CN103643773B - One is photic stores light ceramic brick and production method thereof - Google Patents

One is photic stores light ceramic brick and production method thereof Download PDF

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Publication number
CN103643773B
CN103643773B CN201310672431.8A CN201310672431A CN103643773B CN 103643773 B CN103643773 B CN 103643773B CN 201310672431 A CN201310672431 A CN 201310672431A CN 103643773 B CN103643773 B CN 103643773B
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Prior art keywords
photic
light
temperature frit
frit
accumulating powder
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CN103643773A (en
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张缇
周雅琴
刘俊荣
沈琳
封珍
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Jingdezhen Oushennuo Ceramic Co ltd
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Foshan Oceano Ceramics Co Ltd
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Abstract

The invention discloses and a kind of photicly store light ceramic brick and production method thereof, photic light-storing material is made photic luminescence glass layer through printing or distributing technique by ceramic biscuit, and can present multiple color in the dark, persistence is long.This technique can adopt serigraphy or distributing technique, can change floral designs at any time, and the toning of cooperation colorant, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.Method disclosed by the invention, solves the problem of existing photic light-storing material abrasion performance, weatherability, chemical resistance difference.

Description

One is photic stores light ceramic brick and production method thereof
Technical field
The invention belongs to the preparation field of architectural pottery product, be specifically related to a kind of photicly store light ceramic brick and production method thereof.
Background technology
Photic light-storing material is also called light storage type self luminous material, on-radiation light-storing material, non-transformer self-luminescent material etc.This material is initiatively inhaled and is stored the visible rays such as sunshine, light, ultraviolet light, veiling glare after 5 ~ 10 minutes, just can continuous illumination 6-8 hour in the dark, and can according to actual needs, make it send the multiple colouramas such as red, green, blue, Huang, purple.Because its distinctive high brightness, fast extinction, length store the excellent physicochemical properties such as light, making it be widely used in the every field such as architectural decoration, communications and transportation, security against fire, electronic communication, electric apparatus, instrument and meter, petrochemical industry, subway tunnel, printing printing and dyeing, advertising board, bullion, is 21 century extremely rising decorative hair luminescent material.
With the mark that photic light-storing material is made, road warning markers, prohibitory sign, Warning Mark, tourist district's mark, road construction safety sign and facility, changeable-message sign can be widely used in, people can clearly recognize in the weather of dark, foggy, bad weather, reduce the incidence of traffic accident, make the guiding of highway communication more convenient, thoughtful.Photic light-storing material is a kind of luminescent material of Intelligent energy-saving, its not electricity consumption, and equipment that need not be complicated, does not generate heat, can not cause fire, utilize the sunlight on daytime and the light at night to store light; Night automatic luminous, completely without manual operation.
The photic light-storing material great majority employing used for safety sign on the market at present contains the resin paste of transparent resins composition and light-storage luminant pigment ingredient and forms light-storage luminant layer, the transparent resins composition of 95% weight of total amount is coordinated in resin paste, above-mentioned material is as the use such as mark of road, and abrasion performance, weatherability, chemical resistance are all poor.
Summary of the invention
In view of the deficiencies in the prior art, the object of the present invention is to provide and a kind of photicly store light ceramic brick and production method thereof, be intended to the problem solving existing photic light-storing material abrasion performance, weatherability, chemical resistance difference.
For achieving the above object, the technical solution used in the present invention is as follows:
One is photic stores light ceramic brick, and photic light-storing material is made photic luminescence glass layer through printing or distributing technique by ceramic biscuit, and can present multiple color in the dark, persistence is long.
Described photic luminescence glass layer, wherein, if by typography, then fills a prescription by mass percentage, comprise the photic light-accumulating powder of 10 ~ 30%, 10 ~ 30% high temperature frit, the glaze stain of 0 ~ 1% and the stamp-pad ink of 40 ~ 60%; If press distributing technique, then fill a prescription by mass percentage, comprise the photic light-accumulating powder of 10 ~ 50%, the low temperature frit of 60 ~ 80% and the glaze stain of 0 ~ 1%.
Wherein, described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, and be prepared from by rare earth activators doping matrix material, matrix material is specially Sr 4a1 4o 25, SrAl 2o 4, Sr 2mgSi 2o 7, CaA1 2o 4, CaTiO 3in one or more combination.
Wherein, rare earth activators comprises Eu 2+, Dy 3+, Nd 3+, Ce 3+, Pr 3+, Tb 3+, Yb 2+in one or more combination.
Wherein, the fineness of described high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order.
The present invention discloses a kind of photic process storing light ceramic brick product, this technique can adopt serigraphy or distributing technique, can change floral designs at any time, the toning of cooperation colorant, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.
Mainly comprise the steps:
(1) 800 mesh sieves are crossed by by the photic light-accumulating powder taken of filling a prescription;
(2) if by typography, take high temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, take low temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3) if by typography, the slip prepared is crossed 80 orders and lead to reticulated printing on ceramic biscuit; If press distributing technique, mixed frit is crossed 80 orders and lead to screen cloth material on ceramic biscuit;
(4) in adobe, one deck low temperature frit is executed again;
(5) burn till through 850-950 DEG C of kiln after, edging polishing.
beneficial effect
1, photic light-storing material is covered on ceramic body as glass composite bed, the product made compared to resinae product on the market, more wear-resisting, chemical resistance, longer service life.
2, adopt ceramic process to produce, technology controlling and process is easy, can be used for producing in enormous quantities.
3, adopt frit serigraphy or distributing technique, can change floral designs at any time, the toning of cooperation colorant, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.
Accompanying drawing explanation
Fig. 1 is the rear-earth-doped photic process chart storing light ceramic brick and prepare.
Detailed description of the invention
One is photic stores light ceramic brick, and photic light-storing material is made photic luminescence glass layer through printing or distributing technique by ceramic biscuit.
Described photic luminescence glass layer, wherein, if by typography, then fills a prescription by mass percentage, comprise the photic light-accumulating powder of 10 ~ 30%, 10 ~ 30% high temperature frit, the glaze stain of 0 ~ 1% and the stamp-pad ink of 40 ~ 60%; If press distributing technique, then fill a prescription by mass percentage, comprise the photic light-accumulating powder of 10 ~ 50%, the low temperature frit of 60 ~ 80% and the glaze stain of 0 ~ 1%.
Wherein, described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, and be prepared from by rare earth activators doping matrix material, matrix material is specially Sr 4a1 4o 25, SrAl 2o 4, Sr 2mgSi 2o 7, CaA1 2o 4, CaTiO 3in one or more combination.
Wherein, rare earth activators comprises Eu 2+, Dy 3+, Nd 3+, Ce 3+, Pr 3+, Tb 3+, Yb 2+in one or more combination.
Wherein, the fineness of described high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order.
The present invention discloses a kind of photic process storing light ceramic brick, comprise the steps:
(1) 800 mesh sieves are crossed by by the photic light-accumulating powder taken of filling a prescription;
(2) if by typography, take high temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, take low temperature frit and glaze stain by formula, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3) if by typography, the slip prepared is crossed 80 orders and lead to reticulated printing on ceramic biscuit; If press distributing technique, mixed frit is crossed 80 orders and lead to screen cloth material on ceramic biscuit;
(4) in adobe, one deck low temperature frit is executed again;
(5) burn till through 850-950 DEG C of kiln after, edging polishing.
Photic light-storing material is made photic luminescence glass layer through printing or distributing technique by process of the present invention on ceramic biscuit, and can present multiple color in the dark, persistence is long.This technique can adopt serigraphy or distributing technique, can change floral designs at any time, and the toning of cooperation colorant, male and female mold more can present the multiple decorative artistic effect that third dimension is strong, pattern level is abundant.Method disclosed by the invention, solves the problem of existing photic light-storing material abrasion performance, weatherability, chemical resistance difference.
Embodiment 1:
By mass percentage, by the Sr of 15% 4a1 4o 25doping Eu 2+, Dy 3+energy-saving luminous material and 15% CaA1 2o 4doping Eu 2+, Nd 3+energy-saving luminous material crosses 800 mesh sieves together, mixes with the low temperature frit (fineness is 70-100 order) of 70%, crosses 80 mesh sieves afterwards.Get ceramic biscuit, mixed frit is crossed 80 orders and lead to screen cloth material on ceramic biscuit, then execute one deck low temperature frit.After burn till through 850 DEG C of kilns, edging polishing, finished product be send out coloured light in the dark sky blue store light ceramic brick, reach 6.5 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, not easily aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Embodiment 2:
By mass percentage, by the Sr of 25% 2mgSi 2o 7energy-saving luminous material crosses 800 mesh sieves, crosses 80 mesh sieves, then adds the stamp-pad ink of 50%, stir after the high temperature frit (fineness is 100-200 order) with 25% mixes.Mixed slip is crossed 80 orders and lead to reticulated printing on ceramic biscuit, then execute one deck low temperature frit.After burn till through 950 DEG C of kilns, edging polishing, finished product be turn blue green light in the dark store light ceramic brick, reach 8 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, not easily aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Embodiment 3:
By mass percentage, by the SrAl of 30% 2o 4doping Eu 2+, Dy 3+energy-saving luminous material crosses 800 mesh sieves, mixes with the low temperature frit (fineness is 70-100 order) of 70%.The golden yellow colorant of additional 0.3%, the Red pigment of 0.3%, mix respectively.Get ceramic biscuit, mixed frit is crossed respectively 80 order flower nets, through secondary material distributing on ceramic biscuit.After cloth, then execute one deck low temperature frit, after burn till through 900 DEG C of kilns, edging polishing.Finished product is store light ceramic brick with the colour of floral designs, reaches 7 hours persistence.This Ceramic Tiles has 4 grades of abrasion resistancies, good weatherability properties, not easily aging, strong resistance to chemical corrosion, 18%(V/V) hydrochloric acid---GHA level, 100g/L potassium hydroxide---GHA level.
Last it is noted that obviously, above-described embodiment is only for example of the present invention is clearly described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.And thus the apparent change of amplifying out or variation be still among protection scope of the present invention.

Claims (2)

1. photicly store a light ceramic brick, it is characterized in that: on ceramic biscuit, photic light-storing material is made photic luminescence glass layer by printing or distributing technique;
When adopting typography, the raw material mass mixture ratio of described photic luminescence glass layer, comprise the photic light-accumulating powder of 10 ~ 30%, 10 ~ 30% high temperature frit, the glaze stain of 0 ~ 1% and the stamp-pad ink of 40 ~ 60%; Adopt distributing technique, the raw material mass mixture ratio of described photic luminescence glass layer, comprises the photic light-accumulating powder of 10 ~ 50%, the low temperature frit of 60 ~ 80% and the glaze stain of 0 ~ 1%;
Described photic light-accumulating powder is rear-earth-doped high temperature long-afterglow material, is prepared from by rare earth activators doping matrix material,
Wherein, described matrix material is specially Sr 4a1 4o 25, SrAl 2o 4, Sr 2mgSi 2o 7, CaA1 2o 4, CaTiO 3in one or more combination;
Described rare earth activators comprises Eu 2+, Dy 3+, Nd 3+, Ce 3+, Pr 3+, Tb 3+, Yb 2+in one or more combination.
2. the photic production method storing light ceramic brick as claimed in claim 1, is characterized in that: comprise the steps,
(1) the photic light-accumulating powder taken by pulp furnish is sieved;
(2) if by typography, take high temperature frit and glaze stain by pulp furnish, after mixing with photic light-accumulating powder, cross 80 mesh sieves, add stamp-pad ink, stir; If press distributing technique, take low temperature frit and glaze stain by pulp furnish, after mixing with photic light-accumulating powder, cross 80 mesh sieves;
(3) if by typography, the slip prepared is crossed logical reticulated printing on ceramic biscuit; If press distributing technique, mixed frit is crossed logical screen cloth material on ceramic biscuit;
(4) in adobe, one deck low temperature frit is executed again;
(5) burn till through kiln after, edging polishing;
Photic light-accumulating powder in described step (1) crosses grit number: 800 orders;
In described step (2), the fineness of high temperature frit is 100-200 order; The fineness of low temperature frit is 70-100 order;
The order number crossing logical reticulated printing or cloth in described step (3) is: 80 orders;
In described step (5), firing temperature is 850-950 DEG C.
CN201310672431.8A 2013-12-12 2013-12-12 One is photic stores light ceramic brick and production method thereof Active CN103643773B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108423991B (en) * 2015-12-30 2020-01-03 潮州市金酉陶瓷科技有限公司 Energy storage type luminous glaze glass ceramic material
CN112010673A (en) * 2020-10-26 2020-12-01 佛山市东鹏陶瓷发展有限公司 Luminous ceramic tile and preparation method thereof
CN113845306B (en) * 2021-10-09 2023-03-28 广东松发陶瓷股份有限公司 Ceramic color glaze material for underglaze transfer printing decoration, daily ceramic utensil and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1197043A (en) * 1998-04-27 1998-10-28 况学成 Luminous printing glaze and prodn. method of printed luminous glazed tile
CN1408679A (en) * 2002-08-28 2003-04-09 佛山欧神诺陶瓷有限公司 Method for producing pattern permeating ceramic tile
GB2404379A (en) * 2003-07-12 2005-02-02 Andrew David Curtis Method of producing a photoluminescent mosaic glass tile
CN1609027A (en) * 2003-10-20 2005-04-27 梁锋 High temperature luminous glazing and its production process and application in luminous glazed tile
CN101215189A (en) * 2008-01-21 2008-07-09 尤晴波 Outdoor cold-light source (luminous brick, noctilucent brick, fluorescent brick)
KR20090007342U (en) * 2008-01-16 2009-07-21 김진철 A Photo Luminescence Tile For Safety Refuge Mark

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1197043A (en) * 1998-04-27 1998-10-28 况学成 Luminous printing glaze and prodn. method of printed luminous glazed tile
CN1408679A (en) * 2002-08-28 2003-04-09 佛山欧神诺陶瓷有限公司 Method for producing pattern permeating ceramic tile
GB2404379A (en) * 2003-07-12 2005-02-02 Andrew David Curtis Method of producing a photoluminescent mosaic glass tile
CN1609027A (en) * 2003-10-20 2005-04-27 梁锋 High temperature luminous glazing and its production process and application in luminous glazed tile
KR20090007342U (en) * 2008-01-16 2009-07-21 김진철 A Photo Luminescence Tile For Safety Refuge Mark
CN101215189A (en) * 2008-01-21 2008-07-09 尤晴波 Outdoor cold-light source (luminous brick, noctilucent brick, fluorescent brick)

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Address after: 528138 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan

Patentee after: FOSHAN OCEANO CERAMICS Co.,Ltd.

Address before: 528137 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan

Patentee before: OCEANO CERAMICS Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20231228

Address after: 333000 Jingdezhen Ceramic Industrial Park, Fuliang County, Jingdezhen City, Jiangxi Province

Patentee after: JINGDEZHEN OUSHENNUO CERAMIC CO.,LTD.

Address before: 528138 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan

Patentee before: FOSHAN OCEANO CERAMICS Co.,Ltd.