CN107032617A - A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application - Google Patents
A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application Download PDFInfo
- Publication number
- CN107032617A CN107032617A CN201710220637.5A CN201710220637A CN107032617A CN 107032617 A CN107032617 A CN 107032617A CN 201710220637 A CN201710220637 A CN 201710220637A CN 107032617 A CN107032617 A CN 107032617A
- Authority
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- China
- Prior art keywords
- coat enamel
- illumination effect
- ceramic cover
- powder
- cover
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Abstract
The invention discloses a kind of ceramic cover-coat enamel with illumination effect, it is made up of the following raw material component by weight percentage：Clear frit powder 15 ~ 40%, luminescent powder 15 ~ 40%, Suzhou soil 3 ~ 5%, feldspar 3 ~ 7%, glass dust 4 ~ 8%, zircon powder 3 ~ 5%, stamp-pad ink 50 ~ 70%, sodium tripolyphosphate 0.1 ~ 0.2%, aluminium-magnesium silicate 0.05 ~ 0.15% and sodium carboxymethylcellulose 0.2 ~ 0.6%.The present invention is matched by adjusting the selection of raw material components and optimizing it, using the radiationless material of environmental protection, not only resistance to chemical corrosion is excellent but also has poultry energy lighting function concurrently for its cover-coat enamel prepared, the self-luminous at dark after luminous energy can be absorbed, enrich decorative artistic effect of the ceramics preparation in luminance shortage, its glaze exquisiteness, texture are good simultaneously, it is ensured that the clean mark of decorative pattern, it is adaptable to the layout of various different-styles.Preparation technology of the present invention is simple, and production efficiency is high, without increasing other equipment, the sintering curve matching existing calcining system of kiln, without adjustment.
Description
Technical field
The present invention relates to ceramic glaze field, more particularly to a kind of ceramic cover-coat enamel and its preparation side with illumination effect
Method and application.
Background technology
Traditional ceramic cover-coat enamel is main based on common white glaze, although beneficial to realizing pattern decorative, but prepared pottery
Ceramic products are only capable of showing the Art Design pattern on surface in the case of light, and in the case of luminance shortage or when dark
It is that can not show the original decorative effect of product, without new intention and development, does not adapt to current culture and arts development
And pursuit of the people to innovation art.If preparing a kind of ceramic cover-coat enamel with illumination effect, Ceramic Tiles can be made in the dark
Pattern is presented, the problem of pattern can not be appreciated by solving its night, necessarily make the excellent decoration effect of Ceramic Tiles.But luminescent powder should
For light cover-coat enamel when, because luminescent powder particle specific gravity is larger, therefore there is the problem of suspending difficult, present invention aims at system
For going out, suspension is good, the good luminous cover-coat enamel of noctilucence performance.
The content of the invention
It is an object of the invention to the decoration monotonicity for the ceramic cover-coat enamel that breaks traditions, ceramic is enriched at dark place or bright
Decorative effect in the case of degree is not enough, and a kind of ceramic cover-coat enamel with illumination effect and preparation method thereof is provided.
The technical solution used in the present invention is：A kind of ceramic cover-coat enamel with illumination effect, it is by weight percentage
It is made up of the following raw material component：Clear frit powder 15 ~ 40%, luminescent powder 15 ~ 40%, Suzhou soil 3 ~ 5%, feldspar 3 ~ 7%, glass dust 4 ~
8%th, zircon powder 3 ~ 5%, stamp-pad ink 35 ~ 50%, sodium tripolyphosphate 0.1 ~ 0.2%, aluminium-magnesium silicate 0.05 ~ 0.15% and carboxymethyl cellulose
Plain sodium 0.2 ~ 0.6%.
As the further improvement of such scheme, the clear frit powder is made up of following component by weight percentage：
55~72% SiO2, 5~15% Al2O3, 1~8% CaO, 5~12% B2O3, 1~7% BaO, 0~4% Na2O、
0~4% K2The O and PbO less than 0.01%.
As the further improvement of such scheme, the luminescent powder is prepared from by rare earth activators doping matrix material
's.Wherein, the rare earth element in the rare earth activators is selected from Eu2+、Eu3+、Dy3+、Pr3+、Nd3+、Sm3+And Ho3+In at least
It is a kind of；Described matrix material is selected from Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、
SrSiO3And CaTiO3In one of which.
As the further improvement of such scheme, the fineness of the clear frit powder is 250 ~ 300 mesh.
As the further improvement of such scheme, the fineness of the luminescent powder is 200 ~ 300 mesh.
As the further improvement of such scheme, the stamp-pad ink selects aqueous 80% stamp-pad ink.
A kind of preparation method of the ceramic cover-coat enamel as described above with illumination effect, it is comprised the technical steps that：It is first
First clear frit powder and luminescent powder are well mixed according to the weight percentage of raw materials, remaining raw material components are then added, stirred
0.5 ~ 1h, obtains glaze slip.
A kind of application of the ceramic cover-coat enamel as described above with illumination effect, is to be used for charity in ground glaze layer with carrying figure
Between the glazed colour layer of case, the cover coat with illumination effect is formed.
The beneficial effects of the invention are as follows：The present invention is matched by adjusting the selection of raw material components and optimizing it, using green
The radiationless material of environmental protection, not only resistance to chemical corrosion is excellent but also has poultry energy lighting function concurrently for its cover-coat enamel prepared,
The self-luminous at dark after luminous energy can be absorbed, decorative artistic effect of the ceramics preparation in luminance shortage is enriched, while its glaze
Face is fine and smooth, texture is good, it is ensured that the clean mark of decorative pattern, it is adaptable to the layout of various different-styles.The present invention
Preparation technology is simple, and production efficiency is high, without increasing other equipment, the sintering curve matching existing calcining system of kiln, without adjusting
It is whole.
Embodiment
The present invention is specifically described with reference to embodiment, in order to art personnel to the present invention
Understand.It is necessary that herein the present invention will be further described it is emphasized that embodiment is only intended to, it is impossible to be interpreted as to this
The limitation of invention protection domain, art person skilled in the art, the non-intrinsically safe made according to foregoing invention content to the present invention
The modifications and adaptations of property, should still fall within protection scope of the present invention.Simultaneously following mentioned raw materials are unspecified, are
Commercially available prod；The processing step or preparation method not referred in detail be processing step known to a person skilled in the art or
Preparation method.
Embodiment 1
A kind of ceramic cover-coat enamel with illumination effect, its raw material components is by weight percentage：The clear frit powder of 250 mesh
15%, the luminescent powder 30% of 300 mesh, Suzhou soil 3%, feldspar 3%, glass dust 4%, zircon powder 3%, aqueous 80% stamp-pad ink 41.05%,
Sodium tripolyphosphate 0.2%, aluminium-magnesium silicate 0.15%, sodium carboxymethylcellulose 0.6%.
Wherein, clear frit powder is made up of following component by weight percentage：55~72% SiO2, 5~15%
Al2O3, 1~8% CaO, 5~12% B2O3, 1~7% BaO, 0~4% Na2O, 0~4% K2O and less than 0.01%
PbO；Luminescent powder is by containing Eu2+、Eu3+、Dy3+And Pr3+Rare earth activators doping matrix material be prepared from, it is and described
Matrix material may be selected from Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、SrSiO3With
CaTiO3In one of which.
Preparation method：Clear frit powder and luminescent powder are well mixed first, remaining raw material components are then added, finally
Glaze slip is stirred into, mixing time is 60min, obtains finished product.
Embodiment 2
A kind of ceramic cover-coat enamel with illumination effect, its raw material components is by weight percentage：The clear frit powder of 300 mesh
35%, the luminescent powder 15% of 200 mesh, Suzhou soil 3%, feldspar 3%, glass dust 4%, zircon powder 3%, aqueous 80% stamp-pad ink 36.05%,
Sodium tripolyphosphate 0.2%, aluminium-magnesium silicate 0.15%, sodium carboxymethylcellulose 0.6%.
Wherein, clear frit powder is made up of following component by weight percentage：55~72% SiO2, 5~15%
Al2O3, 1~8% CaO, 5~12% B2O3, 1~7% BaO, 0~4% Na2O, 0~4% K2O and less than 0.01%
PbO；Luminescent powder is by containing Pr3+, Nd3+, Sm3+And Ho3+Rare earth activators doping matrix material be prepared from, it is and described
Matrix material may be selected from Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、SrSiO3With
CaTiO3In one of which.
Preparation method：Clear frit powder and luminescent powder are well mixed first, remaining raw material components are then added, finally
Glaze slip is stirred into, mixing time is 30min, obtains finished product.
Embodiment 3
A kind of ceramic cover-coat enamel with illumination effect, its raw material components is by weight percentage：The clear frit powder of 280 mesh
15%, the luminescent powder 18% of 250 mesh, Suzhou soil 5%, feldspar 7%, glass dust 8%, zircon powder 5%, aqueous 80% stamp-pad ink 41.65%,
Sodium tripolyphosphate 0.1%, aluminium-magnesium silicate 0.05%, sodium carboxymethylcellulose 0.2%.
Wherein, clear frit powder is made up of following component by weight percentage：55~72% SiO2, 5~15%
Al2O3, 1~8% CaO, 5~12% B2O3, 1~7% BaO, 0~4% Na2O, 0~4% K2O and less than 0.01%
PbO；Luminescent powder is by containing Eu3+, Dy3+, Pr3+, Nd3+And Sm3+Rare earth activators doping matrix material be prepared from, and
Described matrix material may be selected from Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、SrSiO3
And CaTiO3In one of which.
Preparation method：Clear frit powder and luminescent powder are well mixed first, remaining raw material components are then added, finally
Glaze slip is stirred into, mixing time is 45min, obtains finished product.
Embodiment 4
A kind of ceramic cover-coat enamel with illumination effect, its raw material components is by weight percentage：The clear frit powder of 300 mesh
18.65%, the luminescent powder 15% of 200 mesh, Suzhou soil 4%, feldspar 4%, glass dust 4%, zircon powder 4%, aqueous 80% stamp-pad ink 50%,
Sodium tripolyphosphate 0.1%, aluminium-magnesium silicate 0.05%, sodium carboxymethylcellulose 0.2%.
Wherein, clear frit powder is made up of following component by weight percentage：55~72% SiO2, 5~15%
Al2O3, 1~8% CaO, 5~12% B2O3, 1~7% BaO, 0~4% Na2O, 0~4% K2O and less than 0.01%
PbO；Luminescent powder is by containing Eu3+, Dy3+And Sm3+Rare earth activators doping matrix material be prepared from, and described matrix
Material may be selected from Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、SrSiO3And CaTiO3
In one of which.
Preparation method：Clear frit powder and luminescent powder are well mixed first, remaining raw material components are then added, finally
Glaze slip is stirred into, mixing time is 50min, obtains finished product.
Above-described embodiment is the preferred embodiments of the present invention, all with similar technique of the invention and the equivalence changes made,
The protection category of the present invention all should be belonged to.
Claims (10)
1. a kind of ceramic cover-coat enamel with illumination effect, it is characterised in that be made up of by weight percentage the following raw material component：
Clear frit powder 15 ~ 40%, luminescent powder 15 ~ 40%, Suzhou soil 3 ~ 5%, feldspar 3 ~ 7%, glass dust 4 ~ 8%, zircon powder 3 ~ 5%, print
Oil 35 ~ 50%, sodium tripolyphosphate 0.1 ~ 0.2%, aluminium-magnesium silicate 0.05 ~ 0.15% and sodium carboxymethylcellulose 0.2 ~ 0.6%.
2. a kind of ceramic cover-coat enamel with illumination effect according to claim 1, it is characterised in that the clear frit powder
It is made up of by weight percentage following component：55~72% SiO2, 5~15% Al2O3, 1~8% CaO, 5~12%
B2O3, 1~7% BaO, 0~4% Na2O, 0~4% K2The O and PbO less than 0.01%.
3. a kind of ceramic cover-coat enamel with illumination effect according to claim 1, it is characterised in that：The luminescent powder be by
Rare earth activators doping matrix material is prepared from.
4. a kind of ceramic cover-coat enamel with illumination effect according to claim 3, it is characterised in that：The rare earth activators
In rare earth element be selected from Eu2+、Eu3+、Dy3+、Pr3+、Nd3+、Sm3+And Ho3+At least one of.
5. a kind of ceramic cover-coat enamel with illumination effect according to claim 3, it is characterised in that：Described matrix material is selected
From Sr4A114O25、SrAl2O4、Sr2MgSi2O7、Ca2MgSi2O7、CaA12O4、CaZrSi2O7、SrSiO3And CaTiO3In wherein
It is a kind of.
6. a kind of ceramic cover-coat enamel with illumination effect according to claim 1 or 2, it is characterised in that：It is described transparent molten
The fineness of block powder is 250 ~ 300 mesh.
7. a kind of ceramic cover-coat enamel with illumination effect according to claim 1 or 3, it is characterised in that：The luminescent powder
Fineness be 200 ~ 300 mesh.
8. a kind of ceramic cover-coat enamel with illumination effect according to claim 1, it is characterised in that：The stamp-pad ink, which is selected, to be contained
The stamp-pad ink of water 80%.
9. a kind of preparation method of ceramic cover-coat enamel with illumination effect as described in any one of claim 1 ~ 8, its feature exists
In comprising the technical steps that：Clear frit powder and luminescent powder are well mixed according to the weight percentage of raw materials first, Ran Houjia
Enter remaining raw material components, stir 0.5 ~ 1h, obtain glaze slip.
10. a kind of application of ceramic cover-coat enamel with illumination effect as described in any one of claim 1 ~ 8, it is characterised in that：
The cover-coat enamel is used for charity in ground glaze layer and between figuratum glazed colour layer, forms the cover coat with illumination effect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710220637.5A CN107032617A (en) | 2017-04-06 | 2017-04-06 | A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710220637.5A CN107032617A (en) | 2017-04-06 | 2017-04-06 | A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application |
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| CN201710220637.5A Pending CN107032617A (en) | 2017-04-06 | 2017-04-06 | A kind of ceramic cover-coat enamel with illumination effect and its preparation method and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107651949A (en) * | 2017-09-30 | 2018-02-02 | 佛山欧神诺陶瓷股份有限公司 | A kind of luminescent ceramic glazed tile and preparation method thereof |
| CN109456064A (en) * | 2019-01-04 | 2019-03-12 | 广东金意陶陶瓷集团有限公司 | The preparation method of light-weight brick formula and preparation method thereof and functional light-weight brick |
| CN111792947A (en) * | 2020-06-22 | 2020-10-20 | 佛山欧神诺陶瓷有限公司 | Foamed ceramic with fluorescent decorative effect and preparation method thereof |
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Cited By (4)
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| CN107651949A (en) * | 2017-09-30 | 2018-02-02 | 佛山欧神诺陶瓷股份有限公司 | A kind of luminescent ceramic glazed tile and preparation method thereof |
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| CN109456064B (en) * | 2019-01-04 | 2021-11-09 | 广东金意陶陶瓷集团有限公司 | Light brick formula, preparation method thereof and preparation method of functional light brick |
| CN111792947A (en) * | 2020-06-22 | 2020-10-20 | 佛山欧神诺陶瓷有限公司 | Foamed ceramic with fluorescent decorative effect and preparation method thereof |
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| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: 528137 fan Lake Industrial Zone, Leping Town, Sanshui District, Guangdong, Foshan Applicant after: Foshan Oushennuo Ceramic Co., Ltd. Address before: 528000 fan Lake Industrial Park, Leping Town, Sanshui District, Foshan, Guangdong Applicant before: Foshan Oceano Ceramic Co., Ltd. |
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Application publication date: 20170811 |
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| RJ01 | Rejection of invention patent application after publication |