The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing
(the present patent application is parent application " the accumulating type luminous glaze glass ceramic material and preparation method of low temperature of glaze firing
And its application " divisional application, parent application application No. is 2015110317385, the applying date is on December 30th, 2016.)
Technical field
The invention belongs to new material technology fields, relate in particular to a kind of accumulating type luminous glaze glass of low temperature of glaze firing
Ceramic material and preparation method and applications.
Background technique
The mark of Noctilucent safety fire-fighting made of Noctilucent material indicates evacuation side with obvious text, distinct arrow mark
Evacuation safety when occurring to, effective guarantee fire.Currently used Noctilucent safety mark is with luminescent coating and plastics system
, moment will deform after these security against fires for containing organic components mark is burnt by open fire in a fire, it turns to dust and ashes,
It loses luminous.It loses the effect for guiding correct escape route soon in a fire, protection people's life safety cannot be played
Effect.In order to solve this technical problem, patent (104003757 A of CN) discloses a kind of production of Luminous fire mark
Method, in ceramic plane with transparent polishing dry granular and luminescent powder silk-screen at luminous glaze glass ceramic material pattern, but it is used
It is transparent polishing dry granular basis glaze firing temperature it is higher (1200 degrees Celsius), at such high temperatures, Noctilucent material easily with
Parent glaze reacts, and influences the luminous intensity of noctilucence powder material, to influence the illumination effect of Noctilucent safety mark.
Summary of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of accumulating type luminous glaze glass of low temperature of glaze firing
Ceramic material and preparation method and applications.
The purpose of the present invention is what is be achieved by following technical proposals.
A kind of accumulating type luminous glaze glass ceramic material of low temperature of glaze firing, by SrAl2O4:Eu2+,Dy3+With parent glaze system
It is standby to form, by mass, SrAl2O4:Eu2+,Dy3+And the ratio of parent glaze is 1:3;Wherein, the parent glaze is by 35-50 mass parts
B2O3, 2-5 mass parts ZrO2, 5-20 mass parts TeO2, 15-20 mass parts ZnO, 20-30 mass parts Na2O2、5-
The Al of 10 mass parts2O3With the La of 2-5 mass parts2O3It is prepared.
In the above-mentioned technical solutions, the B2O3For 40-45 mass parts, ZrO2For 3-4 mass parts, TeO2For 10-15 mass
Part, ZnO are 16-19 mass parts, Na2O2For 22-27 mass parts, Al2O3For 6-9 mass parts and La2O3For 3-6 mass parts.
A kind of preparation method of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, gives as steps described below
With preparation:
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In in 2-4 hour of 900-1200 DEG C of sintering, obtain forerunner's glass;Forerunner's glass machinery is crushed to glass particle, is put into ball
It carries out ball milling 1-12 hours in grinding machine, is sieved after ball milling with the sieve of 300-400 mesh, parent glaze powder is made;
2) by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is sintered under 450-500 degrees Celsius
15-45 minutes to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing.
In the above-mentioned technical solutions, by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled to mixing in proportion
Uniformly, it is put into high temperature furnace in 2-4 hour of 1000-1150 DEG C of sintering, obtains forerunner's glass.
In the above-mentioned technical solutions, by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, in 450-
20-30 minutes are sintered under 500 degrees Celsius to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing.
A kind of application of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, by the low temperature of glaze firing
Accumulating type luminous glaze glass ceramic material is mixed with glycerol, is passed through silk-screen printing after mixing, is brushed or be sprayed on ceramic tile surface
On, accumulating type luminous glaze glass ceramic coating is made, passes through screen printing in the upper surface of described accumulating type luminous glaze glass-ceramic layer
One layer of covering basic glaze layer is brushed or sprayed to brush;The ceramic tile is put into high temperature furnace at 450-550 DEG C of sintering 5-10 points
Clock.
In the above-mentioned technical solutions, by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerol is 9:
1。
The accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention is by (450-500 degrees Celsius) of low temperature burning
It ties, accumulating type luminous glaze glass ceramics made of the accumulating type luminous glaze glass ceramic material by the low temperature of glaze firing applies
Layer, accumulating type luminous glaze glass ceramic coating can also continue to shine after 750 DEG C of high temperature sinterings.
Detailed description of the invention
Fig. 1 is that the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention is brushed to the transmitting after potsherd
Spectrogram;
Fig. 2 is that the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention is brushed to the transmitting after potsherd
Spectrogram;
Fig. 3 is that the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention is brushed to the transmitting after potsherd
Spectrogram;
Fig. 4 is that the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention is brushed to the transmitting after potsherd
Spectrogram.
Specific embodiment
In the present embodiment, raw material B2O3、ZrO2、TeO2、ZnO、Al2O3、Na2O2And La2O3It is purchased from Aladdin examination
Agent, wherein B2O3Article No. is B108406-500g, TeO2Article No. is T103864, and ZnO article No. is Z111836, Al2O3Article No. is
A140802, La2O3Article No. is L103872, Na2O2Article No. is S100113.Test equipment: F-4600 sepectrophotofluorometer (day
Vertical high and new technology company), 320 nanometers of ultraviolet excitation sample of test in the present embodiment.
SrAl2O4:Eu2+,Dy3+Preparation method: will strontium carbonate (99.2%), be added in aluminum oxide (99.99%)
Analytically pure Eu2O3, Dy2O3After be uniformly mixed, at 1300 DEG C in reducing atmosphere 2 hours be burnt into, crushed, shone
Material sample.Wherein, by the meter of substance, strontium carbonate (99.2%), aluminum oxide (99.99%), Eu2O3And Dy2O3Ratio
For 9:10:0.1:0.4.
Application method: the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing is mixed with glycerol, after mixing
One layer is brushed on ceramic tile surface, accumulating type luminous glaze glass ceramic coating is made, in the accumulating type luminous glaze glass ceramics
The upper surface of layer is by brushing one layer of covering basic glaze layer;The ceramic tile is put into high temperature furnace at 450-550 DEG C of sintering 5-10 points
Clock, wherein by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerol is 9:1.
In an embodiment of the present invention, 1 mass parts are 1g.
With reference to the accompanying drawings and examples to the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing of the invention into
Row is described in detail.
Embodiment 1
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In in 1000 DEG C of 3 hours of sintering, obtain forerunner's glass;Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made;Wherein, the parent glaze is by 37
The B of mass parts2O3, 2 mass parts ZrO2, 7 mass parts TeO2, the ZnO of 16 mass parts, 22 mass parts Na2O2, 6 mass parts
Al2O3With the La of 2 mass parts2O3It is prepared.
2) by 1) resulting parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing, wherein by mass, SrAl2O4:
Eu2+,Dy3+And the ratio of parent glaze is 1:3.
Brushing accumulating type luminous glaze glass ceramic material made from embodiment 1 to diameter according to above-mentioned application method is 3
Centimetre, with a thickness of on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometer and is tested, emit light
Spectrum such as the curve 1 in attached drawing 1.
After test, above-mentioned potsherd is put into Muffle furnace, is sintered 30 minutes at 750 degrees c, it is naturally cold after taking-up
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometer and is tested, emission spectrum such as attached drawing 1
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 26%, illustrates accumulating type noctilucence of the invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 2
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In in 1000 DEG C of 3 hours of sintering, obtain forerunner's glass;Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made;Wherein, the parent glaze is by 42
The B of mass parts2O3, 3 mass parts ZrO2, 12 mass parts TeO2, the ZnO of 17 mass parts, 24 mass parts Na2O2, 7 mass parts
Al2O3With the La of 3 mass parts2O3It is prepared.
2) by 1) resulting parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing, wherein by mass, SrAl2O4:
Eu2+,Dy3+And the ratio of parent glaze is 1:3.Curve 2 in its emission spectrum such as attached drawing 1.
Brushing accumulating type luminous glaze glass ceramic material made from embodiment 2 to diameter according to above-mentioned application method is 3
Centimetre, with a thickness of on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometer and is tested, emit light
Spectrum such as the curve 1 in attached drawing 2.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometer and is tested, emission spectrum such as attached drawing 2
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 17%, illustrates accumulating type noctilucence of the invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 3
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In in 1000 DEG C of 3 hours of sintering, obtain forerunner's glass;Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made;Wherein, the parent glaze is by 46
The B of mass parts2O3, 4 mass parts ZrO2, 17 mass parts TeO2, the ZnO of 18 mass parts, 26 mass parts Na2O2, 8 mass parts
Al2O3With the La of 4 mass parts2O3It is prepared.
2) by 1) resulting parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing, wherein by mass, SrAl2O4:
Eu2+,Dy3+And the ratio of parent glaze is 1:3.Curve 3 in its emission spectrum such as attached drawing 1.
Brushing accumulating type luminous glaze glass ceramic material made from embodiment 1 to diameter according to above-mentioned application method is 3
Centimetre, with a thickness of on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometer and is tested, emit light
Spectrum such as the curve 1 in attached drawing 3.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometer and is tested, emission spectrum such as attached drawing 3
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 11%, illustrates accumulating type noctilucence of the invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 4
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In in 1000 DEG C of 3 hours of sintering, obtain forerunner's glass;Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It carries out ball milling 6 hours, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made;Wherein, the parent glaze is by 49
The B of mass parts2O3, 5 mass parts ZrO2, 19 mass parts TeO2, the ZnO of 19 mass parts, 28 mass parts Na2O2, 9 mass parts
Al2O3With the La of 5 mass parts2O3It is prepared.
2) by 1) resulting parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get the accumulating type luminous glaze glass ceramic material for arriving the low temperature of glaze firing, wherein by mass, SrAl2O4:
Eu2+,Dy3+And the ratio of parent glaze is 1:3.Curve 4 in its emission spectrum such as attached drawing 1.
Brushing accumulating type luminous glaze glass ceramic material made from embodiment 1 to diameter according to above-mentioned application method is 3
Centimetre, with a thickness of on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometer and is tested, emit light
Spectrum such as the curve 1 in attached drawing 4.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometer and is tested, emission spectrum such as attached drawing 4
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 73%, illustrates accumulating type noctilucence of the invention
Glaze glass ceramic material can still shine after oversintering,
By above-mentioned test result, it is found that accumulating type luminous glaze glass ceramic material of the invention is by low temperature, (450-500 is taken the photograph
Family name's degree) it is sintered, accumulating type luminous glaze glass made of the accumulating type luminous glaze glass ceramic material by the low temperature of glaze firing
Ceramic coating, accumulating type luminous glaze glass ceramic coating can also continue to shine at after high temperature sintering (500 DEG C).
Illustrative description has been done to the present invention above, it should explanation, the case where not departing from core of the invention
Under, any simple deformation, modification or other skilled in the art can not spend the equivalent replacement of creative work equal
Fall into protection scope of the present invention.