Rice of kind;12 repetitions of each processing setting.6.5kg experiment soil is weighed in bottom diameter 18cm, bore 26cm, high 21cm Polypots in, (modifying agent and soil mix well dress alms bowl) is added in soil sample by set amount in different modifying agents, by rice life Long rule irrigated farmland water on time.Demand by potted plant crop to nutrient applies urea 1.21g, chlorination before rice transplanting per basin Potassium 0.88g, 8d after rice transplanting apply urea 0.58g potassium chloride 0.59g per basin again, and fertilizer uses liquid application mode, with soil It mixes well.
Dry weight yield, bear fruit grains, plant height and the number of productive ear that rice is measured in growth period and maturity period, as a result with flat Mean value indicates as follows:
Influence of 5 different soils modifying agent of the table processing to rice yield, bear fruit grains, plant height and number of productive ear
As shown in Table 5, embodiment 1-3 can improve rice yield, wherein the yield highest of embodiment 1, reach 56.69g, Also significantly greater than quick lime group, crop plant height have reacted the fertility level of plant growth and soil to a certain extent, real The plant height for applying example 1,3 is significantly higher than CK control groups, it is seen that soil can promote fertility after improvement, promote rice plant Growth, for volume increase provide safeguard.
In conclusion the present invention can improve Acid Paddy Soils, soil pH value is improved, increases soil texture and stablizes Property, the dissolution of heavy metal-polluted soil is reduced, Nutrient Elements in Soil content is promoted, growth and volume increase to rice are played promotion and made With laying the first stone, have broad application prospects for the southern Acid Paddy Soils of extensive improvement.
Above example is merely illustrative of the invention's technical idea, and protection scope of the present invention cannot be limited with this, every According to technological thought proposed by the present invention, any change done on the basis of technical solution each falls within the scope of the present invention Within;The technology that the present invention is not directed to can be realized by the prior art.

Claims (6)

1. a kind of Acid Paddy Soils modifying agent, which is characterized in that include the component of following parts by weight:1~5 part of biomass black wood charcoal, 1~10 part of dolomite, 5~15 parts of sepiolite, 10~20 parts of lime stone, 2~10 parts of zeolite, 5~15 parts of vermiculite, bentonite 2~8 Part, 30~50 parts of flyash, 10~30 parts of polyacrylamide, 10~50 parts of bush mycorrhizal fungi preparation, the decomposed object of pig manure 15~ 30 parts, 1~5 part of super absorbent resin.
2. according to a kind of Acid Paddy Soils modifying agent in claim 1, which is characterized in that include the component of following parts by weight:It is raw 3 parts of substance black wood charcoal, 5 parts of dolomite, 10 parts of sepiolite, 15 parts of lime stone, 6 parts of zeolite, 10 parts of vermiculite, 5 parts of bentonite, flyash 40 parts, 20 parts of polyacrylamide, 30 parts of bush mycorrhizal fungi preparation, 22 parts of the decomposed object of pig manure, 3 parts of super absorbent resin.
3. according to a kind of Acid Paddy Soils modifying agent in claim 1, it is characterised in that:The bush mycorrhizal fungi preparation includes At least one of Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould, preparation method is as follows:
(1) substrate preparation:By careless carbon:Vermiculite:Perlite:Zeolite (volume ratio) is 2:2:2:1 ratio mixing, high steam go out Bacterium is spare;
(2) Glomus mosseae bacterium, Glomus intraradices bacterium, deformation sacculus mould three kinds of mycorrhizal fungal spores, mycelia will be contained respectively The Inoculant of body first mixes, then the Inoculant being mixed with is layered on base by 30~100/gram of spore density of each strain again In matter, total Inoculant dosage is the 8~15% of matrix volume, then covers the matrix of one layer of 3.5~5.5 cm thick;
(3) clover and onion are uniformly sowed in the matrix of inoculated fungi, cultivation temperature is 25~35 DEG C, relative humidity 50% ~80%, 10000~15000 lux of intensity of illumination, normal management and fertilising;
(4) plant strain growth removes aerial part after 14~16 weeks, scrapes 2~4 ㎝ matrix of surface layer, underlying substrate is connected to plant Root system dries, and is crushed to 2~5 millimeters of particle.
4. according to a kind of Acid Paddy Soils modifying agent in claim 1, it is characterised in that:The flyash is to be dripped containing 1~3%wt The molecular weight of green alkaline coal ash, the polyacrylamide is 15,000,000~20,000,000, the specification of the vermiculite is 4~ 10mm, the zeolite are zeolite powder, the mesh of 150 mesh of grain size~250.
5. according to a kind of Acid Paddy Soils modifying agent in claim 1, it is characterised in that:The preparation method of the decomposed object of pig manure It is as follows:
(1) use mechanical dehydration that pig manure water content is down to 60~80% hereinafter, mixing the drying crop material after crushing, stalk It is 1 with pig manure weight ratio:1~3:1, control waits for the water content of fermentation materials 50%~60%, with calcium superphosphate adjust pH to 6.5~7.5;
(2) it will wait for that fermentation materials heap enters in fermentation tank, and turn over throwing after adding microbial bacterial agent, winter, every four days stirrings were primary, summer Every 2 days stirrings are primary, and fermentation time is 25 days winters, 20 days summers;
(3) the decomposed object of pig manure is transported into fermentation tank, continues to bank up 10 days.
6. according to a kind of Acid Paddy Soils modifying agent in claim 5, it is characterised in that:It is described as stalk be rape stalk, At least one of wheat stalk, rice straw, length are less than 5cm, and the additive amount of the microbial bacterial agent is 2~5 ‰.
CN201810732507.4A 2018-07-05 2018-07-05 A kind of Acid Paddy Soils modifying agent Pending CN108587644A (en)

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CN115322055A (en) * 2022-08-30 2022-11-11 江苏省农业科学院 Tobacco soil conditioner and preparation method and application thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777432A (en) * 2019-01-25 2019-05-21 平顶山学院 A kind of acidified soil conditioner
CN110622795A (en) * 2019-09-27 2019-12-31 贵州省亚热带作物研究所 Good agricultural operation management method for coix
CN113061440A (en) * 2021-03-19 2021-07-02 中国科学院地理科学与资源研究所 Compound remediation agent for heavy metal pollution of paddy acid red loam and application
CN113083880A (en) * 2021-03-19 2021-07-09 中国科学院地理科学与资源研究所 Safe utilization method of heavy metal polluted paddy field in southern acidic red soil region
CN113512426A (en) * 2021-06-29 2021-10-19 铜仁市锦江绿色蔬菜产业发展有限公司 Method for preventing and treating mercury and manganese pollution in soil in vegetable planting base
CN113860950A (en) * 2021-10-11 2021-12-31 浙江省农业科学院 Medium and low yield farmland plough layer soil reservoir expansion and storage improving agent and preparation method thereof
CN115322055A (en) * 2022-08-30 2022-11-11 江苏省农业科学院 Tobacco soil conditioner and preparation method and application thereof
CN117158282A (en) * 2023-10-26 2023-12-05 内蒙古工业大学 Biomass composite material for preventing and treating desertification and preparation method thereof
CN117158282B (en) * 2023-10-26 2023-12-26 内蒙古工业大学 Biomass composite material for preventing and treating desertification and preparation method thereof

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