CN108457076A - 一种提高纺织品抗静电性能的复合纺织助剂及其制备方法 - Google Patents

一种提高纺织品抗静电性能的复合纺织助剂及其制备方法 Download PDF

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CN108457076A
CN108457076A CN201810144790.9A CN201810144790A CN108457076A CN 108457076 A CN108457076 A CN 108457076A CN 201810144790 A CN201810144790 A CN 201810144790A CN 108457076 A CN108457076 A CN 108457076A
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周华
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Abstract

本发明提供了一种提高纺织品抗静电性能的复合纺织助剂及其制备方法，本发明的复合纺织助剂中含有氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料，通过利用上述材料的物理特性，在各组分的协同作用下，增加该复合纺织助剂的抗静电性能和导热性能。且本发明的防止助剂制备方法简单，易于生产制备。

Description

一种提高纺织品抗静电性能的复合纺织助剂及其制备方法
技术领域
本发明涉及纺织助剂技术领域，特别是涉及一种提高纺织品抗静电性能的复合纺织助剂及其制备方法。
背景技术
纺织助剂是纺织品生产加工过程中必须的化学品。纺织助剂对提高纺织品的产品质量和附加价值具有不可或缺的重要作用，它不仅能赋予纺织品各种特殊功能和风格，如柔软、防皱、防缩、防水、抗菌、抗静电、阻燃等，还可以改进染整工艺，起到节约能源和降低加工成本的作用。纺织助剂对提升纺织工业的整体水平以及在纺织产业链中的作用是至关重要的。常见的纺织助剂包括精练剂、染色剂、匀染剂、柔软剂、毛效提升剂、涤纶低温染色载体、代用碱、CT粉、化纤油剂、高效退煮粉、双氧水稳定剂、除硅剂、起泡剂、起毛剂、固色剂等等。现有的纺织助剂功能单一，综合性能较差，如何设计一种综合性能优异的纺织助剂，是业界亟待解决的问题。
发明内容
本发明的目的是克服上述现有技术的不足，提供一种提高纺织品抗静电性能的复合纺织助剂及其制备方法。
为实现上述目的，本发明提出的一种提高纺织品抗静电性能的复合纺织助剂，所述复合纺织助剂由以下重量份的原料组成：油酸镁10-20份；脂肪醇聚氧乙烯醚5-15份；十二烷基二羟乙基甜菜碱1-3份；亚磷酸二苯基十三烷酯10-15份；椰油二乙醇酰胺5-10份；乙二醇二缩水甘油醚2-4份；柠檬酸三钠2-6份；双十八烷基二甲基氯化铵2-4份；硬脂酸钠1-5份；邻苯二甲酸酐10-20份；乙基香兰素5-10份；醋酸乙烯酯10-20份；偶氮二异丁腈1-3份；甲基丙烯酸二乙基氨基乙酯2-5份；聚丙烯酸酯3-6份；氯化十四烷基二甲基苄基铵1-3份；二乙基三胺5-10份；聚己二酸乙二醇酯2-8份；亚油酸3-6份；琥珀酸二辛酯磺酸钠10-15份；氯化十四烷基二甲基苄基铵2-4份；聚甲基硅树脂2-5份；儿茶素3-6份；氧化锆纳米粉末0.5-2份；氧化钇纳米粉末0.3-0.8份；硫化锆层状纳米材料0.3-0.6份；二硒化铌层状纳米材料0.1-0.5份，二硫化钛层状纳米材料0.5-0.9份；黑磷烯层状纳米材料0.5-1.5份；硫化钨层状纳米材料0.5-1.5份；聚乙烯醇1-2份；乙醇30-40份；去离子水60-80份。
本发明还提供了上述提高纺织品抗静电性能的复合纺织助剂的制备方法，包括以下步骤：
1）按所述复合纺织助剂的所述重量份称取各原料；
2）将氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料加入到乙醇和去离子水组成的混合溶液中，在2500-3000转/分钟的搅拌速度下搅拌4-6小时，得到第一混合溶液；
3）将第一混合溶液置于反应釜中，然后向反应釜中加入聚乙烯醇、油酸镁、脂肪醇聚氧乙烯醚、亚磷酸二苯基十三烷酯、椰油二乙醇酰胺、乙二醇二缩水甘油醚、柠檬酸三钠、双十八烷基二甲基氯化铵、硬脂酸钠、邻苯二甲酸酐、乙基香兰素、醋酸乙烯酯、偶氮二异丁腈、甲基丙烯酸二乙基氨基乙酯、聚丙烯酸酯、聚己二酸乙二醇酯、聚甲基硅树脂，在氮气环境下，控制温度为85-95℃，乳化反应3-5小时，得到乳化混合液；
4）在乳化混合液中加入氯化十四烷基二甲基苄基铵、二乙基三胺、亚油酸、琥珀酸二辛酯磺酸钠、氯化十四烷基二甲基苄基铵、儿茶素以及十二烷基二羟乙基甜菜碱，在65-75℃的温度下，搅拌混合反应1-2小时，制得所述复合纺织助剂。
本发明与现有技术相比具有下列优点：
本发明的复合纺织助剂，各组分之间具有配合作用，使得该复合纺织助剂具有优异的综合性能，可以提高相应纺织品的抗拉伸性能、导热性能以及抗静电性能，具有广泛的工业化前景和市场价值。本发明的复合纺织助剂中含有氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料，通过利用上述材料的物理特性，在各组分的协同作用下，增加该复合纺织助剂的抗静电性能和导热性能。且本发明的防止助剂制备方法简单，易于生产制备。
具体实施方式
实施例1：
1）称取油酸镁15份；脂肪醇聚氧乙烯醚10份；十二烷基二羟乙基甜菜碱2份；亚磷酸二苯基十三烷酯12份；椰油二乙醇酰胺7份；乙二醇二缩水甘油醚3份；柠檬酸三钠4份；双十八烷基二甲基氯化铵3份；硬脂酸钠3份；邻苯二甲酸酐15份；乙基香兰素7份；醋酸乙烯酯15份；偶氮二异丁腈2份；甲基丙烯酸二乙基氨基乙酯3份；聚丙烯酸酯5份；氯化十四烷基二甲基苄基铵2份；二乙基三胺7份；聚己二酸乙二醇酯5份；亚油酸5份；琥珀酸二辛酯磺酸钠12份；氯化十四烷基二甲基苄基铵3份；聚甲基硅树脂4份；儿茶素5份；氧化锆纳米粉末1份；氧化钇纳米粉末0.5份；硫化锆层状纳米材料0.4份；二硒化铌层状纳米材料0.3份，二硫化钛层状纳米材料0.7份；黑磷烯层状纳米材料1份；硫化钨层状纳米材料1份；聚乙烯醇1.5份；乙醇35份；去离子水70份；
2）将氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料加入到乙醇和去离子水组成的混合溶液中，在2800转/分钟的搅拌速度下搅拌5小时，得到第一混合溶液；
3）将第一混合溶液置于反应釜中，然后向反应釜中加入聚乙烯醇、油酸镁、脂肪醇聚氧乙烯醚、亚磷酸二苯基十三烷酯、椰油二乙醇酰胺、乙二醇二缩水甘油醚、柠檬酸三钠、双十八烷基二甲基氯化铵、硬脂酸钠、邻苯二甲酸酐、乙基香兰素、醋酸乙烯酯、偶氮二异丁腈、甲基丙烯酸二乙基氨基乙酯、聚丙烯酸酯、聚己二酸乙二醇酯、聚甲基硅树脂，在氮气环境下，控制温度为90℃，乳化反应4小时，得到乳化混合液；
4）在乳化混合液中加入氯化十四烷基二甲基苄基铵、二乙基三胺、亚油酸、琥珀酸二辛酯磺酸钠、氯化十四烷基二甲基苄基铵、儿茶素以及十二烷基二羟乙基甜菜碱，在70℃的温度下，搅拌混合反应1.5小时，制得所述复合纺织助剂。
实施例2
1）称取油酸镁10份；脂肪醇聚氧乙烯醚5份；十二烷基二羟乙基甜菜碱1份；亚磷酸二苯基十三烷酯10份；椰油二乙醇酰胺5份；乙二醇二缩水甘油醚2份；柠檬酸三钠2份；双十八烷基二甲基氯化铵2份；硬脂酸钠1份；邻苯二甲酸酐10份；乙基香兰素5份；醋酸乙烯酯10份；偶氮二异丁腈1份；甲基丙烯酸二乙基氨基乙酯2份；聚丙烯酸酯3份；氯化十四烷基二甲基苄基铵1份；二乙基三胺5份；聚己二酸乙二醇酯2份；亚油酸3份；琥珀酸二辛酯磺酸钠10份；氯化十四烷基二甲基苄基铵2份；聚甲基硅树脂2份；儿茶素3份；氧化锆纳米粉末0.5份；氧化钇纳米粉末0.3份；硫化锆层状纳米材料0.3份；二硒化铌层状纳米材料0.1份，二硫化钛层状纳米材料0.5份；黑磷烯层状纳米材料0.5份；硫化钨层状纳米材料0.5份；聚乙烯醇1份；乙醇30份；去离子水60份；
2）将氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料加入到乙醇和去离子水组成的混合溶液中，在2500转/分钟的搅拌速度下搅拌6小时，得到第一混合溶液；
3）将第一混合溶液置于反应釜中，然后向反应釜中加入聚乙烯醇、油酸镁、脂肪醇聚氧乙烯醚、亚磷酸二苯基十三烷酯、椰油二乙醇酰胺、乙二醇二缩水甘油醚、柠檬酸三钠、双十八烷基二甲基氯化铵、硬脂酸钠、邻苯二甲酸酐、乙基香兰素、醋酸乙烯酯、偶氮二异丁腈、甲基丙烯酸二乙基氨基乙酯、聚丙烯酸酯、聚己二酸乙二醇酯、聚甲基硅树脂，在氮气环境下，控制温度为85℃，乳化反应5小时，得到乳化混合液；
4）在乳化混合液中加入氯化十四烷基二甲基苄基铵、二乙基三胺、亚油酸、琥珀酸二辛酯磺酸钠、氯化十四烷基二甲基苄基铵、儿茶素以及十二烷基二羟乙基甜菜碱，在65℃的温度下，搅拌混合反应2小时，制得所述复合纺织助剂。
实施例3
1）称取油酸镁20份；脂肪醇聚氧乙烯醚15份；十二烷基二羟乙基甜菜碱3份；亚磷酸二苯基十三烷酯15份；椰油二乙醇酰胺10份；乙二醇二缩水甘油醚4份；柠檬酸三钠6份；双十八烷基二甲基氯化铵4份；硬脂酸钠5份；邻苯二甲酸酐20份；乙基香兰素10份；醋酸乙烯酯20份；偶氮二异丁腈3份；甲基丙烯酸二乙基氨基乙酯5份；聚丙烯酸酯6份；氯化十四烷基二甲基苄基铵3份；二乙基三胺10份；聚己二酸乙二醇酯8份；亚油酸6份；琥珀酸二辛酯磺酸钠15份；氯化十四烷基二甲基苄基铵4份；聚甲基硅树脂5份；儿茶素6份；氧化锆纳米粉末2份；氧化钇纳米粉末0.8份；硫化锆层状纳米材料0.6份；二硒化铌层状纳米材料0.5份，二硫化钛层状纳米材料0.9份；黑磷烯层状纳米材料1.5份；硫化钨层状纳米材料1.5份；聚乙烯醇2份；乙醇40份；去离子水80份；
2）将氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料加入到乙醇和去离子水组成的混合溶液中，在3000转/分钟的搅拌速度下搅拌4小时，得到第一混合溶液；
3）将第一混合溶液置于反应釜中，然后向反应釜中加入聚乙烯醇、油酸镁、脂肪醇聚氧乙烯醚、亚磷酸二苯基十三烷酯、椰油二乙醇酰胺、乙二醇二缩水甘油醚、柠檬酸三钠、双十八烷基二甲基氯化铵、硬脂酸钠、邻苯二甲酸酐、乙基香兰素、醋酸乙烯酯、偶氮二异丁腈、甲基丙烯酸二乙基氨基乙酯、聚丙烯酸酯、聚己二酸乙二醇酯、聚甲基硅树脂，在氮气环境下，控制温度为95℃，乳化反应3小时，得到乳化混合液；
4）在乳化混合液中加入氯化十四烷基二甲基苄基铵、二乙基三胺、亚油酸、琥珀酸二辛酯磺酸钠、氯化十四烷基二甲基苄基铵、儿茶素以及十二烷基二羟乙基甜菜碱，在75℃的温度下，搅拌混合反应1小时，制得所述复合纺织助剂。
最后应当说明的是，以上实施例仅用于说明本发明的技术方案而非对本发明保护范围的限制，尽管参照较佳实施例对本发明作了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的实质和范围。

Claims (2)

1.一种提高纺织品抗静电性能的复合纺织助剂，其特征在于，所述复合纺织助剂由以下重量份的原料组成：油酸镁10-20份；脂肪醇聚氧乙烯醚5-15份；十二烷基二羟乙基甜菜碱1-3份；亚磷酸二苯基十三烷酯10-15份；椰油二乙醇酰胺5-10份；乙二醇二缩水甘油醚2-4份；柠檬酸三钠2-6份；双十八烷基二甲基氯化铵2-4份；硬脂酸钠1-5份；邻苯二甲酸酐10-20份；乙基香兰素5-10份；醋酸乙烯酯10-20份；偶氮二异丁腈1-3份；甲基丙烯酸二乙基氨基乙酯2-5份；聚丙烯酸酯3-6份；氯化十四烷基二甲基苄基铵1-3份；二乙基三胺5-10份；聚己二酸乙二醇酯2-8份；亚油酸3-6份；琥珀酸二辛酯磺酸钠10-15份；氯化十四烷基二甲基苄基铵2-4份；聚甲基硅树脂2-5份；儿茶素3-6份；氧化锆纳米粉末0.5-2份；氧化钇纳米粉末0.3-0.8份；硫化锆层状纳米材料0.3-0.6份；二硒化铌层状纳米材料0.1-0.5份，二硫化钛层状纳米材料0.5-0.9份；黑磷烯层状纳米材料0.5-1.5份；硫化钨层状纳米材料0.5-1.5份；聚乙烯醇1-2份；乙醇30-40份；去离子水60-80份。
2.根据权利要求1所述的提高纺织品抗静电性能的复合纺织助剂的制备方法，包括以下步骤：
1）按所述复合纺织助剂的所述重量份称取各原料；
2）将氧化锆纳米粉末、氧化钇纳米粉末、硫化锆层状纳米材料、二硒化铌层状纳米材料、二硫化钛层状纳米材料、黑磷烯层状纳米材料、硫化钨层状纳米材料加入到乙醇和去离子水组成的混合溶液中，在2500-3000转/分钟的搅拌速度下搅拌4-6小时，得到第一混合溶液；
3）将第一混合溶液置于反应釜中，然后向反应釜中加入聚乙烯醇、油酸镁、脂肪醇聚氧乙烯醚、亚磷酸二苯基十三烷酯、椰油二乙醇酰胺、乙二醇二缩水甘油醚、柠檬酸三钠、双十八烷基二甲基氯化铵、硬脂酸钠、邻苯二甲酸酐、乙基香兰素、醋酸乙烯酯、偶氮二异丁腈、甲基丙烯酸二乙基氨基乙酯、聚丙烯酸酯、聚己二酸乙二醇酯、聚甲基硅树脂，在氮气环境下，控制温度为85-95℃，乳化反应3-5小时，得到乳化混合液；
4）在乳化混合液中加入氯化十四烷基二甲基苄基铵、二乙基三胺、亚油酸、琥珀酸二辛酯磺酸钠、氯化十四烷基二甲基苄基铵、儿茶素以及十二烷基二羟乙基甜菜碱，在65-75℃的温度下，搅拌混合反应1-2小时，制得所述复合纺织助剂。
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