CN108394907B - 一种硅钒复合氧化物及其制备方法 - Google Patents
一种硅钒复合氧化物及其制备方法 Download PDFInfo
- Publication number
- CN108394907B CN108394907B CN201810535387.9A CN201810535387A CN108394907B CN 108394907 B CN108394907 B CN 108394907B CN 201810535387 A CN201810535387 A CN 201810535387A CN 108394907 B CN108394907 B CN 108394907B
- Authority
- CN
- China
- Prior art keywords
- composite oxide
- silicon
- ammonium metavanadate
- vanadium composite
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 46
- MANBDHUBXBMZNV-UHFFFAOYSA-N [V]=[Si] Chemical compound [V]=[Si] MANBDHUBXBMZNV-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 claims abstract description 32
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000010438 heat treatment Methods 0.000 claims abstract description 24
- 239000002243 precursor Substances 0.000 claims abstract description 22
- 239000007864 aqueous solution Substances 0.000 claims abstract description 17
- 239000008139 complexing agent Substances 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 10
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 239000002086 nanomaterial Substances 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 6
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 26
- 239000000243 solution Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 8
- 238000001914 filtration Methods 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 238000005259 measurement Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- 241000446313 Lamella Species 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000012916 structural analysis Methods 0.000 description 3
- 229910001935 vanadium oxide Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810535387.9A CN108394907B (zh) | 2018-05-29 | 2018-05-29 | 一种硅钒复合氧化物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810535387.9A CN108394907B (zh) | 2018-05-29 | 2018-05-29 | 一种硅钒复合氧化物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108394907A CN108394907A (zh) | 2018-08-14 |
CN108394907B true CN108394907B (zh) | 2021-06-22 |
Family
ID=63102397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810535387.9A Active CN108394907B (zh) | 2018-05-29 | 2018-05-29 | 一种硅钒复合氧化物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108394907B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110776007B (zh) * | 2019-11-05 | 2021-11-19 | 北华航天工业学院 | 一种乒乓菊形貌钒酸锂材料的制备方法 |
CN111420429A (zh) * | 2020-04-29 | 2020-07-17 | 清有生态科技(上海)有限公司 | 用于处理铝易拉罐生产废乳化液的多功能纳米离子液 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424824A (en) * | 1977-07-27 | 1979-02-24 | Nippon Kayaku Co Ltd | Preparation of aliphatic nitrile |
US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
CN1500729A (zh) * | 2002-11-13 | 2004-06-02 | 中国石油化工股份有限公司 | 钒硅分子筛的制备方法 |
CN102241482A (zh) * | 2011-04-22 | 2011-11-16 | 中国科学院上海硅酸盐研究所 | 智能控温二氧化钒纳米复合多功能薄膜及其制备方法 |
CN103985850A (zh) * | 2014-05-20 | 2014-08-13 | 武汉纺织大学 | 一种五氧化二钒/导电基底复合电极材料的制备方法 |
CN105858725A (zh) * | 2016-04-14 | 2016-08-17 | 上海大学 | 一种醇水溶液法制备二氧化硅包覆二氧化钒纳米粒子方法 |
-
2018
- 2018-05-29 CN CN201810535387.9A patent/CN108394907B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5424824A (en) * | 1977-07-27 | 1979-02-24 | Nippon Kayaku Co Ltd | Preparation of aliphatic nitrile |
US4576814A (en) * | 1979-04-04 | 1986-03-18 | Union Oil Company Of California | Catalyst and process for oxidizing hydrogen sulfide |
CN1500729A (zh) * | 2002-11-13 | 2004-06-02 | 中国石油化工股份有限公司 | 钒硅分子筛的制备方法 |
CN102241482A (zh) * | 2011-04-22 | 2011-11-16 | 中国科学院上海硅酸盐研究所 | 智能控温二氧化钒纳米复合多功能薄膜及其制备方法 |
CN103985850A (zh) * | 2014-05-20 | 2014-08-13 | 武汉纺织大学 | 一种五氧化二钒/导电基底复合电极材料的制备方法 |
CN105858725A (zh) * | 2016-04-14 | 2016-08-17 | 上海大学 | 一种醇水溶液法制备二氧化硅包覆二氧化钒纳米粒子方法 |
Non-Patent Citations (2)
Title |
---|
"Synthesis of hierarchical nanosheet-assembled V2O5 microflowers with high sensing properties towards amines";X. H. Yang et al.;《RSC Advances》;20160916;第6卷;第87650页右栏第1段和87652页图3和左栏第1段 * |
"V2O5/SiO2催化剂上的异丁烷选择氧化反应性能";耿云峰 等;《催化学报》;20011130;第22卷(第6期);第563页第1.1节 * |
Also Published As
Publication number | Publication date |
---|---|
CN108394907A (zh) | 2018-08-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Song et al. | Prussian blue analogs and their derived nanomaterials for electrochemical energy storage and electrocatalysis | |
Feng et al. | Engineering functional mesoporous materials from plant polyphenol based coordination polymers | |
Bibi et al. | Synthesis and applications of metal oxide derivatives of ZIF-67: a mini-review | |
CN107481827B (zh) | 内部限域生长MOFs的空心磁性碳纳米球的制备方法 | |
JP5458171B2 (ja) | リン酸鉄リチウム合成材料の製造方法 | |
CN108840370A (zh) | 一种过渡金属氧化物/氮掺杂有序介孔碳复合材料及其制备方法 | |
CN106684348B (zh) | 一种纳米氟化铁基正极材料及其制备方法 | |
CN101905166B (zh) | 一种可磁分离的氮掺杂TiO2光催化剂及其制备方法 | |
CN104003368A (zh) | 一种多孔磷-氮共掺杂碳材料及其制备方法 | |
CN109301267A (zh) | 一种磷化物纳米催化剂及其制备方法 | |
CN103663562B (zh) | 一种低温制备微纳米钨酸铋的方法 | |
CN107017398B (zh) | 一种焦磷酸钒钠/碳复合正极材料、制备及其应用 | |
CN108394907B (zh) | 一种硅钒复合氧化物及其制备方法 | |
CN105428621B (zh) | 一种锂离子导体包覆纳米LiMnPO4/C正极材料的改性方法 | |
CN103143717A (zh) | 一种铂铜双金属纳米材料及其制备和应用 | |
CN106390986A (zh) | 一种钒酸铋/钛酸锶复合光催化剂的制备方法 | |
CN106012018A (zh) | 一种钒酸铋介孔单晶的制备方法 | |
CN105502421A (zh) | 一种硅酸锌空心微米球的制备方法 | |
CN107093726A (zh) | 一种提高锂离子电池电极材料电化学性能的方法 | |
CN110534754B (zh) | 一种包裹Fe3C纳米晶的碳纳米管及其制备方法和应用 | |
CN102134089B (zh) | 一种具有纺锤状大尺度铈基复合氧化物粉体及其制备方法 | |
US20140309105A1 (en) | Method for manufacturing homogeneous supported catalyst for carbon nanotubes | |
CN103252234A (zh) | 一种核壳结构纳米催化剂及其制备方法和应用 | |
CN102989521A (zh) | 一种用于苯选择加氢的含锆尖晶石系负载蜂窝整体催化剂及其制备方法 | |
CN110947396B (zh) | 球状氧化锰包覆氧化铁核壳结构复合物及制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240521 Address after: 266101 Shandong Province, Qingdao city Laoshan District Songling Road No. 189 Patentee after: QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Country or region after: China Patentee after: Qingdao Green Hydrogen Chain Technology Co.,Ltd. Address before: 266101 Shandong Province, Qingdao city Laoshan District Songling Road No. 189 Patentee before: QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY, CHINESE ACADEMY OF SCIENCES Country or region before: China |