CN108269863A - A kind of high mechanical load crystal silicon battery - Google Patents

A kind of high mechanical load crystal silicon battery Download PDF

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Publication number
CN108269863A
CN108269863A CN201711433307.0A CN201711433307A CN108269863A CN 108269863 A CN108269863 A CN 108269863A CN 201711433307 A CN201711433307 A CN 201711433307A CN 108269863 A CN108269863 A CN 108269863A
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CN
China
Prior art keywords
crystal silicon
backplate
mechanical load
grid line
silicon battery
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Pending
Application number
CN201711433307.0A
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Chinese (zh)
Inventor
刘苗
严金梅
赵江雷
王松
许志卫
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Jingao Solar Co Ltd
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Ja Solar Co Ltd
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Priority to CN201711433307.0A priority Critical patent/CN108269863A/en
Publication of CN108269863A publication Critical patent/CN108269863A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of high mechanical load crystal silicon batteries, the backplate of the crystal silicon battery includes the grid line of the parallel distribution of multiple row, each column grid line includes the six sections or eight sections sub- grid lines separately set, and gap is equipped between the both ends of every a sub- grid line and the back surface field.The crystal silicon battery passes through the structural adjustment to backplate and lbg, so as to which backplate position discontinuity and damage from laser aggravation backplate stress in welding process is avoided battery to be made to be easier there is a situation where brittle fracture, and assembly end fragment rate and lifting assembly resistance to mechanical load-carrying ability are reduced to realize in terms of the two.

Description

A kind of high mechanical load crystal silicon battery
Technical field
The invention belongs to technical field of solar batteries, and in particular to a kind of high mechanical load crystal silicon battery.
Background technology
It with the progress of human lives, increases sharply for the demand of the energy, however occupies gross generation 70% in the world Above thermal power generation, since increasingly in short supply and environment run down of resource has become increasingly noticeable ask Topic.Solar energy is also increasingly valued by people as renewable resource for generating electricity.
In recent years, with the development of crystal silicon solar energy battery technology, silicon wafer thickness is also gradually thinned to reduce photovoltaic hair Electric cost, but what wafer thinning brought therewith is the resistance to mechanical load-carrying ability of the rising of fragment rate and component in itself in establishment of component Decline, the exploitation of particularly PERC (passivation emitter back side battery) technique, the increase of lbg link makes battery in component Fragment rate in making is further up, and the resistance to mechanical load-carrying ability of component in itself also further declines.In this case, respectively The scheme of kind lifting assembly resistance to mechanical load-carrying ability is also gradually emerged in large numbers.Patent CN104935247A, which uses to increase in module frame, to be added For the method for strengthening tendons with lifting assembly resistance to mechanical load-carrying ability, this method effectively reduces the battery fragment rate after component is pressurized And power loss, but this method not only increases additional reinforcing rib in establishment of component, and Material Cost increases, while also needs Increase additional station to realize that reinforcing rib is installed, processing step is cumbersome and increases additional human cost.
Invention content
The purpose of the present invention is to provide a kind of high mechanical load crystal silicon battery, which passes through to backplate And the structural adjustment of lbg, so as to avoid backplate position discontinuity and laser damage in welding process Wound aggravation backplate stress makes battery be easier there is a situation where brittle fracture, and is reduced in terms of the two to realize Assembly end fragment rate and lifting assembly resistance to mechanical load-carrying ability.
The above-mentioned purpose of the present invention is achieved through the following technical solutions:A kind of high mechanical load crystal silicon battery, The backplate of the crystal silicon battery includes the grid line of the parallel distribution of multiple row, and each column grid line is separately set including six sections or eight sections The sub- grid line put is equipped with gap between the both ends of every a sub- grid line and the back surface field.
Backplate is changed to six segmentations or the sub- grid line structure of eight segmentations, back side electricity by traditional three-stage or four-part form The stress distribution generated in backplate sintering process is gone out in the multisection type design of pole, and reducing component should in pressurized process The influence of power, so as to reduce the fragment ratio and power attenuation percentage in mechanical load test process.
Gap is equipped between the both ends of every a sub- grid line and the back surface field, in this way, avoiding to weld in welding process Band overleaf electrode end positions due to caused by the difference in height of backplate, back surface field lap position and backplate welding Position discontinuity is so as to cause hidden the phenomenon that splitting generation.
As a modification of the present invention, crystal silicon battery of the present invention is preferably PERC crystal silicon batteries.
When the crystal silicon battery is preferably PERC crystal silicon batteries, the back side of the PERC crystal silicon batteries is equipped with passivation Film, the passivating film are equipped with lbg line, and the lbg line disconnects at the backplate position.
The design that lbg line is overleaf disconnected at electrode position, since the introducing of PERC crystal silicon cells makes crystalline silicon Battery efficiency is improved, but lbg increases the damage to silicon substrate, particularly overleaf electrode edge position, The damage of laser is even more to exacerbate the nucleation of crackle, and battery is caused to be easier brittle failure;Therefore lbg line must be in back electrode Position disconnects.
Further, the passivating film is preferably aluminium oxide and silicon nitride stack passivating film.
The preparation method of the above-mentioned high mechanical load crystal silicon battery of the present invention, includes the following steps:
(1) crystalline silicon battery plate is chosen, silicon chip surface is cleaned after making herbs into wool;
(2) silicon chip carries out phosphorus diffusion after cleaning;
(3) the P/N knots and phosphorosilicate glass formed after phosphorus diffusion is removed;
(4) passivating film is deposited in front side of silicon wafer;
(5) in silicon chip back side printed back electrode and back surface field;
(6) front electrode is printed in front side of silicon wafer, high mechanical load crystal silicon battery is formed after co-sintering.
Further, when the crystal silicon battery is PERC crystal silicon batteries, above-mentioned high mechanical load crystal silicon battery Preparation method includes the following steps:
(1) crystalline silicon battery plate is chosen, silicon chip surface is cleaned after making herbs into wool;
(2) silicon chip carries out phosphorus diffusion after cleaning;
(3) the P/N knots and phosphorosilicate glass formed after phosphorus diffusion is removed;
(4) passivating film is deposited in front side of silicon wafer, passivating film is deposited in silicon chip back side;
(5) lbg is overleaf carried out on passivating film;
(6) in silicon chip back side printed back electrode and back surface field;
(7) front electrode is printed in front side of silicon wafer, high mechanical load crystal silicon battery is formed after co-sintering.
The principle of the present invention is:
(1) backplate both ends and the design of back of the body electric field junction gap:Avoid in welding process welding overleaf electrode End positions are due to welding position unbalance stress caused by the difference in height of backplate, back surface field lap position and backplate It is even so as to cause hidden the phenomenon that splitting generation.
(2) backplate is changed to the sub- grid line of six segmentations or eight by the traditional sub- grid line of three-stage or the sub- grid line of four-part form The sub- grid line design of segmentation:The multistage formula grid line design of backplate goes out the stress distribution generated in backplate sintering process Go, reduce the influence of component stress in pressurized process, so as to reduce the fragment ratio in mechanical load test process with And power attenuation percentage.
(3) overleaf electrode position disconnects design to lbg line:The introducing of PERC techniques obtains crystal silicon battery efficiency It is promoted, but lbg increases the damage to silicon substrate, particularly overleaf electrode edge position, the damage of laser is more It is the nucleation for exacerbating crackle, battery is caused to be easier brittle failure, therefore lbg line must overleaf electrode position disconnect.
Compared with prior art, the present invention has the following advantages:
(1) the high mechanical load crystal silicon battery in the present invention reduces the hidden generation split during components welding, so as to Reduce assembly end fragment rate;
(2) the high mechanical load crystal silicon battery in the present invention does not need to add any auxiliary spare part, you can realizes PERC Battery component terminal tool load test is qualified;
(3) preparation method of the high mechanical load crystal silicon battery in the present invention is simple for process, with existing producing line compatibility It is good, it does not need to increase special link, commercial viability is strong, and large-scale promotion is suitble to use.
Description of the drawings
Fig. 1 is the back electrode structure schematic diagram of the polysilicon in the embodiment of the present invention 1;
Fig. 2 is the back electrode structure schematic diagram of the polysilicon in the embodiment of the present invention 2;
Fig. 3 is the backplate of the monocrystalline silicon in the embodiment of the present invention 3 and lbg cable architecture schematic diagram;
Fig. 4 is the backplate of the monocrystalline silicon in the embodiment of the present invention 4 and lbg cable architecture schematic diagram.
Specific embodiment
Being exemplified below specific embodiment, the present invention will be described:
Embodiment 1
As shown in Figure 1, high mechanical load crystal silicon battery provided in this embodiment, the backplate of crystal silicon battery is including more The grid line 1 of parallel distribution is arranged, each column grid line includes six sections of sub- grid lines 2 separately set, the both ends of every a sub- grid line and institute It states and gap 3 is equipped between back surface field.
Wherein crystal silicon cell uses p-type piece.
The preparation method of the high mechanical load crystal silicon battery, includes the following steps:
(1) resistivity is chosen in the p-type piece being lightly doped of 0.1~6 Ω cm, and silicon chip matrix is placed in wool-weaving machine Prepared by middle progress damaging layer removal and matte, the chemical solution that making herbs into wool uses is hydrofluoric acid, nitric acid, hydrochloric acid and other conventional addition One or more mixed aqueous solutions of agent.
(2) silicon chip surface is cleaned, is cleaned using chemical solution, chemical solution can be hydrofluoric acid, nitric acid, One or more mixed aqueous solutions of hydrochloric acid and other conventional additives, scavenging period are 0.5~10 minute, and temperature is 20~30 ℃。
(3) silicon chip is placed in 800~1000 DEG C of boiler tube and carries out phosphorus (P) diffusion, n-type diffusion is formed in silicon chip surface Layer, silicon chip square resistance is 60~90 Ω/sq after diffusion.
(4) silicon chip after diffusion is placed in wet etching machine, the P/N that periphery is etched away using chemical solution is tied, simultaneously Phosphorosilicate glass is removed, chemical solution can be the one or more of hydrofluoric acid, nitric acid, hydrochloric acid, sulfuric acid and other conventional additives Mixed aqueous solution, etch period are 0.5~10 minute, and temperature is 5~20 DEG C.
(5) by the one or more of polysilicon chip front plating silica or silicon nitride after wet etching.
(6) back up silver backplate and Al-BSF, backplate six segmentations design (the i.e. back side using the present invention Electrode includes the grid line 1 of the parallel setting of multiple row, and the sub- grid line 2 that each grid line is separately set by six sections forms), backplate With the design of back surface field junction both ends leakage silicon (the i.e. both ends of every sub- grid line 2 of backplate and back surface field connection Equipped with gap 3, the surface of silicon chip can be exposed, cause the disconnection of backplate and back surface field junction).
(7) front electrode grid line, sintering are printed.
As described in Table 1, according to examples detailed above the result shows that polycrystal silicon cell assembly end fragment rate declines more than 0.2%.
The performance comparison of 1 polycrystal silicon cell component manufactured in the present embodiment of table and conventional batteries component
Cell piece component It is broken to open box Machine damages EL is hidden to be split It is total Yield Fragment rate
The present embodiment 0 2 6 8 111 0.12%
Conventional batteries 3 4 11 18 99 0.34%
Embodiment 2
As schemed as different from Example 1, using p-type piece, backplate includes the parallel setting of multiple row Grid line, the sub- grid line that each grid line is separately set by eight sections forms.
As shown in table 2, according to examples detailed above the result shows that polycrystal silicon cell assembly end fragment rate declines more than 0.2%.
The performance comparison of 2 polycrystal silicon cell component manufactured in the present embodiment of table and conventional batteries component
Battery component It is broken to open box Machine damages EL is hidden to be split It is total Yield Fragment rate
The present embodiment 1 2 3 6 130 0.08%
Conventional batteries 1 4 10 15 80 0.31%
Embodiment 3
As shown in figure 3, high mechanical load crystal silicon battery provided in this embodiment, the backplate of crystal silicon battery is including more The grid line 1 of parallel distribution is arranged, each column grid line includes eight sections of sub- grid lines 2 separately set, the both ends of every a sub- grid line and institute It states and gap 3 is equipped between back surface field.
The crystal silicon chip is p-type PERC monocrystalline silicon pieces.
The back side of the PERC crystal silicon batteries is equipped with passivating film, and passivating film is equipped with lbg line 4, and lbg line 4 exists It is disconnected at backplate position.
Passivating film is preferably aluminium oxide and silicon nitride stack passivating film.
The preparation method of the high mechanical load crystal silicon battery, includes the following steps:
(1) resistivity is chosen in the p-type monocrystalline silicon piece being lightly doped of 0.1~6 Ω cm, and silicon chip matrix is placed in texturing slot It is prepared by middle progress damaging layer removal and matte, in the sodium hydroxide deionized water solution for being 0.5~5% in mass percentage, Surface-texturing, which is carried out, under conditions of being 75~90 DEG C in temperature forms suede structure;
(2) silicon chip surface is cleaned, is cleaned using chemical solution, chemical solution can be hydrofluoric acid, nitric acid, One or more mixed aqueous solutions of hydrochloric acid and other conventional additives, scavenging period are 0.5~10 minute, and temperature is 20~30 ℃;
(3) silicon chip is placed in 800~1000 DEG C of boiler tube and carries out phosphorus (P) diffusion, n-type diffusion is formed in silicon chip surface Layer, silicon chip square resistance is 60-90 Ω/sq after diffusion;
(4) silicon chip after diffusion is placed in wet etching machine, the P/N that periphery is etched away using chemical solution is tied, simultaneously Phosphorosilicate glass is removed, chemical solution can be the one or more of hydrofluoric acid, nitric acid, hydrochloric acid, sulfuric acid and other conventional additives Mixed aqueous solution, etch period are 0.5~10 minute, and temperature is 5~20 DEG C;
(5) lbg technique, lbg will be carried out after silicon chip back side plating aluminium oxide and silicon nitride film after wet etching Design is disconnected at graphic designs backplate position using the present invention;
(6) back up silver backplane and Al-BSF, back electrode eight segmentations design using the present invention, the connection of backplane back surface field Locate the design of both ends leakage silicon (due to the back laminate of backside deposition herein passivation film aluminium oxide and silicon nitride, the surface exposed herein It is the palletizing die);
(7) print positive electrode grid line carries out optical attenuation processing after sintering by light decay processing equipment.
As shown in table 3, show according to the test result of above-mentioned design:PERC battery components terminal tool load test PL values by More than 5% originally is reduced to 1% hereinafter, being determined as qualification:
The performance comparison of 3 polycrystal silicon cell component manufactured in the present embodiment of table and conventional batteries component
Embodiment 4
As shown in figure 4, as different from Example 3, each column grid line includes six sections of sub- grid lines separately set.According to upper The test result for stating design shows:PERC battery components terminal tool load test PL values are reduced to 2% left side by original more than 6% The right side is determined as qualification:
The performance comparison of 4 monocrystalline silicon battery component manufactured in the present embodiment of table and conventional batteries component
A part of specific embodiment is enumerated above, and the present invention will be described, it is necessary to it is indicated herein be more than it is specific real It applies example and is served only for that the invention will be further described, do not represent limiting the scope of the invention.Other people are according to the present invention Some the nonessential modifications and adjustment made still fall within protection scope of the present invention.

Claims (4)

1. a kind of high mechanical load crystal silicon battery, it is characterized in that:It is parallel that the backplate of the crystal silicon battery includes multiple row The grid line of distribution, each column grid line include the six sections or eight sections sub- grid lines separately set, both ends and the back of the body of every sub- grid line Gap is equipped between the electric field of face.
2. high mechanical load crystal silicon battery according to claim 1, it is characterized in that:The crystal silicon battery is brilliant for PERC Silion cell.
3. high mechanical load crystal silicon battery according to claim 2, it is characterized in that:The back of the body of the PERC crystal silicon batteries Face is equipped with passivating film, and the passivating film is equipped with lbg line, and the lbg line breaks at the backplate position It opens.
4. high mechanical load crystal silicon battery according to claim 3, it is characterized in that:The passivating film for aluminium oxide and Silicon nitride stack passivating film.
CN201711433307.0A 2017-12-26 2017-12-26 A kind of high mechanical load crystal silicon battery Pending CN108269863A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711433307.0A CN108269863A (en) 2017-12-26 2017-12-26 A kind of high mechanical load crystal silicon battery

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Application Number Priority Date Filing Date Title
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201853712U (en) * 2010-07-30 2011-06-01 新日光能源科技股份有限公司 Pattern backside alumina gel electrode structure of solar battery and solar battery
CN202934909U (en) * 2012-12-05 2013-05-15 江苏中宇光伏科技有限公司 Sectional type back-electrode screen printing plate
CN103489934A (en) * 2013-09-25 2014-01-01 晶澳(扬州)太阳能科技有限公司 Local aluminum back surface field solar battery with two diaphanous faces and preparation method thereof
WO2014090010A1 (en) * 2012-12-10 2014-06-19 常州天合光能有限公司 Up-and-down type electrode structure of solar cell plate
CN204375763U (en) * 2015-02-04 2015-06-03 苏州阿特斯阳光电力科技有限公司 The back electrode structure of solar cell
CN206076243U (en) * 2016-07-07 2017-04-05 太极能源科技(昆山)有限公司 A kind of solar battery sheet
CN107039544A (en) * 2017-03-03 2017-08-11 广东爱康太阳能科技有限公司 P-type PERC double-sided solar batteries and preparation method thereof, component and system
CN107393995A (en) * 2017-08-31 2017-11-24 常州天合光能有限公司 A kind of photovoltaic interconnecting strip and photovoltaic cell component

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201853712U (en) * 2010-07-30 2011-06-01 新日光能源科技股份有限公司 Pattern backside alumina gel electrode structure of solar battery and solar battery
CN202934909U (en) * 2012-12-05 2013-05-15 江苏中宇光伏科技有限公司 Sectional type back-electrode screen printing plate
WO2014090010A1 (en) * 2012-12-10 2014-06-19 常州天合光能有限公司 Up-and-down type electrode structure of solar cell plate
CN103489934A (en) * 2013-09-25 2014-01-01 晶澳(扬州)太阳能科技有限公司 Local aluminum back surface field solar battery with two diaphanous faces and preparation method thereof
CN204375763U (en) * 2015-02-04 2015-06-03 苏州阿特斯阳光电力科技有限公司 The back electrode structure of solar cell
CN206076243U (en) * 2016-07-07 2017-04-05 太极能源科技(昆山)有限公司 A kind of solar battery sheet
CN107039544A (en) * 2017-03-03 2017-08-11 广东爱康太阳能科技有限公司 P-type PERC double-sided solar batteries and preparation method thereof, component and system
CN107393995A (en) * 2017-08-31 2017-11-24 常州天合光能有限公司 A kind of photovoltaic interconnecting strip and photovoltaic cell component

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