CN109528619A

CN109528619A - A kind of deodorizing type shower cream

Info

Publication number: CN109528619A
Application number: CN201910091694.7A
Authority: CN
Inventors: 黄玉真; 韩菲桐; 谢煌; 杨海景
Original assignee: China Gea Science And Technology (guangzhou) Co Ltd
Current assignee: China Gea Science And Technology (guangzhou) Co Ltd
Priority date: 2019-01-30
Filing date: 2019-01-30
Publication date: 2019-03-29

Abstract

The present invention provides a kind of deodorizing type shower cream, according to weight percent, it consists of the following compositions: modified Nano active carbon, marine algae extract, hamamelis extract, PCA zinc, lemon extract, sweet orange extract, tea seed essential oil, ethereal oil of flower, milk extract, Chinese herbal medicine preservative, other auxiliary agents and deionized water, wherein modified Nano active carbon is acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon, primary raw material used in this formula of bath cream is the raw material that peculiar smell is removed in degradable deodorizing, it can be biodegradable, using safety and environmental protection raw material, deodorizing goes peculiar smell ability strong, performance is mildly safe, it is skin friendly, improve dirt-removing power, using can have excellent dirt-removing power on a small quantity, and the moisturizing and nourishing of skin is acted on.

Description

A kind of deodorizing type shower cream

Technical field

The present invention relates to articles for washing fields, and in particular to a kind of deodorizing type shower cream.

Background technique

Shower cream is also known as bath oil, is a kind of liquid ceanser used when having a bath, and since its effect is good, performance is mild, Calcium deposition will not be generated in use process in skin surface, become a kind of important bath article of substitution perfumed soap, traditional washes one's hair Bath lotion use is single, and alkalinity is larger, larger to skin irritatin and injury, as the improvement of people's living standards, to shower cream Function needs are higher and higher, and the multi-functional shower cream such as sterilization, whitening, which increasingly replaces, has single cleaning solution,

But compared to soap, the dirt-removing power of shower cream is weaker, crowds relatively more or Oily for volume of perspiration, warp Often feel not washing clean, the soap that needs to arrange in pairs or groups uses, program trouble, while be easy to causeing skin peeling dry and cracked.

Summary of the invention

To solve problems of the prior art, the present invention provides a kind of deodorizing type shower cream, which goes It is smelly to go peculiar smell ability strong, it is good to nourish skin effect.

In order to achieve the above objectives, the technical scheme is that a kind of deodorizing type shower cream, according to weight percent, by Following component composition:

Modified Nano active carbon: 25~35%

Marine algae extract: 5~10%

Hamamelis extract: 5~10%

PCA zinc: 2~5%

Lemon extract: 2~5%

Sweet orange extract: 2~5%

Tea seed essential oil: 3~5%

Ethereal oil of flower: 1~2%

Milk extract: 2~5%

Chinese herbal medicine preservative: 0.1~1%

Other auxiliary agents: 0.5~1%

Deionized water: surplus

Wherein, modified Nano active carbon is acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon, Its chemical formula is

Using above-mentioned formula, modified Nano active carbon (AcF) is added in formula of bath cream, active carbon nanoparticles are because of itself Characteristic and the characteristics such as pore structure, pore size distribution, micro pore surface area, make that its large specific surface area, aperture are moderate, are evenly distributed and adsorb Speed is fast, has stronger absorption property, makes shower cream while decontamination is deoiled, and can effectively adsorb sweat secretion or divide The stink of the generations such as solution, female gynecological disease or other peculiar smell, active carbon nanoparticles particle are particulate object, can be used as and rub Liniment is acted on by particle friction, is realized the washing to skin surface and is gone the effect itched, and active carbon nanoparticles particle is small, Human body will not be made to generate sense of discomfort, and be easy to rinse, the active carbon nanoparticles under rinsing can continue to adsorb the discharge ground such as bathroom Stink and the peculiar smell such as musty；The many acyl methyl dodecyl alcohol ether sulphur as surfactant of active carbon nanoparticles surface graft Sour sodium and stearamide, wherein the dodecyl in acyl methyl dodecyl ether sulfate, stearamide octadecyl and Amide groups is the fabulous lipophilic group of oleophylic performance, and lipophilic group value volume and range of product is more, and oleophylic effect is good, sulphation sodium It is stronger hydrophilic radical with the alcohol ether being connected with sulfate, hydrophilicity is good, good water solubility, therefore acyl methyl dodecyl Ether sulfate-stearamide nano modification active carbon amphipathic property can be relatively strong, has higher activity function, decontamination Ability is strong, therefore can reduce the dosage of surfactant, save the cost, to reduce the discharge of surfactant, while acyl Methyl dodecyl ether sulfate and stearamide are degradable within a short period of time, avoid polluting water and environment； Lemon extract is added in formula, stink or peculiar smell are issued by amine, and from pH value, they are weakly alkaline, lemons Contain citric acid in lemon extract, acid-base neutralization reaction played when reacting with it, can thus amine substance be made to become ammonium salt, And ammonium salt be it is insipid, effectively eliminate stink, while adjusting ph value, reduce the alkalinity of entire shower cream；Sweet orange mentions Taking on the orange bark extract in object has the body of gland that can generate volatile oil, and volatile oil caused by it can remove different in air Taste, can also Titian.

Marine algae extract is added in formula, it is interior to contain phycocolloid acid, thick egg for a kind of pure natural marine organisms product White, multivitamin, enzyme and microelement can reduce surface blood lipid after skin absorbs, and promote surface skin hematopoiesis function, There is bacteriostasis to vitro skin, there are also weight-reducing, insulation effects, and contain a large amount of anion in it, can stimulate fiber Cell generates collagen and elastin laminin, promotes the metabolism of skin, to have the function of smoothing wrinkle, anti-aging, simultaneously Have the function of thickening, has both thickener effect in formula；Hazel extract, the effect of Bearberry Extract, calm skin can be with Skin is rapidly permeated into, for adjusting skin, balance skin pH value and fat secretion in shower cream comprehensively from inside to outside, purifies hair Impaired skin is repaired in hole, effectively adjusts the pore of diastole, hence it is evident that convergence enlarged pores prevent blackhead, acne from generating, make skin Fine and smooth, smooth, tight is quickly presented, has very excellent effect for the skin of oily skin or allergy, can receive It holds back pore, mend wet, quiet flesh effect, the cleaning of deeper keeps skin more bright and clean smooth；PCA zinc, i.e. L- pyrrole are added in formula Pyrrolidone carboxylic sodium (L-PCA-Na) is the main component in keratoderma, is one of natural moisturizing factor, provides for skin Moisture-keeping function prevents from causing skin dry hide to crack because surfactant is in acid, while having excellent bacteriostasis property, and zinc can To reduce the excessive secretion of sebum, to help to maintain the eubolism of skin by the inhibition to 5-a reductase； Sweet orange extract has reduction capillary fragility, enhances the effect of blood vessel elasticity, the hesperidine contained in orange fruit can drop Low capillary fragility of blood vessels, prevents microvascular bleeding, is rich in vitamin C and flavone compound, and it is extra in removing human body to have Have the function of destructive free radical, prevent skin aging and skin sensitivity, vitamin C also has whitening function, orange Pulp can be removed the effect of free radical, enhancing haemocyte activity and protection cell, exempt from orange rich in vitamin enhancing human body Epidemic disease power, anti-flu can help removing toxic substances of sobering up；Tea seed essential oil in this formula of bath cream can be extracted from surplus tea grounds, be saved Cost recycles, energy conservation and environmental protection, while tea seed essential oil contains vitamin E and aging ingredient, can prevent skin injury and Aging, make skin have gloss, while can with pore refining, have significant whitening effect；Ethereal oil of flower is in the same of Titian When, according to the characteristic of every kind of fresh flower itself, replenishing water and preserving moisture, whitening nourishing, antiallergic of releiving, antiphlogistic antibacterial, conditioning can also be had both Sebum eliminates the effect of acne, crease-resistant reparation；Protein, vitamin and minerals rich in, have in milk extract Natural moisture preserving effect, is easily less readily available for absorption by the skin, and can prevent dry skin, and can repair dry line, milk has clean skin, skin softening and whitening It is good to nourish skin effect for effect；It selects the extract of edible Chinese herbal medicine as antisepsis antistaling agent in the present invention, usually makes It in range, has no toxic side effect, while according to the pharmacological action of every kind of Chinese herbal medicine itself, seasoning flavouring, nutrition can also be had both The effects of health care, antibacterial anti-inflammatory, cephalocathartic promoting blood circulation, while particle is small, is conducive to the absorption of skin.

Further, the pH value of shower cream is 7~8, and for human body ph between 7.3~7.5, shower cream is weakly acidic, with people Body skin is suitable, will not injure skin, while dirt-removing power is also able to satisfy requirement.

Further, the preparation of acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon includes such as Lower step:

Step 1: active carbon nanoparticles surface oxidation and chlorination

Precise 10g active carbon nanoparticles AcF is placed in reaction kettle, and the dense nitre that 150ml mass fraction is 65wt% is added Reaction kettle is placed in 60 DEG C of constant temperature of magnetic stirring apparatus by acid, and after being condensed back reaction 14h, oxidation product is filtered, and spends Ionized water is rinsed, until solution pH value tends to be neutral, after being dried in vacuo 48h, obtains oxidation product AcF-COOH；

Precise 8gAcF-COOH is added in reaction kettle, and 50ml thionyl chloride solution is added and is mixed with, stirring Under be slowly heated to 50 DEG C, be condensed back after reaction 20h, carried out respectively clearly with anhydrous methylene chloride and tetrahydrofuran solution It washes, removes not reacted raw material, vacuum drying for 24 hours, obtains chlorizate AcF-COCL；

Step 2: the preparation of stearamide modified Nano active carbon

10g chlorizate AcF-COCL and 2.7g octadecylamine is added in reaction kettle, the anhydrous methylene chloride of 80ml is added, At room temperature, it is stirred to react 10h, the mixture after reaction is separated by filtration, to anhydrous methylene chloride and tetrahydrofuran Solution is cleaned respectively, removes not reacted raw material, and vacuum drying for 24 hours, obtains product AcF-ODA；

Step 3: the preparation of acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon

3.2gN methyl dodecyl ether sulfate is added in four mouthfuls of reaction kettles with stirring, 20ml water is added and makees For solvent, after agitated reaction, at 15~20 DEG C, at the same be slowly added dropwise sodium hydroxide solution that mass fraction is 30% and 12gAcF-ODA controls lye rate of addition to maintain the stabilization of the PH of reaction system, after completion of dropwise addition, increases reaction temperature extremely 35 DEG C, continue to be stirred to react 2h, adjusts ph value to alkalescent with hydrochloric acid, obtain acyl methyl dodecyl ether sulfate-ten eight Amide nano modification active carbon.

In step 1 first using concentrated nitric acid to active carbon nanoparticles surface oxidation, keep the carboxyl on the surface of active carbon nanoparticles aobvious Expose, then react to obtain acid chloride groups with thionyl chloride, the C-CL key active force in acyl chlorides is weaker, is easy to happen disconnected Key, to make containing unsaturated electronics on C, while H is to live in the N-H in octadecylamine and N methyl dodecyl ether sulfate H is sprinkled, is easy that scission of link occurs with N, to make containing unsaturated electronics on N, the C containing unsaturated electronics forms saturation in conjunction with N Electronics pair, to form stability height, active force is strong, and the substance of generation is acyl methyl dodecyl ether sulfate-ten eight Amide nano modification active carbon, the wherein octadecane of the dodecyl in acyl methyl dodecyl ether sulfate, stearamide Base and amide groups are the fabulous lipophilic group of oleophylic performance, and lipophilic group value volume and range of product is more, and oleophylic effect is good, sulfuric acid The alcohol ether changing sodium and being connected with sulfate is stronger hydrophilic radical, and hydrophilicity is good, good water solubility, therefore acyl methyl 12 Alkyl alcohol ether sodium sulphate-stearamide nano modification active carbon amphipathic property can be relatively strong, has higher activity function, Dirt-removing power is strong, therefore can reduce the dosage of surfactant, save the cost, to reduce the discharge of surfactant, together When acyl methyl dodecyl ether sulfate and stearamide it is degradable within a short period of time, avoid causing dirt to water and environment Dye；

Further, other auxiliary agents include emulsifier, dispersing agent and thickener.

Existing water-soluble composition in formula, and there is lipophilic component, in order to mix water-soluble composition and lipophilic component more Add uniformly, stability is high, and lamination does not also occur in permanent place, needs that emulsifier is added；Dispersing agent evenly dispersed can be difficult to It is dissolved in the solid particle of liquid, dispersing agent is added in the present invention so that solid is preferably dispersed in the solution, while The sedimentation and cohesion of particle can be prevented, stable suspension is formed；Thickener can increase the viscosity and stability of shower cream.

Further, emulsifier is lecithin, is added to the lecithin as emulsifier in formula, and lecithin is both sexes Ionic surface active agent is generally extracted from soybean or yolk, highly-safe, and stimulation degree is low, and compatibility is good, has excellent cream The property changed and dispersibility keep shower cream particle fine and smooth, while being also a kind of good stabilizer, can coat shower cream raw material, prevent Only material crystal in cosmetics, and lecithin can promote the power of regeneration of skin, prevent lip pachylosis, wrinkle.

Further, dispersing agent is self-emulsifying monoglyceride,

This is securely and reliably used cooperatively with lecithin for food-grade dispersing agent, has excellent dispersion effect.

Further, thickener is sodium chloride, and sodium chloride improves the viscosity and stability of shower cream as thickener, Sodium chloride is safe and non-stimulating as food grade additives, will not injure skin, while also with the effect of preferable bactericidal antiphlogistic Fruit, while having the function of stabilizer.

Further, ethereal oil of flower is pot marigold essential oil, repeatedly one of essential oil, Rosa Damascana, Lavender Or it is a variety of,

Ethereal oil of flower is added in shower cream, while flavouring, also according to different with other the characteristics of plant itself The effect of, if pot marigold essential oil has moisturizing, wrinkle resistant effect, repeatedly there is essential oil clear refreshing restoring consciouness, stimulation nervous system to transport Make, refreshes oneself, enhances the effect of memory；Rosa Damascana has moisturizing, wrinkle resistant effect；Rose extract has moisturizing, wrinkle resistant The effect of；Lavender has antiallergy, anti-inflammatory, and antibacterial controls wound, freckle removing and whitening, and the tender skin of anti-wrinkle promotes damaged tissues Regeneration restores effect.

Further, Chinese herbal medicine preservative is Flos Caryophylli extract or cinnamomum cassia extract.

Flos Caryophylli extract contains volatile oil, and mainly oleic acid containing cloves, acetyl cloves oleic acid and cloves alkene, methyl be just in volatile oil The ingredients such as the positive heptanone of pentanone, methyl, vanillin have antibacterial and anthelmintic action, while also being used as fragrance；Cinnamomum cassia extract There is significant antibacterial action to staphylococcus aureus, typhoid bacillus and Bacillus tuberculosis, there is antibacterial and anthelmintic action, simultaneously It also is used as fragrance.

Further, the preparation method of deodorizing type shower cream, including following preparation step:

S1: being added suitable deionized water in a kettle, is slowly heated to 55~75 DEG C, and 25~35% modification is added Active carbon nanoparticles stir；

S2: after cooling the temperature to 35~40 DEG C, 5~10% marine algae extract is added, 5~10% witch hazel is extracted Object, 2~5% PCA zinc, 2~5% sweet orange extract, 2~5% milk extract and 0.5~1% other auxiliary agents, after It is continuous to stir evenly, form homogeneous phase solution；

S3: 2~5% lemon extract, 3~5% tea seed essential oil, 1~2% are added into the resulting product of step S2 Ethereal oil of flower, 0.1~1% Chinese herbal medicine preservative are mixed evenly up to deodorizing type shower cream.

Specific embodiment

The present invention is described in further details With reference to embodiment.

A kind of preparation method of deodorizing type shower cream, including following preparation step:

S1: being added suitable deionized water in a kettle, is slowly heated to 55~75 DEG C, and 25~35% acyl first is added Base dodecyl ether sulfate-stearamide nano modification active carbon, stirs；

S2: after cooling the temperature to 35~40 DEG C, 5~10% marine algae extract is added, 5~10% witch hazel is extracted Object, 2~5% PCA zinc, 2~5% sweet orange extract, 2~5% milk extract and 0.5~1% other auxiliary agents, Other auxiliary agents in the present invention include emulsifier lecithin, dispersing agent self-emulsifying monoglyceride and thickener sodium chloride, continue to stir Uniformly, homogeneous phase solution is formed；

S3: 2~5% lemon extract, 3~5% tea seed essential oil, 1~2% are added into the resulting product of step S2 Ethereal oil of flower, 0.1~1% Chinese herbal medicine preservative, are mixed evenly, filling to get finished product.

Temperature after heating is as follows in each embodiment step S1:

Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5	Embodiment 6
						75	65	70	68	60	55

Temperature is as follows after cooling down in each embodiment step S2:

Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5	Embodiment 6
						35	39	37	40	38	36

Raw material and percentage are as follows in each embodiment:

Wherein, the preparation of acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon includes following step It is rapid:

Step 1: active carbon nanoparticles surface oxidation and chlorination

Precise 10g active carbon nanoparticles (AcF) are placed in reaction kettle, and it is the dense of 65wt% that 150ml mass fraction, which is added, Reaction kettle is placed in 60 DEG C of constant temperature of magnetic stirring apparatus by nitric acid, after being condensed back reaction 14h, oxidation product is filtered, is used in combination Deionized water is rinsed, until solution pH value tends to be neutral, after being dried in vacuo 48h, obtains oxidation product AcF-COOH；

Precise 8gAcF-COOH is added in reaction kettle, and 50ml thionyl chloride solution is added and is mixed with, stirring Under be slowly heated to 50 DEG C, be condensed back after reaction 20h, carried out respectively clearly with anhydrous methylene chloride and tetrahydrofuran solution It washes, removes not reacted raw material, vacuum drying for 24 hours, obtains chlorizate

It is denoted as AcF-COCL.

Reaction equation is as follows:

Step 2: the preparation of stearamide modified Nano active carbon

10g chlorizate AcF-COCL and 2.7g octadecylamine is added in reaction kettle, the anhydrous methylene chloride of 80ml is added, At room temperature, it is stirred to react 10h, this step is particularly important, is the key that success synthesis final product, it is desirable that necessary Synthetic reaction is carried out under water-less environment, otherwise AcF-COCL meets water decomposition, and the compound after can not grafting will be mixed after reaction It closes object to be separated by filtration, is cleaned respectively to anhydrous methylene chloride and tetrahydrofuran solution, remove not reacted raw material, very Sky is dry for 24 hours, obtains product

It is denoted as AcF-ODA；

Reaction equation is as follows:

Marine algae extract is added in formula, it is interior to contain phycocolloid acid, thick egg for a kind of pure natural marine organisms product White, multivitamin, enzyme and microelement can reduce surface blood lipid after skin absorbs, and promote surface skin hematopoiesis function, There is bacteriostasis to vitro skin, there are also weight-reducing, insulation effects, and contain a large amount of anion in it, can stimulate fiber Cell generates collagen and elastin laminin, promotes the metabolism of skin, to have the function of smoothing wrinkle, anti-aging, simultaneously Have the function of thickening, has both thickener effect in formula；Hazel extract, the effect of Bearberry Extract, calm skin can be with Skin is rapidly permeated into, for adjusting skin, balance skin pH value and fat secretion in shower cream comprehensively from inside to outside, purifies hair Impaired skin is repaired in hole, effectively adjusts the pore of diastole, hence it is evident that convergence enlarged pores prevent blackhead, acne from generating, make skin Fine and smooth, smooth, tight is quickly presented, has very excellent effect for the skin of oily skin or allergy, can receive It holds back pore, mend wet, quiet flesh effect, the cleaning of deeper keeps skin more bright and clean smooth；PCA zinc, i.e. L- pyrrole are added in formula Pyrrolidone carboxylic sodium (L-PCA-Na) is the main component in keratoderma, is one of natural moisturizing factor, provides for skin Moisture-keeping function prevents from causing skin dry hide to crack because surfactant is in acid, while having excellent bacteriostasis property, and zinc can To reduce the excessive secretion of sebum, to help to maintain the eubolism of skin by the inhibition to 5-a reductase； Sweet orange extract has reduction capillary fragility, enhances the effect of blood vessel elasticity, the hesperidine contained in orange fruit can drop Low capillary fragility of blood vessels, prevents microvascular bleeding, is rich in vitamin C and flavone compound, and it is extra in removing human body to have Have the function of destructive free radical, prevent skin aging and skin sensitivity, vitamin C also has whitening function, orange Pulp can be removed the effect of free radical, enhancing haemocyte activity and protection cell, exempt from orange rich in vitamin enhancing human body Epidemic disease power, anti-flu can help removing toxic substances of sobering up；Tea seed essential oil in this formula of bath cream can be extracted from surplus tea grounds, be saved Cost recycles, energy conservation and environmental protection, while tea seed essential oil contains vitamin E and aging ingredient, can prevent skin injury and Aging, make skin have gloss, while can with pore refining, have significant whitening effect；Ethereal oil of flower is in the same of Titian When, according to the characteristic of every kind of fresh flower itself, other effects can also be had both, if pot marigold essential oil has moisturizing, wrinkle resistant effect, Repeatedly there is essential oil clear refreshing restoring consciouness, stimulation nervous system to operate, and refreshes oneself, enhances the effect of memory；Rosa Damascana, which has, to be protected Wet, wrinkle resistant effect；Rose extract has moisturizing, wrinkle resistant effect；Lavender have antiallergy, anti-inflammatory, antibacterial, Wound, freckle removing and whitening are controlled, the tender skin of anti-wrinkle promotes regeneration of damaged tissue to restore effect；Albumen rich in milk extract Matter, vitamin and minerals have natural moisture preserving effect, are easily less readily available for absorption by the skin, can prevent dry skin, and can repair dry Line, milk have clean skin, skin softening and blanching effect；Select the extract of edible Chinese herbal medicine as anti-corrosive fresh-keeping in the present invention Agent has no toxic side effect, while according to the pharmacological action of every kind of Chinese herbal medicine itself, having both other effects usually using in range, Flos Caryophylli extract as the present invention selects has antibacterial and anthelmintic action containing volatile oil, while also being used as fragrance；Cortex cinnamomi is extracted Object has significant antibacterial action to staphylococcus aureus, typhoid bacillus and Bacillus tuberculosis, has antibacterial and anthelmintic action, together When also be used as fragrance；Emulsifier in the present invention selects lecithin, because lecithin is zwitterionic surfactant, generally It is extracted from soybean or yolk, highly-safe, stimulation degree is low, and compatibility is good, has excellent emulsibility and dispersibility, makes to take a shower It is fine and smooth to reveal particle, while being also a kind of good stabilizer, shower cream raw material can be coated, prevent material crystal in cosmetics, And lecithin can promote the power of regeneration of skin, prevent lip pachylosis, wrinkle；Dispersing agent of the invention is self-emulsifying list Sweet rouge, this is securely and reliably used cooperatively with lecithin for food-grade dispersing agent, has excellent dispersion effect；In the present invention Thickener selective chlorination sodium improves the viscosity and stability of shower cream, and for sodium chloride as food grade additives, safety is stingless Swash, skin will not be injured, while also having the effect of preferable bactericidal antiphlogistic, while having the function of stabilizer.

PH test is carried out to the shower cream finished product of each embodiment, test result is as follows:

Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4	Embodiment 5	Embodiment 6
						7.3	7.1	7.3	7.2	7.5	7.8

It can be seen that PH test value, between 7~8, for human body ph between 7.3~7.5, shower cream is weakly acidic, with Human skin is suitable, will not injure skin, while dirt-removing power is also able to satisfy requirement.

Primary raw material used in this formula of bath cream is the raw material that peculiar smell is removed in degradable deodorizing, can be biodegradable, Using safety and environmental protection raw material, deodorizing goes that peculiar smell ability is strong, performance is mild safe, skin friendly, dirt-removing power is improved, using few Amount can have excellent dirt-removing power, and act on the moisturizing and nourishing of skin.

Claims

1. a kind of deodorizing type shower cream is made of according to weight percent following component:

Modified Nano active carbon: 25~35%

Marine algae extract: 5~10%

Hamamelis extract: 5~10%

PCA zinc: 2~5%

Lemon extract: 2~5%

Sweet orange extract: 2~5%

Tea seed essential oil: 3~5%

Ethereal oil of flower: 1~2%

Milk extract: 2~5%

Chinese herbal medicine preservative: 0.1~1%

Other auxiliary agents: 0.5~1%

Deionized water: surplus

The modified Nano active carbon is acyl methyl dodecyl ether sulfate-stearamide nano modification active carbon, is changed Formula is

2. deodorizing type shower cream according to claim 1, it is characterised in that: the pH value of the shower cream is 7~8.

3. deodorizing type shower cream according to claim 2, it is characterised in that: acyl methyl dodecyl ether sulfate-ten The preparation of eight amide nano modification active carbons includes the following steps:

Step 1: active carbon nanoparticles surface oxidation and chlorination

Precise 10g active carbon nanoparticles AcF is placed in reaction kettle, and the concentrated nitric acid that 150ml mass fraction is 65wt% is added, will Reaction kettle is placed in 60 DEG C of constant temperature of magnetic stirring apparatus, after being condensed back reaction 14h, oxidation product is filtered, and use deionization Water is rinsed, until solution pH value tends to be neutral, after being dried in vacuo 48h, obtains oxidation product AcF-COOH；

Precise 8gAcF-COOH is added in reaction kettle, and 50ml thionyl chloride solution is added and is mixed with, delays under stirring Slowly 50 DEG C are heated to, is condensed back after reaction 20h, is cleaned, gone respectively with anhydrous methylene chloride and tetrahydrofuran solution Except not reacted raw material, vacuum drying for 24 hours, obtains chlorizate AcF-COCL；

Step 2: the preparation of stearamide modified Nano active carbon

10g chlorizate AcF-COCL and 2.7g octadecylamine is added in reaction kettle, the anhydrous methylene chloride of 80ml is added, in room Under the conditions of temperature, it is stirred to react 10h, the mixture after reaction is separated by filtration, to anhydrous methylene chloride and tetrahydrofuran solution It is cleaned respectively, removes not reacted raw material, vacuum drying for 24 hours, obtains product AcF-ODA；

3.2gN methyl dodecyl ether sulfate is added in four mouthfuls of reaction kettles with stirring, 20ml water is added as molten Agent, after agitated reaction, at 15~20 DEG C, at the same be slowly added dropwise mass fraction be 30% sodium hydroxide solution and 12gAcF-ODA controls lye rate of addition to maintain the stabilization of the PH of reaction system, after completion of dropwise addition, increases reaction temperature extremely 35 DEG C, continue to be stirred to react 2h, adjusts ph value to alkalescent with hydrochloric acid, obtain acyl methyl dodecyl ether sulfate-ten eight Amide nano modification active carbon.

4. deodorizing type shower cream according to claim 1, it is characterised in that: other auxiliary agents include emulsifier, dispersion Agent and thickener.

5. deodorizing type shower cream according to claim 1, the emulsifier is lecithin.

6. deodorizing type shower cream according to claim 1, the dispersing agent is self-emulsifying monoglyceride.

7. deodorizing type shower cream according to claim 1, the thickener is sodium chloride.

8. deodorizing type shower cream according to claim 1, it is characterised in that: the ethereal oil of flower is pot marigold essential oil, changes Repeatedly one of essential oil, Rosa Damascana, Lavender or a variety of.

9. deodorizing type shower cream according to claim 1, it is characterised in that: the Chinese herbal medicine preservative is Flos Caryophylli extract Or cinnamomum cassia extract.

10. deodorizing type shower cream according to claim 1, it is characterised in that: deodorizing type shower cream preparation method includes such as Lower preparation step:

S1: being added suitable deionized water in a kettle, is slowly heated to 55~75 DEG C, and 25~35% modified Nano is added Active carbon stirs；

S2: after cooling the temperature to 35~40 DEG C, be added 5~10% marine algae extract, 5~10% hamamelis extract, 2~ 5% PCA zinc, 2~5% sweet orange extract, 2~5% milk extract and 0.5~1% other auxiliary agents, continue to stir Uniformly, homogeneous phase solution is formed；

S3: 2~5% lemon extract, 3~5% tea seed essential oil, 1~2% fresh flower are added into the resulting product of step S2 Essential oil, 0.1~1% Chinese herbal medicine preservative, are mixed evenly, and obtain deodorizing type shower cream.