CN108468217A - 一种面料防污整理方法 - Google Patents

一种面料防污整理方法 Download PDF

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Publication number
CN108468217A
CN108468217A CN201810357595.4A CN201810357595A CN108468217A CN 108468217 A CN108468217 A CN 108468217A CN 201810357595 A CN201810357595 A CN 201810357595A CN 108468217 A CN108468217 A CN 108468217A
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China
Prior art keywords
fabric
resistant finish
soil resistant
finish method
methacrylate
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CN201810357595.4A
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王亚宁
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Anhui Star Clothing Ltd By Share Ltd
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Anhui Star Clothing Ltd By Share Ltd
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Priority to CN201810357595.4A priority Critical patent/CN108468217A/zh
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Abstract

本发明提供一种面料防污整理方法，本发明面料防污整理方法用氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯反应携带氧化锌微球粘附在面料上，形成微细凸起，能够起到防污的作用，同时具有抗菌性能，面料的抗菌防污性能得到大大提高，同时面料具有抗皱、挺括、耐晒、防变色的性能。

Description

一种面料防污整理方法
技术领域
本发明涉及面料整理领域，尤其涉及一种面料防污整理方法。
背景技术
作为纺织大国，纺织工业在我国国民经济中占有重要地位，随着纺织工业的快速发展和人们生活水平的上升，对纺织品的要求不再限于单一的舒适功能，而是趋向多层次、多功能的方向发展。服装面料存在大量的纤维间隙及微孔，同时吸纳了大量的人体表分泌物，成为微生物附着、繁殖和传播的良好场所，微生物的滋生非但导致面料表面出现霉点、异味、纤维强度下降等情况，还会导致人体出现瘙痒、过敏反应或其他皮肤疾病，对人们生活造成不便，甚至危害人们身体健康。当前抗菌服装尤其是医院卫生用纺织品需求量大，且在服装类市场份额逐渐增加。尽管经抗菌整理后，织物具有抗菌、防霉、防臭等性能，但是其耐久性问题严重；另外，织物整理前需要对织物纤维进行剧烈化学前处理，来增强整理剂与织物纤维的结合力，造成环境污染加剧，且对织物种类的适用性不高。
防污整理能够防止面料接触细菌，提高抗菌性能，保持面料色泽鲜艳。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种面料防污整理方法。
本发明是通过以下技术方案实现的：
一种面料防污整理方法，步骤为：
（1）将氧化锌微球均匀分散在水中，超声处理，再加入氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯搅拌均匀，加热至50-60℃；
（2）将引发剂加入水中，制成3-4wt%的溶液，滴加入步骤（1）的反应液中，搅拌反应50-70分钟，加入渗透剂，得到浸渍液；
（3）将面料进行退浆，脱水、烘干；
（4）按浴比为100:70-76，浸渍40-60分钟；
（5）取出面料，烘干，即得。
水：氧化锌微球：氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯的质量比为120-130：10-12：6-8:5-6:7-8。
所述渗透剂在浸渍液中的质量浓度为2.5-3.5wt%。
所述引发剂为过硫酸铵、过硫酸钠、过硫酸钾中的一种或多种。
所述超声处理时间为10-20分钟。
所述氧化锌微球的粒径为1-8微米。
本发明的优点是：本发明面料防污整理方法用氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯反应携带氧化锌微球粘附在面料上，形成微细凸起，能够起到防污的作用，同时具有抗菌性能，面料的抗菌防污性能得到大大提高，同时面料具有抗皱、挺括、耐晒、防变色的性能。
具体实施方式
一种面料防污整理方法，步骤为：
（1）将氧化锌微球均匀分散在水中，超声处理，再加入氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯搅拌均匀，加热至55℃；
（2）将引发剂加入水中，制成3.5wt%的溶液，滴加入步骤（1）的反应液中，搅拌反应60分钟，加入渗透剂，得到浸渍液；
（3）将面料进行退浆，脱水、烘干；
（4）按浴比为100:74，浸渍50分钟；
（5）取出面料，烘干，即得。
水：氧化锌微球：氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯的质量比为130：12：8:6:8。
所述渗透剂在浸渍液中的质量浓度为3wt%。
所述引发剂为过硫酸铵、过硫酸钠、过硫酸钾中的一种或多种。
所述超声处理时间为17分钟。
所述氧化锌微球的粒径为1-8微米。

Claims (6)

1.一种面料防污整理方法，其特征在于，步骤为：
（1）将氧化锌微球均匀分散在水中，超声处理，再加入氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯搅拌均匀，加热至50-60℃；
（2）将引发剂加入水中，制成3-4wt%的溶液，滴加入步骤（1）的反应液中，搅拌反应50-70分钟，加入渗透剂，得到浸渍液；
（3）将面料进行退浆，脱水、烘干；
（4）按浴比为100:70-76，浸渍40-60分钟；
（5）取出面料，烘干，即得。
2.如权利要求1所述面料防污整理方法，其特征在于，水：氧化锌微球：氟代甲基丙烯酸酯、含氟喹诺酮类甲基丙烯酸酯、含二苯甲酮的甲基丙烯酸酯的质量比为120-130：10-12：6-8:5-6:7-8。
3.如权利要求1所述面料防污整理方法，其特征在于，所述渗透剂在浸渍液中的质量浓度为2.5-3.5wt%。
4.如权利要求1所述面料防污整理方法，其特征在于，所述引发剂为过硫酸铵、过硫酸钠、过硫酸钾中的一种或多种。
5.如权利要求1所述面料防污整理方法，其特征在于，所述超声处理时间为10-20分钟。
6.如权利要求1所述面料防污整理方法，其特征在于，所述氧化锌微球的粒径为1-8微米。
CN201810357595.4A 2018-04-20 2018-04-20 一种面料防污整理方法 Pending CN108468217A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114481633A (zh) * 2022-01-04 2022-05-13 江苏华峰超纤材料有限公司 一种面层膜及其制备方法和应用

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* Cited by examiner, † Cited by third party
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JPH10130619A (ja) * 1996-11-01 1998-05-19 Mitsui Mining & Smelting Co Ltd 酸化亜鉛微粒子付着複合体及びその製造方法
US20050062010A1 (en) * 2003-09-22 2005-03-24 Xinggao Fang Treated textiles and compositions for treating textiles
CN202276868U (zh) * 2011-11-04 2012-06-20 钟红霞 一种免洗服装布料
CN104153186A (zh) * 2014-07-14 2014-11-19 桐乡大和纺织服饰有限公司 高效抗菌自清洁整理剂及其制备方法和使用方法
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章媛媛: "防污自洁织物的研制及拒水拒油耐久性的研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114481633A (zh) * 2022-01-04 2022-05-13 江苏华峰超纤材料有限公司 一种面层膜及其制备方法和应用
CN114481633B (zh) * 2022-01-04 2023-12-15 江苏华峰超纤材料有限公司 一种面层膜及其制备方法和应用

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Application publication date: 20180831