CN106758139A - 一种具有抗菌性能的纺织助剂及其制备方法 - Google Patents
一种具有抗菌性能的纺织助剂及其制备方法 Download PDFInfo
- Publication number
- CN106758139A CN106758139A CN201611166673.XA CN201611166673A CN106758139A CN 106758139 A CN106758139 A CN 106758139A CN 201611166673 A CN201611166673 A CN 201611166673A CN 106758139 A CN106758139 A CN 106758139A
- Authority
- CN
- China
- Prior art keywords
- parts
- textile auxiliary
- microbial property
- mixed
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004753 textile Substances 0.000 title claims abstract description 46
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 42
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920005989 resin Polymers 0.000 claims abstract description 36
- -1 phosphorous acid diphenyl tridecane ester Chemical class 0.000 claims abstract description 24
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 19
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 19
- 238000000498 ball milling Methods 0.000 claims abstract description 19
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 claims abstract description 19
- 229910001626 barium chloride Inorganic materials 0.000 claims abstract description 19
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 19
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 108010010803 Gelatin Proteins 0.000 claims abstract description 18
- 229920000159 gelatin Polymers 0.000 claims abstract description 18
- 239000008273 gelatin Substances 0.000 claims abstract description 18
- 235000019322 gelatine Nutrition 0.000 claims abstract description 18
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 18
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 17
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 17
- 229920005610 lignin Polymers 0.000 claims abstract description 17
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims abstract description 17
- BWXDHBQGBNPJMN-VBHWJLTNSA-N [(1r,3ar,5ar,5br,7ar,9s,11ar,11br,13ar,13br)-3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysen-9-yl] hexadecanoate Chemical compound C([C@@]1(C)CC[C@H]([C@@H]1[C@H]1CC[C@H]23)C(C)=C)C[C@@]1(C)[C@]3(C)CC[C@@H]1[C@]2(C)CC[C@H](OC(=O)CCCCCCCCCCCCCCC)C1(C)C BWXDHBQGBNPJMN-VBHWJLTNSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 9
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- 238000004945 emulsification Methods 0.000 claims abstract description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims abstract description 3
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 8
- 238000002604 ultrasonography Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims description 2
- 235000020778 linoleic acid Nutrition 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- FYOYCZHNDCCGCE-UHFFFAOYSA-N diphenyl hydrogen phosphite Chemical group C=1C=CC=CC=1OP(O)OC1=CC=CC=C1 FYOYCZHNDCCGCE-UHFFFAOYSA-N 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- IIYFAKIEWZDVMP-UHFFFAOYSA-N linear paraffin C13 Natural products CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 230000001153 anti-wrinkle effect Effects 0.000 abstract description 4
- 238000009413 insulation Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 14
- 235000021314 Palmitic acid Nutrition 0.000 description 7
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 7
- 238000011056 performance test Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000009738 saturating Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001515 polyalkylene glycol Polymers 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- XXQBGBUZLWZPKT-UHFFFAOYSA-N n-prop-2-enoylbuta-2,3-dienamide Chemical group C=CC(=O)NC(=O)C=C=C XXQBGBUZLWZPKT-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- JNRLEMMIVRBKJE-UHFFFAOYSA-N 4,4'-Methylenebis(N,N-dimethylaniline) Chemical compound C1=CC(N(C)C)=CC=C1CC1=CC=C(N(C)C)C=C1 JNRLEMMIVRBKJE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- BWXDHBQGBNPJMN-UHFFFAOYSA-N Lupeol palmitate Natural products C12CCC3C4C(C(C)=C)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(OC(=O)CCCCCCCCCCCCCCC)C1(C)C BWXDHBQGBNPJMN-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000010855 food raising agent Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了一种具有抗菌性能的纺织助剂及其制备方法,其以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分,通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水,辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺,使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果,同时具有一定的抗皱效果,能够满足行业的要求,具有较好的应用前景。
Description
技术领域
本发明涉及纺织助剂技术领域,特别涉及一种具有抗菌性能的纺织助剂及其制备方法。
背景技术
纺织助剂是纺织品生产加工过程中必须的化学品。纺织助剂对提高纺织品的产品质量和附加价值具有不可或缺的重要作用,它不仅能赋予纺织品各种特殊功能和风格,如柔软、防皱、防缩、防水、抗菌、抗静电、阻燃等,还可以改进染整工艺,起到节约能源和降低加工成本的作用。纺织助剂对提升纺织工业的整体水平以及在纺织产业链中的作用是至关重要的。全世界纺织助剂有近100个门类,生产近1.6万个品种,年产量约410万吨。其中欧美纺织助剂品种48个门类,8000多个品种;日本有5500个品种。据报道,世界纺织助剂市场销售额远远超过了染料市场的销售额。现有的纺织助剂主要有精练剂、染色剂、匀染剂、柔软剂、毛效提升剂、涤纶低温染色载体、代用碱、CT粉、化纤油剂、高效退煮粉、双氧水稳定剂、除硅剂、起泡剂、起毛剂、固色剂等。
具体到我国,目前国内能够生产的纺织助剂品种近2000个,经常生产的品种有800余个,主要品种有200个左右。我国纺织助剂产量大,行业产值高,具有广阔的市场前景。但国产纺织助剂在品种和质量以及在合成和应用技术方面与国际先进水平相比还有较大差距,专用和高档纺织助剂尚不得不依赖进口。
针对目前国内纺织助剂使用效果不佳、科技含量低、环保性能欠缺等因素,开发出一批具备优异使用功能的环境有好的新型纺织助剂,以提高产品的市场竞争力就显得尤为必要。
发明内容
为解决上述技术问题,本发明提供一种具有抗菌性能的纺织助剂,通过采用特定的原料进行组合,配合特定的生产工艺,使得制备而成的纺织助剂使用后使纺织物具有良好的抗菌效果,同时具有一定的抗皱效果,能够满足行业的要求,具有较好的应用前景。
本发明的目的可以通过以下技术方案实现:
一种具有抗菌性能的纺织助剂,由下列重量份的原料制成:丙基三乙氧基硅烷35-45份、苯乙烯马来酸酐树脂30-40份、丁苯透明抗冲树脂28-32份、亚磷酸二苯基十三烷酯20-26份、聚乙二醇单硬脂酸酯12-18份、羽扇醇棕榈酸酯10-14份、过氧化苯甲酰8-10份、聚二甲基二烯丙基氯化铵8-10份、十二烷基磺酸钠6-8份、盐酸木质素4-6份、明胶3-5份、氯化钡2-4份、纳米二氧化硅1-3份、有机酸3-5份、交联剂3-5份、去离子水100份。
优选地,所述有机酸选自棕榈酸、柠檬酸、亚油酸中的任意一种。
优选地,所述交联剂选自亚甲基二丙烯酰胺、二甲基丙烯酸聚乙二醇酯、乙二醇二缩水甘油醚中的任意一种。
所述的具有抗菌性能的纺织助剂的制备方法,包括以下步骤:
(1)按所述重量份准确称取各原料;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1-2小时,再向球磨后的混合物加入去离子水,在1000-2000 rpm的搅拌速率下搅拌2-3小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化40-50分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温25-35分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理2-3小时,随后加入有机酸、交联剂,在60-70℃下经高速剪切混合得到成品。
优选地,所述步骤(4)中,超声震荡的功率为500W,超声震荡的时间为2小时。
优选地,所述步骤(4)中,剪切速率为9000-15000 rpm,剪切时间为30分钟。
本发明与现有技术相比,其有益效果为:
(1)本发明的具有抗菌性能的纺织助剂以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分,通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水,辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺,使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果,同时具有一定的抗皱效果,能够满足行业的要求,具有较好的应用前景。
(2)本发明的具有抗菌性能的纺织助剂原料廉价、工艺简单,适于大规模工业化运用,实用性强。
具体实施方式
下面结合具体实施例对发明的技术方案进行详细说明。
实施例1
(1)按所述重量份准确称取丙基三乙氧基硅烷35份、苯乙烯马来酸酐树脂30份、丁苯透明抗冲树脂28份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯12份、羽扇醇棕榈酸酯10份、过氧化苯甲酰8份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠6份、盐酸木质素4份、明胶3份、氯化钡2份、纳米二氧化硅1份、棕榈酸3份、亚甲基二丙烯酰胺3份、去离子水100份;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1小时,再向球磨后的混合物加入去离子水,在1000 rpm的搅拌速率下搅拌2小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化40分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温25分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入棕榈酸、亚甲基二丙烯酰胺,在60℃下经高速剪切混合得到成品,其中剪切速率为9000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例2
(1)按所述重量份准确称取丙基三乙氧基硅烷40份、苯乙烯马来酸酐树脂35份、丁苯透明抗冲树脂30份、亚磷酸二苯基十三烷酯23份、聚乙二醇单硬脂酸酯15份、羽扇醇棕榈酸酯12份、过氧化苯甲酰9份、聚二甲基二烯丙基氯化铵9份、十二烷基磺酸钠7份、盐酸木质素5份、明胶4份、氯化钡3份、纳米二氧化硅2份、柠檬酸4份、二甲基丙烯酸聚乙二醇酯4份、去离子水100份;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1.5小时,再向球磨后的混合物加入去离子水,在1500 rpm的搅拌速率下搅拌2.5小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化45分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温30分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入柠檬酸、二甲基丙烯酸聚乙二醇酯,在65℃下经高速剪切混合得到成品,其中剪切速率为12000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例3
(1)按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂40份、丁苯透明抗冲树脂32份、亚磷酸二苯基十三烷酯26份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯14份、过氧化苯甲酰10份、聚二甲基二烯丙基氯化铵10份、十二烷基磺酸钠8份、盐酸木质素6份、明胶5份、氯化钡4份、纳米二氧化硅3份、亚油酸5份、乙二醇二缩水甘油醚5份、去离子水100份;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨2小时,再向球磨后的混合物加入去离子水,在2000 rpm的搅拌速率下搅拌3小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化50分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温35分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入亚油酸、乙二醇二缩水甘油醚,在70℃下经高速剪切混合得到成品,其中剪切速率为15000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例4
(1)按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂30份、丁苯透明抗冲树脂32份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯10份、过氧化苯甲酰10份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠8份、盐酸木质素4份、明胶5份、氯化钡2份、纳米二氧化硅3份、棕榈酸3份、二甲基丙烯酸聚乙二醇酯5份、去离子水100份;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1小时,再向球磨后的混合物加入去离子水,在2000 rpm的搅拌速率下搅拌2小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化50分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温25分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入棕榈酸、二甲基丙烯酸聚乙二醇酯,在70℃下经高速剪切混合得到成品,其中剪切速率为9000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
对比例1
(1)按所述重量份准确称取丙基三乙氧基硅烷40份、苯乙烯马来酸酐树脂35份、丁苯透明抗冲树脂30份、亚磷酸二苯基十三烷酯23份、聚乙二醇单硬脂酸酯15份、过氧化苯甲酰9份、聚二甲基二烯丙基氯化铵9份、十二烷基磺酸钠7份、明胶4份、氯化钡3份、纳米二氧化硅2份、柠檬酸4份、二甲基丙烯酸聚乙二醇酯4份、去离子水100份;
(2)将十二烷基磺酸钠、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1.5小时,再向球磨后的混合物加入去离子水,在1500 rpm的搅拌速率下搅拌2.5小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯,待混合均匀后高速乳化45分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温30分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入柠檬酸、二甲基丙烯酸聚乙二醇酯,在65℃下经高速剪切混合得到成品,其中剪切速率为12000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
对比例2
(1)按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂30份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯10份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠8份、盐酸木质素4份、明胶5份、氯化钡2份、纳米二氧化硅3份、棕榈酸3份、二甲基丙烯酸聚乙二醇酯5份、去离子水100份;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1小时,再向球磨后的混合物加入去离子水,在2000 rpm的搅拌速率下搅拌2小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化50分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温25分钟;
(4)待混合液冷却至室温后,加入聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理,超声震荡的功率为500W,超声震荡的时间为2小时,随后加入棕榈酸、二甲基丙烯酸聚乙二醇酯,在70℃下经高速剪切混合得到成品,其中剪切速率为9000 rpm,剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
将实施例1-4和对比例1-2的具有抗菌性能的纺织助剂分别施用于纺织物后进行金黄色葡萄球菌杀菌率、绿脓杆菌杀菌率、回复角这几项测试。
表1
金黄色葡萄球菌杀菌率(%) | 绿脓杆菌杀菌率(%) | 回复角(°) | |
实施例1 | 96.9% | 96.0% | 253 |
实施例2 | 97.6% | 96.8% | 261 |
实施例3 | 97.3% | 96.5% | 259 |
实施例4 | 97.1% | 95.7% | 249 |
对比例1 | 92.8% | 91.3% | 196 |
对比例2 | 92.4% | 91.0% | 183 |
本发明的具有抗菌性能的纺织助剂以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分,通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水,辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺,使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果,同时具有一定的抗皱效果,能够满足行业的要求,具有较好的应用前景。本发明的具有抗菌性能的纺织助剂原料廉价、工艺简单,适于大规模工业化运用,实用性强。
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。
Claims (6)
1.一种具有抗菌性能的纺织助剂,其特征在于:由下列重量份的原料制成:丙基三乙氧基硅烷35-45份、苯乙烯马来酸酐树脂30-40份、丁苯透明抗冲树脂28-32份、亚磷酸二苯基十三烷酯20-26份、聚乙二醇单硬脂酸酯12-18份、羽扇醇棕榈酸酯10-14份、过氧化苯甲酰8-10份、聚二甲基二烯丙基氯化铵8-10份、十二烷基磺酸钠6-8份、盐酸木质素4-6份、明胶3-5份、氯化钡2-4份、纳米二氧化硅1-3份、有机酸3-5份、交联剂3-5份、去离子水100份。
2.根据权利要求1所述的具有抗菌性能的纺织助剂,其特征在于:所述有机酸选自棕榈酸、柠檬酸、亚油酸中的任意一种。
3.根据权利要求1所述的具有抗菌性能的纺织助剂,其特征在于:所述交联剂选自亚甲基二丙烯酰胺、二甲基丙烯酸聚乙二醇酯、乙二醇二缩水甘油醚中的任意一种。
4.根据权利要求1-3任一所述的具有抗菌性能的纺织助剂的制备方法,其特征在于,包括以下步骤:
(1)按所述重量份准确称取各原料;
(2)将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中,球磨1-2小时,再向球磨后的混合物加入去离子水,在1000-2000 rpm的搅拌速率下搅拌2-3小时,得初步混合液;
(3)将初步混合液送入反应釜中,加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯,待混合均匀后高速乳化40-50分钟,得乳化混合液,随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5,加热至90℃,保温25-35分钟;
(4)待混合液冷却至室温后,加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵,在超声震荡器中超声处理2-3小时,随后加入有机酸、交联剂,在60-70℃下经高速剪切混合得到成品。
5.根据权利要求4所述的具有抗菌性能的纺织助剂的制备方法,其特征在于,所述步骤(4)中,超声震荡的功率为500W,超声震荡的时间为2小时。
6.根据权利要求4所述的具有抗菌性能的纺织助剂的制备方法,其特征在于,所述步骤(4)中,剪切速率为9000-15000rpm,剪切时间为30分钟。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611166673.XA CN106758139A (zh) | 2016-12-16 | 2016-12-16 | 一种具有抗菌性能的纺织助剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611166673.XA CN106758139A (zh) | 2016-12-16 | 2016-12-16 | 一种具有抗菌性能的纺织助剂及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106758139A true CN106758139A (zh) | 2017-05-31 |
Family
ID=58893023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611166673.XA Pending CN106758139A (zh) | 2016-12-16 | 2016-12-16 | 一种具有抗菌性能的纺织助剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106758139A (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110344251A (zh) * | 2019-07-15 | 2019-10-18 | 江苏方成生物科技有限公司 | 一种环保型纺织助剂 |
CN112281480A (zh) * | 2020-10-30 | 2021-01-29 | 周银川 | 一种纺织助剂的制备工艺 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103409991A (zh) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | 一种衣物抗菌柔顺剂的制备方法 |
CN103668954A (zh) * | 2012-09-21 | 2014-03-26 | 上海韬鸿化工科技有限公司 | 抗菌整理剂、织物的抗菌整理方法及抗菌织物 |
CN104278527A (zh) * | 2014-09-26 | 2015-01-14 | 无锡市东北塘宏良染色厂 | 一种织物抗菌处理剂及其制备方法 |
CN104328655A (zh) * | 2014-09-30 | 2015-02-04 | 青岛叁鼎卫生制品有限公司 | 一种抗菌柔顺剂 |
CN104341985A (zh) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | 一种玻璃门用耐水耐擦洗水性涂料及其制备方法 |
CN105064010A (zh) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | 一种新型天然抗菌整理剂及其制备方法 |
CN105714558A (zh) * | 2016-04-20 | 2016-06-29 | 吴江福汇缘家纺有限公司 | 一种含有抗菌成分的纺织助剂及其制备方法 |
-
2016
- 2016-12-16 CN CN201611166673.XA patent/CN106758139A/zh active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103668954A (zh) * | 2012-09-21 | 2014-03-26 | 上海韬鸿化工科技有限公司 | 抗菌整理剂、织物的抗菌整理方法及抗菌织物 |
CN103409991A (zh) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | 一种衣物抗菌柔顺剂的制备方法 |
CN104278527A (zh) * | 2014-09-26 | 2015-01-14 | 无锡市东北塘宏良染色厂 | 一种织物抗菌处理剂及其制备方法 |
CN104328655A (zh) * | 2014-09-30 | 2015-02-04 | 青岛叁鼎卫生制品有限公司 | 一种抗菌柔顺剂 |
CN104341985A (zh) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | 一种玻璃门用耐水耐擦洗水性涂料及其制备方法 |
CN105064010A (zh) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | 一种新型天然抗菌整理剂及其制备方法 |
CN105714558A (zh) * | 2016-04-20 | 2016-06-29 | 吴江福汇缘家纺有限公司 | 一种含有抗菌成分的纺织助剂及其制备方法 |
Non-Patent Citations (3)
Title |
---|
"90高新技术产品精选编辑组: "《高新技术产品精选》", 31 May 1991, 北京:宇航出版社 * |
张海峰: "《常用危险化学品应急速查手册 第2版》", 31 July 2009, 北京:中国石化出版社 * |
杜强国等: "《塑料工业手册 苯乙烯系树脂》", 31 October 2004, 北京:化学工业出版社 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110344251A (zh) * | 2019-07-15 | 2019-10-18 | 江苏方成生物科技有限公司 | 一种环保型纺织助剂 |
CN112281480A (zh) * | 2020-10-30 | 2021-01-29 | 周银川 | 一种纺织助剂的制备工艺 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105714558A (zh) | 一种含有抗菌成分的纺织助剂及其制备方法 | |
CN106637954A (zh) | 一种环保型纺织助剂及其制备方法 | |
CN105155260B (zh) | 一种固体柔软剂及其制备方法 | |
CN105755813B (zh) | 一种可使纺织品耐磨度提高的纺织助剂及其制备方法 | |
CN101070675A (zh) | 聚酯纤维织物碱减量处理促进剂 | |
CN106758139A (zh) | 一种具有抗菌性能的纺织助剂及其制备方法 | |
CN105862476B (zh) | 一种无甲醛活性染料固色剂及其制备方法 | |
CN105862477B (zh) | 一种提高固色效果的纺织助剂及其制备方法 | |
CN104562692B (zh) | 一种低粘度和高粒径稳定性的碳纤维乳液上浆剂及其制备方法 | |
CN104805696A (zh) | 一种新型织物渗透剂组合物 | |
CN105734964A (zh) | 一种辅助纺织上浆的纺织助剂及其制备方法 | |
CN106192419A (zh) | 一种织物柔软剂及其制备方法 | |
CN103757889B (zh) | 一种抗收缩抗起球的整理剂及其制备方法 | |
CN105648778A (zh) | 一种非离子型亲水性脂肪酰胺有机硅共聚物柔软剂的制备方法 | |
CN106758144A (zh) | 一种用于纺织上浆的复合助剂及其制备方法 | |
CN110344251A (zh) | 一种环保型纺织助剂 | |
CN108611851A (zh) | 一种柔软剂乳液及其生产工艺 | |
CN107653671A (zh) | 一种环保型多功能精练剂及制备方法 | |
CN106496596A (zh) | 一种松香乳液的制备方法 | |
CN107740268A (zh) | 一种织物防霉平滑蓬松柔软剂及其制备方法 | |
CN110578251A (zh) | 一种织物抗菌柔顺剂及其制备方法 | |
CN107780207A (zh) | 一种织物柔软剂及其制备方法 | |
CN105220468A (zh) | 一种用于纺织纤维的新型柔软剂及其制备方法 | |
CN106758248A (zh) | 一种提高织物耐磨度的纺织助剂及其制备方法 | |
KR20150009799A (ko) | 다기능 섬유유연제 및 그의 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170531 |
|
WD01 | Invention patent application deemed withdrawn after publication |