CN108432775A - 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 - Google Patents
基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 Download PDFInfo
- Publication number
- CN108432775A CN108432775A CN201810474587.8A CN201810474587A CN108432775A CN 108432775 A CN108432775 A CN 108432775A CN 201810474587 A CN201810474587 A CN 201810474587A CN 108432775 A CN108432775 A CN 108432775A
- Authority
- CN
- China
- Prior art keywords
- bacterium
- azoles
- reactive compound
- amine
- cooperative compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 70
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 13
- 230000001069 nematicidal effect Effects 0.000 title claims abstract description 9
- 230000000855 fungicidal effect Effects 0.000 title abstract description 22
- WCNKHTIPPVQEQW-UHFFFAOYSA-N 4,4,4-trifluorobut-1-ene Chemical compound FC(F)(F)CC=C WCNKHTIPPVQEQW-UHFFFAOYSA-N 0.000 title abstract description 7
- 239000011149 active material Substances 0.000 title description 3
- 239000013543 active substance Substances 0.000 claims abstract description 28
- 230000000843 anti-fungal effect Effects 0.000 claims abstract description 7
- 229940121375 antifungal agent Drugs 0.000 claims abstract description 7
- 241000894006 Bacteria Species 0.000 claims description 79
- -1 acyl Amine Chemical class 0.000 claims description 61
- 150000003851 azoles Chemical class 0.000 claims description 33
- 150000001412 amines Chemical class 0.000 claims description 27
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 23
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 20
- 241000233866 Fungi Species 0.000 claims description 17
- 239000011737 fluorine Substances 0.000 claims description 15
- 229910052731 fluorine Inorganic materials 0.000 claims description 15
- CJPQIRJHIZUAQP-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)alaninate Chemical compound CC=1C=CC=C(C)C=1N(C(C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-UHFFFAOYSA-N 0.000 claims description 15
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 14
- 239000005784 Fluoxastrobin Substances 0.000 claims description 12
- 239000005807 Metalaxyl Substances 0.000 claims description 12
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 12
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 12
- 230000036541 health Effects 0.000 claims description 12
- ZQEIXNIJLIKNTD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alaninate Chemical compound COCC(=O)N(C(C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-UHFFFAOYSA-N 0.000 claims description 12
- MTBZIGHNGSTDJV-UHFFFAOYSA-N Ditalimfos Chemical compound C1=CC=C2C(=O)N(P(=S)(OCC)OCC)C(=O)C2=C1 MTBZIGHNGSTDJV-UHFFFAOYSA-N 0.000 claims description 10
- UGJQNSILMBYITH-UHFFFAOYSA-N (4-hydroxyphenyl)iminourea Chemical compound NC(=O)N=Nc1ccc(O)cc1 UGJQNSILMBYITH-UHFFFAOYSA-N 0.000 claims description 9
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
- 241000238631 Hexapoda Species 0.000 claims description 9
- 239000005808 Metalaxyl-M Substances 0.000 claims description 9
- 239000005820 Prochloraz Substances 0.000 claims description 9
- 239000005857 Trifloxystrobin Substances 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 claims description 9
- 230000001954 sterilising effect Effects 0.000 claims description 9
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims description 9
- OZOMQRBLCMDCEG-VIZOYTHASA-N 1-[(e)-[5-(4-nitrophenyl)furan-2-yl]methylideneamino]imidazolidine-2,4-dione Chemical compound C1=CC([N+](=O)[O-])=CC=C1C(O1)=CC=C1\C=N\N1C(=O)NC(=O)C1 OZOMQRBLCMDCEG-VIZOYTHASA-N 0.000 claims description 8
- 239000005790 Fosetyl Substances 0.000 claims description 8
- 150000001408 amides Chemical class 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- VUERQRKTYBIULR-UHFFFAOYSA-N fosetyl Chemical compound CCOP(O)=O VUERQRKTYBIULR-UHFFFAOYSA-N 0.000 claims description 8
- 150000002825 nitriles Chemical class 0.000 claims description 8
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 claims description 8
- FSCWZHGZWWDELK-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-5-ethenyl-5-methyl-2,4-oxazolidinedione Chemical compound O=C1C(C)(C=C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FSCWZHGZWWDELK-UHFFFAOYSA-N 0.000 claims description 7
- 239000005736 Benthiavalicarb Substances 0.000 claims description 7
- JDZSMXLTQNHBRF-UHFFFAOYSA-N Dichlozoline Chemical compound O=C1C(C)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 JDZSMXLTQNHBRF-UHFFFAOYSA-N 0.000 claims description 7
- 239000005797 Iprovalicarb Substances 0.000 claims description 7
- NWUWYYSKZYIQAE-ZBFHGGJFSA-N L-(R)-iprovalicarb Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)N[C@H](C)C1=CC=C(C)C=C1 NWUWYYSKZYIQAE-ZBFHGGJFSA-N 0.000 claims description 7
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims description 7
- FTCOKXNKPOUEFH-UHFFFAOYSA-N Myclozolin Chemical compound O=C1C(COC)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 FTCOKXNKPOUEFH-UHFFFAOYSA-N 0.000 claims description 7
- 235000007164 Oryza sativa Nutrition 0.000 claims description 7
- VVSLYIKSEBPRSN-PELKAZGASA-N benthiavalicarb Chemical compound C1=C(F)C=C2SC([C@@H](C)NC(=O)[C@@H](NC(O)=O)C(C)C)=NC2=C1 VVSLYIKSEBPRSN-PELKAZGASA-N 0.000 claims description 7
- 150000008056 dicarboxyimides Chemical class 0.000 claims description 7
- IGUYEXXAGBDLLX-UHFFFAOYSA-N ethyl 3-(3,5-dichlorophenyl)-5-methyl-2,4-dioxo-1,3-oxazolidine-5-carboxylate Chemical compound O=C1C(C(=O)OCC)(C)OC(=O)N1C1=CC(Cl)=CC(Cl)=C1 IGUYEXXAGBDLLX-UHFFFAOYSA-N 0.000 claims description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
- AMEKQAFGQBKLKX-UHFFFAOYSA-N oxycarboxin Chemical compound O=S1(=O)CCOC(C)=C1C(=O)NC1=CC=CC=C1 AMEKQAFGQBKLKX-UHFFFAOYSA-N 0.000 claims description 7
- 235000009566 rice Nutrition 0.000 claims description 7
- 244000025254 Cannabis sativa Species 0.000 claims description 6
- 239000005754 Cyazofamid Substances 0.000 claims description 6
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- YXKMMRDKEKCERS-UHFFFAOYSA-N cyazofamid Chemical compound CN(C)S(=O)(=O)N1C(C#N)=NC(Cl)=C1C1=CC=C(C)C=C1 YXKMMRDKEKCERS-UHFFFAOYSA-N 0.000 claims description 6
- KGVPNLBXJKTABS-UHFFFAOYSA-N hymexazol Chemical compound CC1=CC(O)=NO1 KGVPNLBXJKTABS-UHFFFAOYSA-N 0.000 claims description 6
- CIEXPHRYOLIQQD-UHFFFAOYSA-N methyl N-(2,6-dimethylphenyl)-N-2-furoylalaninate Chemical compound CC=1C=CC=C(C)C=1N(C(C)C(=O)OC)C(=O)C1=CC=CO1 CIEXPHRYOLIQQD-UHFFFAOYSA-N 0.000 claims description 6
- 239000011570 nicotinamide Substances 0.000 claims description 6
- 229960003966 nicotinamide Drugs 0.000 claims description 6
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 claims description 6
- MXMXHPPIGKYTAR-UHFFFAOYSA-N silthiofam Chemical compound CC=1SC([Si](C)(C)C)=C(C(=O)NCC=C)C=1C MXMXHPPIGKYTAR-UHFFFAOYSA-N 0.000 claims description 6
- 150000003672 ureas Chemical class 0.000 claims description 6
- LDVVMCZRFWMZSG-OLQVQODUSA-N (3ar,7as)-2-(trichloromethylsulfanyl)-3a,4,7,7a-tetrahydroisoindole-1,3-dione Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)Cl)C(=O)[C@H]21 LDVVMCZRFWMZSG-OLQVQODUSA-N 0.000 claims description 5
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 claims description 5
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical compound C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 claims description 5
- ULCWZQJLFZEXCS-UHFFFAOYSA-N 1-[[2-(2,4-dichlorophenyl)-5-(2,2,2-trifluoroethoxy)oxolan-2-yl]methyl]-1,2,4-triazole Chemical compound O1C(OCC(F)(F)F)CCC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 ULCWZQJLFZEXCS-UHFFFAOYSA-N 0.000 claims description 5
- STMIIPIFODONDC-UHFFFAOYSA-N 2-(2,4-dichlorophenyl)-1-(1H-1,2,4-triazol-1-yl)hexan-2-ol Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(O)(CCCC)CN1C=NC=N1 STMIIPIFODONDC-UHFFFAOYSA-N 0.000 claims description 5
- UFNOUKDBUJZYDE-UHFFFAOYSA-N 2-(4-chlorophenyl)-3-cyclopropyl-1-(1H-1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C=1C=CC(Cl)=CC=1)C(C)C1CC1 UFNOUKDBUJZYDE-UHFFFAOYSA-N 0.000 claims description 5
- IRCMYGHHKLLGHV-UHFFFAOYSA-N 2-ethoxy-3,3-dimethyl-2,3-dihydro-1-benzofuran-5-yl methanesulfonate Chemical compound C1=C(OS(C)(=O)=O)C=C2C(C)(C)C(OCC)OC2=C1 IRCMYGHHKLLGHV-UHFFFAOYSA-N 0.000 claims description 5
- 239000005741 Bromuconazole Substances 0.000 claims description 5
- 239000005745 Captan Substances 0.000 claims description 5
- MKZGVGOBXZJKGV-UHFFFAOYSA-N Cypendazole Chemical compound C1=CC=C2N(C(=O)NCCCCCC#N)C(NC(=O)OC)=NC2=C1 MKZGVGOBXZJKGV-UHFFFAOYSA-N 0.000 claims description 5
- 239000005757 Cyproconazole Substances 0.000 claims description 5
- 239000005512 Ethofumesate Substances 0.000 claims description 5
- 239000005785 Fluquinconazole Substances 0.000 claims description 5
- 239000005786 Flutolanil Substances 0.000 claims description 5
- 239000005789 Folpet Substances 0.000 claims description 5
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 claims description 5
- 239000005822 Propiconazole Substances 0.000 claims description 5
- 239000005869 Pyraclostrobin Substances 0.000 claims description 5
- 239000005846 Triadimenol Substances 0.000 claims description 5
- BABJTMNVJXLAEX-UHFFFAOYSA-N Triamiphos Chemical compound N1=C(N)N(P(=O)(N(C)C)N(C)C)N=C1C1=CC=CC=C1 BABJTMNVJXLAEX-UHFFFAOYSA-N 0.000 claims description 5
- 239000005859 Triticonazole Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- LJOZMWRYMKECFF-UHFFFAOYSA-N benodanil Chemical compound IC1=CC=CC=C1C(=O)NC1=CC=CC=C1 LJOZMWRYMKECFF-UHFFFAOYSA-N 0.000 claims description 5
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 claims description 5
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 claims description 5
- HJJVPARKXDDIQD-UHFFFAOYSA-N bromuconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCC(Br)C1 HJJVPARKXDDIQD-UHFFFAOYSA-N 0.000 claims description 5
- 229940117949 captan Drugs 0.000 claims description 5
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 5
- 235000013877 carbamide Nutrition 0.000 claims description 5
- 239000006013 carbendazim Substances 0.000 claims description 5
- 229960003344 climbazole Drugs 0.000 claims description 5
- VNFPBHJOKIVQEB-UHFFFAOYSA-N clotrimazole Chemical compound ClC1=CC=CC=C1C(N1C=NC=C1)(C=1C=CC=CC=1)C1=CC=CC=C1 VNFPBHJOKIVQEB-UHFFFAOYSA-N 0.000 claims description 5
- 229960004022 clotrimazole Drugs 0.000 claims description 5
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 claims description 5
- 201000010099 disease Diseases 0.000 claims description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 5
- AWZOLILCOUMRDG-UHFFFAOYSA-N edifenphos Chemical compound C=1C=CC=CC=1SP(=O)(OCC)SC1=CC=CC=C1 AWZOLILCOUMRDG-UHFFFAOYSA-N 0.000 claims description 5
- DWRKFAJEBUWTQM-UHFFFAOYSA-N etaconazole Chemical compound O1C(CC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 DWRKFAJEBUWTQM-UHFFFAOYSA-N 0.000 claims description 5
- JFSPBVWPKOEZCB-UHFFFAOYSA-N fenfuram Chemical compound O1C=CC(C(=O)NC=2C=CC=CC=2)=C1C JFSPBVWPKOEZCB-UHFFFAOYSA-N 0.000 claims description 5
- IJJVMEJXYNJXOJ-UHFFFAOYSA-N fluquinconazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1C(=O)C2=CC(F)=CC=C2N=C1N1C=NC=N1 IJJVMEJXYNJXOJ-UHFFFAOYSA-N 0.000 claims description 5
- FQKUGOMFVDPBIZ-UHFFFAOYSA-N flusilazole Chemical compound C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 FQKUGOMFVDPBIZ-UHFFFAOYSA-N 0.000 claims description 5
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 claims description 5
- HKIOYBQGHSTUDB-UHFFFAOYSA-N folpet Chemical compound C1=CC=C2C(=O)N(SC(Cl)(Cl)Cl)C(=O)C2=C1 HKIOYBQGHSTUDB-UHFFFAOYSA-N 0.000 claims description 5
- 235000005152 nicotinamide Nutrition 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 claims description 5
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 5
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 claims description 5
- 229950000975 salicylanilide Drugs 0.000 claims description 5
- 235000015096 spirit Nutrition 0.000 claims description 5
- 238000004659 sterilization and disinfection Methods 0.000 claims description 5
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 claims description 5
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 claims description 5
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 claims description 4
- OLXMODWSCGZHKO-UHFFFAOYSA-N 2-ethoxy-1h-imidazole Chemical class CCOC1=NC=CN1 OLXMODWSCGZHKO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005735 Benalaxyl-M Substances 0.000 claims description 4
- GQBZOKZFJYNVPJ-UHFFFAOYSA-N C(=O)N.C(C1=CC=CC=C1)#N.[S] Chemical compound C(=O)N.C(C1=CC=CC=C1)#N.[S] GQBZOKZFJYNVPJ-UHFFFAOYSA-N 0.000 claims description 4
- UMIVDQOVSJFWOH-UHFFFAOYSA-N C1(=CC=CC=C1)C1=CC=CC=C1.[F] Chemical group C1(=CC=CC=C1)C1=CC=CC=C1.[F] UMIVDQOVSJFWOH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005755 Cyflufenamid Substances 0.000 claims description 4
- 239000005759 Diethofencarb Substances 0.000 claims description 4
- 239000005762 Dimoxystrobin Substances 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 239000005776 Fenhexamid Substances 0.000 claims description 4
- 241000244206 Nematoda Species 0.000 claims description 4
- KYGZCKSPAKDVKC-UHFFFAOYSA-N Oxolinic acid Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC2=C1OCO2 KYGZCKSPAKDVKC-UHFFFAOYSA-N 0.000 claims description 4
- 239000005813 Penconazole Substances 0.000 claims description 4
- 241000219000 Populus Species 0.000 claims description 4
- YPCALTGLHFLNGA-UHFFFAOYSA-N Pyracarbolid Chemical compound C1CCOC(C)=C1C(=O)NC1=CC=CC=C1 YPCALTGLHFLNGA-UHFFFAOYSA-N 0.000 claims description 4
- 239000005842 Thiophanate-methyl Substances 0.000 claims description 4
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 claims description 4
- RXDMAYSSBPYBFW-PKFCDNJMSA-N carpropamide Chemical compound N([C@@H](C)C=1C=CC(Cl)=CC=1)C(=O)[C@@]1(CC)[C@H](C)C1(Cl)Cl RXDMAYSSBPYBFW-PKFCDNJMSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- ACMXQHFNODYQAT-UHFFFAOYSA-N cyflufenamid Chemical compound FC1=CC=C(C(F)(F)F)C(C(NOCC2CC2)=NC(=O)CC=2C=CC=CC=2)=C1F ACMXQHFNODYQAT-UHFFFAOYSA-N 0.000 claims description 4
- YEJGPFZQLRMXOI-PKEIRNPWSA-N diclocymet Chemical compound N#CC(C(C)(C)C)C(=O)N[C@H](C)C1=CC=C(Cl)C=C1Cl YEJGPFZQLRMXOI-PKEIRNPWSA-N 0.000 claims description 4
- LNJNFVJKDJYTEU-UHFFFAOYSA-N diethofencarb Chemical compound CCOC1=CC=C(NC(=O)OC(C)C)C=C1OCC LNJNFVJKDJYTEU-UHFFFAOYSA-N 0.000 claims description 4
- WXUZAHCNPWONDH-DYTRJAOYSA-N dimoxystrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1COC1=CC(C)=CC=C1C WXUZAHCNPWONDH-DYTRJAOYSA-N 0.000 claims description 4
- VDLGAVXLJYLFDH-UHFFFAOYSA-N fenhexamid Chemical compound C=1C=C(O)C(Cl)=C(Cl)C=1NC(=O)C1(C)CCCCC1 VDLGAVXLJYLFDH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
- GNVDAZSPJWCIQZ-UHFFFAOYSA-N flusulfamide Chemical compound ClC1=CC([N+](=O)[O-])=CC=C1NS(=O)(=O)C1=CC=C(Cl)C(C(F)(F)F)=C1 GNVDAZSPJWCIQZ-UHFFFAOYSA-N 0.000 claims description 4
- IQECZGDVZMVJSH-UHFFFAOYSA-N furan 1H-pyrazole Chemical class O1C=CC=C1.N1N=CC=C1 IQECZGDVZMVJSH-UHFFFAOYSA-N 0.000 claims description 4
- 150000002466 imines Chemical class 0.000 claims description 4
- WUHLVXDDBHWHLQ-UHFFFAOYSA-N pentazole Chemical class N=1N=NNN=1 WUHLVXDDBHWHLQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 claims description 4
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims description 4
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 4
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 claims description 4
- BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical compound C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 claims description 3
- XMIWZAAFHXNIJV-UHFFFAOYSA-N C(CC)P.N Chemical compound C(CC)P.N XMIWZAAFHXNIJV-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- VDEUYMSGMPQMIK-UHFFFAOYSA-N benzhydroxamic acid Chemical compound ONC(=O)C1=CC=CC=C1 VDEUYMSGMPQMIK-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001448 anilines Chemical class 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical group 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 241000209094 Oryza Species 0.000 claims 2
- JHMIHJYIJSMCQH-UHFFFAOYSA-N azane;furan Chemical compound N.C=1C=COC=1 JHMIHJYIJSMCQH-UHFFFAOYSA-N 0.000 claims 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 claims 1
- 229940073608 benzyl chloride Drugs 0.000 claims 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims 1
- 229940125898 compound 5 Drugs 0.000 claims 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 claims 1
- 239000000417 fungicide Substances 0.000 abstract description 18
- 230000000694 effects Effects 0.000 abstract description 15
- 125000000623 heterocyclic group Chemical group 0.000 abstract description 5
- 241000196324 Embryophyta Species 0.000 description 25
- 230000012010 growth Effects 0.000 description 16
- 239000000463 material Substances 0.000 description 10
- 241000233679 Peronosporaceae Species 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 241001149949 Phytophthora cactorum Species 0.000 description 8
- 230000000857 drug effect Effects 0.000 description 8
- 239000003995 emulsifying agent Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 description 6
- 239000005746 Carboxin Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 241000918584 Pythium ultimum Species 0.000 description 6
- 239000005839 Tebuconazole Substances 0.000 description 6
- GYSSRZJIHXQEHQ-UHFFFAOYSA-N carboxin Chemical compound S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 GYSSRZJIHXQEHQ-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 239000005734 Benalaxyl Substances 0.000 description 5
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
- 240000007594 Oryza sativa Species 0.000 description 5
- 239000005814 Pencycuron Substances 0.000 description 5
- 241000228453 Pyrenophora Species 0.000 description 5
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 description 5
- 150000003852 triazoles Chemical class 0.000 description 5
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 description 4
- AFNXATANNDIXLG-SFHVURJKSA-N 1-[(2r)-2-[(4-chlorophenyl)methylsulfanyl]-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound C1=CC(Cl)=CC=C1CS[C@H](C=1C(=CC(Cl)=CC=1)Cl)CN1C=NC=C1 AFNXATANNDIXLG-SFHVURJKSA-N 0.000 description 4
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- SOUGWDPPRBKJEX-UHFFFAOYSA-N 3,5-dichloro-N-(1-chloro-3-methyl-2-oxopentan-3-yl)-4-methylbenzamide Chemical compound ClCC(=O)C(C)(CC)NC(=O)C1=CC(Cl)=C(C)C(Cl)=C1 SOUGWDPPRBKJEX-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000223600 Alternaria Species 0.000 description 4
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 239000005787 Flutriafol Substances 0.000 description 4
- RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 4
- 241000813090 Rhizoctonia solani Species 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 239000005863 Zoxamide Substances 0.000 description 4
- 125000002877 alkyl aryl group Chemical group 0.000 description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 4
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 4
- WYEMLYFITZORAB-UHFFFAOYSA-N boscalid Chemical compound C1=CC(Cl)=CC=C1C1=CC=CC=C1NC(=O)C1=CC=CN=C1Cl WYEMLYFITZORAB-UHFFFAOYSA-N 0.000 description 4
- ULDHMXUKGWMISQ-UHFFFAOYSA-N carvone Chemical compound CC(=C)C1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- YPHMISFOHDHNIV-FSZOTQKASA-N cycloheximide Chemical compound C1[C@@H](C)C[C@H](C)C(=O)[C@@H]1[C@H](O)CC1CC(=O)NC(=O)C1 YPHMISFOHDHNIV-FSZOTQKASA-N 0.000 description 4
- WURGXGVFSMYFCG-UHFFFAOYSA-N dichlofluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=CC=C1 WURGXGVFSMYFCG-UHFFFAOYSA-N 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 4
- 239000012770 industrial material Substances 0.000 description 4
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 4
- 239000010695 polyglycol Substances 0.000 description 4
- 229920000151 polyglycol Polymers 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 229960002607 sulconazole Drugs 0.000 description 4
- URDNHJIVMYZFRT-KGLIPLIRSA-N (2r,3r)-1-(2,4-dichlorophenyl)-4,4-dimethyl-2-(1,2,4-triazol-1-yl)pentan-3-ol Chemical compound C([C@H]([C@H](O)C(C)(C)C)N1N=CN=C1)C1=CC=C(Cl)C=C1Cl URDNHJIVMYZFRT-KGLIPLIRSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 241000228212 Aspergillus Species 0.000 description 3
- 241000221198 Basidiomycota Species 0.000 description 3
- 239000005740 Boscalid Substances 0.000 description 3
- 241000228437 Cochliobolus Species 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 241000223218 Fusarium Species 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 3
- 235000003228 Lactuca sativa Nutrition 0.000 description 3
- 239000005805 Mepanipyrim Substances 0.000 description 3
- IUOKJNROJISWRO-UHFFFAOYSA-N N-(2-cyano-3-methylbutan-2-yl)-2-(2,4-dichlorophenoxy)propanamide Chemical compound CC(C)C(C)(C#N)NC(=O)C(C)OC1=CC=C(Cl)C=C1Cl IUOKJNROJISWRO-UHFFFAOYSA-N 0.000 description 3
- 241000736122 Parastagonospora nodorum Species 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 3
- 241000589516 Pseudomonas Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 241000221576 Uromyces Species 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000005068 cooling lubricant Substances 0.000 description 3
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 3
- 239000012990 dithiocarbamate Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- CIFWZNRJIBNXRE-UHFFFAOYSA-N mepanipyrim Chemical compound CC#CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 CIFWZNRJIBNXRE-UHFFFAOYSA-N 0.000 description 3
- 230000000813 microbial effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- NCXMLFZGDNKEPB-FFPOYIOWSA-N natamycin Chemical compound O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C[C@@H](C)OC(=O)/C=C/[C@H]2O[C@@H]2C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 NCXMLFZGDNKEPB-FFPOYIOWSA-N 0.000 description 3
- JHIPUJPTQJYEQK-ZLHHXESBSA-N orysastrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1CO\N=C(/C)\C(=N\OC)\C(\C)=N\OC JHIPUJPTQJYEQK-ZLHHXESBSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000013558 reference substance Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- XERJKGMBORTKEO-VZUCSPMQSA-N (1e)-2-(ethylcarbamoylamino)-n-methoxy-2-oxoethanimidoyl cyanide Chemical compound CCNC(=O)NC(=O)C(\C#N)=N\OC XERJKGMBORTKEO-VZUCSPMQSA-N 0.000 description 2
- MYUPFXPCYUISAG-UHFFFAOYSA-N (2,4-dichlorophenyl)(phenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC(Cl)=CC=1)Cl)(O)C1=CC=CC=C1 MYUPFXPCYUISAG-UHFFFAOYSA-N 0.000 description 2
- QQHRSBLQLJPBPJ-UHFFFAOYSA-N (2,4-dinitro-6-pentan-2-ylphenyl) propan-2-yl carbonate Chemical compound CCCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C QQHRSBLQLJPBPJ-UHFFFAOYSA-N 0.000 description 2
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 2
- SAPGTCDSBGMXCD-UHFFFAOYSA-N (2-chlorophenyl)-(4-fluorophenyl)-pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(F)C=C1 SAPGTCDSBGMXCD-UHFFFAOYSA-N 0.000 description 2
- IXNUTQCZWAHNPN-UHFFFAOYSA-N (2-tert-butyl-4,6-dinitrophenyl) ethyl carbonate Chemical compound CCOC(=O)OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1C(C)(C)C IXNUTQCZWAHNPN-UHFFFAOYSA-N 0.000 description 2
- CXNPLSGKWMLZPZ-GIFSMMMISA-N (2r,3r,6s)-3-[[(3s)-3-amino-5-[carbamimidoyl(methyl)amino]pentanoyl]amino]-6-(4-amino-2-oxopyrimidin-1-yl)-3,6-dihydro-2h-pyran-2-carboxylic acid Chemical compound O1[C@@H](C(O)=O)[C@H](NC(=O)C[C@@H](N)CCN(C)C(N)=N)C=C[C@H]1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-GIFSMMMISA-N 0.000 description 2
- BKBSMMUEEAWFRX-NBVRZTHBSA-N (E)-flumorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(F)=CC=1)=C\C(=O)N1CCOCC1 BKBSMMUEEAWFRX-NBVRZTHBSA-N 0.000 description 2
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 description 2
- CKPCAYZTYMHQEX-NBVRZTHBSA-N (e)-1-(2,4-dichlorophenyl)-n-methoxy-2-pyridin-3-ylethanimine Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=N/OC)/CC1=CC=CN=C1 CKPCAYZTYMHQEX-NBVRZTHBSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- NCJRWSQYSLEKEI-UHFFFAOYSA-N 1-(1,3-benzothiazol-2-yl)-3-propan-2-ylurea Chemical compound C1=CC=C2SC(NC(=O)NC(C)C)=NC2=C1 NCJRWSQYSLEKEI-UHFFFAOYSA-N 0.000 description 2
- VGPIBGGRCVEHQZ-UHFFFAOYSA-N 1-(biphenyl-4-yloxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC(C=C1)=CC=C1C1=CC=CC=C1 VGPIBGGRCVEHQZ-UHFFFAOYSA-N 0.000 description 2
- MGNFYQILYYYUBS-UHFFFAOYSA-N 1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1CCCCC1 MGNFYQILYYYUBS-UHFFFAOYSA-N 0.000 description 2
- YIKWKLYQRFRGPM-UHFFFAOYSA-N 1-dodecylguanidine acetate Chemical compound CC(O)=O.CCCCCCCCCCCCN=C(N)N YIKWKLYQRFRGPM-UHFFFAOYSA-N 0.000 description 2
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 2
- OTWBGXPTCSGQEJ-UHFFFAOYSA-N 2-[(dimethylcarbamothioyldisulfanyl)carbothioylamino]ethylcarbamothioylsulfanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)SSC(=S)NCCNC(=S)SSC(=S)N(C)C OTWBGXPTCSGQEJ-UHFFFAOYSA-N 0.000 description 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 2
- ZRDUSMYWDRPZRM-UHFFFAOYSA-N 2-sec-butyl-4,6-dinitrophenyl 3-methylbut-2-enoate Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)C=C(C)C ZRDUSMYWDRPZRM-UHFFFAOYSA-N 0.000 description 2
- BZGLBXYQOMFXAU-UHFFFAOYSA-N 3-(2-methylpiperidin-1-yl)propyl 3,4-dichlorobenzoate Chemical compound CC1CCCCN1CCCOC(=O)C1=CC=C(Cl)C(Cl)=C1 BZGLBXYQOMFXAU-UHFFFAOYSA-N 0.000 description 2
- PCCSBWNGDMYFCW-UHFFFAOYSA-N 5-methyl-5-(4-phenoxyphenyl)-3-(phenylamino)-1,3-oxazolidine-2,4-dione Chemical compound O=C1C(C)(C=2C=CC(OC=3C=CC=CC=3)=CC=2)OC(=O)N1NC1=CC=CC=C1 PCCSBWNGDMYFCW-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000223651 Aureobasidium Species 0.000 description 2
- 241000223678 Aureobasidium pullulans Species 0.000 description 2
- 241001480061 Blumeria graminis Species 0.000 description 2
- 239000005739 Bordeaux mixture Substances 0.000 description 2
- 241001465180 Botrytis Species 0.000 description 2
- 241000123650 Botrytis cinerea Species 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZZVVDIVWGXTDRQ-BSYVCWPDSA-N Buthiobate Chemical compound C=1C=CN=CC=1\N=C(/SCCCC)SCC1=CC=C(C(C)(C)C)C=C1 ZZVVDIVWGXTDRQ-BSYVCWPDSA-N 0.000 description 2
- MPKTWNYCNKUVKZ-UHFFFAOYSA-N Carbamorph Chemical compound CN(C)C(=S)SCN1CCOCC1 MPKTWNYCNKUVKZ-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241001157813 Cercospora Species 0.000 description 2
- 241001515917 Chaetomium globosum Species 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- 241001600093 Coniophora Species 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- 241000371644 Curvularia ravenelii Species 0.000 description 2
- 239000005756 Cymoxanil Substances 0.000 description 2
- KRZUZYJEQBXUIN-UHFFFAOYSA-N Cyprofuram Chemical compound ClC1=CC=CC(N(C2C(OCC2)=O)C(=O)C2CC2)=C1 KRZUZYJEQBXUIN-UHFFFAOYSA-N 0.000 description 2
- 239000005644 Dazomet Substances 0.000 description 2
- 239000004287 Dehydroacetic acid Substances 0.000 description 2
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 2
- IIUZTXTZRGLYTI-UHFFFAOYSA-N Dihydrogriseofulvin Natural products COC1CC(=O)CC(C)C11C(=O)C(C(OC)=CC(OC)=C2Cl)=C2O1 IIUZTXTZRGLYTI-UHFFFAOYSA-N 0.000 description 2
- 239000005761 Dimethomorph Substances 0.000 description 2
- HDWLUGYOLUHEMN-UHFFFAOYSA-N Dinobuton Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)OC(C)C HDWLUGYOLUHEMN-UHFFFAOYSA-N 0.000 description 2
- 239000005766 Dodine Substances 0.000 description 2
- OOTHTARUZHONSW-LCYFTJDESA-N Drazoxolon Chemical compound CC1=NOC(=O)\C1=N/NC1=CC=CC=C1Cl OOTHTARUZHONSW-LCYFTJDESA-N 0.000 description 2
- 241000588722 Escherichia Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 239000004258 Ethoxyquin Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000005772 Famoxadone Substances 0.000 description 2
- 239000005774 Fenamidone Substances 0.000 description 2
- IWDQPCIQCXRBQP-UHFFFAOYSA-M Fenaminosulf Chemical compound [Na+].CN(C)C1=CC=C(N=NS([O-])(=O)=O)C=C1 IWDQPCIQCXRBQP-UHFFFAOYSA-M 0.000 description 2
- OQOULEWDDRNBSG-UHFFFAOYSA-N Fenapanil Chemical compound C=1C=CC=CC=1C(CCCC)(C#N)CN1C=CN=C1 OQOULEWDDRNBSG-UHFFFAOYSA-N 0.000 description 2
- 239000005777 Fenpropidin Substances 0.000 description 2
- UXWOXTQWVMFRSE-UHFFFAOYSA-N Griseoviridin Natural products O=C1OC(C)CC=C(C(NCC=CC=CC(O)CC(O)C2)=O)SCC1NC(=O)C1=COC2=N1 UXWOXTQWVMFRSE-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 241000222418 Lentinus Species 0.000 description 2
- 241000222451 Lentinus tigrinus Species 0.000 description 2
- 241000228456 Leptosphaeria Species 0.000 description 2
- 241000243786 Meloidogyne incognita Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LGDSHSYDSCRFAB-UHFFFAOYSA-N Methyl isothiocyanate Chemical compound CN=C=S LGDSHSYDSCRFAB-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- XFOXDUJCOHBXRC-UHFFFAOYSA-N N-Ethyl-N-methyl-4-(trifluoromethyl)-2-(3,4-dimethoxyphenyl)benzamide Chemical compound CCN(C)C(=O)C1=CC=C(C(F)(F)F)C=C1C1=CC=C(OC)C(OC)=C1 XFOXDUJCOHBXRC-UHFFFAOYSA-N 0.000 description 2
- NQRFDNJEBWAUBL-UHFFFAOYSA-N N-[cyano(2-thienyl)methyl]-4-ethyl-2-(ethylamino)-1,3-thiazole-5-carboxamide Chemical compound S1C(NCC)=NC(CC)=C1C(=O)NC(C#N)C1=CC=CS1 NQRFDNJEBWAUBL-UHFFFAOYSA-N 0.000 description 2
- DDUHZTYCFQRHIY-UHFFFAOYSA-N Negwer: 6874 Natural products COC1=CC(=O)CC(C)C11C(=O)C(C(OC)=CC(OC)=C2Cl)=C2O1 DDUHZTYCFQRHIY-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 241000233654 Oomycetes Species 0.000 description 2
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 description 2
- 241000228143 Penicillium Species 0.000 description 2
- 241000233614 Phytophthora Species 0.000 description 2
- 241000233622 Phytophthora infestans Species 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 241001503436 Plasmodiophora brassicae Species 0.000 description 2
- 241000896242 Podosphaera Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000005823 Propineb Substances 0.000 description 2
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 2
- 241001281805 Pseudoperonospora cubensis Species 0.000 description 2
- 241001123569 Puccinia recondita Species 0.000 description 2
- OVZITGHGWBXFEA-UHFFFAOYSA-N Pyridinitril Chemical compound ClC1=NC(Cl)=C(C#N)C(C=2C=CC=CC=2)=C1C#N OVZITGHGWBXFEA-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 239000005831 Quinoxyfen Substances 0.000 description 2
- 241000221662 Sclerotinia Species 0.000 description 2
- KSQXVLVXUFHGJQ-UHFFFAOYSA-M Sodium ortho-phenylphenate Chemical compound [Na+].[O-]C1=CC=CC=C1C1=CC=CC=C1 KSQXVLVXUFHGJQ-UHFFFAOYSA-M 0.000 description 2
- 241000579741 Sphaerotheca <fungi> Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- JZFICWYCTCCINF-UHFFFAOYSA-N Thiadiazin Chemical compound S=C1SC(C)NC(C)N1CCN1C(=S)SC(C)NC1C JZFICWYCTCCINF-UHFFFAOYSA-N 0.000 description 2
- GNOOAFGERMHQJE-UHFFFAOYSA-N Thicyofen Chemical compound CCS(=O)C=1SC(C#N)=C(Cl)C=1C#N GNOOAFGERMHQJE-UHFFFAOYSA-N 0.000 description 2
- 239000005843 Thiram Substances 0.000 description 2
- 241000722093 Tilletia caries Species 0.000 description 2
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 2
- 241000223259 Trichoderma Species 0.000 description 2
- 241000223261 Trichoderma viride Species 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 241000221566 Ustilago Species 0.000 description 2
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000005870 Ziram Substances 0.000 description 2
- VQSUKBFBVMSNES-UHFFFAOYSA-K [Cl-].[Cl-].[Cu+].[Cu+].[Cu+].CN(C)C([S-])=S Chemical compound [Cl-].[Cl-].[Cu+].[Cu+].[Cu+].CN(C)C([S-])=S VQSUKBFBVMSNES-UHFFFAOYSA-K 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 235000010419 agar Nutrition 0.000 description 2
- 239000011717 all-trans-retinol Substances 0.000 description 2
- 235000019169 all-trans-retinol Nutrition 0.000 description 2
- IMHBYKMAHXWHRP-UHFFFAOYSA-N anilazine Chemical compound ClC1=CC=CC=C1NC1=NC(Cl)=NC(Cl)=N1 IMHBYKMAHXWHRP-UHFFFAOYSA-N 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- CXNPLSGKWMLZPZ-UHFFFAOYSA-N blasticidin-S Natural products O1C(C(O)=O)C(NC(=O)CC(N)CCN(C)C(N)=N)C=CC1N1C(=O)N=C(N)C=C1 CXNPLSGKWMLZPZ-UHFFFAOYSA-N 0.000 description 2
- 229940118790 boscalid Drugs 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- PFIADAMVCJPXSF-UHFFFAOYSA-N chloroneb Chemical compound COC1=CC(Cl)=C(OC)C=C1Cl PFIADAMVCJPXSF-UHFFFAOYSA-N 0.000 description 2
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 description 2
- HPDFFVBPXCTEDN-UHFFFAOYSA-N copper manganese Chemical compound [Mn].[Cu] HPDFFVBPXCTEDN-UHFFFAOYSA-N 0.000 description 2
- 244000038559 crop plants Species 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- QAYICIQNSGETAS-UHFFFAOYSA-N dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 description 2
- 229940061632 dehydroacetic acid Drugs 0.000 description 2
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 description 2
- 235000019258 dehydroacetic acid Nutrition 0.000 description 2
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 2
- BIXZHMJUSMUDOQ-UHFFFAOYSA-N dichloran Chemical compound NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl BIXZHMJUSMUDOQ-UHFFFAOYSA-N 0.000 description 2
- UWQMKVBQKFHLCE-UHFFFAOYSA-N diclomezine Chemical compound C1=C(Cl)C(C)=C(Cl)C=C1C1=NNC(=O)C=C1 UWQMKVBQKFHLCE-UHFFFAOYSA-N 0.000 description 2
- FFYPMLJYZAEMQB-UHFFFAOYSA-N diethyl pyrocarbonate Chemical compound CCOC(=O)OC(=O)OCC FFYPMLJYZAEMQB-UHFFFAOYSA-N 0.000 description 2
- CJHXCRMKMMBYJQ-UHFFFAOYSA-N dimethirimol Chemical compound CCCCC1=C(C)NC(N(C)C)=NC1=O CJHXCRMKMMBYJQ-UHFFFAOYSA-N 0.000 description 2
- 229960002563 disulfiram Drugs 0.000 description 2
- 150000004659 dithiocarbamates Chemical class 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 2
- 229940093500 ethoxyquin Drugs 0.000 description 2
- 235000019285 ethoxyquin Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- LMVPQMGRYSRMIW-KRWDZBQOSA-N fenamidone Chemical compound O=C([C@@](C)(N=C1SC)C=2C=CC=CC=2)N1NC1=CC=CC=C1 LMVPQMGRYSRMIW-KRWDZBQOSA-N 0.000 description 2
- FKLFBQCQQYDUAM-UHFFFAOYSA-N fenpiclonil Chemical compound ClC1=CC=CC(C=2C(=CNC=2)C#N)=C1Cl FKLFBQCQQYDUAM-UHFFFAOYSA-N 0.000 description 2
- GOWLARCWZRESHU-AQTBWJFISA-N ferimzone Chemical compound C=1C=CC=C(C)C=1C(/C)=N\NC1=NC(C)=CC(C)=N1 GOWLARCWZRESHU-AQTBWJFISA-N 0.000 description 2
- IPENDKRRWFURRE-UHFFFAOYSA-N fluoroimide Chemical compound C1=CC(F)=CC=C1N1C(=O)C(Cl)=C(Cl)C1=O IPENDKRRWFURRE-UHFFFAOYSA-N 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- UYJUZNLFJAWNEZ-UHFFFAOYSA-N fuberidazole Chemical compound C1=COC(C=2NC3=CC=CC=C3N=2)=C1 UYJUZNLFJAWNEZ-UHFFFAOYSA-N 0.000 description 2
- DDUHZTYCFQRHIY-RBHXEPJQSA-N griseofulvin Chemical compound COC1=CC(=O)C[C@@H](C)[C@@]11C(=O)C(C(OC)=CC(OC)=C2Cl)=C2O1 DDUHZTYCFQRHIY-RBHXEPJQSA-N 0.000 description 2
- 229960002867 griseofulvin Drugs 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 2
- 150000007857 hydrazones Chemical class 0.000 description 2
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- UFHLMYOGRXOCSL-UHFFFAOYSA-N isoprothiolane Chemical compound CC(C)OC(=O)C(C(=O)OC(C)C)=C1SCCS1 UFHLMYOGRXOCSL-UHFFFAOYSA-N 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 description 2
- 229920000940 maneb Polymers 0.000 description 2
- IXJOSTZEBSTPAG-UHFFFAOYSA-N methasulfocarb Chemical compound CNC(=O)SC1=CC=C(OS(C)(=O)=O)C=C1 IXJOSTZEBSTPAG-UHFFFAOYSA-N 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000003129 miticidal effect Effects 0.000 description 2
- 210000003097 mucus Anatomy 0.000 description 2
- 230000021332 multicellular organism growth Effects 0.000 description 2
- UWVQIROCRJWDKL-UHFFFAOYSA-N oxadixyl Chemical compound CC=1C=CC=C(C)C=1N(C(=O)COC)N1CCOC1=O UWVQIROCRJWDKL-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 description 2
- YRRBXJLFCBCKNW-UHFFFAOYSA-N prothiocarb Chemical compound CCSC(=O)NCCCN(C)C YRRBXJLFCBCKNW-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- XRJLAOUDSILTFT-UHFFFAOYSA-N pyroquilon Chemical compound O=C1CCC2=CC=CC3=C2N1CC3 XRJLAOUDSILTFT-UHFFFAOYSA-N 0.000 description 2
- QJBZDBLBQWFTPZ-UHFFFAOYSA-N pyrrolnitrin Chemical compound [O-][N+](=O)C1=C(Cl)C=CC=C1C1=CNC=C1Cl QJBZDBLBQWFTPZ-UHFFFAOYSA-N 0.000 description 2
- FBQQHUGEACOBDN-UHFFFAOYSA-N quinomethionate Chemical compound N1=C2SC(=O)SC2=NC2=CC(C)=CC=C21 FBQQHUGEACOBDN-UHFFFAOYSA-N 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- WRPIRSINYZBGPK-UHFFFAOYSA-N quinoxyfen Chemical compound C1=CC(F)=CC=C1OC1=CC=NC2=CC(Cl)=CC(Cl)=C12 WRPIRSINYZBGPK-UHFFFAOYSA-N 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 description 2
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 description 2
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 2
- 239000004308 thiabendazole Substances 0.000 description 2
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 2
- 235000010296 thiabendazole Nutrition 0.000 description 2
- 229960004546 thiabendazole Drugs 0.000 description 2
- ILERPRJWJPJZDN-UHFFFAOYSA-N thioquinox Chemical compound C1=CC=C2N=C(SC(=S)S3)C3=NC2=C1 ILERPRJWJPJZDN-UHFFFAOYSA-N 0.000 description 2
- 229960002447 thiram Drugs 0.000 description 2
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 2
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 2
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 2
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 description 1
- PTKVPQXEKZOPNA-UHFFFAOYSA-N (2,4-dinitro-6-octan-2-ylphenyl) methylsulfanylformate Chemical compound CCCCCCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)SC PTKVPQXEKZOPNA-UHFFFAOYSA-N 0.000 description 1
- YHVJMJFNSRLYIC-WEVVVXLNSA-N (2,6-dinitro-4-octan-2-ylphenyl) (e)-but-2-enoate Chemical compound CCCCCCC(C)C1=CC([N+]([O-])=O)=C(OC(=O)\C=C\C)C([N+]([O-])=O)=C1 YHVJMJFNSRLYIC-WEVVVXLNSA-N 0.000 description 1
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 description 1
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 1
- XDEHMKQLKPZERH-BYPYZUCNSA-N (2s)-2-amino-3-methylbutanamide Chemical compound CC(C)[C@H](N)C(N)=O XDEHMKQLKPZERH-BYPYZUCNSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- ULDHMXUKGWMISQ-VIFPVBQESA-N (S)-(+)-Carvone Natural products CC(=C)[C@H]1CC=C(C)C(=O)C1 ULDHMXUKGWMISQ-VIFPVBQESA-N 0.000 description 1
- WBEJYOJJBDISQU-UHFFFAOYSA-N 1,2-Dibromo-3-chloropropane Chemical compound ClCC(Br)CBr WBEJYOJJBDISQU-UHFFFAOYSA-N 0.000 description 1
- CPLBLNGVYBSVPU-UHFFFAOYSA-N 1,3,3-trimethyl-1,2-dihydroindene Chemical class C1=CC=C2C(C)CC(C)(C)C2=C1 CPLBLNGVYBSVPU-UHFFFAOYSA-N 0.000 description 1
- TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 description 1
- QWEWLLNSJDTOKH-UHFFFAOYSA-N 1,3-thiazole-2-carboxamide Chemical compound NC(=O)C1=NC=CS1 QWEWLLNSJDTOKH-UHFFFAOYSA-N 0.000 description 1
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical class ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- HZTCLDNADGMACV-UHFFFAOYSA-N 1-(8-hydroxyquinolin-5-yl)ethanone Chemical compound C1=CC=C2C(C(=O)C)=CC=C(O)C2=N1 HZTCLDNADGMACV-UHFFFAOYSA-N 0.000 description 1
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 description 1
- PZBPKYOVPCNPJY-UHFFFAOYSA-N 1-[2-(allyloxy)-2-(2,4-dichlorophenyl)ethyl]imidazole Chemical compound ClC1=CC(Cl)=CC=C1C(OCC=C)CN1C=NC=C1 PZBPKYOVPCNPJY-UHFFFAOYSA-N 0.000 description 1
- DELJNDWGTWHHFA-UHFFFAOYSA-N 1-azaniumylpropyl(hydroxy)phosphinate Chemical compound CCC(N)P(O)(O)=O DELJNDWGTWHHFA-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- PISOEPKMXSTHCQ-UHFFFAOYSA-N 1h-benzimidazol-2-amine;carbamic acid Chemical class NC(O)=O.C1=CC=C2NC(N)=NC2=C1 PISOEPKMXSTHCQ-UHFFFAOYSA-N 0.000 description 1
- YRBRVMGXTWJLBZ-UHFFFAOYSA-N 1h-imidazole;1h-pyrrole Chemical class C=1C=CNC=1.C1=CNC=N1 YRBRVMGXTWJLBZ-UHFFFAOYSA-N 0.000 description 1
- PTWBGBDKDZWGCL-UHFFFAOYSA-N 2,4-dinitro-1-pentylsulfonylbenzene Chemical compound CCCCCS(=O)(=O)C1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O PTWBGBDKDZWGCL-UHFFFAOYSA-N 0.000 description 1
- XEPBBUCQCXXTGR-UHFFFAOYSA-N 2,5-dimethyl-n-phenylfuran-3-carboxamide Chemical compound O1C(C)=CC(C(=O)NC=2C=CC=CC=2)=C1C XEPBBUCQCXXTGR-UHFFFAOYSA-N 0.000 description 1
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 1
- BCPFWSWROVXGQA-UHFFFAOYSA-N 2-(2,4,4-trimethylpentan-2-yl)guanidine Chemical compound CC(C)(C)CC(C)(C)N=C(N)N BCPFWSWROVXGQA-UHFFFAOYSA-N 0.000 description 1
- OILIYWFQRJOPAI-UHFFFAOYSA-N 2-(2-chlorophenyl)-1h-benzimidazole Chemical compound ClC1=CC=CC=C1C1=NC2=CC=CC=C2N1 OILIYWFQRJOPAI-UHFFFAOYSA-N 0.000 description 1
- DNBMPXLFKQCOBV-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OCCOCCOCC)=NC2=C1 DNBMPXLFKQCOBV-UHFFFAOYSA-N 0.000 description 1
- RUGYNGIMTAFTLP-UHFFFAOYSA-N 2-(3,5-dimethylpyrazol-1-yl)-1h-benzimidazole Chemical compound N1=C(C)C=C(C)N1C1=NC2=CC=CC=C2N1 RUGYNGIMTAFTLP-UHFFFAOYSA-N 0.000 description 1
- HZJKXKUJVSEEFU-UHFFFAOYSA-N 2-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)hexanenitrile Chemical compound C=1C=C(Cl)C=CC=1C(CCCC)(C#N)CN1C=NC=N1 HZJKXKUJVSEEFU-UHFFFAOYSA-N 0.000 description 1
- YABFPHSQTSFWQB-UHFFFAOYSA-N 2-(4-fluorophenyl)-1-(1,2,4-triazol-1-yl)-3-(trimethylsilyl)propan-2-ol Chemical compound C=1C=C(F)C=CC=1C(O)(C[Si](C)(C)C)CN1C=NC=N1 YABFPHSQTSFWQB-UHFFFAOYSA-N 0.000 description 1
- QKJJCZYFXJCKRX-HZHKWBLPSA-N 2-[(2s,3s,6r)-6-[4-amino-5-(hydroxymethyl)-2-oxopyrimidin-1-yl]-3-[[(2s)-2-amino-3-hydroxypropanoyl]amino]-3,6-dihydro-2h-pyran-2-yl]-5-(diaminomethylideneamino)-2,4-dihydroxypentanoic acid Chemical compound O1[C@H](C(O)(CC(O)CN=C(N)N)C(O)=O)[C@@H](NC(=O)[C@H](CO)N)C=C[C@@H]1N1C(=O)N=C(N)C(CO)=C1 QKJJCZYFXJCKRX-HZHKWBLPSA-N 0.000 description 1
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 description 1
- FSKNXCHJIFBRBT-UHFFFAOYSA-N 2-[2-[2-(dodecylamino)ethylamino]ethylamino]acetic acid Chemical compound CCCCCCCCCCCCNCCNCCNCC(O)=O FSKNXCHJIFBRBT-UHFFFAOYSA-N 0.000 description 1
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 description 1
- CFWRDBDJAOHXSH-SECBINFHSA-N 2-azaniumylethyl [(2r)-2,3-diacetyloxypropyl] phosphate Chemical compound CC(=O)OC[C@@H](OC(C)=O)COP(O)(=O)OCCN CFWRDBDJAOHXSH-SECBINFHSA-N 0.000 description 1
- OGBSAJWRIPNIER-UHFFFAOYSA-N 2-chloro-6-(furan-2-ylmethoxy)-4-(trichloromethyl)pyridine Chemical compound ClC1=CC(C(Cl)(Cl)Cl)=CC(OCC=2OC=CC=2)=N1 OGBSAJWRIPNIER-UHFFFAOYSA-N 0.000 description 1
- RPCKKUFLSMORHB-UHFFFAOYSA-N 2-chloro-6-methoxy-4-(trichloromethyl)pyridine Chemical compound COC1=CC(C(Cl)(Cl)Cl)=CC(Cl)=N1 RPCKKUFLSMORHB-UHFFFAOYSA-N 0.000 description 1
- OWDLFBLNMPCXSD-UHFFFAOYSA-N 2-chloro-N-(2,6-dimethylphenyl)-N-(2-oxotetrahydrofuran-3-yl)acetamide Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)C1C(=O)OCC1 OWDLFBLNMPCXSD-UHFFFAOYSA-N 0.000 description 1
- NCVGSSQICKMAIA-UHFFFAOYSA-N 2-heptadecyl-4,5-dihydro-1h-imidazole Chemical compound CCCCCCCCCCCCCCCCCC1=NCCN1 NCVGSSQICKMAIA-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 description 1
- PIAOLBVUVDXHHL-UHFFFAOYSA-N 2-nitroethenylbenzene Chemical compound [O-][N+](=O)C=CC1=CC=CC=C1 PIAOLBVUVDXHHL-UHFFFAOYSA-N 0.000 description 1
- AVGVFDSUDIUXEU-UHFFFAOYSA-N 2-octyl-1,2-thiazolidin-3-one Chemical compound CCCCCCCCN1SCCC1=O AVGVFDSUDIUXEU-UHFFFAOYSA-N 0.000 description 1
- NRAYWXLNSHEHQO-UHFFFAOYSA-N 3-(1-benzothiophen-2-yl)-5,6-dihydro-1,4,2-oxathiazine 4-oxide Chemical compound O=S1CCON=C1C1=CC2=CC=CC=C2S1 NRAYWXLNSHEHQO-UHFFFAOYSA-N 0.000 description 1
- OVFHHJZHXHZIHT-UHFFFAOYSA-N 3-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)quinazolin-4-one Chemical compound ClC1=CC(Cl)=CC=C1N1C(=O)C2=CC=CC=C2N=C1N1N=CN=C1 OVFHHJZHXHZIHT-UHFFFAOYSA-N 0.000 description 1
- GPUHJQHXIFJPGN-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-1-(3-methylbutanoyl)imidazolidine-2,4-dione Chemical compound O=C1N(C(=O)CC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 GPUHJQHXIFJPGN-UHFFFAOYSA-N 0.000 description 1
- HBLSGPQATABNRY-UHFFFAOYSA-N 3-(4-chlorophenyl)-2-n-methyl-4-n,5-n-bis(trifluoromethyl)-1,3-thiazolidine-2,4,5-triimine Chemical compound CN=C1SC(=NC(F)(F)F)C(=NC(F)(F)F)N1C1=CC=C(Cl)C=C1 HBLSGPQATABNRY-UHFFFAOYSA-N 0.000 description 1
- LCOWUMNPNWEMAZ-UHFFFAOYSA-N 3-[benzyl(methyl)amino]-2-cyanoprop-2-enoic acid Chemical compound N#CC(C(O)=O)=CN(C)CC1=CC=CC=C1 LCOWUMNPNWEMAZ-UHFFFAOYSA-N 0.000 description 1
- NMWKWBPNKPGATC-UHFFFAOYSA-N 4,5,6,7-tetrachloro-2-benzofuran-1(3H)-one Chemical compound ClC1=C(Cl)C(Cl)=C2COC(=O)C2=C1Cl NMWKWBPNKPGATC-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 description 1
- UJVMVEZTSSMXAC-UHFFFAOYSA-N 4-[(3-chlorophenyl)diazenyl]-3-methyl-2H-1,2-oxazol-5-one Chemical compound ClC=1C=C(C=CC=1)N=NC1=C(NOC1=O)C UJVMVEZTSSMXAC-UHFFFAOYSA-N 0.000 description 1
- ZOMKCDYJHAQMCU-UHFFFAOYSA-N 4-butyl-1,2,4-triazole Chemical compound CCCCN1C=NN=C1 ZOMKCDYJHAQMCU-UHFFFAOYSA-N 0.000 description 1
- QCPASDYEQAVIJF-UHFFFAOYSA-N 4-chloro-3-methyl-1,3-benzothiazol-2-one Chemical compound C1=CC=C2SC(=O)N(C)C2=C1Cl QCPASDYEQAVIJF-UHFFFAOYSA-N 0.000 description 1
- NNPRCLUGHFXSOU-UHFFFAOYSA-N 4-chloro-n-[cyano(ethoxy)methyl]benzamide Chemical compound CCOC(C#N)NC(=O)C1=CC=C(Cl)C=C1 NNPRCLUGHFXSOU-UHFFFAOYSA-N 0.000 description 1
- YLJLLELGHSWIDU-UHFFFAOYSA-N 4-cyclododecyl-2,6-dimethylmorpholin-4-ium;acetate Chemical compound CC([O-])=O.C1C(C)OC(C)C[NH+]1C1CCCCCCCCCCC1 YLJLLELGHSWIDU-UHFFFAOYSA-N 0.000 description 1
- SBUKOHLFHYSZNG-UHFFFAOYSA-N 4-dodecyl-2,6-dimethylmorpholine Chemical compound CCCCCCCCCCCCN1CC(C)OC(C)C1 SBUKOHLFHYSZNG-UHFFFAOYSA-N 0.000 description 1
- BFTGQIQVUVTBJU-UHFFFAOYSA-N 5,6-dihydroimidazo[2,1-c][1,2,4]dithiazole-3-thione Chemical compound C1CN2C(=S)SSC2=N1 BFTGQIQVUVTBJU-UHFFFAOYSA-N 0.000 description 1
- NRTLIYOWLVMQBO-UHFFFAOYSA-N 5-chloro-1,3-dimethyl-N-(1,1,3-trimethyl-1,3-dihydro-2-benzofuran-4-yl)pyrazole-4-carboxamide Chemical compound C=12C(C)OC(C)(C)C2=CC=CC=1NC(=O)C=1C(C)=NN(C)C=1Cl NRTLIYOWLVMQBO-UHFFFAOYSA-N 0.000 description 1
- NEKULYKCZPJMMJ-UHFFFAOYSA-N 5-chloro-N-{1-[4-(difluoromethoxy)phenyl]propyl}-6-methylpyrimidin-4-amine Chemical compound C=1C=C(OC(F)F)C=CC=1C(CC)NC1=NC=NC(C)=C1Cl NEKULYKCZPJMMJ-UHFFFAOYSA-N 0.000 description 1
- BIHPYCDDPGNWQO-UHFFFAOYSA-N 5-iai Chemical compound C1=C(I)C=C2CC(N)CC2=C1 BIHPYCDDPGNWQO-UHFFFAOYSA-N 0.000 description 1
- SJDGOKGRYGWNTC-UHFFFAOYSA-N 5-isothiocyanato-2-methoxy-n,n,3-trimethylbenzamide Chemical compound COC1=C(C)C=C(N=C=S)C=C1C(=O)N(C)C SJDGOKGRYGWNTC-UHFFFAOYSA-N 0.000 description 1
- GABNAHQQEVWYNS-UHFFFAOYSA-N 5-phenyl-2,3-dihydro-1,4-dithiine 1,1,4,4-tetraoxide Chemical compound O=S1(=O)CCS(=O)(=O)C(C=2C=CC=CC=2)=C1 GABNAHQQEVWYNS-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 241000223602 Alternaria alternata Species 0.000 description 1
- 241001149961 Alternaria brassicae Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000005730 Azoxystrobin Substances 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- MQIVNMHALJNFMG-ILYHAJGMSA-N Benquinox Chemical compound O/N=C(\C=C1)/C=C/C\1=N\NC(C1=CC=CC=C1)=O MQIVNMHALJNFMG-ILYHAJGMSA-N 0.000 description 1
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- 241000190150 Bipolaris sorokiniana Species 0.000 description 1
- 235000011303 Brassica alboglabra Nutrition 0.000 description 1
- 235000011302 Brassica oleracea Nutrition 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 241000219193 Brassicaceae Species 0.000 description 1
- 241000233684 Bremia Species 0.000 description 1
- 241000233685 Bremia lactucae Species 0.000 description 1
- 239000005742 Bupirimate Substances 0.000 description 1
- DPKVMWZHBXODRF-UHFFFAOYSA-N C(C1=CC=CC=C1)(=O)NO.C(C1=CC=CC=C1)(=O)NO Chemical compound C(C1=CC=CC=C1)(=O)NO.C(C1=CC=CC=C1)(=O)NO DPKVMWZHBXODRF-UHFFFAOYSA-N 0.000 description 1
- SLVBYWGNYOLBEU-UHFFFAOYSA-N C1(=CC=CC=C1)O.[N+](=O)([O-])C1=C(C=CC=C1)[N+](=O)[O-] Chemical class C1(=CC=CC=C1)O.[N+](=O)([O-])C1=C(C=CC=C1)[N+](=O)[O-] SLVBYWGNYOLBEU-UHFFFAOYSA-N 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000005973 Carvone Substances 0.000 description 1
- 241000906476 Cercospora canescens Species 0.000 description 1
- 241000221955 Chaetomium Species 0.000 description 1
- REEFSLKDEDEWAO-UHFFFAOYSA-N Chloraniformethan Chemical compound ClC1=CC=C(NC(NC=O)C(Cl)(Cl)Cl)C=C1Cl REEFSLKDEDEWAO-UHFFFAOYSA-N 0.000 description 1
- 239000005747 Chlorothalonil Substances 0.000 description 1
- 241000760356 Chytridiomycetes Species 0.000 description 1
- 241000233652 Chytridiomycota Species 0.000 description 1
- 241001478240 Coccus Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 239000005752 Copper oxychloride Substances 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 239000005758 Cyprodinil Substances 0.000 description 1
- URDNHJIVMYZFRT-UHFFFAOYSA-N Diclobutrazol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)CC1=CC=C(Cl)C=C1Cl URDNHJIVMYZFRT-UHFFFAOYSA-N 0.000 description 1
- 239000005760 Difenoconazole Substances 0.000 description 1
- ODOSVAWLEGXOPB-UHFFFAOYSA-N Dinocton 6 Chemical compound COC(=O)OC1=C(CCCCCC(C)C)C=C([N+]([O-])=O)C=C1[N+]([O-])=O ODOSVAWLEGXOPB-UHFFFAOYSA-N 0.000 description 1
- 239000005764 Dithianon Substances 0.000 description 1
- 239000005765 Dodemorph Substances 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 239000005767 Epoxiconazole Substances 0.000 description 1
- 241000588698 Erwinia Species 0.000 description 1
- 241000588694 Erwinia amylovora Species 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000221787 Erysiphe Species 0.000 description 1
- 239000005769 Etridiazole Substances 0.000 description 1
- 239000005775 Fenbuconazole Substances 0.000 description 1
- AYBALPYBYZFKDS-OLZOCXBDSA-N Fenitropan Chemical compound CC(=O)OC[C@@H]([N+]([O-])=O)[C@@H](OC(C)=O)C1=CC=CC=C1 AYBALPYBYZFKDS-OLZOCXBDSA-N 0.000 description 1
- 239000005778 Fenpropimorph Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005780 Fluazinam Substances 0.000 description 1
- 239000005781 Fludioxonil Substances 0.000 description 1
- LXMQMMSGERCRSU-UHFFFAOYSA-N Fluotrimazole Chemical compound FC(F)(F)C1=CC=CC(C(C=2C=CC=CC=2)(C=2C=CC=CC=2)N2N=CN=C2)=C1 LXMQMMSGERCRSU-UHFFFAOYSA-N 0.000 description 1
- 239000005791 Fuberidazole Substances 0.000 description 1
- 229930184093 Furanether Natural products 0.000 description 1
- ILACEZQKVDMRMW-UHFFFAOYSA-N Furanether A Natural products C1C2=COC=C2C2C3CC(C)(C)CC3C1(C)O2 ILACEZQKVDMRMW-UHFFFAOYSA-N 0.000 description 1
- ULCWZQJLFZEXCS-KGLIPLIRSA-N Furconazole-cis Chemical compound O1[C@@H](OCC(F)(F)F)CC[C@@]1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 ULCWZQJLFZEXCS-KGLIPLIRSA-N 0.000 description 1
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 description 1
- 241000223194 Fusarium culmorum Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DYMNZCGFRHLNMT-UHFFFAOYSA-N Glyodin Chemical compound CC(O)=O.CCCCCCCCCCCCCCCCCC1=NCCN1 DYMNZCGFRHLNMT-UHFFFAOYSA-N 0.000 description 1
- 206010018498 Goitre Diseases 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- YDNLKBDXQCHOTH-UHFFFAOYSA-N Halacrinate Chemical compound C1=CC=C2C(Cl)=CC(Br)=C(OC(=O)C=C)C2=N1 YDNLKBDXQCHOTH-UHFFFAOYSA-N 0.000 description 1
- 239000005794 Hymexazol Substances 0.000 description 1
- 239000005795 Imazalil Substances 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 239000005796 Ipconazole Substances 0.000 description 1
- 239000005867 Iprodione Substances 0.000 description 1
- VROYMKJUVCKXBU-UHFFFAOYSA-N Irumamycin Natural products CCC(=O)C1(C)OC1C(C)CC(C)C1C(C)C(O)C(C)C=CC(OC2OC(C)C(O)C(OC(N)=O)C2)CCCC=C(C)C(O2)C(C)=CCC2(O)CC(=O)O1 VROYMKJUVCKXBU-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000005800 Kresoxim-methyl Substances 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- 241001344131 Magnaporthe grisea Species 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- ZCAHBOURBFRXOT-UHFFFAOYSA-N Mecarbinzid Chemical compound C1=CC=C2N(C(=O)NCCSC)C(NC(=O)OC)=NC2=C1 ZCAHBOURBFRXOT-UHFFFAOYSA-N 0.000 description 1
- 241001143352 Meloidogyne Species 0.000 description 1
- 241000243785 Meloidogyne javanica Species 0.000 description 1
- 239000002169 Metam Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000005868 Metconazole Substances 0.000 description 1
- 239000005809 Metiram Substances 0.000 description 1
- 239000005810 Metrafenone Substances 0.000 description 1
- 241001459558 Monographella nivalis Species 0.000 description 1
- 239000005811 Myclobutanil Substances 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- VJAWBEFMCIINFU-UHFFFAOYSA-N Nitrothal-isopropyl Chemical compound CC(C)OC(=O)C1=CC(C(=O)OC(C)C)=CC([N+]([O-])=O)=C1 VJAWBEFMCIINFU-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- GPSSJHKOZAOGIF-UHFFFAOYSA-N O1C=CC=C1.N1C=CC=C1.[Cl] Chemical compound O1C=CC=C1.N1C=CC=C1.[Cl] GPSSJHKOZAOGIF-UHFFFAOYSA-N 0.000 description 1
- 241001668536 Oculimacula yallundae Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical class C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 241001123663 Penicillium expansum Species 0.000 description 1
- 241001223281 Peronospora Species 0.000 description 1
- 241000201565 Peronospora viciae f. sp. pisi Species 0.000 description 1
- HEMINMLPKZELPP-UHFFFAOYSA-N Phosdiphen Chemical compound C=1C=C(Cl)C=C(Cl)C=1OP(=O)(OCC)OC1=CC=C(Cl)C=C1Cl HEMINMLPKZELPP-UHFFFAOYSA-N 0.000 description 1
- 244000302661 Phyllostachys pubescens Species 0.000 description 1
- 235000003570 Phyllostachys pubescens Nutrition 0.000 description 1
- 239000005818 Picoxystrobin Substances 0.000 description 1
- 241001503460 Plasmodiophorida Species 0.000 description 1
- 241000233626 Plasmopara Species 0.000 description 1
- 241001281803 Plasmopara viticola Species 0.000 description 1
- 241000500439 Plutella Species 0.000 description 1
- 241000317981 Podosphaera fuliginea Species 0.000 description 1
- 241001337928 Podosphaera leucotricha Species 0.000 description 1
- 229930182764 Polyoxin Natural products 0.000 description 1
- 241000222640 Polyporus Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000005821 Propamocarb Substances 0.000 description 1
- 239000005824 Proquinazid Substances 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 239000005825 Prothioconazole Substances 0.000 description 1
- 241000682843 Pseudocercosporella Species 0.000 description 1
- 241000521936 Pseudomonas amygdali pv. lachrymans Species 0.000 description 1
- 241000589615 Pseudomonas syringae Species 0.000 description 1
- 241001281802 Pseudoperonospora Species 0.000 description 1
- 241000342307 Pseudoperonospora humuli Species 0.000 description 1
- 241000221300 Puccinia Species 0.000 description 1
- 241000228454 Pyrenophora graminea Species 0.000 description 1
- 241000231139 Pyricularia Species 0.000 description 1
- 239000005828 Pyrimethanil Substances 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 241000233639 Pythium Species 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 241001533598 Septoria Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000005835 Silthiofam Substances 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 239000005837 Spiroxamine Substances 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 241000907561 Sydowia polyspora Species 0.000 description 1
- 239000005840 Tetraconazole Substances 0.000 description 1
- 241001617088 Thanatephorus sasakii Species 0.000 description 1
- 241000722133 Tilletia Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000005845 Tolclofos-methyl Substances 0.000 description 1
- 241000222355 Trametes versicolor Species 0.000 description 1
- 239000005847 Triazoxide Substances 0.000 description 1
- NHTFLYKPEGXOAN-UHFFFAOYSA-N Trichlamide Chemical compound CCCCOC(C(Cl)(Cl)Cl)NC(=O)C1=CC=CC=C1O NHTFLYKPEGXOAN-UHFFFAOYSA-N 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- 241000221577 Uromyces appendiculatus Species 0.000 description 1
- 241000514371 Ustilago avenae Species 0.000 description 1
- 241000007070 Ustilago nuda Species 0.000 description 1
- 229930195482 Validamycin Natural products 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- 241000589634 Xanthomonas Species 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- 241001272684 Xanthomonas campestris pv. oryzae Species 0.000 description 1
- LYVWMIHLNQLWAC-UHFFFAOYSA-N [Cl].[Cu] Chemical compound [Cl].[Cu] LYVWMIHLNQLWAC-UHFFFAOYSA-N 0.000 description 1
- QBQQMUDUVXZUOS-UHFFFAOYSA-N [Cl].[O].N1C=CC=C1 Chemical compound [Cl].[O].N1C=CC=C1 QBQQMUDUVXZUOS-UHFFFAOYSA-N 0.000 description 1
- BAOWVDHYZBLYMB-UHFFFAOYSA-N [F].C1=CC=NC=C1 Chemical compound [F].C1=CC=NC=C1 BAOWVDHYZBLYMB-UHFFFAOYSA-N 0.000 description 1
- ZJOCMGQZWCTWNX-UHFFFAOYSA-N [ethoxy(ethylsulfanyl)phosphoryl]oxycyclohexane Chemical compound CCOP(=O)(SCC)OC1CCCCC1 ZJOCMGQZWCTWNX-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- CGIHPACLZJDCBQ-UHFFFAOYSA-N acibenzolar Chemical compound SC(=O)C1=CC=CC2=C1SN=N2 CGIHPACLZJDCBQ-UHFFFAOYSA-N 0.000 description 1
- 238000001720 action spectrum Methods 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940051881 anilide analgesics and antipyretics Drugs 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- RGHILYZRVFRRNK-UHFFFAOYSA-N anthracene-1,2-dione Chemical compound C1=CC=C2C=C(C(C(=O)C=C3)=O)C3=CC2=C1 RGHILYZRVFRRNK-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 229940111121 antirheumatic drug quinolines Drugs 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 1
- 229950000294 azaconazole Drugs 0.000 description 1
- JFILLDQSIUEZPE-UHFFFAOYSA-N azane;piperazine Chemical compound N.C1CNCCN1 JFILLDQSIUEZPE-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 150000007980 azole derivatives Chemical class 0.000 description 1
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- 229940054066 benzamide antipsychotics Drugs 0.000 description 1
- 150000003936 benzamides Chemical class 0.000 description 1
- ZWIPGARCRSFMHK-UHFFFAOYSA-N benzene;1h-imidazole Chemical class C1=CNC=N1.C1=CC=CC=C1 ZWIPGARCRSFMHK-UHFFFAOYSA-N 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical class C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 238000003339 best practice Methods 0.000 description 1
- 229960002326 bithionol Drugs 0.000 description 1
- JFIOVJDNOJYLKP-UHFFFAOYSA-N bithionol Chemical compound OC1=C(Cl)C=C(Cl)C=C1SC1=CC(Cl)=CC(Cl)=C1O JFIOVJDNOJYLKP-UHFFFAOYSA-N 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- DSKJPMWIHSOYEA-UHFFFAOYSA-N bupirimate Chemical compound CCCCC1=C(C)N=C(NCC)N=C1OS(=O)(=O)N(C)C DSKJPMWIHSOYEA-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- JHRWWRDRBPCWTF-OLQVQODUSA-N captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- RXDMAYSSBPYBFW-UHFFFAOYSA-N carpropamid Chemical compound C=1C=C(Cl)C=CC=1C(C)NC(=O)C1(CC)C(C)C1(Cl)Cl RXDMAYSSBPYBFW-UHFFFAOYSA-N 0.000 description 1
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 1
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 1
- NHTGQOXRZFUGJX-UHFFFAOYSA-N chlorquinox Chemical compound N1=CC=NC2=C(Cl)C(Cl)=C(Cl)C(Cl)=C21 NHTGQOXRZFUGJX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- SVOAENZIOKPANY-CVBJKYQLSA-L copper;(z)-octadec-9-enoate Chemical compound [Cu+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O SVOAENZIOKPANY-CVBJKYQLSA-L 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- JOXAXMBQVHFGQT-UHFFFAOYSA-J copper;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Cu+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S JOXAXMBQVHFGQT-UHFFFAOYSA-J 0.000 description 1
- FHTUCVJPHHUQIS-UHFFFAOYSA-N copper;zinc;dioxido(dioxo)chromium Chemical compound [Cu+2].[Zn+2].[O-][Cr]([O-])(=O)=O.[O-][Cr]([O-])(=O)=O FHTUCVJPHHUQIS-UHFFFAOYSA-N 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- AIMMVWOEOZMVMS-UHFFFAOYSA-N cyclopropanecarboxamide Chemical compound NC(=O)C1CC1 AIMMVWOEOZMVMS-UHFFFAOYSA-N 0.000 description 1
- HAORKNGNJCEJBX-UHFFFAOYSA-N cyprodinil Chemical compound N=1C(C)=CC(C2CC2)=NC=1NC1=CC=CC=C1 HAORKNGNJCEJBX-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229960003887 dichlorophen Drugs 0.000 description 1
- 229940004812 dicloran Drugs 0.000 description 1
- PNKGIAQRMACYGQ-UHFFFAOYSA-N dicopper;dizinc;chromium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Cr+3].[Cr+3].[Cu+2].[Cu+2].[Zn+2].[Zn+2] PNKGIAQRMACYGQ-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 description 1
- ZHIKKPYAYGUYPV-UHFFFAOYSA-N dimethylaminocarbamothioylsulfanyl n-(dimethylamino)carbamodithioate Chemical compound CN(C)NC(=S)SSC(=S)NN(C)C ZHIKKPYAYGUYPV-UHFFFAOYSA-N 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- ZHDBTKPXEJDTTQ-UHFFFAOYSA-N dipyrithione Chemical compound [O-][N+]1=CC=CC=C1SSC1=CC=CC=[N+]1[O-] ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- PYZSVQVRHDXQSL-UHFFFAOYSA-N dithianon Chemical compound S1C(C#N)=C(C#N)SC2=C1C(=O)C1=CC=CC=C1C2=O PYZSVQVRHDXQSL-UHFFFAOYSA-N 0.000 description 1
- JMXKCYUTURMERF-UHFFFAOYSA-N dodemorph Chemical compound C1C(C)OC(C)CN1C1CCCCCCCCCCC1 JMXKCYUTURMERF-UHFFFAOYSA-N 0.000 description 1
- 229940044165 dodicin Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000012407 engineering method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229960002125 enilconazole Drugs 0.000 description 1
- BBXXLROWFHWFQY-UHFFFAOYSA-N ethirimol Chemical compound CCCCC1=C(C)NC(NCC)=NC1=O BBXXLROWFHWFQY-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- KQTVWCSONPJJPE-UHFFFAOYSA-N etridiazole Chemical compound CCOC1=NC(C(Cl)(Cl)Cl)=NS1 KQTVWCSONPJJPE-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 description 1
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 description 1
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 229940026651 gly-oxide Drugs 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 229950000289 guanoctine Drugs 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- AGKSTYPVMZODRV-UHFFFAOYSA-N imibenconazole Chemical compound C1=CC(Cl)=CC=C1CSC(CN1N=CN=C1)=NC1=CC=C(Cl)C=C1Cl AGKSTYPVMZODRV-UHFFFAOYSA-N 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- QTYCMDBMOLSEAM-UHFFFAOYSA-N ipconazole Chemical compound C1=NC=NN1CC1(O)C(C(C)C)CCC1CC1=CC=C(Cl)C=C1 QTYCMDBMOLSEAM-UHFFFAOYSA-N 0.000 description 1
- FCOAHACKGGIURQ-UHFFFAOYSA-N iprobenfos Chemical compound CC(C)OP(=O)(OC(C)C)SCC1=CC=CC=C1 FCOAHACKGGIURQ-UHFFFAOYSA-N 0.000 description 1
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- VROYMKJUVCKXBU-YACXGCCLSA-N irumamycin Chemical compound CCC(=O)[C@@]1(C)OC1[C@H](C)C[C@@H](C)[C@@H]1[C@H](C)C(O)[C@@H](C)/C=C/[C@H](OC2O[C@H](C)[C@@H](O)[C@H](OC(N)=O)C2)CCC/C=C(C)/[C@@H](O2)C(C)=CC[C@]2(O)CC(=O)O1 VROYMKJUVCKXBU-YACXGCCLSA-N 0.000 description 1
- GRHBQAYDJPGGLF-UHFFFAOYSA-N isothiocyanic acid Chemical compound N=C=S GRHBQAYDJPGGLF-UHFFFAOYSA-N 0.000 description 1
- 229950003188 isovaleryl diethylamide Drugs 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- PVTHJAPFENJVNC-MHRBZPPQSA-N kasugamycin Chemical compound N[C@H]1C[C@H](NC(=N)C(O)=O)[C@@H](C)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O PVTHJAPFENJVNC-MHRBZPPQSA-N 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- BCTQJXQXJVLSIG-UHFFFAOYSA-N mepronil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C)=C1 BCTQJXQXJVLSIG-UHFFFAOYSA-N 0.000 description 1
- HYVVJDQGXFXBRZ-UHFFFAOYSA-N metam Chemical compound CNC(S)=S HYVVJDQGXFXBRZ-UHFFFAOYSA-N 0.000 description 1
- XWPZUHJBOLQNMN-UHFFFAOYSA-N metconazole Chemical compound C1=NC=NN1CC1(O)C(C)(C)CCC1CC1=CC=C(Cl)C=C1 XWPZUHJBOLQNMN-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- ZWJNEYVWPYIKMB-UHFFFAOYSA-N methfuroxam Chemical compound CC1=C(C)OC(C)=C1C(=O)NC1=CC=CC=C1 ZWJNEYVWPYIKMB-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- TZUAKKVHNFEFBG-UHFFFAOYSA-N methyl n-[[2-(furan-2-ylmethylideneamino)phenyl]carbamothioyl]carbamate Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1N=CC1=CC=CO1 TZUAKKVHNFEFBG-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229920000257 metiram Polymers 0.000 description 1
- HIIRDDUVRXCDBN-OBGWFSINSA-N metominostrobin Chemical compound CNC(=O)C(=N\OC)\C1=CC=CC=C1OC1=CC=CC=C1 HIIRDDUVRXCDBN-OBGWFSINSA-N 0.000 description 1
- AMSPWOYQQAWRRM-UHFFFAOYSA-N metrafenone Chemical compound COC1=CC=C(Br)C(C)=C1C(=O)C1=C(C)C=C(OC)C(OC)=C1OC AMSPWOYQQAWRRM-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- KCIRYJNISRMYFI-UHFFFAOYSA-N mildiomycin Natural products NC(CO)C(=O)NC1C=CC(OC1C(O)(CC(O)CNC(=N)N)C(=O)O)N2CN=C(N)C(=C2)CO KCIRYJNISRMYFI-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OYRIKLVYHTWHCZ-UHFFFAOYSA-N n-cyclohexyl-2,5-dimethylfuran-3-carboxamide Chemical compound O1C(C)=CC(C(=O)NC2CCCCC2)=C1C OYRIKLVYHTWHCZ-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- UQJQVUOTMVCFHX-UHFFFAOYSA-L nabam Chemical compound [Na+].[Na+].[S-]C(=S)NCCNC([S-])=S UQJQVUOTMVCFHX-UHFFFAOYSA-L 0.000 description 1
- 229960003255 natamycin Drugs 0.000 description 1
- 239000004311 natamycin Substances 0.000 description 1
- 235000010298 natamycin Nutrition 0.000 description 1
- 229940042880 natural phospholipid Drugs 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- YBKGERLDRMINOV-UHFFFAOYSA-N oxathiine Chemical class O1SC=CC=C1 YBKGERLDRMINOV-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- LKPLKUMXSAEKID-UHFFFAOYSA-N pentachloronitrobenzene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl LKPLKUMXSAEKID-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- PWXJULSLLONQHY-UHFFFAOYSA-N phenylcarbamic acid Chemical class OC(=O)NC1=CC=CC=C1 PWXJULSLLONQHY-UHFFFAOYSA-N 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical compound NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 1
- IBSNKSODLGJUMQ-SDNWHVSQSA-N picoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC(C(F)(F)F)=N1 IBSNKSODLGJUMQ-SDNWHVSQSA-N 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 description 1
- JPFWJDMDPLEUBD-ITJAGOAWSA-N polyoxorim Polymers O[C@@H]1[C@H](O)[C@@H]([C@H](NC(=O)[C@H]([C@H](O)[C@@H](O)COC(N)=O)N)C(O)=O)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 JPFWJDMDPLEUBD-ITJAGOAWSA-N 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- QXJKBPAVAHBARF-BETUJISGSA-N procymidone Chemical compound O=C([C@]1(C)C[C@@]1(C1=O)C)N1C1=CC(Cl)=CC(Cl)=C1 QXJKBPAVAHBARF-BETUJISGSA-N 0.000 description 1
- WZZLDXDUQPOXNW-UHFFFAOYSA-N propamocarb Chemical compound CCCOC(=O)NCCCN(C)C WZZLDXDUQPOXNW-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- NNOBHPBYUHDMQF-UHFFFAOYSA-N propylphosphine Chemical compound CCCP NNOBHPBYUHDMQF-UHFFFAOYSA-N 0.000 description 1
- FLVBXVXXXMLMOX-UHFFFAOYSA-N proquinazid Chemical compound C1=C(I)C=C2C(=O)N(CCC)C(OCCC)=NC2=C1 FLVBXVXXXMLMOX-UHFFFAOYSA-N 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- JOOMJVFZQRQWKR-UHFFFAOYSA-N pyrazophos Chemical compound N1=C(C)C(C(=O)OCC)=CN2N=C(OP(=S)(OCC)OCC)C=C21 JOOMJVFZQRQWKR-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 1
- 229960003811 pyrithione disulfide Drugs 0.000 description 1
- 229960002132 pyrrolnitrin Drugs 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- MRUMAIRJPMUAPZ-UHFFFAOYSA-N quinolin-8-ol;sulfuric acid Chemical compound OS(O)(=O)=O.C1=CN=C2C(O)=CC=CC2=C1 MRUMAIRJPMUAPZ-UHFFFAOYSA-N 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 150000003252 quinoxalines Chemical class 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 235000020995 raw meat Nutrition 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 201000010153 skin papilloma Diseases 0.000 description 1
- ZEVCJZRMCOYJSP-UHFFFAOYSA-N sodium;2-(dithiocarboxyamino)ethylcarbamodithioic acid Chemical compound [Na+].SC(=S)NCCNC(S)=S ZEVCJZRMCOYJSP-UHFFFAOYSA-N 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- PUYXTUJWRLOUCW-UHFFFAOYSA-N spiroxamine Chemical compound O1C(CN(CC)CCC)COC11CCC(C(C)(C)C)CC1 PUYXTUJWRLOUCW-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- 150000004867 thiadiazoles Chemical class 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical compound C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1
- XBRCDWHXULVEFB-UHFFFAOYSA-N triphenyltin(1+) Chemical compound C1=CC=CC=C1[Sn+](C=1C=CC=CC=1)C1=CC=CC=C1 XBRCDWHXULVEFB-UHFFFAOYSA-N 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the groups —CO—N< and, both being directly attached by their carbon atoms to the same carbon skeleton, e.g. H2N—NH—CO—C6H4—COOCH3; Thio-analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
公开了新型活性物质的结合物,包括特定的杂环三氟丁烯基化合物及先前已知的杀真菌剂。所述活性物质结合物具有非常好的协同的杀真菌、杀线虫、杀昆虫和/或杀螨虫效应。
Description
本申请是2004年4月20日提交的发明名称为“基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物”的中国发明专利申请第200480018511.0号的分案申请。
技术领域
本发明涉及新型的活性化合物的结合物(combination),包括,第一,已知的杂环三氟丁烯基化合物,第二,已知的杀真菌活性化合物,所述结合物非常适于防治动物害虫、例如昆虫及线虫,以及防治真菌。
背景技术
已知某些杂环三氟丁烯基化合物具有杀线虫特性(WO 01/02378 A1)。这些化合物尚未报道具有杀昆虫或杀真菌活性。
而且,已知多种吡咯衍生物、芳香族羧酸衍生物、吗啉化合物及其它杂环可用于防治真菌(参见K.H.Büchel“Pflanzenschutz und ”[作物保护和害虫防治],第87、136、141及146至153页,Georg Thieme Verlag,Stuttgart 1977;C.D.S.Thomlin(编辑):“The Pesticide Manual”,第11版,British Crop ProtectionCouncil,Farnham,Surrey,1997)。然而,所述化合物低施用率(application rate)时的活性和/或其作用谱并不总是令人满意。
发明内容
现已发现一种活性化合物的结合物具有非常好的杀线虫、杀昆虫和/或杀真菌特性,所述结合物包括式(I)的杂环三氟丁烯基化合物,
其中
X代表卤素,并且
n代表0、1或2,
(“第1组活性化合物”)
以及
至少一种选自以下种类杀真菌剂的活性化合物,
含氮脂族杀真菌剂:氨丁烷(butylamine),清菌脲(cymoxanil),多敌菌(dodicin),多果定(dodine),双胍盐(guazatine),双胍辛醋酸盐(iminoctadine);
酰胺类:氯环丙酰胺(carpropamid),双胺灵(chloraniformethan),clozylacon,氰霜唑(cyazofamid),环氟菌胺(cyflufenamid),diclocymet,韩乐宁(ethaboxam),稻瘟酰胺(fenoxanil),氟联苯菌(flumetover),呋吡唑灵(furametpyr),丙氯灵(prochloraz),醌菌腙(quinazamid),硅噻菌胺(silthiofam),嗪氨灵(triforine),氨基酸类、例如苯霜灵(benalaxyl)、苯霜灵(benalaxyl)-M呋氨丙灵(furalaxyl)、甲霜灵(metalaxyl)、精甲霜灵(metalaxyl-M)、稻瘟酯(pefurazoate),苯甲酰胺类、例如苯氧肟酸(benzohydroxamicacid)、硫氰苯甲酰胺(tioxymid)、杨菌胺(trichlamide)、tricyclamide、氯菌胺(zarilamid)、苯酰菌胺(zoxamide),糠酰胺类、例如环糠酰胺(cyclafuramid)、拌种胺(furmecyclox),苯基硫酰胺类、例如抑菌灵(dichlofluanid)、对甲抑菌灵(tolyfluanid),缬氨酰胺类(valinamide)、例如benthiavalicarb、缬霉威(iprovalicarb),N-酰苯胺类、例如苯霜灵(benalaxyl)、苯霜灵(benalaxyl)-M、烟酰胺(boscalid)、萎锈灵(carboxin)、环酰菌胺(fenhexamid)、甲霜灵(metalaxyl)、精甲霜灵(metalaxyl-M)、噻菌胺(metsulfovax)、甲呋酰胺(ofurace)、噁霜灵(oxadixyl)、氧化萎锈灵(oxycarboxin)、比锈灵(pyracarbolid)、溴氟唑菌(trifluzamide)、thiadinil,N-苯甲酰苯胺类、例如麦锈灵(benodanil)、氟酰胺(flutolanil)、灭锈胺(mebenil)、丙氧灭锈胺(mepronil)、防霉胺(salicylanilide)、叶枯酞(tecloftalam),N-呋喃甲酰苯胺类、例如呋菌胺(fenfuram)、呋氨丙灵furalaxyl)、灭菌胺(furcarbanil)、甲呋菌胺(methfuroxam),磺酰苯胺类、例如磺菌胺(flusulfamide);
抗菌素类杀真菌剂:多马霉素(aureofungin),灭瘟素(blasticidin-S),卡巴西霉素(capsimycin),放线菌酮(cycloheximide),灰黄霉素(griseofulvin),irumamycin,春雷霉素(kasugamycin),米多霉素(mildiomycin),多马霉素(natamycin),多抗霉素(polyxins),保粒霉素(丁)(polyoxorim),链霉素(streptomycin),有效霉素(validamycin),strobin类、例如腈嘧菌酯(azoxystrobin)、dimoxystrobin、氟嘧菌酯(fluoxastrobin)、亚胺菌(kresoxim-methyl)、叉氨苯酰胺(metominostrobin)、orysastrobin、啶氧菌酯(picoxystrobin)、吡唑醚菌酯(pyraclostrobin)、肟菌酯(trifloxystrobin);
芳香族杀真菌剂:联苯(biphenyl),地茂散(chloroneb),百菌清(chlorothalonil),甲酚(cresol),氯硝胺(dicloran),六氯苯(hexachlorobenzene),五氯酚(pentachlorophenol),五氯硝基苯(quintozenen),五氯酚钠(sodiumpentachlorophenoxide),四氯硝基苯(tecnazene);
苯并咪唑类:苯菌灵(benomyl),多菌灵(carbendazim),苯咪唑菌(chlorfenazole),氰菌灵(cypendazole),双乙氧咪唑威(debacarb),麦穗宁(fuberidazole),咪卡病西(mecarbinzid),吡咪唑菌(rabenzazole),涕必灵(thiabendazole);
苯并噻唑类:丙唑草隆(bentaluron),灭瘟唑(chlobenthiazone),TCMTB;
二苯类杀真菌剂:氯赛多(bithionol),双氯酚(dichlorophen),二苯胺(diphenylamine);
氨基甲酸酯类:benthiavalicarb,呋菌隆(furophanate),缬霉威,百维灵(propamocarb),托布津(thiophanate),甲基托布津(thiophanate-methyl),苯并咪唑基氨基甲酸酯类、例如苯菌灵、多菌灵、氰菌灵、双乙氧咪唑威、咪卡病西,苯氨基甲酸酯类、例如乙霉威(diethofencarb);
康唑类(conazole):康唑类(咪唑)、例如同菌唑(climbazole)、克霉唑(clotrimazole)、烯菌灵(imazalil)、oxpocanazole、丙氯灵、氟菌唑(triflumizole),康唑类(三唑)、例如戊环唑(azaconazole)、糠菌唑(bromuconazole)、环唑醇(cyproconazole)、苄氯三唑醇(diclobutrazole)、噁醚唑(difenoconazole)、烯唑醇(diniconazole)、diniconazole-M、氧唑菌(epoxiconazole)、乙环唑(etaconazole)、腈苯唑(fenbuconazole)、喹唑菌酮(fluquinconazole)、氟硅唑(flusilazole)、粉唑醇(flutriafol)、呋菌唑(furconazole)、呋菌唑-顺式(furconazole-cis)、己唑醇(hexaconazole)、酰胺唑(imibenconazole)、环戊唑醇(ipconazole)、环戊唑菌(metconazole)、腈菌唑(myclobutanil)、戊菌唑(penconazole)、丙环唑(propiconazole)、丙硫康唑(prothioconazole)、唑喹菌酮(quinconazole)、硅氟唑(simeconazole)、戊唑醇(tebuconazole)、氟醚唑(tetraconazole)、三唑酮(triadimefon)、唑菌醇(triadimenol)、戊叉唑菌(triticonazole)、烯效唑(uniconazole)、高烯效唑(uniconazole-P);
铜类杀真菌剂:波尔多液(Bordeaux mixture),大土克斯(Burgundymixture),菌杀特(Cheshunt mixture),醋酸铜,碱式碳酸铜,氢氧化铜,环烷酸铜,油酸铜,王铜(copperoxychloride),硫酸铜、碱式硫酸铜,铬酸铜锌(copper zinc chromate),硫杂灵(cufraneb),福美铜氯(cuprobam),氧化亚铜,锰铜混剂(mancopper),喹啉铜(oxinecopper);
二甲酰亚胺类:噁唑酮菌(famoxadone),唑啶草(fluoroimide),二氯苯基二甲酰亚胺类、例如乙菌利(chlozolinate)、菌核利(dichlozoline)、异丙定(iprodione)、氯苯咪菌酮(isovaledione)、甲菌利(myclozolin)、杀菌利(procymidone)、烯菌酮(vinclozolin),邻苯二甲酰亚胺类、例如敌菌丹(captafol)、克菌丹(captan)、灭菌磷(ditalimfos)、灭菌丹(folpet)、苯菌胺(thiochorfenphim);
二硝基苯酚类:乐杀螨(binapacryl),敌螨通(dinobuton),敌螨普(dinocap),敌螨普-4(dinocap-4),敌螨普-6(dinocap-6),二硝酯(dinocton),硝戊酯(dinopenton),硝辛酯(dinosulfon),硝丁酯(dinoterbon)、DNOC;
二硫代氨基甲酸盐类:肼硫双(azithiram),卡巴莫夫(carbamorph),硫杂灵,福美铜氯,双硫仑(disulfiram),福美铁(ferbam),威百亩(metam),代森钠(nabam),福代硫(tecoram),福美双(thiram),福美锌(ziram),环状二硫代氨基甲酸盐类、例如棉隆(dazomet)、伊藤(etem)、代森环(milneb),聚合二硫代氨基甲酸盐类、例如锰铜混剂、代森锰锌(mancozeb)、代森锰(maneb)、代森联(metiram)、代森福美锌(polycarbamate)、丙森锌(propineb)、代森锌(zineb);
咪唑类:氰霜唑,咪唑菌酮(fenamidone),菌拿灵(fenapanil),果绿定(glyodin),异丙定,氯苯咪菌酮,稻瘟酯,唑菌嗪(triazoxide),(亦见:康唑类(咪唑类));
吗啉类:aldimorph,苯杂吗(benzamorf),卡巴莫夫(carbamorph),烯酰吗啉(dimethomorph),吗菌灵(dodemorph),丁苯吗啉(fenpropimorph),氟吗啉(flumorph),克啉菌(tridemorph);
有机磷类杀真菌剂:氨丙膦酸(ampropylfos),灭菌磷(ditalimfos),克瘟散(edifenphos),藻菌磷(fosetyl),环己硫磷(hexylthiofos),异稻瘟净(iprobenfos),双氯苯磷(phosdiphen),定菌磷(pyrazophos),甲基立枯磷(tolclofos-methyl),三唑磷胺(triamiphos);
有机锡化合物:癸磷锡(decafentin),三苯基锡(fentin),丁蜗锡(tributyltinoxide);
氧硫杂环己二烯类:萎锈灵(carboxin)、氧化萎锈灵(oxycarboxin)、oxyfenthiin;
噁唑类:乙菌利(chlozolinate),菌核利(dichlozoline),敌菌酮(drazoxolon),噁唑酮菌(famoxadone),土菌消(hymexazol),肼叉噁唑酮(metazoxolon),甲菌利(myclozolin),噁霜灵(oxadixyl),烯菌酮(vinclozolin);
吡啶类:烟酰胺(boscalid),粉病定(buthiobate),吡菌硫(dipyrithione),氟啶胺(fluazinam),病定清(pyridinitril),啶斑肟(pyrifenox),吡氧氯(pyroxychlor),氯吡呋醚(pyroxyfur);
嘧啶类:andoprim,磺嘧菌灵(bupirimate),环丙嘧啶(cyprodinil),氟嘧菌胺(diflumetorim),甲菌定(dimethirimol),乙菌定(ethirimol),异嘧菌醇(fenarimol),嘧菌腙(ferimzone),meferimzone,嘧菌胺(mepanipyrim),氟苯嘧啶醇(nuarimol),二甲嘧菌胺(pyrimethanil),嘧菌醇(triarimol);
吡咯类:拌种咯(fenpiclonil),氟噁菌(fludioxonil),唑啶草(fluoroimide),pyrrolnitrine;
喹啉类:促长啉(ethoxyquin),烯菌酯(halacrinate),8-羟基喹啉硫酸盐,quinacetol,喹氧灵(quinoxyfen);
醌类:敌菌腙(benquinox),四氯对醌(chloranil),二氯萘醌(dichlone),二氰蒽醌(dithianon);
喹喔啉类:灭螨猛(chinomethionat),四氯喹噁啉(chlorquinox),克杀螨(thioquinox);
噻唑类:韩乐宁(ethaboxam),氯唑灵(etridiazole),噻菌胺(metsulfovax),异噻菌酮(octhilinone),涕必灵(thiabendazole),噻二氟(thiadifluor),溴氟唑菌(thifluzamide);
硫代氨基甲酸酯类:磺菌威(methasulfocarb),胺丙威(prothiocarb);
噻吩类:韩乐宁,硅噻菌胺;
三嗪类:敌菌灵(anilazine);
三唑类:双苯三唑醇(bitertanol),菌唑灵(fluotrimazole),丁三唑(triazbutil)(亦见康唑类(三唑类));
脲类:丙唑草隆(bentaluron),戊菌隆(pencycuron),醌菌腙(quinazamid);
未分类的杀真菌剂:噻二唑素(acibenzolar),脂酸盐(acypetacs),烯丙醇(allylalcohol),苄菌铵(benzalkonium chloride),苄烯酸(benzamacril),bethoxazin,香芹酮(carvone),氯化苦(chloropicrin),酯菌胺(cyprofuram),DBCP,保果鲜(dehydroaceticacid),哒菌清(diclomezine),焦碳酸二乙酯(diethylpyrocarbonate),敌磺钠(fenaminosulf),种衣酯(fenitropan),苯锈啶(fenpropidin),甲醛,六氯丁二烯(hexachlorobutadiene),稻瘟灵(isoprothiolane),溴甲烷(methylbromid),异硫氰酸甲酯(methylisothiocyanate),metrafenone,BAS510(nicobifen),硫氰散(nitrostyrene),异丙消(nitrothal-isopropyl),八氯酮(OCH),oxolinix acid,联苯酚,四氯苯酞(phthalide),粉病灵(piperalin),烯丙苯噻唑(probenazole),proquinazid,咯喹酮(pyroquilon),联苯酚钠(sodium orthophenylphenoxide),螺噁茂胺(spiroxamine),硫酰氟(sultropen),噻菌腈(thicyofen),三环唑(tricyclazole),环烷酸锌(zincnaphthenate),(2S)-N-[2-[4-[[3-(4-氯苯基)-2-丙炔基]氧]-3-甲氧苯基]乙基]-3-甲基-2-[(甲磺酰基)氨基]-丁酰胺;1-(1-萘基)-1H-吡咯-2,5-二酮;2,3,5,6-四氯-4-(甲磺酰基)-吡啶;2-氨基-4-甲基-N-苯基-5-噻唑甲酰胺(thiazolecarboxamide);2-氯-N-(2,3-二氢-1,1,3-三甲基-1H-茚-1-基)-3-吡啶甲酰胺(pyridincarboxamide);3,4,5-三氯-2,6-吡啶二腈;顺式-1-(4-氯苯基)-2-(1H-1,2,4-三唑-1-基)-环庚醇;1-(2,3-二氢-2,2-二甲基-1H-茚-1-基)-1H-咪唑-5-羧酸甲酯;碳酸氢钾;N-(6-甲氧基-3-吡啶基)-环丙烷甲酰胺(cyclopropanecarboxamide);N-丁基-8-(1,1-二甲基乙基)-1-氧杂螺[4.5]癸-3-胺;
(“第2组活性化合物”)。
出人意料的是,本发明活性化合物的结合物的杀线虫、杀真菌和/或杀昆虫活性显著高于单独的活性化合物的活性总和。存在真实的非可预见的协同效应,而并不仅仅是活性的叠加。
具体实施方式
除至少一种式(I)的活性化合物之外,本发明的活性化合物结合物还包括至少一种第2组活性化合物。
优选上述活性化合物结合物包括至少一种式(I)的化合物作为第1组活性化合物,其中
X代表氟、氯或溴,并且
n代表0或2。
特别优选上述活性化合物结合物包括至少一种式(I)的化合物作为第1组活性化合物,其中
X代表氟或氯,并且
n代表2。
本发明特别提供的上述活性化合物结合物,除包括至少一种选自上文定义之一的第1组活性化合物的活性化合物之外,还包括至少一种选自上文定义的以下种类杀真菌剂之一的第2组活性化合物:酰胺类、strobin类、康唑类、二甲酰亚胺类、有机磷类杀真菌剂、氨基甲酸酯类及脲衍生物。
特别优选上述活性化合物结合物包括根据上文定义的第1组活性化合物的式(IA)化合物,
或根据上文定义第1组活性化合物的式(IB)化合物
或根据上文定义第1组活性化合物的式(IC)化合物
优选活性化合物结合物包括一种式(IA)、(IB)或(IC)的活性化合物,以及一种以下选自酰胺类、strobin类、康唑类、二甲酰亚胺类、有机磷类杀真菌剂、氨基甲酸酯类或脲类衍生物的活性化合物:
对甲抑菌灵(tolylfluanid),氯环丙酰胺,双胺灵,clozylacon,氰霜唑,环氟菌胺,diclocymet,韩乐宁,稻瘟酰胺,氟联苯菌,呋吡唑灵,丙氯灵,醌菌腙,硅噻菌胺,嗪氨灵,苯霜灵,苯霜灵(benalaxyl)-M,呋氨丙灵,甲霜灵,精甲霜灵,稻瘟酯,苯氧肟酸,硫氰苯甲酰胺,杨菌胺,tricyclamide,氯菌胺,苯酰菌胺,环糠酰胺,拌种胺,抑菌灵,benthiavalicarb,缬霉威,苯霜灵,benalaxyl-M,烟酰胺,萎锈灵,环酰菌胺,甲霜灵,精甲霜灵,噻菌胺,甲呋酰胺,噁霜灵,氧化萎锈灵,比锈灵,溴氟唑菌,tiadinil,N-苯甲酰苯胺、例如麦锈灵、氟酰胺、灭锈胺、丙氧灭锈胺、防霉胺、叶枯酞;呋喃甲酰苯胺、例如呋菌胺、呋氨丙灵、灭菌胺、甲呋菌胺,磺菌胺(“酰胺类”);
肟菌酯,氟嘧菌酯,腈嘧菌酯,dimoxystrobin,亚胺菌,叉氨苯酰胺,orysastrobin,啶氧菌酯,吡唑醚菌酯(“strobin”);
戊唑醇,丙硫康唑,丙氯灵,同菌唑,克霉唑,烯菌灵,oxpocanazole,氟菌唑,戊环唑,糠菌唑,环唑醇,苄氯三唑醇,噁醚唑,烯唑醇,diniconazole-M,氧唑菌,乙环唑,腈苯唑,喹唑菌酮,氟硅唑,粉唑醇,呋菌唑,呋菌唑-顺式,己唑醇,酰胺唑,环戊唑醇,环戊唑菌,腈菌唑,戊菌唑,丙环唑,唑喹菌酮,硅氟唑,氟醚唑,三唑酮,唑菌醇,戊叉唑菌,烯效唑,高烯效唑(“康唑类”);
异丙定,噁唑酮菌,唑啶草,乙菌利,菌核利,氯苯咪菌酮,甲菌利,杀菌利,烯菌酮,敌菌丹、克菌丹、灭菌磷、灭菌丹、苯菌胺(“二甲酰亚胺类”);
藻菌磷,氨丙膦酸,灭菌磷,克瘟散,环己硫磷,异稻瘟净,双氯苯磷,定菌磷,甲基立枯磷,三唑磷胺(“有机磷类杀真菌剂”);
benthiavalicarb,呋菌隆,缬霉威,百维灵,托布津,甲基托布津,苯菌灵,多菌灵,氰菌灵,双乙氧咪唑威,咪卡病西,乙霉威(“氨基甲酸酯类”);
戊菌隆,丙唑草隆,醌菌腙(“脲类”),
或活性化合物土菌消(hymexazole)(噁唑类)或氟噁菌(吡咯类)之一。
特别优选活性化合物结合物包括一种式(IC)的活性化合物(第1组活性化合物)及一种以下选自酰胺类、strobin类、康唑类、二甲酰亚胺类、有机磷类杀真菌剂或脲类衍生物的活性化合物:
对甲抑菌灵,氯环丙酰胺,双胺灵,clozylacon,氰霜唑,环氟菌胺,diclocymet,韩乐宁,稻瘟酰胺,氟联苯菌(flumetover),呋吡唑灵,丙氯灵,醌菌腙,硅噻菌胺,嗪氨灵,苯霜灵,benalaxyl-M,呋氨丙灵,甲霜灵,精甲霜灵,稻瘟酯,苯氧肟酸,硫氰苯甲酰胺,杨菌胺,tricyclamide,氯菌胺,苯酰菌胺,环糠酰胺,拌种胺,抑菌灵,benthiavalicarb,缬霉威,苯霜灵,苯霜灵-M,烟酰胺,萎锈灵,环酰菌胺,甲霜灵,精甲霜灵,噻菌胺,甲呋酰胺,噁霜灵,氧化萎锈灵,比锈灵,溴氟唑菌,tiadinil,N-苯甲酰苯胺、例如麦锈灵、氟酰胺、灭锈胺、丙氧灭锈胺、防霉胺、叶枯酞;呋喃甲酰苯胺、例如呋菌胺、呋氨丙灵、灭菌胺、甲呋菌胺,磺菌胺(“酰胺类”);
肟菌酯,氟嘧菌酯,腈嘧菌酯,dimoxystrobin,亚胺菌,叉氨苯酰胺,orysastrobin,啶氧菌酯,吡唑醚菌酯、(“strobin”);
戊唑醇,丙氯灵,同菌唑,克霉唑,烯菌灵,oxpocanazole,氟菌唑,戊环唑,糠菌唑,环唑醇,苄氯三唑醇,噁醚唑,烯唑醇,diniconazole-M,氧唑菌,乙环唑,腈苯唑,喹唑菌酮,氟硅唑,粉唑醇,呋菌唑,呋菌唑-顺式,己唑醇,酰胺唑,环戊唑醇,环戊唑菌,腈菌唑,戊菌唑,丙环唑,丙硫康唑,唑喹菌酮,硅氟唑,氟醚唑,三唑酮,唑菌醇,戊叉唑菌,烯效唑,高烯效唑(“康唑类”);
异丙定,噁唑酮菌,唑啶草,乙菌利,菌核利,氯苯咪菌酮,甲菌利,杀菌利,烯菌酮,敌菌丹、克菌丹、灭菌磷、灭菌丹、苯菌胺(“二甲酰亚胺类”);
藻菌磷,氨丙膦酸,灭菌磷,克瘟散,环己硫磷,异稻瘟净,双氯苯磷,定菌磷,甲基立枯磷,三唑磷胺(“有机磷类杀真菌剂”);
戊菌隆,丙唑草隆,醌菌腙(“脲类”),
或活性化合物土菌消或氟噁菌之一。
上述优选的康唑类中,三唑类具有特别的意义(interest)。上述优选二甲酰亚胺类中,二氯苯基二甲酰亚胺类具有特别的意义。
下表示出特别优选的本发明的结合物。
表1
此外,活性化合物结合物还可包括其它可混合的杀真菌、杀螨虫或杀昆虫活性组分。
若本发明活性化合物结合物中各活性化合物以某种重量比存在,则协同效应特别显著。然而,活性化合物结合物中活性化合物的重量比可在相对宽的范围内变化。一般而言,本发明的结合物包括下表以实例方式给出的优选及特别优选混合比的式(I)的活性化合物及第2组的共存组分(co-component):
●混合比基于重量比。该比例的含义应理解为式(I)的活性化合物:共存组分
表2:
杀真菌剂在农作物保护中用于防治根肿菌(Plasmodiophoromycete)、卵菌(Oomycete)、壶菌(Chytridiomycete)、接合菌(Zygomycete)、子囊菌(Asomycete)、担子菌(Basidiomycete)及半知菌(Deuteromycete)。
作为实例、而并非以限制的方式提出归入以上所列类名的引起真菌及细菌疾病的病原体:
黄单胞(Xanthomonas)菌种,例如野油菜黄单胞菌水稻致病变种(Xanthomonascampestris pv.oryzae);假单胞(Pseudomonas)菌种,例如丁香假单胞菌黄瓜致病变种(Pseudomonas syringae pv.lachrymans);欧文氏(Erwinia)菌种,例如解淀粉欧文氏菌(Erwinia amylovora);腐霉(Pythium)菌种,例如终极腐霉(Pythiumultimum);疫霉(Phytophthora)菌种,例如致病疫霉(Phytophthora infestans);假霜霉(Pseudoperonospora)菌种,例如草假霜霉(Pseudoperonospora humuli)或古巴假霜霉(Pseudoperonospora cubensis);轴霜霉(Plasmopara)菌种,例如葡萄生轴霜霉(Plasmopara viticola);盘霜霉(Bremia)菌种,例如莴苣盘霜霉(Bremia lactucae);霜霉(Peronospora)菌种,例如豌豆霜霉(Peronospora pisi)或十字花科霜霉(P.brassicae);白粉菌(Erysiphe)菌种,例如禾谷白粉菌(Erysiphe graminis);单囊壳属(Sphaerotheca)菌种,例如凤仙花单囊壳(Sphaerotheca fuliginea);叉丝单囊壳属(Podosphaera)菌种,例如白叉丝单囊壳(Podosphaera leucotricha);黑星菌属(Venturia)菌种,例如苹果黑星病菌(Venturia inaequalis);核腔菌属(Pyrenophora)菌种,例如圆核腔菌(Pyrenophorateres)或麦类核腔菌(P.graminea)(分生孢子形式:Drechslera,syn:Helminthosporium);旋孢腔菌属(Cochliobolus)菌种,例如禾旋孢腔菌(Cochliobolus sativus)(分生孢子形式:Drechslera,syn:Helminthosporium);单胞锈菌属(Uromyces)菌种,例如疣顶单胞锈菌(Uromyces appendiculatus);柄锈菌(Puccinia)菌种,例如隐匿柄锈菌(Pucciniarecondita);核盘菌属(Sclerotinia)菌种,例如核盘菌(Sclerotinia sclerotiorum);腥黑粉菌属(Tilletia)菌种,例如小麦网腥黑粉菌(Tilletia caries);黑粉菌(Ustilago)菌种,例如裸黑粉菌(Ustilago nuda)或燕麦黑粉菌(Ustilago avenae);薄膜革菌属(Pellicularia)菌种,例如佐佐木薄膜革菌(Pellicularia sasakii);梨孢(Pyricularia)菌种,例如稻梨孢(Pyricularia oryzae);镰孢属(Fusarium)菌种,例如黄色镰孢(Fusarium culmorum);葡萄孢属(Botrytis)菌种,例如灰葡萄孢(Botrytis cinerea);壳针孢属(Septoria)菌种,例如颖枯壳针孢(Septoria nodorum);小球腔菌属(Leptosphaeria)菌种,例如Leptosphaeria nodorum;尾孢属(Cercospora)菌种,例如变灰尾孢(Cercospora canescens);链格孢属(Alternaria)菌种,例如芸薹链格孢(Alternariabrassicae);及假小尾孢属(Pseudocercosporella)菌种,例如小麦基腐病菌(Pseudocercosporella herpotrichoides)。
活性化合物结合物在防治植物疾病所需浓度下具有的良好植物耐受性,这就使得可对植物的地上部分、离体繁殖株(propagation stock)和种子、及土壤进行处理。
本发明的活性化合物结合物还适用于提高农作物产量。而且,所述结合物还具有降低的毒性及良好的植物耐受性。
在保护材料方面,本发明的活性化合物结合物可用于保护工业材料免受不需要的微生物的侵染及破坏。
本发明中的工业材料的含义应理解为已制成准备用于工业的非活体(non-living)材料。例如,拟由本发明的活性化合物结合物保护以免受微生物改变(change)或破坏的工业材料可为粘合剂、胶料、纸张及板材、织物、皮革、木材、漆及塑料制品、冷却润滑剂(cooling lubricant)及其它可受微生物侵染或破坏的材料。可被微生物繁殖损害的生产工厂部件,例如冷却水回路,亦在待保护材料的范围内。可在本发明范围内提出的工业材料优选为粘合剂、胶料、纸张及板材、皮革、木材、漆、冷却润滑剂及传热液体,特别优选木材。
可提及的使工业材料发生退化(degrading)或改变的微生物为,例如细菌、真菌、酵母菌、藻类及粘液生物。本发明的活性化合物结合物优选作用于真菌,特别是霉菌、木材退色真菌及木腐真菌(担子菌),以及粘液生物及藻类。
作为实例可提出以下属微生物:
链格孢属(Alternaria)、例如链格孢(Alternaria tenuis),曲霉属(Aspergillus)、例如黑曲霉(Aspergillus nigar),毛壳菌(Chaetomium)、例如球毛壳菌(Chaetomium globosum),Coniophora、例如Coniophora puetana,香菇属(Lentinus)、例如虎皮香菇菌(Lentinus tigrinus),青霉属(Penicillium)、例如灰绿青霉(Penicilliumglaucum),多孔菌(Polyporus)、例如杂色多孔菌(Polyporus versicolor),短梗霉属(Aureobasidium)、例如出芽短梗霉(Aureobasidium pullulans),核茎点属(Sclerophoma),例如Sclerophoma pityophila,木霉属(Trichoderma)、例如绿色木霉(Trichoderma viride),埃希氏菌属(Escherichia)、例如大肠埃希氏菌(Escherichiacoli),假单胞菌属(Pseudomonas)、例如铜绿假单胞菌(Pseudomonas aeruginosa),及葡萄球菌属(Staphylococcus)、例如金黄色葡萄球菌(Staphylococcus aureus)。
依据其具体的物理和/或化学特性,活性化合物结合物可转化为常规制剂,例如溶液、乳剂、悬浮剂、粉剂、泡沫、膏剂、颗粒剂、气雾剂、及聚合物与种子包衣(coating)组合物中的微胶囊剂、及ULV冷却与加温弥雾(fogging)制剂。
所述制剂以已知方式制备,例如将活性化合物与填料(extender)混合,即与液体溶剂、加压液化气和/或固体载体混合,同时可选择地使用表面活性剂,即乳化剂和/或分散剂和/或发泡剂。如果使用的填料为水,还可使用,例如有机溶剂作为辅助溶剂。适合的液体溶剂主要有:芳香族化合物、例如二甲苯、甲苯或烷基萘,氯化芳香族化合物或氯化脂肪烃、例如氯苯、氯乙烯或二氯甲烷,脂肪烃、例如环己烷或石蜡(如石油馏分),醇、例如丁醇或乙二醇及其醚及酯,酮、例如丙酮、甲乙酮、甲基异丁基酮或环己酮,强极性溶剂、例如二甲基甲酰胺或二甲基亚砜,或水。液化气填料或载体的含义应理解为标准温度及大气压下为气态的液体,例如气溶胶喷雾剂、例如卤代烃,或丁烷、丙烷、氮气及二氧化碳。适合的固体载体为:例如粉碎的天然矿物、例如高岭土、粘土、滑石粉、白垩、石英、凹凸棒石、蒙脱石或硅藻土,以及粉碎的合成矿物、例如高分散二氧化硅、氧化铝及硅酸盐。适用于颗粒剂的固体载体为:例如粉碎并分级的天然岩石、例如方解石、大理石、浮石、海泡石及白云石,或合成的无机及有机粉颗粒,及有机物颗粒、例如锯木屑、椰壳、玉米穗轴及烟草茎。适合的乳化剂和/或发泡剂为:例如非离子及阴离子乳化剂、例如聚氧乙烯脂肪酸酯、聚氧乙烯脂肪醇醚、例如烷基芳基聚乙二醇醚、烷基磺酸盐、烷基硫酸盐、芳基磺酸盐、或蛋白质水解产物。适合的分散剂为:例如木素亚硫酸盐废液及甲基纤维素。
制剂中可使用增粘剂、例如羧甲基纤维素,及粉末、颗粒或胶乳形式的天然及合成聚合物、例如阿拉伯树胶、聚乙烯醇及聚乙酸乙烯酯、或天然磷脂、例如脑磷脂及卵磷脂,及合成磷脂。其它添加剂可为矿物油及植物油。
可使用着色剂,例如无机颜料、例如氧化铁、氧化钛及普鲁士蓝,及有机染料、例如茜素染料、偶氮染料及金属酞菁染料,及微量营养物、例如铁盐、镁盐、硼盐、铜盐、钴盐、钼盐及锌盐。
制剂一般包括0.1至95重量百分比的活性化合物,优选0.5至90%。
活性化合物结合物可以其本身、其制剂形式或由其制备的使用形式使用,例如即用(ready-to-use)的溶液、悬浮剂、可湿性粉剂、膏剂、可溶性粉剂、粉剂及颗粒剂。施用以常规方式进行,例如浇灌、喷雾、雾化(atomizing)、撒播(broadcasting)、喷粉、发泡、抛撒(spreading)等。还可通过超低容量法(ultra-low volume method)施用活性化合物,或者将活性化合物制剂或活性化合物本身向土壤内注射。还可处理植物种子。
本发明的活性化合物结合物用作杀真菌剂时,施用率可依据施用类型在相对较宽的范围内变化。对于植物某些的部位(part)的处理,活性化合物的施用率一般为0.1至10000g/ha(公顷),优选10至1000g/ha。对于拌种,活性化合物的施用率一般为0.001至50g每公斤种子,优选0.01至10g每公斤种子。对于土壤处理,活性化合物的施用率一般为0.1至10000g/ha,优选1至5000g/ha。
用于保护工业材料的组合物包括的活性化合物的量一般为1至95重量%,优选10至75重量%。
本发明的活性化合物结合物的使用浓度取决于待防治微生物的特性(nature)及出现率(occurrence),以及待保护材料的组成。最佳使用量可通过一系列试验确定。一般而言,基于待保护材料,使用浓度为0.001至5重量%,优选0.05至1.0重量%。
依据本发明,可处理所有的植物及植物部位。本发明中植物的含义应理解为所有植物及植物种群,例如需要的及不需要的野生植物或农作物植物(包括自然存在的农作物植物)。农作物植物可以是通过常规育种及最优方法、或通过生物技术及基因工程方法、或通过所述方法结合而获得的植物,包括转基因植物,也包括可受植物种苗权保护或不受其保护的植物栽培品种。植物部位的含义应理解为植物的所有的地上及地下部位及器官,例如芽、叶、花及根,可提及的实例为叶、针叶(needle)、茎、干、花、子实体、果实和种子、以及根、块茎及根茎。植物部位还包括采收的植物以及无性与有性繁殖物,例如幼苗、块茎、根茎、插条及种子。
本发明的使用活性化合物对植物及植物部位进行的处理,依据常规处理方法直接进行或作用于其环境、生境或贮存区域,所述常规处理方法例如浸渍、喷雾、蒸发、雾化、撒播、刷涂(brushing-on),在繁殖物、特别是种子的情况下,再刷涂一层或多层。
活性化合物结合物的杀真菌、杀线虫、杀昆虫和/或杀螨虫活性高于单独使用的活性化合物的活性总和时,表现出杀真菌剂、杀线虫剂、杀昆虫剂及杀螨虫剂的协同效应。
给定的两种活性化合物的结合物的预期活性可如下计算(参见Colby,S.R.,“Calculating Synergistic and Antagonistic Responses of HerbicideCombinations”,Weeds 15(1967),20-22):
若
X为药效或杀灭率,当以m ppm浓度使用活性化合物A时,表示为未处理对照品的百分比,
Y为药效或杀灭率,当以m ppm浓度使用活性化合物B时,表示为未处理对照品的百分比,
E为药效或杀灭率,当以m ppm及n ppm浓度使用活性化合物A及B时,表示为未处理对照品的百分比,
则
若实际的杀真菌或杀线虫、杀昆虫和/或杀螨虫活性高于计算值,则结合物的活性具有超加和性(superadditive),即存在协同效应。此时,实际观测的药效或杀灭率必须高于用于计算预期药效(E)的上式的计算值。
实施例
实施例A
根结线虫(Meloidogyne)试验(杀线虫活性)
溶剂: 7重量份二甲基甲酰胺
乳化剂: 2重量份烷基芳基聚乙二醇醚
为制备活性化合物的适合制剂,将1重量份的活性化合物与所述量的溶剂及乳化剂混合,并用水稀释浓缩液至所需浓度。
用沙、活性化合物的溶液、南方根结线虫(Meloidogyne incognita)卵/幼虫的悬浮液及莴苣种子装满容器。莴苣种子发芽,植物生长。在根部形成虫瘿(gall)。
经过所需一段时间后,通过虫瘿的形成以%确定杀线虫活性。100%表示未发现虫瘿;0%表示处理过的植物上的虫瘿量等于未处理的对照品的虫瘿量。将确定的杀灭率代入Colby公式。
本试验中,本发明的以下活性化合物结合物较单独使用的活性化合物表现出协同增强的活性(实测值*=试验中发现的活性;计算值**=Colby公式计算的活性):
表3:(IC)+丙硫康唑
表4:(IC)+氟噁菌
表5:(IC)+肟菌酯
实施例B
菜蛾(Plutella)试验,敏感株(杀昆虫活性)
溶剂: 7重量份二甲基甲酰胺
乳化剂: 2重量份烷基芳基聚乙二醇醚
为制备活性化合物的适合制剂,将1重量份的活性化合物与所述量的溶剂及乳化剂混合,并用含有乳化剂的水稀释浓缩液至所需浓度。
将甘蓝叶(Brassica oleracea)浸渍至所需浓度的活性化合物制剂中进行处理,并在叶子湿润时接入菜蛾(Plutella xylostella,敏感株)蠋。经过所需一段时间后,确定杀灭%。100%表示杀灭所有蠋;0%表示未杀灭蠋。将确定的杀灭率代入Colby公式。
本试验中,以下本发明的活性化合物结合物较单独使用的活性化合物表现出协同增强的活性(实测值*=试验中发现的活性;计算值**=Colby公式计算的活性):
表6:(IC)+肟菌酯
实施例C
菌丝体生长试验
培养基: 39重量份马铃薯葡萄糖琼脂
5重量份琼脂
将上述物质溶解于1000ml蒸馏水中,并在121℃下高压灭菌30分钟。
溶剂: 49重量份丙酮
乳化剂: 1重量份烷基芳基聚乙二醇醚
为制备活性化合物的适合制剂,将1重量份的活性化合物或活性化合物结合物与所述量的溶剂及乳化剂混合,并用水稀释浓缩液至要求的原液浓度。为确定试验浓度,在各种情况下将1体积的活性化合物原液与9体积的液体培养基完全混合,并倒入培养皿中。一旦培养基冷却且固化,即将板与下表所列的微生物接种,接种温度约20℃。
依据微生物的生长率,在2至8天后进行评定。0%药效表示等于对照品的药效,而100%药效表示未观察到菌丝体生长。
下表清楚表示出本发明的活性化合物结合物的实测活性高于计算的活性,即存在协同效应。
表7:恶疫霉(Phytophthora cactorum)菌丝体生长试验
(IC)+戊菌隆
表8:恶疫霉菌丝体生长试验
(IC)+藻菌磷
表9:恶疫霉菌丝体生长试验
(IC)+对甲抑菌灵
表10:恶疫霉菌丝体生长试验
(IC)+肟菌酯
表11:恶疫霉菌丝体生长试验
(IC)+氟嘧菌酯
表12:恶疫霉菌丝体生长试验
(IC)+戊唑醇
表13:恶疫霉菌丝体生长试验
(IC)+丙氯灵
表14:雪腐镰孢菌(Fusarium nivale)菌丝体生长试验
(IC)+藻菌磷
表15:立枯丝核菌(Rhizoctonia solani)菌丝体生长试验
(IC)+藻菌磷
表16:立枯丝核菌菌丝体生长试验
(IC)+肟菌酯
表17:立枯丝核菌菌丝体生长试验
(IC)+氟嘧菌酯
表18:终极腐霉(Phythium ultimum)菌丝体生长试验
(IC)+异丙定
表19:终极腐霉菌丝体生长试验
(IC)+对甲抑菌灵
表20:终极腐霉菌丝体生长试验
(IC)+氟嘧菌酯
表21:终极腐霉菌丝体生长试验
(IC)+戊唑醇
Claims (8)
1.一种协同组合物,其特征在于所述协同组合物包括一种活性化合物结合物,所述结合物包括
(a)一种或多种式(I)的活性化合物
其中
X代表卤素
n代表0、1或2,
(“第1组活性化合物”)
及
(b)一种或多种选自以下(b1)至(b7)组中同一组或不同组的活性化合物:
(b1)氯环丙酰胺,双胺灵、clozylacon,氰霜唑,环氟菌胺,diclocymet,韩乐宁,稻瘟酰胺,氟联苯菌,呋吡唑灵,丙氯灵,醌菌腙,硅噻菌胺,嗪氨灵,苯霜灵,benalaxyl-M,呋氨丙灵,甲霜灵,精甲霜灵,稻瘟酯,苯氧肟酸,硫氰苯甲酰胺,杨菌胺,tricyclamide,氯菌胺,苯酰菌胺,环糠酰胺,拌种胺,benthiavalicarb,缬霉威,苯霜灵,benalaxyl-M,烟酰胺,萎锈灵,环酰菌胺,甲霜灵,精甲霜灵,噻菌胺,甲呋酰胺,噁霜灵,氧化萎锈灵,比锈灵,溴氟唑菌,tiadinil,N-苯甲酰苯胺类、例如麦锈灵、氟酰胺、灭锈胺、丙氧灭锈胺、防霉胺、叶枯酞,N-呋喃甲酰苯胺类、例如呋菌胺、呋氨丙灵、灭菌胺、甲呋菌胺,磺菌胺(“酰胺类”);
(b2)肟菌酯,氟嘧菌酯,腈嘧菌酯,dimoxystrobin,亚胺菌,叉氨苯酰胺,ocysastrobin,啶氧菌酯,吡唑醚菌酯(“strobin类”);
(b3)同菌唑,克霉唑,烯菌灵,oxpoconazole,氟菌唑,戊环唑,糠菌唑,环唑醇,苄氯三唑醇,噁醚唑,烯唑醇,diniconazole-M,氧唑菌,乙环唑,腈苯唑,喹唑菌酮,氟硅唑,粉唑醇,呋菌唑,呋菌唑-顺式,己唑醇,酰胺唑,环戊唑醇,环戊唑菌,腈菌唑,戊菌唑,丙环唑,唑喹菌酮,硅氟唑,氟醚唑,三唑酮,唑菌醇,戊叉唑菌,烯效唑,高烯效唑(“康唑类”);
(b4)异丙定,噁唑酮菌,唑啶草,乙菌利,菌核利,氯苯咪菌酮,甲菌利,杀菌利,烯菌酮,敌菌丹,克菌丹,灭菌磷,灭菌丹,苯菌胺(“二甲酰亚胺类”);
(b5)藻菌磷,氨丙膦酸,灭菌磷,克瘟散,环己硫磷,异稻瘟净,双氯苯磷,定菌磷,甲基立枯磷,三唑磷胺(“有机磷杀真菌剂”);
(b6)benthiavalicarb,呋菌隆,缬霉威,百维灵,托布津,甲基托布津,苯菌灵,多菌灵,氰菌灵,双乙氧咪唑威,咪卡病西,乙霉威(“氨基甲酸酯类”);
(b7)丙唑草隆,醌菌腙(“脲类”);
或活性化合物土菌消
(“第2组活性化合物”)。
2.权利要求1的协同组合物,其特征在于所述协同组合物包括一种或多种式(I)的化合物,其中
X代表氟、氯或溴,并且
n代表0或2。
3.权利要求1的协同组合物,其特征在于所述协同组合物包括一种或多种式(I)的化合物,其中
X代表氟或氯,并且
n代表2。
4.权利要求1的协同组合物,其特征在于所述协同组合物包括下式(IA)、(IB)及(IC)化合物的其中一种,作为第1组活性化合物
5.权利要求1的协同组合物,其特征在于所述协同组合物包括式(IC)化合物,作为第1组活性化合物。
6.权利要求1至5之一的组合物用于防治真菌、线虫、昆虫和/或螨虫的用途。
7.一种防治真菌、线虫、昆虫及螨虫的方法,其特征在于使权利要求1至5之一的组合物作用于线虫和/或昆虫和/或真菌和/或其生境。
8.一种制备杀真菌、杀线虫、杀昆虫和/或杀螨虫组合物的方法,其特征在于将权利要求1至5之一的组合物与填料和/或表面活性剂混合。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10319591.2 | 2003-05-02 | ||
DE10319591A DE10319591A1 (de) | 2003-05-02 | 2003-05-02 | Wirkstoffkombinationen mit nematiziden, insektiziden und fungiziden Eigenschaften basierend auf Trifluorbutenyl-Verbindungen |
CN2004800185110A CN1812715B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2004800185110A Division CN1812715B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108432775A true CN108432775A (zh) | 2018-08-24 |
CN108432775B CN108432775B (zh) | 2021-04-13 |
Family
ID=33305090
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510309247.6A Expired - Lifetime CN105104414B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN201810474587.8A Expired - Lifetime CN108432775B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN2010101414171A Expired - Lifetime CN101843248B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN2004800185110A Expired - Lifetime CN1812715B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN201110390537.XA Expired - Lifetime CN102550570B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510309247.6A Expired - Lifetime CN105104414B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010101414171A Expired - Lifetime CN101843248B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN2004800185110A Expired - Lifetime CN1812715B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
CN201110390537.XA Expired - Lifetime CN102550570B (zh) | 2003-05-02 | 2004-04-20 | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 |
Country Status (23)
Country | Link |
---|---|
US (5) | US8426605B2 (zh) |
EP (1) | EP1622453B1 (zh) |
JP (1) | JP4657199B2 (zh) |
KR (2) | KR20090075756A (zh) |
CN (5) | CN105104414B (zh) |
AT (1) | ATE508634T1 (zh) |
AU (1) | AU2004233565B2 (zh) |
BR (1) | BRPI0410040B1 (zh) |
CA (1) | CA2524058C (zh) |
CR (1) | CR8065A (zh) |
CY (1) | CY1111800T1 (zh) |
DE (1) | DE10319591A1 (zh) |
DK (1) | DK1622453T3 (zh) |
EC (1) | ECSP056139A (zh) |
ES (1) | ES2366029T3 (zh) |
IL (1) | IL171586A (zh) |
MA (1) | MA27792A1 (zh) |
MX (1) | MXPA05011786A (zh) |
PL (1) | PL1622453T3 (zh) |
PT (1) | PT1622453E (zh) |
SI (1) | SI1622453T1 (zh) |
WO (1) | WO2004095929A1 (zh) |
ZA (1) | ZA200508712B (zh) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10319591A1 (de) | 2003-05-02 | 2004-11-18 | Bayer Cropscience Ag | Wirkstoffkombinationen mit nematiziden, insektiziden und fungiziden Eigenschaften basierend auf Trifluorbutenyl-Verbindungen |
DE10319590A1 (de) | 2003-05-02 | 2004-11-18 | Bayer Cropscience Ag | Wirkstoffkombinationen mit nematiziden und insektiziden Eigenschaften basierend auf Trifluorbutenyl-Verbindungen |
CN1306874C (zh) * | 2004-11-18 | 2007-03-28 | 上海工程技术大学 | 一种用于防治蔬菜苗期病害的种子处理剂 |
EP1941799A3 (en) * | 2004-12-17 | 2008-09-17 | Devgen NV | Nematicidal compositions |
EP1830647A2 (de) * | 2004-12-20 | 2007-09-12 | Basf Aktiengesellschaft | Verfahren zur bekämpfung von pilzkrankheiten bei leguminosen |
DE102004062513A1 (de) * | 2004-12-24 | 2006-07-06 | Bayer Cropscience Ag | Insektizide auf Basis von Neonicotinoiden und ausgewählten Strobilurinen |
AR056260A1 (es) * | 2004-12-28 | 2007-10-03 | Syngenta Participations Ag | MÉTODO PARA EL CONTROL DE HONGOS PAToGENOS DE LAS PLANTAS |
GB0508993D0 (en) | 2005-05-03 | 2005-06-08 | Syngenta Participations Ag | Pesticidal compositions |
DE102005023835A1 (de) * | 2005-05-24 | 2006-12-07 | Bayer Cropscience Ag | Fungizide Wirkstoffkombination |
AU2006311031B2 (en) | 2005-11-10 | 2012-02-02 | Basf Se | Fungicidal mixtures |
WO2008011191A1 (en) * | 2006-07-21 | 2008-01-24 | Replidyne, Inc. | Antibacterial heterocyclic ureas |
CN101209049B (zh) * | 2006-12-29 | 2010-12-29 | 河南农业大学 | 植物生长调节剂组合物 |
WO2009015208A1 (en) * | 2007-07-23 | 2009-01-29 | Replidyne, Inc. | Antibacterial amide and sulfonamide substituted heterocyclic urea compounds |
WO2009015193A1 (en) * | 2007-07-23 | 2009-01-29 | Replidyne, Inc. | Antibacterial sulfone and sulfoxide substituted heterocyclic urea compounds |
KR101398632B1 (ko) * | 2008-01-07 | 2014-05-22 | 삼성전자주식회사 | 반도체 패키지 테스트 장치 및 그에 채용되는 멀티 레벨푸셔 |
TWI526535B (zh) * | 2008-09-12 | 2016-03-21 | 住友化學股份有限公司 | 噻唑菌胺對於基因轉殖植物在植物病害之防治方法的用途 |
WO2010043553A1 (en) * | 2008-10-16 | 2010-04-22 | Basf Se | Pesticidal mixtures comprising metaflumizone and a fungicidal compound |
WO2010043552A1 (en) * | 2008-10-16 | 2010-04-22 | Basf Se | Pesticidal mixtures comprising metaflumizone and an azole fungicide |
WO2013071365A1 (en) * | 2011-11-16 | 2013-05-23 | Macquarie University | A method of treatment and prophylaxis and compositions useful therefor |
CN103430945B (zh) * | 2012-04-13 | 2014-12-03 | 永农生物科学有限公司 | 含有肟菌酯和氟菌唑的复配农药杀菌组合物及其应用 |
CN103891732B (zh) * | 2012-12-31 | 2015-06-17 | 江苏丰登作物保护股份有限公司 | 一种含吡唑萘菌胺和己唑醇的杀菌组合物及其应用 |
CN103704230A (zh) * | 2013-12-13 | 2014-04-09 | 广西田园生化股份有限公司 | 含吡唑醚菌酯与苯酰胺类杀菌剂组合物的超低容量液剂 |
CN106061260A (zh) | 2013-12-31 | 2016-10-26 | 美国陶氏益农公司 | 用于谷类中真菌防治的协同杀真菌混合物 |
CN105454251B (zh) * | 2014-09-12 | 2018-07-03 | 沈阳中化农药化工研发有限公司 | 一种杀真菌组合物及其用途 |
US20170295788A1 (en) * | 2014-09-18 | 2017-10-19 | Adama Makhteshim Ltd. | Use of heterocyclic fluoroalkenyl sulfone compounds for repelling molluscs |
CN104430477A (zh) * | 2014-11-25 | 2015-03-25 | 广东中迅农科股份有限公司 | 一种含有氟噻虫砜和烟碱类杀虫剂的农药组合物 |
CN104855392B (zh) * | 2015-02-04 | 2016-08-17 | 东莞市瑞德丰生物科技有限公司 | 一种杀线虫组合物 |
BR122020007824B1 (pt) | 2015-12-10 | 2022-05-03 | Adama Makhteshim Ltd. | Composição de material agrícola, seu processo de preparação e métodos para controlar e prevenir peste e para aperfeiçoar o crescimento de planta |
CN105594713A (zh) * | 2015-12-18 | 2016-05-25 | 广东中迅农科股份有限公司 | 含有氟烯线砜和氟嘧菌酯的农药组合物 |
CN105532695A (zh) * | 2015-12-18 | 2016-05-04 | 广东中迅农科股份有限公司 | 含有中生菌素和吡唑醚菌酯以及氟烯线砜的农药组合物 |
CN106937637A (zh) * | 2017-04-22 | 2017-07-11 | 北京科发伟业农药技术中心 | 含氟烯线砜的组合物 |
BR112020012614A2 (pt) | 2017-12-20 | 2020-11-24 | Pi Industries Ltd | compostos de fluoralquenil, processo de preparação e utilização |
AR114185A1 (es) | 2018-01-23 | 2020-07-29 | Adama Makhteshim Ltd | Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1359379A (zh) * | 1999-07-06 | 2002-07-17 | 日本拜耳农药株式会社 | 杀线虫的三氟丁烯化合物 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2758115A (en) | 1955-02-10 | 1956-08-07 | Bayer Ag | Derivatives of thiophosphoric acid |
US3058990A (en) | 1961-01-19 | 1962-10-16 | Monsanto Chemicals | Haloallylthiadiazoles |
US3264117A (en) * | 1963-10-17 | 1966-08-02 | American Sugar | Free-flowing, non-caking brown sugar |
US3264177A (en) | 1964-02-17 | 1966-08-02 | Dow Chemical Co | Methods for the control of arachnids |
US3309266A (en) | 1965-07-01 | 1967-03-14 | Chevron Res | Insecticidal compositions containing oalkyl-s-alkyl phosphoroamidothioates and methods for killing insects therewith |
US3513172A (en) | 1965-09-27 | 1970-05-19 | Stauffer Chemical Co | 3-phenyl-5-(3,4,4-trifluoro-3-butenylthio)1,2,4-thiadiazole |
GB1181657A (en) | 1966-03-31 | 1970-02-18 | Ici Ltd | Pyrimidine Derivatives and Compositions Containing them |
FI762480A (zh) | 1975-09-15 | 1977-03-16 | Du Pont | |
HU204022B (en) | 1985-06-20 | 1991-11-28 | Fmc Corp | Nematocidal compositions comprising polyhalogen alkene derivatives and process for producing polyhalogen alkene derivatives |
IL79360A (en) | 1985-07-12 | 1993-02-21 | Ciba Geigy Ag | Aleyrodidae-controlling compositions containing n-(4-phenoxy-2,6- diisopropylphenyl) -n)-tert- butylthiourea as active agent |
CA1300137C (en) | 1985-12-27 | 1992-05-05 | Hiroshi Hamaguchi | Pyrazole oxime derivative and its production and use |
US4748186A (en) | 1986-06-30 | 1988-05-31 | Fmc Corporation | S-trifluorobutenyl derivatives and pesticidal uses thereof |
US5010098A (en) | 1987-07-29 | 1991-04-23 | American Cyanamid Company | Arylpyrrole insecticidal acaricidal and nematicidal agents and methods for the preparation thereof |
DK0640069T3 (da) | 1991-03-01 | 1999-07-19 | Monsanto Co | Fluoralkenylforbindelser og deres anvendelse som midler til bekæmpelse af skadelige organismer |
ATE148104T1 (de) | 1991-11-22 | 1997-02-15 | Uniroyal Chem Co Inc | Insekttötende phenylhydrazin-derivate |
ES2118816T3 (es) | 1992-04-28 | 1998-10-01 | Yashima Kagaku Kogyo Kk | 2-(2,6-difluorofenil)-4-(2-etoxi-4-terc-butilfenil)-2-oxazolina. |
IL112721A0 (en) | 1994-03-10 | 1995-05-26 | Zeneca Ltd | Azole derivatives |
US5514717A (en) | 1994-10-26 | 1996-05-07 | Monsanto Company | Fluoroalkenyl compounds and their use as pest control agents |
DE19750012A1 (de) | 1997-11-12 | 1999-05-20 | Bayer Ag | Isothiazolcarbonsäureamide |
JP2001322988A (ja) | 2000-03-09 | 2001-11-20 | Nippon Bayer Agrochem Co Ltd | 殺センチュウ性トリフルオロブテン類 |
FR2828196A1 (fr) * | 2001-08-03 | 2003-02-07 | Aventis Cropscience Sa | Derives de chromone a action fongicide, procede de preparation et application dans le domaine de l'agriculture |
JP2003113168A (ja) * | 2001-09-28 | 2003-04-18 | Bayer Ag | 殺センチュウ性トリフルオロブテン誘導体 |
JP2003192675A (ja) | 2001-12-13 | 2003-07-09 | Bayer Ag | 殺センチュウ性トリフルオロブテニルイミダゾールチオエーテル誘導体 |
DE10201238A1 (de) | 2002-01-15 | 2003-07-24 | Bayer Cropscience Ag | Verfahren zur Herstellung von halogenierten 2-(3-Butenylsulfanyl)-1,3-thiazolen |
DE10221120A1 (de) | 2002-05-13 | 2003-11-27 | Bayer Cropscience Ag | Verfahren zur Herstellung von substituierten Trifluorethylenen |
DE10229776A1 (de) | 2002-07-03 | 2004-01-22 | Bayer Cropscience Ag | Verfahren zum Herstellen von heterocyclischen Fluoralkenylsulfonen |
DE10319591A1 (de) | 2003-05-02 | 2004-11-18 | Bayer Cropscience Ag | Wirkstoffkombinationen mit nematiziden, insektiziden und fungiziden Eigenschaften basierend auf Trifluorbutenyl-Verbindungen |
DE10319590A1 (de) | 2003-05-02 | 2004-11-18 | Bayer Cropscience Ag | Wirkstoffkombinationen mit nematiziden und insektiziden Eigenschaften basierend auf Trifluorbutenyl-Verbindungen |
JP2005008567A (ja) | 2003-06-19 | 2005-01-13 | Bayer Cropscience Ag | 殺センチュウ性チアゾリン含有フルオロブテン類 |
WO2007089455A1 (en) | 2006-01-27 | 2007-08-09 | E. I. Du Pont De Nemours And Company | Fluoroalkenyl derivatives as insecticides and nematicides |
EP2604118A1 (en) | 2011-12-15 | 2013-06-19 | Bayer CropScience AG | Active ingredient combinations having insecticidal and acaricidal properties |
BR112014017298B1 (pt) | 2012-01-17 | 2020-11-03 | Syngenta Participations Ag | mistura pesticida, método de controle de insetos, ácaros, nematódeos ou moluscos e método de proteção de uma semente contra o ataque de pragas |
US20170006872A1 (en) | 2014-01-28 | 2017-01-12 | Sumitomo Chemical Company, Limited | Method for controlling pests |
US20170295788A1 (en) | 2014-09-18 | 2017-10-19 | Adama Makhteshim Ltd. | Use of heterocyclic fluoroalkenyl sulfone compounds for repelling molluscs |
-
2003
- 2003-05-02 DE DE10319591A patent/DE10319591A1/de not_active Withdrawn
-
2004
- 2004-04-20 CN CN201510309247.6A patent/CN105104414B/zh not_active Expired - Lifetime
- 2004-04-20 DK DK04728352.8T patent/DK1622453T3/da active
- 2004-04-20 AU AU2004233565A patent/AU2004233565B2/en not_active Ceased
- 2004-04-20 US US10/555,106 patent/US8426605B2/en active Active
- 2004-04-20 EP EP04728352A patent/EP1622453B1/de not_active Expired - Lifetime
- 2004-04-20 BR BRPI0410040A patent/BRPI0410040B1/pt active IP Right Grant
- 2004-04-20 PT PT04728352T patent/PT1622453E/pt unknown
- 2004-04-20 CN CN201810474587.8A patent/CN108432775B/zh not_active Expired - Lifetime
- 2004-04-20 CN CN2010101414171A patent/CN101843248B/zh not_active Expired - Lifetime
- 2004-04-20 CN CN2004800185110A patent/CN1812715B/zh not_active Expired - Lifetime
- 2004-04-20 PL PL04728352T patent/PL1622453T3/pl unknown
- 2004-04-20 KR KR1020097012663A patent/KR20090075756A/ko not_active Application Discontinuation
- 2004-04-20 SI SI200431708T patent/SI1622453T1/sl unknown
- 2004-04-20 WO PCT/EP2004/004165 patent/WO2004095929A1/de active Application Filing
- 2004-04-20 CA CA2524058A patent/CA2524058C/en not_active Expired - Fee Related
- 2004-04-20 CN CN201110390537.XA patent/CN102550570B/zh not_active Expired - Lifetime
- 2004-04-20 MX MXPA05011786A patent/MXPA05011786A/es active IP Right Grant
- 2004-04-20 AT AT04728352T patent/ATE508634T1/de active
- 2004-04-20 JP JP2006505198A patent/JP4657199B2/ja not_active Expired - Lifetime
- 2004-04-20 ES ES04728352T patent/ES2366029T3/es not_active Expired - Lifetime
-
2005
- 2005-10-27 ZA ZA200508712A patent/ZA200508712B/en unknown
- 2005-10-27 IL IL171586A patent/IL171586A/en active IP Right Grant
- 2005-10-31 CR CR8065A patent/CR8065A/es unknown
- 2005-10-31 KR KR1020057020631A patent/KR100918519B1/ko active IP Right Grant
- 2005-11-01 EC EC2005006139A patent/ECSP056139A/es unknown
- 2005-11-02 MA MA28578A patent/MA27792A1/fr unknown
-
2011
- 2011-05-19 CY CY20111100488T patent/CY1111800T1/el unknown
-
2013
- 2013-03-15 US US13/838,183 patent/US9072300B2/en not_active Expired - Fee Related
-
2015
- 2015-06-03 US US14/729,301 patent/US9642366B2/en not_active Expired - Lifetime
-
2017
- 2017-03-30 US US15/474,249 patent/US10412966B2/en not_active Expired - Fee Related
-
2019
- 2019-08-02 US US16/529,965 patent/US11026425B2/en active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1359379A (zh) * | 1999-07-06 | 2002-07-17 | 日本拜耳农药株式会社 | 杀线虫的三氟丁烯化合物 |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105104414B (zh) | 基于三氟丁烯基化合物的、具有杀线虫、杀昆虫及杀真菌特性的活性物质的结合物 | |
CN104883884B (zh) | 用于谷物里的真菌防治的协同增效杀真菌混合物 | |
CN105409971B (zh) | 用于谷物中的真菌控制的协同增效的杀真菌混合物 | |
CN109169678B (zh) | 一种杀菌剂及其组合物 | |
EP1943901A2 (en) | Method of controlling plant disease | |
JP2005512947A (ja) | 脂肪酸含有除草性組成物 | |
UA116554C2 (uk) | Синергічні фунгіцидні композиції | |
BR112019023021A2 (pt) | misturas sinérgicas para controle fúngico em cereais | |
UA126065C2 (uk) | Фунгіцидні композиції і суміші для боротьби із грибковими захворюваннями зернових культур | |
CN107683192A (zh) | 抗真菌增效剂 | |
CN109982564A (zh) | 用于谷物中真菌防治的杀真菌化合物和混合物 | |
JP4434638B2 (ja) | 植物病害防除組成物及び植物病害防除方法 | |
US20200060273A1 (en) | Fungicidal compositions | |
NZ764487B2 (en) | Anti-fungal potentiators |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20210413 |