CN108395803A - 一种新型超能纳米五防粉末涂料 - Google Patents
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Abstract
本发明涉及一种新型超能纳米五防粉末涂料,其组分及配比按质量百分比如下:TPNE1601三官能团环氧树脂5%‑10%,环氧树脂E20 30%‑40%,酰肼树脂10%‑20%;脲类树脂1%‑5%;纳米耐磨预混料(EAIEN‑1)15%‑30%,低表面能超细蜡粉预混料(EAIEN‑2)1%‑5%,绢云母1‑5%、流平剂5%‑10%、增光剂1%‑5%、附着力促进剂LTH1%‑5%。该涂料具有超耐磨、耐高温、防蜡、防垢、防腐蚀的粉末涂料配方,它适用于最高使用温度达到150℃油田油水介质管道长期使用,能够长效防腐蚀耐高温耐磨损,并有效节约清腊、清垢成本。
Description
技术领域:
本发明涉及油气田开发油井及地面采出油管防腐涂料,具体是一种新型超能纳米五防粉末涂料。
背景技术:
油田油气田开发过程中,井下采油管、地面采出油管结、结蜡、腐蚀、偏磨等问题突出,严重影响了油井采油量及地面系统输油效率,而清垢、清腊又造成采油成本大幅度增加。特别是,采油后期三元复合驱驱油技术的应用,结垢问题更加突出。油田在用粉末涂料由于耐温、耐磨效果差,应用中涂层易发生脱落、失效,达不到长期防腐、防蜡、防垢、防偏磨的效果。
发明内容:
本发明在于克服背景技术中存在的问题,提供一种新型超能纳米五防粉末涂料。该网络互穿纳米超微细防腐防蜡防垢耐高温耐磨粉末涂料具有防腐、防腊、防垢、耐磨、耐高温多重功能,可在温度最高达到150℃油田油水介质中长期使用,能够长效耐高温防腐蚀耐磨损,并有效节约清腊、清垢成本。
本发明技术方案:该网络互穿纳米超微细防腐防蜡防垢耐高温耐磨粉末涂料,其组分及配比按质量百分比如下:
新型超能纳米五防粉末涂料包括下列各组分,各组分及配比按质量百分比如下:TPNE1601三官能团环氧树脂5%-10%,环氧树脂E2030%-40%,酰肼树脂10%-20%;脲类树脂1%-5%;纳米耐磨预混料EAIEN-115%-30%,低表面能超细蜡粉预混料EAIEN-21%-5%,绢云母1-5%、流平剂5%-10%、增光剂1%-5%、附着力促进剂LTH 1%-5%;低表面能超细蜡粉预混料EAIEN-2的粒度是1500目;纳米耐磨预混料EAIEN-1的粒度为50-150nm。
本发明选择能够形成网络互穿结构的成膜物质TPNE1601三官能团环氧树脂和环氧树脂E20和固化剂酰肼树脂和脲类树脂,形成网络大分子的空间结构,能够有效提高粉末涂料耐高温、耐磨效果;加入纳米级耐磨预混合助剂,进一步提高耐磨效果的同时,具有较高的韧性;加入低表面能超微细蜡粉预混合助剂,有效提高其防垢、防蜡效果;加入能够提高粉末涂料附着和表观性能的流平剂、附着力促进剂等功能助剂,利用已有的粉末涂料制备设备,经过粉碎、挤出、压片、破碎、磨粉,形成功能型重防腐粉末涂料。所述纳米耐磨预混料EAIEN-1为纳米SiO2、纳米碳化硅、纳米Al2O3等纳米耐磨粒子经超高速混合工艺预混合而成粒度为50-150nm,购自黑龙江易爱蒽新材料科技发展有限公司;所述低表面能超细蜡粉预混料EAIEN-2为超微细聚四氟微蜡粉、超微细聚乙烯微蜡粉等蜡粉经高温熔融混合粒度是1500目,冷却破碎等工艺预混合而成,购自黑龙江易爱蒽新材料科技发展有限公司。三官能团环氧树脂TPNE1601购自上海华谊树脂有限公司;附着力促进剂LTH购自上海广凌化工有限公司。酰肼树脂为间苯二甲酸二酰肼ADH购自南京市利源化工有限公司;脲类树脂为二甲基脲UREA购自南京市利源化工有限公司。
为了实现涂料在150℃油田油水介质长期使用,要求涂料成膜物质具有较好的耐温性能、耐磨性能和化学稳定性能。本发明采用TPNE1601三官能团环氧树脂、环氧树脂E20、酰肼树脂、脲类树脂树脂,经过高温熔融网络互穿反应固化。为进一步提高涂料体系的耐磨性能,本发明根据粒子粒度分布对耐磨性的影响特征,采用纳米级耐磨预混料EAIEN-1作为粉末涂料的耐磨功能助剂。为增强粉末涂料具备防垢、防蜡的功能,本发明采用与超细蜡粉预混料EAIEN-2作为粉末涂料防垢防蜡功能助剂。
本发明与上述背景技术相比较,具有如下有益效果:该新型超能纳米五防粉末涂料,具有防腐、防垢、防蜡、耐温、耐磨特性,即降低了管道的防腐技术成本,又降低了管道清垢、清腊等作业成本,具有显著的经济效益和社会效益。
具体实施方式:
下面将结合具体实施例对本发明作进一步说明:
实施例1、
称取TPNE1601三官能团环氧树脂50g,环氧树脂E20 300g,酰肼树脂200g;脲类树脂50g;纳米耐磨预混料(EAIEN-1)300g,低表面能超细蜡粉预混料(EAIEN-2)20g,绢云母10g、流平剂50g、增光剂10g、附着力促进剂LTH10g。混合配制成本发明防垢防蜡耐磨耐高温防腐专用粉末涂料。
实施例2、
称取TPNE1601三官能团环氧树脂100g,环氧树脂E20 320g,酰肼树脂150g;脲类树脂10g;纳米耐磨预混料(EAIEN-1)250g,低表面能超细蜡粉预混料(EAIEN-2)20g,绢云母20g、流平剂90g、增光剂20g、附着力促进剂LTH20g。混合配制成本发明防垢防蜡耐磨耐高温防腐专用粉末涂料。
实施例3、
称取TPNE1601三官能团环氧树脂50g,环氧树脂E20 400g,酰肼树脂120g;脲类树脂40g;纳米耐磨预混料(EAIEN-1)200g,低表面能超细蜡粉预混料(EAIEN-2)30g,绢云母20g、流平剂100g、增光剂20g、附着力促进剂LTH20g,混合配制成本发明防垢防蜡耐磨耐高温防腐专用粉末涂料。
实施例4、
称取TPNE1601三官能团环氧树脂70g,环氧树脂E20 350g,酰肼树脂120g;脲类树脂40g;纳米耐磨预混料(EAIEN-1)200g,低表面能超细蜡粉预混料(EAIEN-2)30g,绢云母20g、流平剂100g、增光剂20g、附着力促进剂LTH50g,混合配制成本发明防垢防蜡耐磨耐高温防腐专用粉末涂料。
通过室内评价试验将上述实施例1-实施例4制备的防垢防蜡耐磨耐高温防腐专用粉末涂料进行实验室评价,实验室评价的参数和指标要求见下表。
表1
通过对10项涂层检测项目的室内试验,实施例1-实施例4制备的防垢防蜡耐磨耐高温防腐专用粉末涂料,所有指标能够满足要求。其中耐磨性≤6mg、与水和油的接触角可达120°以上。
在大庆油田采油三厂井下油管,将上述实施例1-实施例4制备的防垢防蜡耐磨耐高温防腐专用粉末涂料,进行试验性应用各200m,试验井号分别为北2-5-SP094、北2-6-SP063。实施例的应用本涂料前,油井清垢、清腊周期约为56d,应用本涂层后延长进行清垢、清腊作业时间长达1a以上。同时,涂层也未发生脱落、起泡、磨损等失效情况。
Claims (3)
1.一种新型超能纳米五防粉末涂料,包括下列各组分,各组分及配比按质量百分比如下:TPNE1601三官能团环氧树脂5%-10%,环氧树脂E20 30%-40%,酰肼树脂10%-20%;脲类树脂1%-5%;纳米耐磨预混料EAIEN-115%-30%,低表面能超细蜡粉预混料
EAIEN-21%-5%,绢云母1-5%、流平剂5%-10%、增光剂1%-5%、附着力促进剂LTH1%-5%;低表面能超细蜡粉预混料EAIEN-2的粒度是1500目;纳米耐磨预混料EAIEN-1的粒度为50-150nm。
2.根据权利要求1所述的新型超能纳米五防粉末涂料,其特征在于:脲类树脂为二甲基脲。
3.根据权利要求1所述的新型超能纳米五防粉末涂料,其特征在于:酰肼树脂为间苯二甲酸二酰肼。
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CN112812655A (zh) * | 2021-01-05 | 2021-05-18 | 海隆石油产品技术服务(上海)有限公司 | 一种油管用高抗硫化氢粉末涂料的组成物 |
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