CN108451836A - A kind of shower cream composition and preparation method thereof - Google Patents
A kind of shower cream composition and preparation method thereof Download PDFInfo
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- CN108451836A CN108451836A CN201810680489.XA CN201810680489A CN108451836A CN 108451836 A CN108451836 A CN 108451836A CN 201810680489 A CN201810680489 A CN 201810680489A CN 108451836 A CN108451836 A CN 108451836A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
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Abstract
The present invention relates to a kind of shower cream compositions and preparation method thereof.The constituent of the shower cream composition is natural materials, wherein in terms of the gross mass of the shower cream composition, including following components：Soapberry extract：5 50%, preferably 10 40%；Tea seed extract：1 30%, preferably：5 25%；Natural oil：0.1 5%, preferably：0.2 3%；Natural antiseptic agent：0.1 2%, preferably：0.2 1%；Natural thickener：0.1 5%, preferably：0.2 3%.The shower cream composition of the present invention is derived from natural materials, not only has cleaning function, and have both the multi-efficiencies such as moisturizing degerming, small to skin irritation, safety is excellent.Further, the preparation method of shower cream composition of the invention has very high safety and lower cost, is suitble to the production of industrial-scale.
Description
Technical field
The present invention relates to a kind of shower cream composition and preparation method thereof, the constituent of the shower cream composition is day
Right substance, belongs to cosmetic field.
Background technology
As the improvement of people's living standards, the quality requirement to shower cream is also higher and higher.Such as：It needs mildly to moisten
Skin will not cause skin the shower cream of stimulation.
Existing shower cream is usually soap base type shower cream.The alkalinity of soap base type shower cream is strong, and skin is easy to cause after shower
Skin is dry and astringent, tight, itch.And the shower cream containing surfactant based on synthetic surfactant is easy in skin surface
Excessive residual and a variety of skin problems such as cause skin irritatin.Such as account for larger " the fatty alcohol polyoxyethylene ether sulfuric acid in washing market
Salt AES ", raw material will produce dioxanes in sulphation production.Dioxanes is during the generally acknowledged meeting in the whole world causes human skin to contact
Poison, it is irritant to skin, eye and respiratory system, and liver, kidney and nervous system may be damaged, while being also one kind
Chemical carcinogen, although the low toxicity accumulation results being used for a long time (between 25PPM) caused by the cleaning product of content are
Very important.
With the improvement of quickening and the living conditions of modern life rhythm, the frequency of use of shower cream also improves therewith,
In this regard, a kind of shower cream that is more natural mild and nourishing is needed to have become technology urgently to be resolved hurrily to meet daily use demand
Problem.
Invention content
Problems to be solved by the invention
In view of shower cream in the prior art, such as：Lead to that skin is dry and astringent, tight, scabies after shower
Itch；There is certain irritation to skin, easily causes allergy, safety poor；Present invention firstly provides a kind of all natural shower creams
Composition not only has cleaning function, has both the multi-efficiencies such as moisturizing degerming.
Further, the present invention also provides a kind of raw materials to be easy to obtain, the system of the simple shower cream composition of preparation method
Preparation Method.
The solution to the problem
The present invention provides a kind of shower cream composition, and the constituent of the shower cream composition is natural materials, wherein
In terms of the gross mass of the shower cream composition, including following components：
Soapberry extract：5-50%, preferably 10-40%；
Tea seed extract：1-30%, preferably：5-25%；
Natural oil：0.1-5%, preferably：0.2-3%；
Natural antiseptic agent：0.1-2%, preferably：0.2-1%；
Natural thickener：0.1-5%, preferably：0.2-3%.
Shower cream composition according to the present invention, wherein in the soapberry extract, sapindoside substance contains
Amount is more than 50 mass %, preferably more than 70 mass %.
Shower cream composition according to the present invention, wherein in the tea seed extract, the content of tea saponin is in 40 mass %
More than, preferably more than 60 mass %.
Shower cream composition according to the present invention, wherein the natural oil includes grape seed oil, macadimia nut oil, olive
Olive oil, Sweet Almond Oil, sunflower oil, avocado oil, thorn A Gan trees benevolence oil, saualane, jojoba oil, baobab seeds of trees oil, cashew nut
The combination of one or more of seed oil, borage seed oil, rapeseed oil, Butyrospermum parkii fruit fat and camellia seed oil.
Shower cream composition according to the present invention, wherein the natural thickener includes sodium alginate, tara gum, determines
The combination of one or more of gelatin, melon bean gum and carrageenan sodium.
Shower cream composition according to the present invention, wherein the natural antiseptic agent includes chitosan, clove leaf oil and p-
The combination of one or more of anisic acid, preferably includes chitosan.
Shower cream composition according to the present invention, wherein the shower cream composition further includes natural aromatic agent, with described
The addition of the gross mass meter of shower cream composition, the natural aromatic agent is 0.001-1%, preferably 0.01-0.5%.
Shower cream composition according to the present invention, wherein the natural aromatic agent includes Yilan caul-fat, rose oil, smokes
Clothing grass essential oil, chamomile essential oil, Geranium Essential, flores aurantii essential oil, Peppermint essential oil, Rosemary Oil, sweet orange oil and tea tree essence
The combination of one or more of oil.
The present invention also provides a kind of preparation methods of shower cream composition according to the present invention, wherein including being washed one's hair described
The step of each component mixing of bath lotion composition.
Preparation in accordance with the present invention, wherein include the following steps：
Soapberry extract, tea seed extract, natural thickener and water are placed in reaction kettle, 70- is heated with stirring to
It 75 DEG C and dissolves, stirring cools to 45-55 DEG C；
By natural oil, natural antiseptic agent and optionally natural aromatic agent be added reaction kettle after stir 20-40 minutes.
The effect of invention
The shower cream composition of the present invention is derived from natural materials, not only have cleaning function, and have both moisturizing degerming etc.
Multi-efficiency, small to skin irritation, safety is excellent.
Further, the preparation method of shower cream composition of the invention has very high safety and lower cost,
It is suitble to the production of industrial-scale.
Specific implementation mode
It will be detailed below various exemplary embodiments, feature and the aspect of the present invention.Dedicated word " example herein
Property " mean " being used as example, embodiment or illustrative ".Any embodiment here as illustrated by " exemplary " should not necessarily be construed as
Preferred or advantageous over other embodiments.
In addition, in order to better illustrate the present invention, numerous details is given in specific implementation mode below.
It will be appreciated by those skilled in the art that without certain details, the present invention can equally be implemented.In other example,
Method well known to those skilled in the art, means, equipment and step are not described in detail, in order to highlight the master of the present invention
Purport.
The present invention provides a kind of shower cream composition, and the constituent of the shower cream composition is natural materials, this hair
Bright natural materials mean non-chemical synthetic, wherein
In terms of the gross mass of the shower cream composition, including following components：
Soapberry extract：5-50%, preferably 10-40%；
Tea seed extract：1-30%, preferably：5-25%；
Natural oil：0.1-5%, preferably：0.2-3%；
Natural antiseptic agent：0.1-2%, preferably：0.2-1%；
Natural thickener：0.1-5%, preferably：0.2-3%.
The soapberry extract of the present invention is derived from soapberry.Soapberry benevolence contains protein about 31.87%, and ash content is about
5.19%, total non-fiber carbohydrate about 14.86%, pentosan about 2.21%, starch about 11.94%, crude fibre is about
14.14%.In addition, also containing aliphatic acid , behenic acids (behenic acid) and lignoceric acid.The seed of soapberry is fatty
Oil about 43.18%.Soapberry contains Surface Active Substance, containing terpene, steroid saponin in the surface reactive material, amino acid,
Protein, vitamin, oleic acid, grease.The pericarp of soapberry contains I a of soapberry Sesquiterpene glucoside, I b, II a, II b, soapberry soap
Glucoside X, Y1, Y2, E, G, Sapindus saponin A, B, hederagenin, hederagenin a-L- pyrans Ah Bais glycosyl (1 →
3)-a-L- rhamnopyranosyls (1 → 2)-a-L- arabopyranose glucosides, hederagenin-a-L- arabinofuranosyls
(1 → 3)-a-L- rhamnopyranosyls (1 → 2)-a-L- arabopyranose glucosides etc..
In the soapberry extract of the present invention, the content of sapindoside substance is more than 50 mass %, preferably 70
Quality % or more.Its content of ashes is generally in 10 mass % hereinafter, impurity is less；Moisture in 10 mass % hereinafter, it is preferred that
Below 9 mass %.In addition, the silty of soapberry extract is fine and smooth, at least 80 mass % can be sieved by 80 mesh.
The soapberry extract of the present invention can effectively reduce the surface tension of water, make the shower cream composition of the present invention
Foaming abundancy, feel is fine and smooth, strong detergency, has antibacterial, environmental protection, takes out stains, antibacterial beauty, tender skin, brightens and dispel
The features such as spot, anti-acne, prevention skin disease.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of soapberry extract is 5-50%,
Preferably 10-40%.
The tea seed extract of the present invention is derived from the seed of plant of theaceae.Contain triterpene soap in the seed of plant of theaceae
Glucoside.Camellia sapogenol A, theasapogenol A and B, D-Glucose aldehydic acid, D-Glucose, D- galactolipins, D- xyloses, Radix Angelicae Sinensis are obtained after hydrolysis
Acid, crotonic acid and alpha -methyl butyric acid etc..
Tea saponin is a kind of sugared formula compound, it belongs to saponin class, is a kind of natural nonionic surface active agent.The present invention
Tea seed extract in, the content of tea saponin is more than 40 mass %, preferably more than 60 mass %.
In the present invention, when tea seed extract mass concentration in aqueous solution is 10%, pH value 5.0-6.5 it
Between.
In the present invention, tea saponin has the function of good emulsification, dispersion, foaming, moistening etc., and can have and disappear
The pharmacological actions such as inflammation, analgesia, impermeabilisation, antibacterial.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of tea seed extract is 1-30%, excellent
It is selected as 5-25%.
The natural oil of the present invention is derived from natural materials, can be moisturized the skin, and skin tight feeling is reduced.It is described natural
Grease includes but not limited to grape seed oil, macadimia nut oil, olive oil, Sweet Almond Oil, sunflower oil, avocado oil, thorn A Ganshu
Benevolence oil, saualane, jojoba oil, baobab seeds of trees oil, cashew nut seed oil, borage seed oil, rapeseed oil, Butyrospermum parkii fruit fat and
The combination of one or more of camellia seed oil.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of natural oil is 0.1-5%, excellent
It is selected as 0.2-3%.
In the present invention, used preservative is natural antiseptic agent, and natural antiseptic agent of the invention derives from naturally
Substance.
In the present invention, the natural antiseptic agent includes but not limited to one in chitosan, clove leaf oil and p- anisic acid
Kind or two or more combinations.
The chitosan of the present invention be using chitin as raw material, it is not soluble in water then through refining, diluted acid can be dissolved in, can quilt
Absorption of human body.Chitosan is the first order derivatives of chitin.Its chemical constitution is that the macromolecule alkaline polysaccharide with cation polymerize
Object, and have the function of unique physicochemical property and bioactivation.In the present invention, chitosan has good moisture absorption, moisturizing, tune
The functions such as reason, antibacterial.
Using after chitosan, shower cream composition of the invention can not only play the role of corrosion-resistant, and compare and make
With other natural antiseptic agents, the great promotion obtained using the foaming abundancy sense of shower cream composition after chitosan.In this hair
In bright, it is preferable to use chitosans for natural antiseptic agent.
The clove leaf oil of the present invention is to carry out steam distillation from clove leaf with steam distillation to extract the essential oil obtained.
Specific ingredient is mainly based on eugenol, acetyl group eugenol (acetic acid cloves ester), second position carypohyllene.In the present invention, it uses
Clove leaf oil can play the role of certain antisepsis and sterilization.
The p- anisic acid of the present invention is steamed using water vapour from the sprout, blade and fruit of the fresh Chinese anise of plant
It evaporates and obtains fennel oil, then p- anisic acid is made to fennel oil rectification and purification.In cosmetic composition, due to p- anisic acid
Antiseptic property is weaker, therefore it can generally be applied as anti-corrosive aids in cosmetics.But in the present invention, use is p-
Anisic acid can effectively play corrosion-resistant effect, and the shower cream composition of the present invention can be made to resist the pollution of microorganism etc., had
Effect improves the antiseptic property of shower cream.In addition, can be with the pH value of regulation system using p- anisic acid.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of natural antiseptic agent is 0.1-2%,
Preferably 0.2-1%.
The natural thickener of the present invention is derived from natural materials, and the shower cream composition for the present invention provides suitable viscosity
And have both good moisture retention.In the present invention, the natural thickener includes sodium alginate, tara gum, cassia gum, melon
The combination of one or more of bean gum and carrageenan sodium.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of natural thickener is 0.1-5%,
Preferably 0.5-3%.
In the present invention, the shower cream composition can also include natural aromatic agent, can assign shower cream composition
The smell of fragrance.Preferably, the natural aromatic agent include Yilan caul-fat, rose oil, Lavender, chamomile essential oil,
One or more of Geranium Essential, flores aurantii essential oil, Peppermint essential oil, Rosemary Oil, sweet orange oil and tea tree ethereal oil
Combination.Above-mentioned natural aromatic agent is selected also to have the effect of skin maintenance.
In the present invention, in terms of the gross mass of the shower cream composition, the addition of the natural aromatic agent is
0.001-1%, preferably 0.01-0.5%.
In addition, the present invention can also add a certain amount of other natural extracts with moisturizing, Bearberry Extract.With institute
The gross mass meter of shower cream composition is stated, the content of other natural extracts can be between 0-20%.
Preferably, in the present invention, also contain water, it is however generally that, in terms of the gross mass of the shower cream composition, water
Content can be 15-90%, preferably 30-84.4%.
The present invention also provides a kind of preparation methods of shower cream composition according to the present invention, including by the shower cream group
The step of closing each component mixing of object.
Specifically, the preparation method of the shower cream composition of the present invention includes the following steps：
Soapberry extract, tea seed extract, natural thickener and water are placed in reaction kettle, 70- is heated with stirring to
It 75 DEG C and dissolves, stirring cools to 45-55 DEG C；
By natural oil, natural antiseptic agent and optionally natural aromatic agent be added reaction kettle after stir 20-40 minutes.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
It can be with conventional products that are commercially available.
Embodiment 1-12
According to the mass percent of each component in the following table 1, based on total weight 100%, and it is prepared by the following method
The shower cream composition of embodiment 1-12.
Wherein, in soapberry extract, the content of sapindoside substance is 70 mass %, and content of ashes is 10 matter
Measure %；Moisture is 8 mass %；The soapberry extract of 90 mass % can be sieved by 80 mesh.
In tea seed extract, the content of tea saponin is 67.4 mass %.Its moisture is 5.6 mass %.When tea seed carries
Take the mass concentration of object in aqueous solution be 10% when, pH value 5.6.
The preparation method of embodiment 1-12 is：
Soapberry extract, tea seed extract, natural thickener and water are placed in reaction kettle, are heated with stirring to 75 DEG C
And dissolve, stirring cools to 50 DEG C；
It stirs 30 minutes, obtains after reaction kettle is added in natural oil and natural antiseptic agent and optionally natural aromatic agent
Shower cream composition.
Table 1
Table 2
Comparative example 1-6
According to the mass percent of each component of comparative example 1-6 in the following table 3, based on total weight 100%, and according to implementation
The shower cream composition of comparative example 1-6 is prepared in the identical methods of example 1-12.
Table 3
Performance test
Preservation challenge tests (being tested according to the method for European Pharmacopoeia (EP 7.0)), and test result is as follows shown in table 4：
Table 4
As can be seen from Table 4, the present invention can effectively reduce product microbial contamination by the way that natural antiseptic agent is added
Risk.Without add natural antiseptic agent comparative example 1 it is higher at 7 days, 14 days, 21 days and 28 days containing bacteria concentration, because
This, preparation-obtained shower cream composition can microbial contamination.
Effect assessment is tested
The shower cream of embodiment 5 and comparative example 1-6 are dispensed 60 parts in the test Packaging Bottle of 100mL, purchase is commercially available
Shower cream M is dispensed in 60 parts of test Packaging Bottles to 100mL, is issued test crowd (60 people) and is compared use.Each shower cream
Continuous use two weeks, tester scores according to use feeling.Standards of grading are using 7 points of systems, and 1 point is worst, and 7 points are best, point
The higher the better for number.Effect assessment experimental result is as shown in table 5 below.
Table 5
As can be seen from Table 5, shower cream composition of the invention be easy to rinse well and use after it is antipruritic, grow
Profit, moisturizing etc. have greater advantage compared to the shower cream composition of comparative example 1 and commercially available shower cream M.In addition, the present invention exists
After natural antiseptic agent (especially chitosan), the foaming abundancy sense of shower cream composition of the invention also obtains great
It is promoted.
Natural antiseptic agent is not contained in comparative example 1, the lather quickness of shower cream composition is slower, and foaming abundancy degree is relatively low.
Not within the scope of this application, shower cream combines for soapberry extract and the content of tea seed extract in comparative example 2
The lather quickness of object is slower, and the careful degree of foam, richness are relatively low, and effectively antibacterial situation is poor.
Tea seed extract is not contained in comparative example 3, although the soapberry extract containing high level, uses comparison
After the shower cream composition of example 3 is taken a shower, the moisturizing degree of skin is poor, and it is poor to moisten comfort level.
Soapberry extract is not contained in comparative example 4, although the tea seed extract containing high level, uses comparison
After the shower cream composition of example 4 is taken a shower, the moisturizing degree of skin is also poor, and it is also poor to moisten comfort level.
The content of sodium alginate is only 0.08wt% in comparative example 5, and not within the scope of this application, the appearance of shower cream is liked
Spend well it is poor, and using comparative example 5 shower cream composition take a shower after, the moisturizing degree of skin is slightly poor, moisten comfort level it is slightly poor.
Natural oil is not contained in comparative example 6, after being taken a shower using the shower cream composition of comparative example 6, the moisturizing degree of skin
It is slightly poor, it is slightly poor to moisten comfort level.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain
Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.
Claims (10)
1. a kind of shower cream composition, which is characterized in that the constituent of the shower cream composition is natural materials, wherein
In terms of the gross mass of the shower cream composition, including following components：
Soapberry extract：5-50%, preferably 10-40%；
Tea seed extract：1-30%, preferably：5-25%；
Natural oil：0.1-5%, preferably：0.2-3%；
Natural antiseptic agent：0.1-2%, preferably：0.2-1%；
Natural thickener：0.1-5%, preferably：0.2-3%.
2. shower cream composition according to claim 1, which is characterized in that in the soapberry extract, soapberry soap
The content of glucoside substance is more than 50 mass %, preferably more than 70 mass %.
3. shower cream composition according to claim 1 or 2, which is characterized in that in the tea seed extract, tea saponin
Content is more than 40 mass %, preferably more than 60 mass %.
4. according to claim 1-3 any one of them shower cream compositions, which is characterized in that the natural oil includes grape
Seed oil, macadimia nut oil, olive oil, Sweet Almond Oil, sunflower oil, avocado oil, thorn A Gan trees benevolence oil, saualane, jojoba oil,
Baobab seeds of trees oil, cashew nut seed oil, borage seed oil, rapeseed oil, Butyrospermum parkii fruit fat and one kind in camellia seed oil or two
Kind or more combination.
5. according to claim 1-4 any one of them shower cream compositions, which is characterized in that the natural thickener includes brown
The combination of one or more of mosanom, tara gum, cassia gum, melon bean gum and carrageenan sodium.
6. according to claim 1-5 any one of them shower cream compositions, which is characterized in that the natural antiseptic agent includes shell
The combination of one or more of glycan, clove leaf oil and p- anisic acid, preferably includes chitosan.
7. according to claim 1-6 any one of them shower cream compositions, which is characterized in that the shower cream composition also wraps
Natural aromatic agent is included, in terms of the gross mass of the shower cream composition, the addition of the natural aromatic agent is 0.001-1%,
Preferably 0.01-0.5%.
8. shower cream composition according to claim 7, which is characterized in that the natural aromatic agent include Yilan caul-fat,
Rose oil, Lavender, chamomile essential oil, Geranium Essential, flores aurantii essential oil, Peppermint essential oil, Rosemary Oil, sweet orange essence
The combination of oil and one or more of tea tree ethereal oil.
9. a kind of preparation method according to claim 1-8 any one of them shower cream compositions, which is characterized in that including inciting somebody to action
The step of each component mixing of the shower cream composition.
10. preparation method according to claim 9, which is characterized in that include the following steps：
Soapberry extract, tea seed extract, natural thickener and water are placed in reaction kettle, are heated with stirring to 70-75 DEG C
And dissolve, stirring cools to 45-55 DEG C；
By natural oil, natural antiseptic agent and optionally natural aromatic agent be added reaction kettle after stir 20-40 minutes.
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| CN201810680489.XA CN108451836B (en) | 2018-06-27 | 2018-06-27 | Shower gel composition and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528619A (en) * | 2019-01-30 | 2019-03-29 | 中吉亚科技(广州)有限公司 | A kind of deodorizing type shower cream |
| CN111419772A (en) * | 2020-05-11 | 2020-07-17 | 广州市科能化妆品科研有限公司 | Natural mild shower gel and preparation method thereof |
| CN111617004A (en) * | 2020-06-28 | 2020-09-04 | 厦门伟礼沐浴用品有限公司 | Exfoliating shower gel and preparation method thereof |
| CN113499284A (en) * | 2021-07-09 | 2021-10-15 | 上海北即电子商务有限公司 | Shampoo oil capable of purifying scalp hair follicles and preparation method thereof |
| CN115252505A (en) * | 2022-09-09 | 2022-11-01 | 中华全国供销合作总社南京野生植物综合利用研究所 | Compound plant composition with cleaning effect and preparation method and application thereof |
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| CN103479539A (en) * | 2013-08-16 | 2014-01-01 | 广州环亚化妆品科技有限公司 | Shampoo containing natural saponin and natural thickener |
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| CN109528619A (en) * | 2019-01-30 | 2019-03-29 | 中吉亚科技(广州)有限公司 | A kind of deodorizing type shower cream |
| CN111419772A (en) * | 2020-05-11 | 2020-07-17 | 广州市科能化妆品科研有限公司 | Natural mild shower gel and preparation method thereof |
| CN111419772B (en) * | 2020-05-11 | 2022-09-13 | 广州市科能化妆品科研有限公司 | Natural mild shower gel and preparation method thereof |
| CN111617004A (en) * | 2020-06-28 | 2020-09-04 | 厦门伟礼沐浴用品有限公司 | Exfoliating shower gel and preparation method thereof |
| CN113499284A (en) * | 2021-07-09 | 2021-10-15 | 上海北即电子商务有限公司 | Shampoo oil capable of purifying scalp hair follicles and preparation method thereof |
| CN115252505A (en) * | 2022-09-09 | 2022-11-01 | 中华全国供销合作总社南京野生植物综合利用研究所 | Compound plant composition with cleaning effect and preparation method and application thereof |
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Effective date of registration: 20220110 Address after: No.23, Xianke 2nd Road, Huadong Town, Huadu District, Guangzhou City, Guangdong Province, 510890 Patentee after: GUANGZHOU KENENG COSMETIC RESEARCH Co.,Ltd. Patentee after: Guangdong Danzi Group Co., Ltd Address before: No.23, Xianke 2nd Road, Huadong Town, Huadu District, Guangzhou City, Guangdong Province, 510890 Patentee before: GUANGZHOU KENENG COSMETIC RESEARCH Co.,Ltd. Patentee before: GUANGZHOU BAIYUN LIANJIA FINE CHEMICAL PLANT Patentee before: GUANGDONG DANZ GROUP Co.,Ltd. |