CN105503274B - The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing - Google Patents
The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing Download PDFInfo
- Publication number
- CN105503274B CN105503274B CN201511031738.5A CN201511031738A CN105503274B CN 105503274 B CN105503274 B CN 105503274B CN 201511031738 A CN201511031738 A CN 201511031738A CN 105503274 B CN105503274 B CN 105503274B
- Authority
- CN
- China
- Prior art keywords
- glaze
- mass parts
- accumulating type
- ceramic material
- low temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses the accumulating type luminous glaze glass ceramic materials and preparation method and applications of a kind of low temperature of glaze firing, and the accumulating type luminous glaze glass ceramic material is by SrAl2O4:Eu2+,Dy3+It is prepared with parent glaze；Wherein, the parent glaze by 35 50 mass parts B2O3, 25 mass parts ZrO2, 5 20 mass parts TeO2, 15 20 mass parts ZnO, the Na of 20 30 mass parts2O2, 5 10 mass parts Al2O3With the La of 25 mass parts2O3It is prepared, the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is sintered by low temperature (450 500 degrees Celsius), by accumulating type luminous glaze glass ceramic coating made of the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, accumulating type luminous glaze glass ceramic coating can also continue to shine after 750 DEG C of high temperature sinterings.
Description
Technical field
The invention belongs to new material technology field, a kind of accumulating type luminous glaze glass of low temperature of glaze firing is related in particular to
Ceramic material and preparation method and applications.
Background technology
Noctilucent safety fire-fighting made of Noctilucent material identifies, and evacuation side is indicated with obvious word, distinct arrow mark
Evacuation safety when fire occurs to, effective guarantee.Currently used Noctilucent safety mark is with luminescent coating and plastics system
, these security against fires for containing organic components mark burnt in a fire by open fire after moment will deform, turn to dust and ashes,
It loses luminous.Lose the effect for guiding correct escape route soon in a fire, it is impossible to play protection people's life safety
Effect.In order to solve this technical problem, patent (CN 104003757A) discloses a kind of making side of Luminous fire mark
Method, with transparent polishing dry granular and luminescent powder silk-screen into luminous glaze glass ceramic material pattern in ceramic plane, but its use it is saturating
The glaze firing temperature on bright polishing dry granular basis is higher (1200 degrees Celsius), at such high temperatures, Noctilucent material easily with base
Plinth glaze reacts, and influences the luminous intensity of noctilucence powder material, so as to influence the illumination effect of Noctilucent safety mark.
The content of the invention
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of accumulating type luminous glaze glass of low temperature of glaze firing
Ceramic material and preparation method and applications.
The purpose of the present invention is what is be achieved by following technical proposals.
The accumulating type luminous glaze glass ceramic material of a kind of low temperature of glaze firing, by SrAl2O4:Eu2+,Dy3+With parent glaze system
It is standby to form, by mass, SrAl2O4:Eu2+,Dy3+Ratio with parent glaze is 1：3；Wherein, the parent glaze is by 35-50 mass parts
B2O3, 2-5 mass parts ZrO2, 5-20 mass parts TeO2, 15-20 mass parts ZnO, 20-30 mass parts Na2O2、5-
The Al of 10 mass parts2O3With the La of 2-5 mass parts2O3It is prepared.
In the above-mentioned technical solutions, the B2O3For 40-45 mass parts, ZrO2For 3-4 mass parts, TeO2For 10-15 mass
Part, ZnO are 16-19 mass parts, Na2O2For 22-27 mass parts, Al2O3For 6-9 mass parts and La2O3For 3-6 mass parts.
A kind of preparation method of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, gives as steps described below
To prepare：
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In 900-1200 DEG C be sintered 2-4 hour, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball
When progress ball milling 1-12 is small in grinding machine, is sieved after ball milling with the sieve of 300-400 mesh, parent glaze powder is made；
2) by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is sintered under 450-500 degrees Celsius
15-45 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
In the above-mentioned technical solutions, by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3Mixing is milled in proportion
Uniformly, it is put into high temperature furnace and is sintered 2-4 hour at 1000-1150 DEG C, obtains forerunner's glass.
In the above-mentioned technical solutions, by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, in 450-
20-30 minutes are sintered under 500 degrees Celsius to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
A kind of application of the accumulating type luminous glaze glass ceramic material of above-mentioned low temperature of glaze firing, by the low temperature of glaze firing
Accumulating type luminous glaze glass ceramic material is mixed with glycerine, after mixing by silk-screen printing, brush or be sprayed on ceramic tile surface
On, accumulating type luminous glaze glass ceramic coating is made, passes through screen printing above the accumulating type luminous glaze glass-ceramic layer
Brush brushes or sprays the basic glaze layer of one layer of covering；The ceramic tile is put into high temperature furnace and is sintered 5-10 points at 450-550 DEG C
Clock.
In the above-mentioned technical solutions, by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerine is 9:
1。
The accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is by (450-500 degrees Celsius) burning of low temperature
It ties, accumulating type luminous glaze glass ceramics made of the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing is applied
Layer, accumulating type luminous glaze glass ceramic coating can also continue to shine after 750 DEG C of high temperature sinterings.
Description of the drawings
Fig. 1 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting after potsherd
Spectrogram；
Fig. 2 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting after potsherd
Spectrogram；
Fig. 3 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting after potsherd
Spectrogram；
Fig. 4 is that the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing of the present invention is brushed to the transmitting after potsherd
Spectrogram.
Specific embodiment
In the present embodiment, raw material B2O3、ZrO2、TeO2、ZnO、Al2O3、Na2O2And La2O3It buys from Aladdin and tries
Agent, wherein, B2O3Article No. is B108406-500g, TeO2Article No. is T103864, and ZnO article No.s are Z111836, Al2O3Article No. is
A140802, La2O3Article No. is L103872, Na2O2Article No. is S100113.Test equipment：F-4600 sepectrophotofluorometer (days
Vertical high and new technology company), 320 nanometers of ultraviolet excitation sample of test in the present embodiment.
SrAl2O4:Eu2+,Dy3+Preparation method：It will be added in strontium carbonate (99.2%), alundum (Al2O3) (99.99%)
Analytically pure Eu2O3, Dy2O3After be uniformly mixed, burnt till when 2 is small in reducing atmosphere at 1300 DEG C, through crush, shone
Material sample.Wherein, by the gauge of substance, strontium carbonate (99.2%), alundum (Al2O3) (99.99%), Eu2O3And Dy2O3Ratio
For 9:10:0.1:0.4.
Application process：The accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing is mixed with glycerine, after mixing
One layer is brushed on ceramic tile surface, accumulating type luminous glaze glass ceramic coating is made, in the accumulating type luminous glaze glass ceramics
Layer the upper surface of is by brushing the basic glaze layer of one layer of covering；The ceramic tile is put into high temperature furnace and is sintered 5-10 points at 450-550 DEG C
Clock, wherein, by mass, the ratio of the accumulating type luminous glaze glass ceramic material and glycerine is 9:1.
In an embodiment of the present invention, 1 mass parts are 1g.
With reference to the accompanying drawings and examples to the present invention low temperature of glaze firing accumulating type luminous glaze glass ceramic material into
Row is described in detail.
Embodiment 1
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It when progress ball milling 6 is small, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made；Wherein, the parent glaze is by 37
The B of mass parts2O3, 2 mass parts ZrO2, 7 mass parts TeO2, 16 mass parts ZnO, the Na of 22 mass parts2O2, 6 mass parts
Al2O3With the La of 2 mass parts2O3It is prepared.
2) by the parent glaze powder and SrAl obtained by 1)2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein, by mass, SrAl2O4:
Eu2+,Dy3+Ratio with parent glaze is 1：3.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometers and is tested, emits light
Curve 1 in spectrum such as attached drawing 1.
After test, above-mentioned potsherd is put into Muffle furnace, is sintered 30 minutes at 750 degrees c, it is naturally cold after taking-up
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 1
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 26%, illustrates the accumulating type noctilucence of the present invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 2
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It when progress ball milling 6 is small, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made；Wherein, the parent glaze is by 42
The B of mass parts2O3, 3 mass parts ZrO2, 12 mass parts TeO2, 17 mass parts ZnO, the Na of 24 mass parts2O2, 7 mass parts
Al2O3With the La of 3 mass parts2O3It is prepared.
2) by the parent glaze powder and SrAl obtained by 1)2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein, by mass, SrAl2O4:
Eu2+,Dy3+Ratio with parent glaze is 1：3.Curve 2 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 2 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometers and is tested, emits light
Curve 1 in spectrum such as attached drawing 2.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 2
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 17%, illustrates the accumulating type noctilucence of the present invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 3
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It when progress ball milling 6 is small, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made；Wherein, the parent glaze is by 46
The B of mass parts2O3, 4 mass parts ZrO2, 17 mass parts TeO2, 18 mass parts ZnO, the Na of 26 mass parts2O2, 8 mass parts
Al2O3With the La of 4 mass parts2O3It is prepared.
2) by the parent glaze powder and SrAl obtained by 1)2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein, by mass, SrAl2O4:
Eu2+,Dy3+Ratio with parent glaze is 1：3.Curve 3 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometers and is tested, emits light
Curve 1 in spectrum such as attached drawing 3.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 3
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 11%, illustrates the accumulating type noctilucence of the present invention
Glaze glass ceramic material can still shine after oversintering,
Embodiment 4
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled in proportion uniformly mixed, is put into high temperature furnace
In 1000 DEG C be sintered 3 hours, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
It when progress ball milling 6 is small, is sieved after ball milling with the sieve of 300 mesh, parent glaze powder is made；Wherein, the parent glaze is by 49
The B of mass parts2O3, 5 mass parts ZrO2, 19 mass parts TeO2, 19 mass parts ZnO, the Na of 28 mass parts2O2, 9 mass parts
Al2O3With the La of 5 mass parts2O3It is prepared.
2) by the parent glaze powder and SrAl obtained by 1)2O4:Eu2+,Dy3+It mixes to uniform, is burnt under 500 degrees Celsius
Knot 25 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing, wherein, by mass, SrAl2O4:
Eu2+,Dy3+Ratio with parent glaze is 1：3.Curve 4 in its emission spectrum such as attached drawing 1.
Accumulating type luminous glaze glass ceramic material made from embodiment 1 is brushed to a diameter of 3 according to above application method
Centimetre, thickness be on 1 millimeter of potsherd, potsherd is put into F-4600 sepectrophotofluorometers and is tested, emits light
Curve 1 in spectrum such as attached drawing 4.
After test, above-mentioned potsherd is put into Muffle furnace, calcination 30 minutes, naturally cold after taking-up at 750 degrees c
But to 20-25 DEG C of room temperature, which is put into F-4600 sepectrophotofluorometers and is tested, emission spectrum such as attached drawing 4
In curve 2.
As seen from the figure, compared to curve 1, the luminous intensity of curve 2 has dropped 73%, illustrates the accumulating type noctilucence of the present invention
Glaze glass ceramic material can still shine after oversintering,
From above-mentioned test result, (450-500 takes the photograph accumulating type luminous glaze glass ceramic material of the invention by low temperature
Family name's degree) it is sintered, by accumulating type luminous glaze glass made of the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing
Ceramic coating, accumulating type luminous glaze glass ceramic coating can also continue to shine at after high temperature sintering (500 DEG C).
Illustrative description has been done to the present invention above, it should explanation, in the situation for the core for not departing from the present invention
Under, any simple deformation, modification or other skilled in the art can not spend the equivalent substitution of creative work equal
Fall into protection scope of the present invention.
Claims (4)
1. the accumulating type luminous glaze glass ceramic material of a kind of low temperature of glaze firing, which is characterized in that by SrAl2O4:Eu2+,Dy3+With
Parent glaze is prepared, by mass, SrAl2O4:Eu2+,Dy3+Ratio with parent glaze is 1：3；Wherein, the parent glaze is by 35-
The B of 50 mass parts2O3, 2-5 mass parts ZrO2, 5-20 mass parts TeO2, 15-20 mass parts ZnO, 20-30 mass parts
Na2O2, 5-10 mass parts Al2O3With the La of 2-5 mass parts2O3It is prepared；The accumulating type luminous glaze glass of low temperature of glaze firing
The preparation method of ceramic material, is prepared as steps described below：
1) by B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled to uniformly mixed, is put into high temperature furnace in proportion
900-1200 DEG C of 2-4 hour of sintering, obtain forerunner's glass；Forerunner's glass machinery is crushed to glass particle, is put into ball mill
When middle progress ball milling 1-12 is small, is sieved after ball milling with the sieve of 300-400 mesh, parent glaze powder is made；
2) by 1) gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, 15- is sintered under 450-500 degrees Celsius
45 minutes to get to the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
2. the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing according to claim 1, which is characterized in that described
B2O3For 40-45 mass parts, ZrO2For 3-4 mass parts, TeO2It is 16-19 mass parts, Na for 10-15 mass parts, ZnO2O2For 22-
27 mass parts, Al2O3For 6-9 mass parts and La2O3For 3-6 mass parts.
3. the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing according to claim 2, which is characterized in that will
B2O3、ZrO2、TeO2、ZnO、Na2O2、Al2O3And La2O3It is milled to uniformly mixed, is put into high temperature furnace in 1000- in proportion
1150 DEG C of 2-4 hours of sintering, obtain forerunner's glass.
4. the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing according to claim 3, which is characterized in that will 1)
Gained parent glaze powder and SrAl2O4:Eu2+,Dy3+It mixes to uniform, is sintered under 450-500 degrees Celsius 20-30 minutes,
Obtain the accumulating type luminous glaze glass ceramic material of the low temperature of glaze firing.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810363487.8A CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
| CN201810363496.7A CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN201711437992.4A CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
| CN201511031738.5A CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
| CN201810363499.0A CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511031738.5A CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
Related Child Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810363487.8A Division CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
| CN201810363499.0A Division CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
| CN201810363496.7A Division CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN201711437992.4A Division CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105503274A CN105503274A (en) | 2016-04-20 |
| CN105503274B true CN105503274B (en) | 2018-06-01 |
Family
ID=55711653
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810363499.0A Pending CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
| CN201711437992.4A Expired - Fee Related CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
| CN201810363496.7A Pending CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
| CN201511031738.5A Expired - Fee Related CN105503274B (en) | 2015-12-30 | 2015-12-30 | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing |
| CN201810363487.8A Active CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810363499.0A Pending CN108516687A (en) | 2015-12-30 | 2015-12-30 | A kind of preparation method of accumulating type luminous glaze glass ceramic material |
| CN201711437992.4A Expired - Fee Related CN108117260B (en) | 2015-12-30 | 2015-12-30 | The preparation method of the accumulating type luminous glaze glass ceramic material of low temperature of glaze firing |
| CN201810363496.7A Pending CN108484225A (en) | 2015-12-30 | 2015-12-30 | A kind of application of accumulating type luminous glaze glass ceramic material |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810363487.8A Active CN108423991B (en) | 2015-12-30 | 2015-12-30 | Energy storage type luminous glaze glass ceramic material |
Country Status (1)
| Country | Link |
|---|---|
| CN (5) | CN108516687A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020049432A1 (en) * | 2018-09-04 | 2020-03-12 | 3M Innovative Properties Company | Fluorescent glazing composition for a dental zirconia article, process of sintering and kit of parts |
| CN113307496B (en) * | 2021-06-15 | 2022-09-16 | 亚细亚建筑材料股份有限公司 | Luminescent glaze ceramic material and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1609027A (en) * | 2003-10-20 | 2005-04-27 | 梁锋 | High temperature luminous glazing and its production process and application in luminous glazed tile |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100268605B1 (en) * | 1997-12-30 | 2000-10-16 | 이용재 | Luminous tile and its manufacturing method |
| CN1081171C (en) * | 1999-04-02 | 2002-03-20 | 中国建筑材料科学研究院 | Light-accumulative luminous ceramic products |
| CN102898185B (en) * | 2012-11-06 | 2014-12-10 | 淄博泰如工业新材料有限公司 | Production process of luminous ceramic product |
| CN103643773B (en) * | 2013-12-12 | 2015-11-25 | 佛山欧神诺陶瓷股份有限公司 | One is photic stores light ceramic brick and production method thereof |
-
2015
- 2015-12-30 CN CN201810363499.0A patent/CN108516687A/en active Pending
- 2015-12-30 CN CN201711437992.4A patent/CN108117260B/en not_active Expired - Fee Related
- 2015-12-30 CN CN201810363496.7A patent/CN108484225A/en active Pending
- 2015-12-30 CN CN201511031738.5A patent/CN105503274B/en not_active Expired - Fee Related
- 2015-12-30 CN CN201810363487.8A patent/CN108423991B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1609027A (en) * | 2003-10-20 | 2005-04-27 | 梁锋 | High temperature luminous glazing and its production process and application in luminous glazed tile |
Non-Patent Citations (1)
| Title |
|---|
| SrAl2O4:Eu2+，Dy3+光致发光搪瓷涂层的制备;张希艳 等;《材料科学与工艺》;20020930;第10卷(第3期);第314~317页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108117260B (en) | 2019-11-29 |
| CN108516687A (en) | 2018-09-11 |
| CN108117260A (en) | 2018-06-05 |
| CN108484225A (en) | 2018-09-04 |
| CN108423991B (en) | 2020-01-03 |
| CN108423991A (en) | 2018-08-21 |
| CN105503274A (en) | 2016-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2310503T3 (en) | ENAMELING COMPOSITIONS. | |
| CN107651949B (en) | Luminous ceramic glazed tile and preparation method thereof | |
| US5091345A (en) | Glass composition | |
| CN105503274B (en) | The accumulating type luminous glaze glass ceramic material and preparation method and applications of low temperature of glaze firing | |
| CN106673439B (en) | A kind of glaze compositions and preparation method thereof using manganese tungstate as active material with photo-catalysis function | |
| DE60307254D1 (en) | PROTECTION OF COMPOSITE MATERIALS AGAINST OXIDATION | |
| CN105776861A (en) | Bright red nanometer glaze slip for ceramic sanitary wares as well as preparation method and application of bright red nanometer glaze slip | |
| CN106565092A (en) | Lightweight low-temperature fancy golden silk white glazed porcelain and manufacturing process | |
| CN102020461A (en) | High-temperature bright red ceramic and preparation method thereof | |
| BR0318230A (en) | luminous tile and method of preparation thereof | |
| CN110054413A (en) | It is a kind of to remove simultaneously formaldehyde, except the ceramic glaze of toluene and antibacterial | |
| CN109627053A (en) | A kind of light-accumulated luminous Imitation Rock Porcelain Tiles and its manufacturing method | |
| CN108658463A (en) | A kind of Fluorescent glaze, the ceramic being made from it and the method for preparing the product | |
| CN112010673A (en) | Luminous ceramic tile and preparation method thereof | |
| CN108842991A (en) | Anti-skid brick and preparation method thereof | |
| WO2003050050A1 (en) | Night glow glaze for ceramics | |
| CN102010232A (en) | Building ceramic aventurine glaze and preparation method thereof | |
| CN114350349B (en) | Luminescent ceramic and preparation method and application thereof | |
| CN102690131B (en) | Manufacturing method of underglaze flashing K gold glazed brick | |
| JP5638759B2 (en) | Light emitting device coating glass powder, light emitting device coating slurry, light emitting device coating paste, and glass coated light emitting device | |
| CN1308254C (en) | High temperature luminous glazing and its production process and application in luminous glazed tile | |
| RU2329213C1 (en) | Glaze | |
| JPS60151250A (en) | Enamel film backed phosphor | |
| JP5381131B2 (en) | Manufacturing method of glass powder for light emitting device coating | |
| CN102731154A (en) | High weather resistant ceramic glaze |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Chen Tianyu Inventor before: Song Weiwei Inventor before: Mao Zhiyong Inventor before: Li Rui Inventor before: Wang Yanze Inventor before: Wang Zhongkai |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180428 Address after: 362000 Chengdong Development Zone, Xun Zhong town, Dehua County, Quanzhou, Fujian Applicant after: Praise Dehua County the ceramic Co.,Ltd. of wound in Fujian Province Address before: 300384 Tianjin Binhai New Area, Tianjin Huayuan Industrial Zone, No. 7, 531, Zi Yuan Road, 7 Applicant before: QUANTUM PHOTOELECTRIC TECHNOLOGY (TIANJIN) CO.,LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180601 Termination date: 20211230 |