CN106758139A - 一种具有抗菌性能的纺织助剂及其制备方法 - Google Patents

一种具有抗菌性能的纺织助剂及其制备方法 Download PDF

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CN106758139A
CN106758139A CN201611166673.XA CN201611166673A CN106758139A CN 106758139 A CN106758139 A CN 106758139A CN 201611166673 A CN201611166673 A CN 201611166673A CN 106758139 A CN106758139 A CN 106758139A
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钱华
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WUJIANG BEISHE SHENGYUAN TEXTILE AUXILIARIES FACTORY
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Abstract

本发明公开了一种具有抗菌性能的纺织助剂及其制备方法，其以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分，通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水，辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺，使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果，同时具有一定的抗皱效果，能够满足行业的要求，具有较好的应用前景。

Description

一种具有抗菌性能的纺织助剂及其制备方法
技术领域
本发明涉及纺织助剂技术领域，特别涉及一种具有抗菌性能的纺织助剂及其制备方法。
背景技术
纺织助剂是纺织品生产加工过程中必须的化学品。纺织助剂对提高纺织品的产品质量和附加价值具有不可或缺的重要作用，它不仅能赋予纺织品各种特殊功能和风格，如柔软、防皱、防缩、防水、抗菌、抗静电、阻燃等，还可以改进染整工艺，起到节约能源和降低加工成本的作用。纺织助剂对提升纺织工业的整体水平以及在纺织产业链中的作用是至关重要的。全世界纺织助剂有近100个门类，生产近1.6万个品种，年产量约410万吨。其中欧美纺织助剂品种48个门类，8000多个品种；日本有5500个品种。据报道，世界纺织助剂市场销售额远远超过了染料市场的销售额。现有的纺织助剂主要有精练剂、染色剂、匀染剂、柔软剂、毛效提升剂、涤纶低温染色载体、代用碱、CT粉、化纤油剂、高效退煮粉、双氧水稳定剂、除硅剂、起泡剂、起毛剂、固色剂等。
具体到我国，目前国内能够生产的纺织助剂品种近2000个，经常生产的品种有800余个，主要品种有200个左右。我国纺织助剂产量大，行业产值高，具有广阔的市场前景。但国产纺织助剂在品种和质量以及在合成和应用技术方面与国际先进水平相比还有较大差距，专用和高档纺织助剂尚不得不依赖进口。
针对目前国内纺织助剂使用效果不佳、科技含量低、环保性能欠缺等因素，开发出一批具备优异使用功能的环境有好的新型纺织助剂，以提高产品的市场竞争力就显得尤为必要。
发明内容
为解决上述技术问题，本发明提供一种具有抗菌性能的纺织助剂，通过采用特定的原料进行组合，配合特定的生产工艺，使得制备而成的纺织助剂使用后使纺织物具有良好的抗菌效果，同时具有一定的抗皱效果，能够满足行业的要求，具有较好的应用前景。
本发明的目的可以通过以下技术方案实现：
一种具有抗菌性能的纺织助剂，由下列重量份的原料制成：丙基三乙氧基硅烷35-45份、苯乙烯马来酸酐树脂30-40份、丁苯透明抗冲树脂28-32份、亚磷酸二苯基十三烷酯20-26份、聚乙二醇单硬脂酸酯12-18份、羽扇醇棕榈酸酯10-14份、过氧化苯甲酰8-10份、聚二甲基二烯丙基氯化铵8-10份、十二烷基磺酸钠6-8份、盐酸木质素4-6份、明胶3-5份、氯化钡2-4份、纳米二氧化硅1-3份、有机酸3-5份、交联剂3-5份、去离子水100份。
优选地，所述有机酸选自棕榈酸、柠檬酸、亚油酸中的任意一种。
优选地，所述交联剂选自亚甲基二丙烯酰胺、二甲基丙烯酸聚乙二醇酯、乙二醇二缩水甘油醚中的任意一种。
所述的具有抗菌性能的纺织助剂的制备方法，包括以下步骤：
（1）按所述重量份准确称取各原料；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1-2小时，再向球磨后的混合物加入去离子水，在1000-2000 rpm的搅拌速率下搅拌2-3小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化40-50分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温25-35分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理2-3小时，随后加入有机酸、交联剂，在60-70℃下经高速剪切混合得到成品。
优选地，所述步骤（4）中，超声震荡的功率为500W，超声震荡的时间为2小时。
优选地，所述步骤（4）中，剪切速率为9000-15000 rpm，剪切时间为30分钟。
本发明与现有技术相比，其有益效果为：
（1）本发明的具有抗菌性能的纺织助剂以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分，通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水，辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺，使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果，同时具有一定的抗皱效果，能够满足行业的要求，具有较好的应用前景。
（2）本发明的具有抗菌性能的纺织助剂原料廉价、工艺简单，适于大规模工业化运用，实用性强。
具体实施方式
下面结合具体实施例对发明的技术方案进行详细说明。
实施例1
（1）按所述重量份准确称取丙基三乙氧基硅烷35份、苯乙烯马来酸酐树脂30份、丁苯透明抗冲树脂28份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯12份、羽扇醇棕榈酸酯10份、过氧化苯甲酰8份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠6份、盐酸木质素4份、明胶3份、氯化钡2份、纳米二氧化硅1份、棕榈酸3份、亚甲基二丙烯酰胺3份、去离子水100份；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1小时，再向球磨后的混合物加入去离子水，在1000 rpm的搅拌速率下搅拌2小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化40分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温25分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入棕榈酸、亚甲基二丙烯酰胺，在60℃下经高速剪切混合得到成品，其中剪切速率为9000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例2
（1）按所述重量份准确称取丙基三乙氧基硅烷40份、苯乙烯马来酸酐树脂35份、丁苯透明抗冲树脂30份、亚磷酸二苯基十三烷酯23份、聚乙二醇单硬脂酸酯15份、羽扇醇棕榈酸酯12份、过氧化苯甲酰9份、聚二甲基二烯丙基氯化铵9份、十二烷基磺酸钠7份、盐酸木质素5份、明胶4份、氯化钡3份、纳米二氧化硅2份、柠檬酸4份、二甲基丙烯酸聚乙二醇酯4份、去离子水100份；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1.5小时，再向球磨后的混合物加入去离子水，在1500 rpm的搅拌速率下搅拌2.5小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化45分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温30分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入柠檬酸、二甲基丙烯酸聚乙二醇酯，在65℃下经高速剪切混合得到成品，其中剪切速率为12000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例3
（1）按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂40份、丁苯透明抗冲树脂32份、亚磷酸二苯基十三烷酯26份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯14份、过氧化苯甲酰10份、聚二甲基二烯丙基氯化铵10份、十二烷基磺酸钠8份、盐酸木质素6份、明胶5份、氯化钡4份、纳米二氧化硅3份、亚油酸5份、乙二醇二缩水甘油醚5份、去离子水100份；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨2小时，再向球磨后的混合物加入去离子水，在2000 rpm的搅拌速率下搅拌3小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化50分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温35分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入亚油酸、乙二醇二缩水甘油醚，在70℃下经高速剪切混合得到成品，其中剪切速率为15000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
实施例4
（1）按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂30份、丁苯透明抗冲树脂32份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯10份、过氧化苯甲酰10份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠8份、盐酸木质素4份、明胶5份、氯化钡2份、纳米二氧化硅3份、棕榈酸3份、二甲基丙烯酸聚乙二醇酯5份、去离子水100份；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1小时，再向球磨后的混合物加入去离子水，在2000 rpm的搅拌速率下搅拌2小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化50分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温25分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入棕榈酸、二甲基丙烯酸聚乙二醇酯，在70℃下经高速剪切混合得到成品，其中剪切速率为9000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
对比例1
（1）按所述重量份准确称取丙基三乙氧基硅烷40份、苯乙烯马来酸酐树脂35份、丁苯透明抗冲树脂30份、亚磷酸二苯基十三烷酯23份、聚乙二醇单硬脂酸酯15份、过氧化苯甲酰9份、聚二甲基二烯丙基氯化铵9份、十二烷基磺酸钠7份、明胶4份、氯化钡3份、纳米二氧化硅2份、柠檬酸4份、二甲基丙烯酸聚乙二醇酯4份、去离子水100份；
（2）将十二烷基磺酸钠、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1.5小时，再向球磨后的混合物加入去离子水，在1500 rpm的搅拌速率下搅拌2.5小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯，待混合均匀后高速乳化45分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温30分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入柠檬酸、二甲基丙烯酸聚乙二醇酯，在65℃下经高速剪切混合得到成品，其中剪切速率为12000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
对比例2
（1）按所述重量份准确称取丙基三乙氧基硅烷45份、苯乙烯马来酸酐树脂30份、亚磷酸二苯基十三烷酯20份、聚乙二醇单硬脂酸酯18份、羽扇醇棕榈酸酯10份、聚二甲基二烯丙基氯化铵8份、十二烷基磺酸钠8份、盐酸木质素4份、明胶5份、氯化钡2份、纳米二氧化硅3份、棕榈酸3份、二甲基丙烯酸聚乙二醇酯5份、去离子水100份；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1小时，再向球磨后的混合物加入去离子水，在2000 rpm的搅拌速率下搅拌2小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化50分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温25分钟；
（4）待混合液冷却至室温后，加入聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理，超声震荡的功率为500W，超声震荡的时间为2小时，随后加入棕榈酸、二甲基丙烯酸聚乙二醇酯，在70℃下经高速剪切混合得到成品，其中剪切速率为9000 rpm，剪切时间为30分钟。
制得的具有抗菌性能的纺织助剂的性能测试结果如表1所示。
将实施例1-4和对比例1-2的具有抗菌性能的纺织助剂分别施用于纺织物后进行金黄色葡萄球菌杀菌率、绿脓杆菌杀菌率、回复角这几项测试。
表1
金黄色葡萄球菌杀菌率（%） 绿脓杆菌杀菌率（%） 回复角（°）
实施例1 96.9% 96.0% 253
实施例2 97.6% 96.8% 261
实施例3 97.3% 96.5% 259
实施例4 97.1% 95.7% 249
对比例1 92.8% 91.3% 196
对比例2 92.4% 91.0% 183
本发明的具有抗菌性能的纺织助剂以丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯为主要成分，通过加入聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯、过氧化苯甲酰、聚二甲基二烯丙基氯化铵、十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅、有机酸、交联剂、去离子水，辅以球磨、搅拌、乳化、调节pH、加热、保温、超声震荡、高速剪切等工艺，使得制备而成的纺织助剂在使用后可使纺织物具有良好的抗菌效果，同时具有一定的抗皱效果，能够满足行业的要求，具有较好的应用前景。本发明的具有抗菌性能的纺织助剂原料廉价、工艺简单，适于大规模工业化运用，实用性强。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (6)

1.一种具有抗菌性能的纺织助剂，其特征在于：由下列重量份的原料制成：丙基三乙氧基硅烷35-45份、苯乙烯马来酸酐树脂30-40份、丁苯透明抗冲树脂28-32份、亚磷酸二苯基十三烷酯20-26份、聚乙二醇单硬脂酸酯12-18份、羽扇醇棕榈酸酯10-14份、过氧化苯甲酰8-10份、聚二甲基二烯丙基氯化铵8-10份、十二烷基磺酸钠6-8份、盐酸木质素4-6份、明胶3-5份、氯化钡2-4份、纳米二氧化硅1-3份、有机酸3-5份、交联剂3-5份、去离子水100份。
2.根据权利要求1所述的具有抗菌性能的纺织助剂，其特征在于：所述有机酸选自棕榈酸、柠檬酸、亚油酸中的任意一种。
3.根据权利要求1所述的具有抗菌性能的纺织助剂，其特征在于：所述交联剂选自亚甲基二丙烯酰胺、二甲基丙烯酸聚乙二醇酯、乙二醇二缩水甘油醚中的任意一种。
4.根据权利要求1-3任一所述的具有抗菌性能的纺织助剂的制备方法，其特征在于，包括以下步骤：
（1）按所述重量份准确称取各原料；
（2）将十二烷基磺酸钠、盐酸木质素、明胶、氯化钡、纳米二氧化硅加入球磨机中，球磨1-2小时，再向球磨后的混合物加入去离子水，在1000-2000 rpm的搅拌速率下搅拌2-3小时，得初步混合液；
（3）将初步混合液送入反应釜中，加入丙基三乙氧基硅烷、苯乙烯马来酸酐树脂、丁苯透明抗冲树脂、亚磷酸二苯基十三烷酯、聚乙二醇单硬脂酸酯、羽扇醇棕榈酸酯，待混合均匀后高速乳化40-50分钟，得乳化混合液，随后加入0.5 mol/L的HCl溶液调节混合液pH至5.5，加热至90℃，保温25-35分钟；
（4）待混合液冷却至室温后，加入过氧化苯甲酰、聚二甲基二烯丙基氯化铵，在超声震荡器中超声处理2-3小时，随后加入有机酸、交联剂，在60-70℃下经高速剪切混合得到成品。
5.根据权利要求4所述的具有抗菌性能的纺织助剂的制备方法，其特征在于，所述步骤（4）中，超声震荡的功率为500W，超声震荡的时间为2小时。
6.根据权利要求4所述的具有抗菌性能的纺织助剂的制备方法，其特征在于，所述步骤（4）中，剪切速率为9000-15000rpm，剪切时间为30分钟。
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