CN108516687A - A kind of preparation method of accumulating type luminous glaze glass ceramic material - Google Patents
A kind of preparation method of accumulating type luminous glaze glass ceramic material Download PDFInfo
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- CN108516687A CN108516687A CN201810363499.0A CN201810363499A CN108516687A CN 108516687 A CN108516687 A CN 108516687A CN 201810363499 A CN201810363499 A CN 201810363499A CN 108516687 A CN108516687 A CN 108516687A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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Abstract
The invention discloses a kind of preparation methods of accumulating type luminous glaze glass ceramic material, and the accumulating type luminous glaze glass ceramic material is by SrAl2O4:Eu2+, Dy3+ and parent glaze are prepared；Wherein, the parent glaze by 35 50 mass parts B2O3, the ZrO2 of 25 mass parts, the TeO2 of 5 20 mass parts, the ZnO of 15 20 mass parts, the Na2O2 of 20 30 mass parts, the Al2O3 of 5 10 mass parts and the La2O3 of 25 mass parts are prepared, the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is sintered by low temperature (450 500 degrees Celsius), accumulating type luminous glaze glass ceramic coating made of accumulating type luminous glaze glass ceramic material by the low temperature of glaze firing, accumulating type luminous glaze glass ceramic coating is after 750 DEG C of high temperature sinterings, it can also continue to shine.
Description
Technical field
The invention belongs to new material technology fields, relate in particular to a kind of accumulating type luminous glaze glass of low temperature of glaze firing
Ceramic material and preparation method and applications.
Background technology
Noctilucent safety fire-fighting made of Noctilucent material identifies, and evacuation side is indicated with obvious word, distinct arrow mark
Evacuation safety when occurring to, effective guarantee fire.Currently used Noctilucent safety mark is with luminescent coating and plastics system
, these security against fires for containing organic components mark burnt in a fire by open fire after moment will deform, turn to ash
Cinder loses luminous.It loses the effect for guiding correct escape route soon in a fire, protection people's life cannot be played
The effect of safety.In order to solve this technical problem, patent (CN104003757A) discloses a kind of Luminous fire mark
Production method, with transparent polishing dry granular and luminescent powder silk-screen at luminous glaze glass ceramic material pattern in ceramic plane, but it is adopted
The glaze firing temperature on transparent polishing dry granular basis is higher (1200 degrees Celsius), at such high temperatures, Noctilucent material pole
It easily reacts with parent glaze, influences the luminous intensity of noctilucence powder material, to influence the illumination effect of Noctilucent safety mark.
Invention content
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of accumulating type luminous glaze glass of low temperature of glaze firing
Ceramic material and preparation method and applications.
The purpose of the present invention is what is be achieved by following technical proposals.
A kind of accumulating type luminous glaze glass ceramic material of low temperature of glaze firing, by SrAl2O4:Eu2+, Dy3+ and parent glaze
It is prepared, by mass, SrAl2O4:The ratio of Eu2+, Dy3+ and parent glaze is 1：3；Wherein, the parent glaze is by 35-50
ZnO, 20-30 mass parts of TeO2,15-20 mass parts of ZrO2,5-20 mass parts of B2O3,2-5 mass parts of mass parts
The La2O3 of Al2O3 and 2-5 mass parts of Na2O2,5-10 mass parts be prepared.
In the above-mentioned technical solutions, the B2O3 is 40-45 mass parts, ZrO2 is 3-4 mass parts, TeO2 is 10-15 matter
Measure part, ZnO is 16-19 mass parts, Na2O2 is 22-27 mass parts, Al2O3 is 6-9 mass parts and La2O3 is 3-6 mass parts.
A kind of preparation method of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, gives as steps described below
To prepare：
1) B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion uniformly mixed, are put into high temperature furnace
In at 900-1200 DEG C be sintered 2-4 hour, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball
Ball milling is carried out in grinding machine 1-12 hours, be sieved with the sieve of 300-400 mesh after ball milling, parent glaze powder is made；
2) by 1) gained parent glaze powder and SrAl2O4:Eu2+, Dy3+ are mixed to uniform, are sintered under 450-500 degrees Celsius
15-45 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
In the above-mentioned technical solutions, B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion
It is uniformly mixed, is put into high temperature furnace the 2-4 hour of sintering at 1000-1150 DEG C, obtains forerunner's glass.
In the above-mentioned technical solutions, by 1) gained parent glaze powder and SrAl2O4:Eu2+, Dy3+ are mixed to uniform,
20-30 minutes are sintered under 450-500 degrees Celsius to get to the accumulating type luminous glaze glass ceramics of the low temperature of glaze firing
Material.
A kind of application of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, by the low temperature of glaze firing
Accumulating type luminous glaze glass ceramic material is mixed with glycerine, after mixing by silk-screen printing, brush or be sprayed on ceramic tile surface
On, accumulating type luminous glaze glass ceramic coating is made, passes through screen printing in the upper surface of described accumulating type luminous glaze glass-ceramic layer
The basic glaze layer of one layer of covering is brushed or sprayed to brush；The ceramic tile is put into high temperature furnace and is sintered 5-10 points at 450-550 DEG C
Clock.
In the above-mentioned technical solutions, by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerine is 9:
1。
The accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is by (450-500 degrees Celsius) burning of low temperature
It ties, accumulating type luminous glaze glass ceramics made of the accumulating type luminous glaze glass ceramic material by the low temperature of glaze firing applies
Layer, accumulating type luminous glaze glass ceramic coating can also continue to shine after 750 DEG C of high temperature sinterings.
Description of the drawings
Fig. 1 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting after potsherd
Spectrogram；
Fig. 2 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting light after potsherd
Spectrogram；
Fig. 3 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting light after potsherd
Spectrogram；
Fig. 4 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting light after potsherd
Spectrogram.
Specific implementation mode
In the present embodiment, raw material B2O3, ZrO2, TeO2, ZnO, Al2O3, Na2O2 and La2O3 is purchased from Aladdin
Reagent, wherein B2O3 article No.s are B108406-500g, and TeO2 article No.s are T103864, and ZnO article No.s are Z111836, Al2O3 goods
Number be A140802, La2O3 article No.s be L103872, Na2O2 article No.s be S100113.Test equipment：F-4600 fluorescence spectrophotometer light
Degree counts (high and new technology company of Hitachi), the ultraviolet excitation sample tested with 320 nanometers in the present embodiment.
SrAl2O4:The preparation method of Eu2+, Dy3+：It will add in strontium carbonate (99.2%), alundum (Al2O3) (99.99%)
Enter analytically pure Eu2O3, be uniformly mixed after Dy2O3, is burnt within 2 hours in reducing atmosphere at 1300 DEG C, through crushing, obtains
Luminescent material sample.Wherein, by the gauge of substance, strontium carbonate (99.2%), alundum (Al2O3) (99.99%), Eu2O3 and
The ratio of Dy2O3 is 9:10:0.1:0.4.
Application process：The accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing is mixed with glycerine, after mixing
One layer is brushed on ceramic tile surface, accumulating type luminous glaze glass ceramic coating is made, in the accumulating type luminous glaze glass ceramics
The upper surface of layer is by brushing the basic glaze layer of one layer of covering；The ceramic tile is put into high temperature furnace and is sintered 5-10 points at 450-550 DEG C
Clock, wherein by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerine is 9:1.
In an embodiment of the present invention, 1 mass parts are 1g.
With reference to the accompanying drawings and examples to the present invention low temperature of glaze firing accumulating type luminous glaze glass ceramic material into
Row is described in detail.
Embodiment 1
1) B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion uniformly mixed, are put into high temperature furnace
In at 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved with the sieve of 300 mesh after ball milling, parent glaze powder is made；Wherein, the parent glaze is by 37
The B2O3 of mass parts, the ZrO2 of 2 mass parts, the TeO2 of 7 mass parts, the ZnO of 16 mass parts, the Na2O2 of 22 mass parts, 6 mass
The Al2O3 of part and the La2O3 of 2 mass parts are prepared.
2) by the parent glaze powder and SrAl2O4 obtained by 1):Eu2+, Dy3+ are mixed to uniform, are carried out under 500 degrees Celsius
Sintering 25 minutes is to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein by mass,
SrAl2O4:The ratio of Eu2+, Dy3+ and parent glaze is 1：3.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be that potsherd is put into F-4600 sepectrophotofluorometers and is tested on 1 millimeter of potsherd, emit
Curve 1 in spectrum such as attached drawing 1.
After test, above-mentioned potsherd is put into Muffle furnace, is sintered 30 minutes at 750 degrees c, it is naturally cold after taking-up
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 1
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 26%, illustrates the accumulating type night of the present invention
Light glaze glass ceramic material can still shine after oversintering,
Embodiment 2
1) B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion uniformly mixed, are put into high temperature furnace
In at 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved with the sieve of 300 mesh after ball milling, parent glaze powder is made；Wherein, the parent glaze is by 42
The B2O3 of mass parts, the ZrO2 of 3 mass parts, the TeO2 of 12 mass parts, the ZnO of 17 mass parts, the Na2O2 of 24 mass parts, 7 matter
The La2O3 of the Al2O3 and 3 mass parts that measure part are prepared.
2) by the parent glaze powder and SrAl2O4 obtained by 1):Eu2+, Dy3+ are mixed to uniform, are carried out under 500 degrees Celsius
Sintering 25 minutes is to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein by mass,
SrAl2O4:The ratio of Eu2+, Dy3+ and parent glaze is 1：3.Curve 2 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 2 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be that potsherd is put into F-4600 sepectrophotofluorometers and is tested on 1 millimeter of potsherd, emit
Curve 1 in spectrum such as attached drawing 2.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 2
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 17%, illustrates the accumulating type night of the present invention
Light glaze glass ceramic material can still shine after oversintering,
Embodiment 3
1) B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion uniformly mixed, are put into high temperature furnace
In at 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved with the sieve of 300 mesh after ball milling, parent glaze powder is made；Wherein, the parent glaze is by 46
The B2O3 of mass parts, the ZrO2 of 4 mass parts, the TeO2 of 17 mass parts, the ZnO of 18 mass parts, the Na2O2 of 26 mass parts, 8 matter
The La2O3 of the Al2O3 and 4 mass parts that measure part are prepared.
2) by the parent glaze powder and SrAl2O4 obtained by 1):Eu2+, Dy3+ are mixed to uniform, are carried out under 500 degrees Celsius
Sintering 25 minutes is to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein by mass,
SrAl2O4:The ratio of Eu2+, Dy3+ and parent glaze is 1：3.Curve 3 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be that potsherd is put into F-4600 sepectrophotofluorometers and is tested on 1 millimeter of potsherd, emit
Curve 1 in spectrum such as attached drawing 3.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 3
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 11%, illustrates the accumulating type night of the present invention
Light glaze glass ceramic material can still shine after oversintering,
Embodiment 4
1) B2O3, ZrO2, TeO2, ZnO, Na2O2, Al2O3 and La2O3 are milled in proportion uniformly mixed, are put into high temperature furnace
In at 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved with the sieve of 300 mesh after ball milling, parent glaze powder is made；Wherein, the parent glaze is by 49
The B2O3 of mass parts, the ZrO2 of 5 mass parts, the TeO2 of 19 mass parts, the ZnO of 19 mass parts, the Na2O2 of 28 mass parts, 9 matter
The La2O3 of the Al2O3 and 5 mass parts that measure part are prepared.
2) by the parent glaze powder and SrAl2O4 obtained by 1):Eu2+, Dy3+ are mixed to uniform, are carried out under 500 degrees Celsius
Sintering 25 minutes is to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein by mass,
SrAl2O4:The ratio of Eu2+, Dy3+ and parent glaze is 1：3.Curve 4 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be that potsherd is put into F-4600 sepectrophotofluorometers and is tested on 1 millimeter of potsherd, emit
Curve 1 in spectrum such as attached drawing 4.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 4
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 73%, illustrates the accumulating type night of the present invention
Light glaze glass ceramic material can still shine after oversintering,
By above-mentioned test result, it is found that the accumulating type luminous glaze glass ceramic material of the present invention is by low temperature, (450-500 is Celsius
Degree) it is sintered, accumulating type luminous glaze glass made of the accumulating type luminous glaze glass ceramic material by the low temperature of glaze firing is made pottery
Porcelain coating, accumulating type luminous glaze glass ceramic coating can also continue to shine at after high temperature sintering (500 DEG C).
Illustrative description has been done to the present invention above, it should explanation, the case where not departing from core of the invention
Under, any simple deformation, modification or other skilled in the art can not spend the equivalent replacement of creative work equal
Fall into protection scope of the present invention.
Claims (1)
1. a kind of preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing, which is characterized in that accumulating type night
Light glaze glass ceramic material is by SrAl2O4:Eu2+,Dy3+It is prepared with parent glaze, by mass, SrAl2O4:Eu2+,Dy3+With
The ratio of parent glaze is 1：3；Wherein, the parent glaze by 42 mass parts B2O3, 3 mass parts ZrO2, 12 mass parts TeO2、
The Na of the ZnO of 17 mass parts, 24 mass parts2O2, 7 mass parts Al2O3With the La of 3 mass parts2O3It is prepared；
Accumulating type luminous glaze glass ceramic material is prepared as steps described below：
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled to uniformly mixed, is put into high temperature furnace in proportion
1000 DEG C of 3 hours of sintering, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill and carries out
Ball milling 6 hours, is sieved after ball milling with the sieve of 300 mesh, and parent glaze powder is made；
2) by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is sintered 25 minutes under 500 degrees Celsius,
Obtain the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810363499.0A CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511031738.5A CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
| CN201810363499.0A CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
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| CN201511031738.5A Division CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
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| CN201711437992.4A Expired - Fee Related CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
| CN201810363496.7A Pending CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN201511031738.5A Expired - Fee Related CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
| CN201810363487.8A Active CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
| CN201810363499.0A Pending CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
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| CN201711437992.4A Expired - Fee Related CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
| CN201810363496.7A Pending CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN201511031738.5A Expired - Fee Related CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
| CN201810363487.8A Active CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
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| EP3846769A1 (en) * | 2018-09-04 | 2021-07-14 | 3M Innovative Properties Company | Fluorescent glazing composition for a dental zirconia article, process of sintering and kit of parts |
| CN113307496B (en) * | 2021-06-15 | 2022-09-16 | 亚细亚建筑材料股份有限公司 | Luminescent glaze ceramic material and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1236754A (en) * | 1999-04-02 | 1999-12-01 | 中国建筑材料科学研究院 | Light-accumulative luminous ceramic products |
| CN102898185A (en) * | 2012-11-06 | 2013-01-30 | 淄博泰如工业新材料有限公司 | Production process of luminous ceramic product |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100268605B1 (en) * | 1997-12-30 | 2000-10-16 | 이용재 | Luminous tile and its manufacturing method |
| CN1308254C (en) * | 2003-10-20 | 2007-04-04 | 梁锋 | High temperature luminous glazing and its production process and application in luminous glazed tile |
| CN103643773B (en) * | 2013-12-12 | 2015-11-25 | 佛山欧神诺陶瓷股份有限公司 | One is photic stores light ceramic brick and production method thereof |
-
2015
- 2015-12-30 CN CN201711437992.4A patent/CN108117260B/en not_active Expired - Fee Related
- 2015-12-30 CN CN201810363496.7A patent/CN108484225A/en active Pending
- 2015-12-30 CN CN201511031738.5A patent/CN105503274B/en not_active Expired - Fee Related
- 2015-12-30 CN CN201810363487.8A patent/CN108423991B/en active Active
- 2015-12-30 CN CN201810363499.0A patent/CN108516687A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1236754A (en) * | 1999-04-02 | 1999-12-01 | 中国建筑材料科学研究院 | Light-accumulative luminous ceramic products |
| CN102898185A (en) * | 2012-11-06 | 2013-01-30 | 淄博泰如工业新材料有限公司 | Production process of luminous ceramic product |
Non-Patent Citations (2)
| Title |
|---|
| 康桂峦: "铝酸锶型荧光粉的制备研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
| 廉志红 等: "长余辉发光粉SrAl2O4：Eu，Dy在搪瓷涂层中的发光性质", 《发光学报》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105503274A (en) | 2016-04-20 |
| CN108423991B (en) | 2020-01-03 |
| CN108423991A (en) | 2018-08-21 |
| CN108117260A (en) | 2018-06-05 |
| CN108117260B (en) | 2019-11-29 |
| CN108484225A (en) | 2018-09-04 |
| CN105503274B (en) | 2018-06-01 |
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