CN108258286A - A kind of water hydrogen power generation base station with remote monitoring function - Google Patents
A kind of water hydrogen power generation base station with remote monitoring function Download PDFInfo
- Publication number
- CN108258286A CN108258286A CN201611263828.1A CN201611263828A CN108258286A CN 108258286 A CN108258286 A CN 108258286A CN 201611263828 A CN201611263828 A CN 201611263828A CN 108258286 A CN108258286 A CN 108258286A
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- water
- user
- base station
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 270
- 239000001257 hydrogen Substances 0.000 title claims abstract description 249
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 249
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910001868 water Inorganic materials 0.000 title claims abstract description 69
- 238000012544 monitoring process Methods 0.000 title claims abstract description 58
- 238000010248 power generation Methods 0.000 title claims abstract description 21
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims abstract description 108
- 238000004519 manufacturing process Methods 0.000 claims abstract description 59
- 238000004891 communication Methods 0.000 claims abstract description 22
- 230000005611 electricity Effects 0.000 claims description 93
- 238000003860 storage Methods 0.000 claims description 58
- 239000002994 raw material Substances 0.000 claims description 48
- 239000000446 fuel Substances 0.000 claims description 32
- 230000003139 buffering effect Effects 0.000 claims description 24
- 239000012528 membrane Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 230000007246 mechanism Effects 0.000 claims description 9
- 150000002431 hydrogen Chemical class 0.000 claims description 8
- 230000003183 myoelectrical effect Effects 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000009434 installation Methods 0.000 claims description 3
- 238000006479 redox reaction Methods 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 2
- 230000003111 delayed effect Effects 0.000 claims 1
- 238000004080 punching Methods 0.000 claims 1
- 230000007306 turnover Effects 0.000 abstract description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 117
- 238000010438 heat treatment Methods 0.000 description 34
- 238000000926 separation method Methods 0.000 description 29
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- 238000002309 gasification Methods 0.000 description 16
- 239000003054 catalyst Substances 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 13
- 229960004424 carbon dioxide Drugs 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 8
- 239000001569 carbon dioxide Substances 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000007858 starting material Substances 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000010949 copper Substances 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000004134 energy conservation Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- OQKKZVLQGHUHKD-UHFFFAOYSA-N methanol dihydrate Chemical compound O.O.OC.OC OQKKZVLQGHUHKD-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- 239000006200 vaporizer Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
- H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
- H01M8/04022—Heating by combustion
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04L—TRANSMISSION OF DIGITAL INFORMATION, e.g. TELEGRAPHIC COMMUNICATION
- H04L67/00—Network arrangements or protocols for supporting network services or applications
- H04L67/01—Protocols
- H04L67/02—Protocols based on web technology, e.g. hypertext transfer protocol [HTTP]
- H04L67/025—Protocols based on web technology, e.g. hypertext transfer protocol [HTTP] for remote control or remote monitoring of applications
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04W—WIRELESS COMMUNICATION NETWORKS
- H04W88/00—Devices specially adapted for wireless communication networks, e.g. terminals, base stations or access point devices
- H04W88/08—Access point devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02D—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN INFORMATION AND COMMUNICATION TECHNOLOGIES [ICT], I.E. INFORMATION AND COMMUNICATION TECHNOLOGIES AIMING AT THE REDUCTION OF THEIR OWN ENERGY USE
- Y02D30/00—Reducing energy consumption in communication networks
- Y02D30/70—Reducing energy consumption in communication networks in wireless communication networks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Signal Processing (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Computer Networks & Wireless Communication (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Fuel Cell (AREA)
Abstract
Present invention is disclosed a kind of water hydrogen power generation base stations with remote monitoring function, including water hydrogen generator, base station ontology, monitoring and controlling terminal, monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, monitoring and controlling terminal is communicated with water hydrogen generator, base station ontology, and water hydrogen generator, base station ontology remotely monitor or/and control；Base station ontology includes base station towers, antenna for base station, base transceiver station, base station controller, reserve battery；Water hydrogen generator includes methanol-water reformation hydrogen production equipment, hydrogen gas generation equipment.Water hydrogen power generation base station proposed by the present invention with remote monitoring function, works using the electric energy that methanol-water reformation hydrogen production is sent out, can power in the place of no power grid for communication base station, improve the convenience of arrangement of base stations, reduce the pollution to environment；It can ensure the steady operation of each base station in the work of long-range monitoring base station, save labour turnover simultaneously simultaneously.
Description
Technical field
The invention belongs to technical field of generators, are related to a kind of generator more particularly to a kind of with remote monitoring function
Water hydrogen power generation base station.
Background technology
The power supply incorporation way of existing base station is mostly introduced using three-phase or single phase ac mains-supplied.However some regions
(such as many remote sections), because high voltage supply covers difficulty, nothing draws electric resources, and honourable resource is also extremely limited, leads to base station
Drawing electric problem cannot solve always, which directly affects base station construction delivery rate, seriously affect customer service index.Because drawing
Electric problem leads to problems such as to shelve.
In addition, existing water hydrogen generator (such as reformation of Chinese patent CN201410311217.4, methanol-water hydrogen producer
Device and its manufacturing process；Chinese patent CN201410622203.4, a kind of generator and its hair based on Methanol water hydrogen production system
Method for electrically) there are the following problems, and reformer chamber is equipped with heating and gasifying pipeline, for heating and gasifying methanol-water raw material, heating and gasifying pipe
Road is generally arranged at outside reformer chamber, and heating and gasifying pipeline is susceptible to the situation of peeling disengaging, influences the service life of pipeline.
In view of this, nowadays there is an urgent need to design a kind of new base station power supply mode, to overcome existing base station supplier of electricity
The drawbacks described above of formula.
Invention content
The technical problems to be solved by the invention are：A kind of water hydrogen power generation base station with remote monitoring function is provided, it can
It is worked using the electric energy that methanol-water reformation hydrogen production is sent out, can power in the place of no power grid for communication base station, improve base station
The convenience of arrangement reduces the pollution to environment.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：
A kind of water hydrogen power generation base station with remote monitoring function, it is whole including water hydrogen generator, base station ontology, monitoring and controlling
End；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, terminal control unit point
Not Lian Jie wireless communication module, input/output module, monitoring and controlling terminal passes through wireless communication mode and water hydrogen generator, base station
Ontology communicates, and water hydrogen generator, base station ontology remotely monitor or/and control；
The base station ontology includes base station towers, antenna for base station, base transceiver station, base station controller；Base is set on base station towers
Station antenna, base transceiver station connect antenna for base station, base station controller respectively；The water hydrogen generator distinguishes linker by cable
It stands sending and receiving stations, base station controller, antenna for base station.
Preferably, the water hydrogen generator includes methanol-water device for producing hydrogen, hydrogen fuel cell, air pump, control circuit board；
Methanol-water device for producing hydrogen includes delivery pump, heat exchanger, reformer, membrane separator；
The methanol-water storage container is equipped with the first temperature sensor, liquid level sensor, and second temperature is equipped in heat exchanger
Sensor, first flow sensor, reformer is interior to be equipped with third temperature sensor, and air flow inlet, the air-flow of hydrogen fuel cell go out
Mouth sets pressure sensor and solenoid valve respectively；
The control circuit board connects delivery pump respectively, second temperature sensor, first flow sensor in heat exchanger,
Third temperature sensor in reformer, the pressure sensor and solenoid valve of hydrogen fuel cell, and control the work of all parts；
The methanol-water raw material of liquid is stored in the methanol-water storage container；The delivery pump is used to store methanol-water
Methanol-water raw material in container is pumped to the reformer chamber of reformer by conveyance conduit；The heat exchanger is installed on methanol-water raw material
Conveyance conduit on, methanol-water raw material in heat exchanger, with reformer output high-temperature hydrogen exchange heat, methanol-water raw material temperature
Degree raising, hydrogen temperature reduce；Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through film point
Hydrogen is obtained from device；Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell；Hydrogen leads to the oxygen in air
Hydrogen fuel cell generation redox reaction is crossed to produce electricl energy.
The beneficial effects of the present invention are：Water hydrogen power generation base station proposed by the present invention with remote monitoring function, can profit
It is worked with the electric energy that methanol-water reformation hydrogen production is sent out, can power in the place of no power grid for communication base station, improve base station cloth
The convenience put reduces the pollution to environment.The stabilization work of each base station in the work of long-range monitoring base station, can be ensured simultaneously
Make, save labour turnover simultaneously.The present invention can also effectively utilize generating electricity by natural energy, and can be by extra electric energy with methanol
Mode stores, and can be generated electricity on power supply peak by methanol.The present invention is more advantageous to fully utilizing the energy, energy conservation and environmental protection.
Description of the drawings
Fig. 1 is the composition schematic diagram of the base station of water hydrogen generator powered of the present invention.
Fig. 2 is the composition schematic diagram of water hydrogen generator of the present invention.
Fig. 3 is the structure diagram of methanol-water reformation hydrogen production equipment.
Fig. 4 is the appearance diagram of methanol-water reformation hydrogen production equipment.
Fig. 5 is the composition schematic diagram of methanol-water reformation hydrogen production equipment.
Specific embodiment
The preferred embodiment that the invention will now be described in detail with reference to the accompanying drawings.
Embodiment one
It please refers to Fig.1, Fig. 2, present invention is disclosed a kind of water hydrogen power generation base station with remote monitoring function, including water hydrogen
Generator, base station ontology, monitoring and controlling terminal 10.The monitoring and controlling terminal includes terminal control unit, wireless communication module, defeated
Enter output module, terminal control unit 10 connects wireless communication module, input/output module respectively, and monitoring and controlling terminal passes through wireless
Communication modes are communicated with water hydrogen generator, base station ontology, and water hydrogen generator, base station ontology remotely monitor or/and control.
The base station ontology includes second shell 306, third housing 307, base station towers 301, antenna for base station 302, base station receipts
Send out platform 303, base station controller 304, reserve battery 305；Antenna for base station 302 is set on base station towers 301, and base transceiver station 303 divides
It Lian Jie not antenna for base station 302, base station controller 304.
The water hydrogen generator connects base transceiver station 303, base station controller 304, antenna for base station by cable respectively
302nd, reserve battery 305；Reserve battery 305 connects base transceiver station 303, base station controller 304 respectively；The base transceiver station
303rd, base station controller 304 is set in second shell 306, and reserve battery 305 is set in third housing 307.
The basic composition of water hydrogen generator is that those skilled in the art can be basic according to the related patents of the applicant
(the patent of invention of such as three mandates realized：Chinese patent CN201210339912.2, it is a kind of to prepare hydrogen using methanol-water
System and method；Chinese patent CN201310578035.9, instant preparing hydrogen, generating power system and method；Chinese patent CN
A kind of 201310520538.0, instant preparing hydrogen, generating power system and method), but here in order to embody the present invention disclose it is abundant, this
In also slightly introduce, and it is partly improved simultaneously.
The water hydrogen generator includes：Methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3, wind
It can generating equipment 4, steam-electric power plant 5, charge storage unit 6, charging control unit 7, water-electrolytic hydrogen making equipment 8, main control unit
9th, monitoring and controlling terminal 10 (other generator units, such as marsh gas power generation unit can also be included).
The main control unit 9 connect respectively methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3,
Wind energy generating plant 4, steam-electric power plant 5, charge storage unit 6, charging control unit 7, water-electrolytic hydrogen making equipment 8, monitoring control
Terminal 10 processed, control methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3, wind energy generating plant 4, too
It is positive can generating equipment 5, charging control unit 7, water-electrolytic hydrogen making equipment 8 work, and to 10 sending device of monitoring and controlling terminal
Relevant information.
The methanol-water reformation hydrogen production equipment 1 is connect with hydrogen gas generation equipment 2, methanol Preparation equipment 3, hydrogen gas generation equipment
2 connect with methanol Preparation equipment 3；Methanol Preparation equipment 3 is worked by the electric energy that hydrogen gas generation equipment 2 is sent out.
The wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2 connect electrical equipment 11, energy respectively
Directly power for electrical equipment 11；Electrical equipment 11 include methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2 and this be
Electricity requiring equipment except system.
The wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2 connect charging control unit 7 respectively,
It is charged by charging control unit for charge storage unit 6.
The main control unit 9 is also to obtain the use electricity condition of electrical equipment 11, so as to obtain real-time power demand data；
Meanwhile the real-time generated energy number of the acquisition of main control unit 9 wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2
According to.
The main control unit 9 does corresponding control according to real-time power demand data, real-time generated energy data；When generated energy number
During according to more than power demand data, control charging control unit charges extra electric energy for charge storage unit；When generated energy data are small
When power demand data, by starting charge storage unit as power supply for electrical equipment.
In the present embodiment, the main control unit includes power supply dispatching subelement, to monitor the electricity consumption of the electrical equipment
Power when the rated output power of hydrogen gas generation equipment is more than the electric power of electrical equipment, controls hydrogen gas generation tables of equipment
It is solely power supply for electrical equipment；When monitoring that electric power increases and change rate is more than given threshold, hydrogen gas generation equipment is controlled
And charge storage unit is power supply for electrical equipment jointly；When hydrogen gas generation equipment breaks down, control charge storage unit is electrical equipment
Power supply；The power supply dispatching subelement also to the rated output power for judging hydrogen gas generation equipment be more than the electrical equipment
Electric power when, judge the charge storage unit whether power shortage, such as power shortage, then the electric energy additionally exported using hydrogen gas generation equipment
It charges for charge storage unit.
The water-electrolytic hydrogen making equipment 8 is to surplus made from the utilization wind energy generating plant 4, steam-electric power plant 5
Hydrogen, oxygen is made by electrolysis water in remaining electric energy；Hydrogen obtained is delivered to methanol Preparation equipment 3, in case preparing methanol；System
The oxygen obtained stores, and when fuel cell system (part for hydrogen gas generation equipment 2) needs, is delivered to fuel cell system
System.
Referring to Fig. 5, the methanol-water reformation hydrogen production equipment 1 includes storage container 130, raw material conveying device 101, methanol
It is water transfer pipeline 102, reformer 103, separator 104, hydrogen delivery tube road 105, carbon dioxide collection pipeline 106, remaining
Gas discharge pipe 107, starter 108, control circuit board 109.
The control circuit board 109 connects raw material conveying device 101, reformer 103, separator 104 respectively, control
Each device work.
The raw material conveying device 101 connects storage container 130 and reformer respectively by methanol-water transfer pipeline 102
103, the raw material conveying device 101 is by the methanol-water feedstock transportation in storage container 130 to reformer 103.
The reformer 103 connects separator 104, and separator 104 connects hydrogen delivery tube road 105, two respectively
Carbonoxide collecting 106, residual air discharge pipe 107；The separator includes membrane separation device.
The reformer includes heat exchanger, vaporizer, reformer chamber, separation chamber, and the membrane separation device is set to separation
Interior, separation chamber are set to the top of reformer chamber.Methanol-water raw material enters vaporizer after exchanging heat in heat exchanger and vaporizes；Vaporization
Methanol steam and water vapour afterwards enters reformer chamber, and reformer chamber is equipped with catalyst, and reformer chamber lower part and middle portion temperature are 300 DEG C
~420 DEG C, the temperature on the reformer chamber top is 400 DEG C~570 DEG C；Reformer chamber is connect with separation chamber by connecting line, even
The all or part for taking over road is set to the top of reformer chamber, and it is defeated from reformer chamber to continue heating by the high temperature on reformer chamber top
The gas gone out；The connecting line is as the buffering between reformer chamber and separation chamber so that the temperature of the gas exported from reformer chamber
Degree is identical or close with the temperature of separation chamber；The indoor temperature of separation is set as 350 DEG C~570 DEG C, indoor from detaching
The aerogenesis end of membrane separation device obtains hydrogen.By above-mentioned improvement, it can ensure the low temperature requirements of reformer chamber catalyst respectively,
And the high temperature requirement of separation chamber, and then improve hydrogen preparation efficiency；Meanwhile preheating method of the invention (is set separation chamber
In the top of reformer chamber) it is very convenient.Pressurization cooling processing is carried out to residual air simultaneously so that carbon dioxide becomes liquid dioxy
Change carbon or dry ice, collect carbon dioxide in the residual air generated from membrane separation device, pass through carbon dioxide collection Pipeline transport；It is described
Hydrogen partial made from reformer or/and residual air maintain reformer to run by burning.
The raw material conveying device provides power, by the feedstock transportation in storage container to device for producing hydrogen；The raw material is defeated
Device is sent to provide the pressure of 0.15~5MPa to raw material so that hydrogen made from device for producing hydrogen has enough pressure.The system
Hydrogen is delivered to membrane separation device and is detached made from hydrogen production device, for detach the inside and outside pressure of the membrane separation device of hydrogen it
Difference is more than or equal to 0.7M Pa.Pass through the improvement so that hydrogen made from device for producing hydrogen has enough pressure, can improve hydrogen manufacturing
The purity of efficiency and obtained hydrogen.
Hydrogen made from the methanol-water reformation hydrogen production equipment is delivered to membrane separation device and is detached, for detaching hydrogen
Membrane separation device inside and outside pressure difference be more than or equal to 0.7M Pa；The membrane separation device is in porous ceramic surface vacuum
The membrane separation device of palladium-silver is plated, film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%~78%, silver
Account for 22%~25%.
The catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, Zn oxide,
Rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%~1.8% of catalyst gross mass,
Pd contents account for 1.1%~4%, Cu of catalyst gross mass oxide account for catalyst gross mass 6%~12%, Fe oxidation
The oxide that object accounts for 3%~8%, Zn of catalyst gross mass accounts for the 8%~20% of catalyst gross mass, rare-earth oxide
The 6%~40% of catalyst gross mass is accounted for, remaining is transition metal oxide.Alternatively, the catalyst is copper-based catalysts, packet
It includes substance and its mass fraction is：3-17 parts of CuO, 3-18 parts of ZnO, 0.5-3 parts of ZrO, 55-80 parts of Al2O3, 1-3 parts
CeO2, 1-3 parts of La2O3。
In the present embodiment, the storage container 130 can be equipped with the first temperature sensor, liquid level sensor, in heat exchanger
Equipped with second temperature sensor, first flow sensor, reformer chamber is equipped with third temperature sensor, the air-flow of hydrogen fuel cell
Entrance, air stream outlet set pressure sensor and solenoid valve respectively.The control circuit board connects delivery pump (feedstock transportation respectively
Device 101), second temperature sensor, first flow sensor in heat exchanger, the third temperature sensor in reformer, hydrogen
The pressure sensor and solenoid valve of fuel cell, and control the work of all parts.
The methanol-water raw material of liquid is stored in the methanol-water storage container；The delivery pump is used to store methanol-water
Methanol-water raw material in container is pumped to the reformer chamber of reformer by conveyance conduit；The heat exchanger is installed on methanol-water raw material
Conveyance conduit on, methanol-water raw material in heat exchanger, with reformer output high-temperature hydrogen exchange heat, methanol-water raw material temperature
Degree raising, hydrogen temperature reduce；Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through film point
Hydrogen is obtained from device；Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell；Hydrogen leads to the oxygen in air
Hydrogen fuel cell generation redox reaction is crossed to produce electricl energy.
Fig. 3, Fig. 4 are please referred to, the reformer 103 includes heat exchanger, heating and gasifying pipeline 1038, reformer chamber 1037,
The membrane separation device is set to the top in reformer chamber 1037.The heat exchanger includes methanol-water and preheats pipeline, the heat exchange
Device is installed on the conveyance conduit (this section of conveyance conduit can be used as methanol-water to preheat pipeline) of methanol-water raw material, methanol-water raw material
High-temperature hydrogen with reformer output in heat exchanger exchanges heat, and methanol-water material temperature raising, hydrogen temperature reduces.Methanol
Water raw material gasifies after exchanging heat in heat exchanger into heating and gasifying pipeline 1038；Methanol steam and water vapour after gasification enter weight
Whole room, reformer chamber are equipped with catalyst.
The entirety of a reformer 103 substantially hollow cylinder 1031, the top of hollow cylinder 1031 are equipped with gas vent
1032.Described 103 one end of reformer is equipped with starter 108, which includes cup holder 1033, cup holder 1033
On methanol-water preheating pipeline, heating and gasifying pipeline, igniter and temperature detection device are installed；The raw material input channel is defeated
Enter first alcohol and water raw material, raw material input channel is connected with heating and gasifying pipeline, first alcohol and water raw material through raw material input channel into
After entering heating and gasifying pipeline, exported from the end of heating and gasifying pipeline；The position of the igniter and heating and gasifying pipeline
End is corresponding, and for lighting a fire to the first alcohol and water raw material exported in heating and gasifying pipeline, first alcohol and water raw material is through igniting
Device ignition, combustion heats heating and gasifying pipeline, makes first alcohol and water material gasification in heating and gasifying pipeline and fast
Speed increases combustion intensity, and then is heated for reformer；The temperature detection device is used to detect the temperature by heating and gasifying pipeline
Degree；After the reformer starts hydrogen manufacturing, hydrogen partial made from reformer or/and residual air maintain reformer by burning
Operation.
The bottom side of the cup holder 1033 is equipped with air inlet cover board, which is equipped with air duct, and outside air can be through the wind
Road is entered in reformer；The raw material input channel is equipped with solenoid valve, so that raw material input channel is controlled to play on or off
It closes, while controls the flow of raw material input channel.After the hydrogen producer starts, hydrogen producer passes through hydrogen made from device for producing hydrogen
The energy of the air lift needed for for operation；At this point it is possible to close starter.Due to hydrogen partial made from device for producing hydrogen or/and remaining
Gas maintains hydrogen producer to run by burning, and so as to reduce the dependence to extra power, adaptive ability is strong.
As shown in figure 3, the reformer chamber 1037 includes hollow circuit cylinder housing, catalyst is equipped in hollow circuit cylinder housing
1039；Partly or entirely being set in hollow circuit cylinder housing, being wrapped up by catalyst 1039 for heating and gasifying pipeline 1038, is effectively protected
Protect heating and gasifying pipeline.By the improvement, the present invention can preferably preheat, and avoid heating and gasifying pipeline for methanol water liquid
There is the situation that peeling is detached from, effectively extend the service life of pipeline.
In addition, in order to efficiently use the heat of residual air, methanol-water pre-add pipe line can exchange heat with residual air discharge pipe.Institute
The part for stating methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water raw material in shape of threads pipeline；Shape of threads
Pipeline wraps the residual air discharge pipe of reformer；Residual air discharge pipe temperature after shape of threads pipeline reduces, shape of threads
Pipeline temperature after residual air discharge pipe increases；One end of shape of threads pipeline is equipped with input port, and the other end is set there are two defeated
Exit port, each output port are equipped with valve；The other parts of one output port connection methanol-water transfer pipeline, another is defeated
Exit port is connected to input port by circulation line；The set temperature sensor at the output port close to shape of threads pipeline,
Temperature sensor connects pre-add heat controller；Pre-add heat controller is according to the temperature data of temperature sensor and the original of reformer apparatus
The switch of material demand two valves of adjusting and the aperture of valve.
The hydrogen gas generation equipment includes fuel cell system 208, buffered sources 206, and the connection of fuel cell system 208 is slow
Rush power supply 206；The buffered sources 206 are lithium battery or super capacitor.
【Generated energy electricity consumption monitors】
The hydrogen gas generation equipment further include hydrogen conveying monitoring module, generated energy monitoring modular, electricity demand monitoring modular,
Electricity judgment module, power supply handover module, charge control module, extra electricity conveyor module.
The hydrogen conveying monitoring module is monitoring the amounts of hydrogen of methanol-water reformation hydrogen production equipment conveying.The hair
Electric quantity monitoring module is real-time using the hydrogen of methanol-water reformation hydrogen production equipment conveying to monitor the fuel cell system
Electricity obtained.The electricity demand monitoring modular is monitoring real-time power demand.The electricity judgment module is to by described in
Generated energy monitoring modular is compared with the data that electricity demand monitoring modular obtains, and judges electricity obtained in real time and real-time electricity consumption
The relationship of demand, and comparison result is fed back into power supply handover module, extra electricity conveyor module.The power supply handover module is used
With when electricity judgment module obtains real-time electricity obtained less than real-time power demand, control buffered sources is have power demand
Power supply for electrical equipment.The extra electricity conveyor module is more than in fact to obtain electricity obtained in real time in electricity judgment module
When power demand when, by extra electric energy buffered sources charging or/and part electricity to be delivered to the methanol-water weight
Whole hydrogen producer needs electric installation to provide electric energy for the methanol-water reformation hydrogen production equipment；The methanol-water reformation hydrogen production equipment
Need electric installation include for reformer chamber heating electric heater and control circuit board, each sensor.
The fuel cell system connects low-temperature cogeneration unit, and low-temperature cogeneration unit utilizes fuel cell system
Thermal energy, the residual air temperature of the methanol-water reformation hydrogen production equipment and residual air combustion power generation.
The low-temperature cogeneration unit connects generating set switch control unit, the connection of generating set switch control unit
If dry temperature sensor, when the data of each temperature sensor senses meet sets requirement, low-temperature cogeneration unit is controlled
It opens；When the data of each temperature sensor senses meet sets requirement, control low-temperature cogeneration unit is closed.
The hydrogen gas generation equipment further includes control parameter logging modle, historical data base, historical data acquisition module, reality
When control parameter acquisition module, data comparing module, adaptation module.
For the control parameter logging modle recording control parameter into historical data base, control parameter includes work
In mean power within the setting period of electrical equipment mark, the electrical equipment in each work, ambient parameter data, generated energy
Data, hydrogen supply, methanol-water feedstock transportation amount.The historical data base to storing control parameter historical data.Institute
Historical data acquisition module is stated to obtain history control parameter from historical data base.The real-time control parameter acquisition module
To obtain real-time control parameter.The data comparing module is to the real-time control that obtains real-time control parameter acquisition module
Parameter processed is compared with the history control parameter that historical data acquisition module obtains, emphatically the electrical equipment mark in comparison work
Know, the electrical equipment in each work is setting the mean power in the period, ambient parameter data；It obtains and real-time control parameter phase
Like the highest history control parameter of degree.The adaptation module is to the similarity highest that is obtained according to the data comparing module
History control parameter deposit methanol-water raw material, and in this, as the reference for being initially powered up hydrogen manufacturing amount under state.
The hydrogen gas generation equipment further includes Collection utilization device；The Collection utilization device connection hydrogen gas generating system
Vent passageway collects hydrogen, oxygen gas and water respectively from the gas of discharge, sub for hydrogen manufacturing using the hydrogen, oxygen that are collected into
System or/and hydrogen gas generating system use, raw material of the water being collected into as hydrogen manufacturing subsystem, so as to recycle.
The Collection utilization device includes hydrogen/oxygen separator, hydrogen separator, hydrogen check-valves, oxygen separator, oxygen
Hydrogen by hydrogen and oxygen separation, is then separated from water, oxygen is separated from water by check-valves respectively.
【Methanol-water Collection utilization】
The methanol-water reformation hydrogen production equipment further includes：Methanol water collecting device, methanol concentration sensor, concentration allotment dress
It puts, high concentration methanol water container.
The fuel cell system includes water collecting device, the first heat-exchanger rig, air compression plant.It is prepared by the methanol
Equipment includes carbon dioxide interfacing conveyor, hydrogen interfacing conveyor, and carbon dioxide interfacing conveyor connects the methanol-water reformation hydrogen production
The carbon dioxide collection pipeline of equipment, hydrogen interfacing conveyor connect the hydrogen delivery tube road of the methanol-water reformation hydrogen production equipment.
The methanol-water reformation hydrogen production equipment will partly be delivered to fuel cell system in hydrogen obtained, partly maintain first by burning
The operation of alcohol water reformation hydrogen production equipment；The carbon dioxide of collection is delivered to methanol Preparation equipment, the residual air of discharge passes through burning
For maintaining the operation of methanol-water reformation hydrogen production equipment.The fuel cell system is by the electrical energy transportation of part generation to methanol-water
Reformation hydrogen production equipment, methanol Preparation equipment, the water that fuel cell system is collected are delivered to methanol-water reformation hydrogen production equipment；Fuel electricity
The heat of cell system discharge is the methanol-water raw material preheating of methanol-water reformation hydrogen production equipment by the first heat-exchanger rig.
Methanol aqueous solution is made in the methanol Preparation equipment, is delivered to methanol-water reformation hydrogen production equipment.The methanol-water is received
Acquisition means connect methanol Preparation equipment, to collect methanol aqueous solution made from methanol Preparation equipment.The methanol concentration sensing
Device is set in methanol water collecting device, to sense the methanol concentration in methanol aqueous solution.The concentration deployment device includes
Allocates container, the first allotment valve body, the second allotment valve body, third allotment valve body, rabbling mechanism, allotment control unit, first adjusts
Valve body control mechanism is respectively equipped with valve body, the second allotment valve body.The methanol water collecting device, water collecting device, high concentration
Methanol water container connects allocates container by respective pipeline and delivery pump respectively, and rabbling mechanism is set in allocates container.
The first allotment of methanol water collecting device setting valve body, water collecting device setting the second allotment valve body, high concentration
Methanol water container setting third allocates valve body；Allotment control unit calculates methanol-water according to the data that methanol concentration sensor senses
The proportioning of solution or/and water or/and high concentration methanol aqueous solution, control methanol water collecting device, water collecting device, high concentration first
Alcohol water container corresponds to the switch of allotment valve body so that in the methanol aqueous solution allocated in allocates container, methanol concentration, which reaches, to be set
Definite value.
The base station further includes main storage container, and main storage container includes the first liquid level recognition unit, valve, delivery pump
Body, connecting line；For first liquid level recognition unit to identify the liquid level of main storage container, connecting line is equipped with valve and delivery pump
Body；
The storage container is equipped with the second liquid level identification mechanism, to identify the liquid level of storage container；In storage container
Liquid level be less than setting value when, conveying the pump housing methanol-water raw material is conveyed from main storage container to storage container.
【Speech recognition controlled】
The water hydrogen generator further includes speech database, sound identification module, voice command execution module, voice and learns by oneself
Practise module, speech database update module.
The speech database is to voice data and each voice data is corresponding performs order；The voice
Identification module is the voice data of acquisition to be compared with the voice data in the speech database, if speech database
It is middle to there is the voice data met, comparison result is fed back into voice command execution module；Institute's speech commands execution module is used
To perform corresponding order according to the recognition result of sound identification module；The voice self-learning module is to the language according to user
Sound sounding custom sets specific voice comparison data for it；Voice comparison data is by voice self-learning module according to user's
Pronunciation custom self study obtains；The speech database update module to by the voice self-learning module for setting user set
Fixed special sound comparison data is updated in speech database so that user is set in speech database has specific voice
Comparison data library.
Specifically, the voice self-learning module judges the first voice number to obtain the first voice data of user
According to whether having record, if no record, its voice value sequence is initialized；If there is record, the voice of first voice data is obtained
Value sequence；At least one data are recorded in voice value sequence, which represents the voice of certain voice data and another voice data
Value, when which reaches given threshold, represents that certain voice data is close with another voice data, it is believed that the two corresponds to same
Voice command；
If sound identification module fails to find corresponding voice data in speech database or by user feedback voice
Identification module identifies mistake；If user sent out in setting time second speech data by sound identification module identify successfully or
Person user sends control command by other approach, the corresponding voice data of the control command is second speech data；Then by
The speech value that one voice data corresponds to second speech data increases setting value, then, judges whether the speech value reaches setting threshold
Value；If reaching given threshold, in the corresponding voice comparison data library of the user, the first voice data is increased into the second voice
Voice data corresponding to the corresponding control command of data, and the comparison priority of the first voice data is more than the second voice number
According to preferentially being compared in follow-up comparison process.
【Gesture identification controls】
The water hydrogen generator further includes gesture database, gesture recognition module, gesture command execution module, gesture and learns by oneself
Practise module, gesture database update module.The gesture database is corresponding to store gesture data and each gesture data
Perform order.The gesture recognition module is the gesture data in the gesture data obtained and the gesture database to be carried out
It compares, if there is the gesture data met in gesture database, comparison result is fed back into gesture command execution module.The hand
Gesture command execution module is to according to the corresponding order of the recognition result of gesture recognition module execution.The gesture self-learning module
To set specific gesture comparison data for it according to the gesture of user custom；Gesture comparison data passes through gesture self study mould
Root tuber is obtained according to the gesture custom self study of user.The gesture database update module is to by the gesture self-learning module
It is updated in gesture database to set certain gestures comparison data set by user so that user's tool is set in gesture database
There is specific gesture comparison data library.
Specifically, the gesture self-learning module judges the first gesture number to obtain the first gesture data of user
According to whether having record, if no record, its gesture value sequence is initialized；If there is record, the gesture of the first gesture data is obtained
Value sequence；At least one data are recorded in gesture value sequence, which represents the gesture of certain gesture data and another another data
Value, when which reaches given threshold, represents that certain gesture data is close with another another data, it is believed that the two corresponds to same
Gesture command.If gesture recognition module fails to find corresponding gesture data in gesture database or by user feedback hand
Gesture identification module identifies mistake；If user sends out second gesture data in setting time and is identified successfully by gesture recognition module,
Or user sends control command by other approach, the corresponding gesture data of the control command is second gesture data；Then will
The gesture value that first gesture data correspond to second gesture data increases setting value, then, judges whether the gesture value reaches setting
Threshold value；If reaching given threshold, in the corresponding gesture comparison data library of the user, first gesture data are increased into second-hand
Gesture data corresponding to the corresponding control command of gesture data, and the comparison priority of first gesture data is more than second gesture number
According to preferentially being compared in follow-up comparison process.
【Power consumption prediction】
The water hydrogen generator further includes electricity demand forecasting module, hydrogen buffering storage container.The electricity demand forecasting mould
Block is to according to the electricity consumption in the consumption habit of historical data or/and different user prediction setting time.
The electricity demand forecasting module includes electricity consumption historical data base, user's living habit database, customer position information
Acquiring unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit.
The electricity consumption historical data base records each use to store the electricity consumption situation of each electrical equipment in setting time
Electric equipment opened by which user, is closed by which or which user's use, by which user；User plays opening/closing electricity consumption and sets
User's living habit data, user's real-time position information in standby setting time.
User's living habit database is given birth to record the user for the portable electronic piece terminal storage that user carries at any time
Custom data living；The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip
Myoelectric sensor, wireless communication module are connected respectively；Myoelectric sensor records the real-time myoelectricity data of user.
The customer position information acquiring unit is obtaining the real-time position information of user.
Each electrical equipment is respectively provided with user identification unit, the user identification unit to when opening electrical equipment,
The user of the electrical equipment is opened, closes in identification when closing electrical equipment, while identifies electrical equipment by which every setting time
A or which user uses；The user identification unit is face recognition device.
The user is accustomed to analytic unit to each user for being recorded according to electricity consumption historical data base to each electrical equipment
Electricity consumption situation, with reference to user's living habit data of user's living habit data-base recording, therefrom obtain each electrical equipment
The rule unlatched and closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens every time
The second electrical equipment whether can be opened after first electrical equipment all in setting time or opens the probability of the second electrical equipment
More than given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit is known in user
When other unit recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be beaten in setting time
It opens；The user is accustomed to analytic unit to judge whether are the service condition of each electrical equipment and user's myoelectricity data variation rule
Meet given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur
The look-ahead that identical user's myoelectricity data variation rule is used as the electrical equipment, and it is sent to electricity demand forecasting list
Member；The electricity demand forecasting unit when there is corresponding changing rule in the user's myoelectricity data for recognizing myoelectric sensor sensing,
The corresponding electrical equipment of prediction is in the service condition of setting time.
The electrical equipment is accustomed to analytic unit to the use of each electrical equipment recorded according to electricity consumption historical data base
Electric situation obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；With
Electric equipment is accustomed to analytic unit according to electricity consumption historical data base, judges sometime section, each electrical equipment is no to be opened；If
It is that setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit is carried before time interval arrival
Preceding hydrogen storage prepares.
The electricity demand forecasting unit is to according to electricity consumption historical data base, user's living habit database, portable electronic piece
Terminal, customer position information acquiring unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit
Data prediction setting time in electricity consumption situation, if having more than the electric energy of given threshold in prediction setting time needs to consume
When, control methanol-water reformation hydrogen production equipment improves hydrogen manufacturing amount, and using hydrogen partial be stored in hydrogen buffering storage container as
Electricity consumption buffers；
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will in setting time for selection by the user
The electrical equipment of opening；After the information for receiving user feedback, given a forecast judgement according to the selection of user.
The hydrogen buffering storage container is follow-up hydrogen to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation
Gas power generation is prepared.
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense in hydrogen buffering storage container
Air pressure.
The methanol-water reformation hydrogen production equipment includes the hydrogen conveying pump housing, hydrogen delivery controller, hydrogen delivery controller
The transmission power of the real-time barometric information control hydrogen conveying pump housing sensed according to the hydrogen gas pressure sensor；Transmission power with
It the increase of air pressure in hydrogen buffering storage container and increases, reduced with the reduction of air pressure in hydrogen buffering storage container.
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container,
It is made adjustments according to the pressure size in hydrogen buffering storage container；If pressure in hydrogen buffering storage container is more than/less than setting
Level pressure is strong, and volume adjustment mechanism increases/reduce the volume of hydrogen buffering storage container by adjusting the position of side wall.
Embodiment two
A kind of water hydrogen power generation base station with remote monitoring function, it is whole including water hydrogen generator, base station ontology, monitoring and controlling
End, monitoring and controlling terminal include terminal control unit, wireless communication module, input/output module, and terminal control unit connects nothing respectively
Line communication module, input/output module, monitoring and controlling terminal are led to by wireless communication mode and water hydrogen generator, base station ontology
News to water hydrogen generator, base station ontology remotely monitor or/and control；The base station ontology includes base station towers, base station day
Line, base transceiver station, base station controller；Antenna for base station is set on base station towers, and base transceiver station connects antenna for base station, base station respectively
Controller；The water hydrogen generator connects base transceiver station, base station controller, antenna for base station by cable respectively；The water hydrogen
Generator includes methanol-water reformation hydrogen production equipment, hydrogen gas generation equipment；The methanol-water reformation hydrogen production equipment includes feedstock transportation
Device, methanol-water transfer pipeline, reformer, separator, hydrogen delivery tube road, control circuit board；The control circuit board
Raw material conveying device, reformer, separator are connected respectively, and each device is controlled to work；The raw material conveying device passes through
Methanol-water transfer pipeline connects storage container and reformer respectively, and the raw material conveying device is by the methanol-water in storage container
Feedstock transportation is to reformer；The reformer connects separator, separator connection hydrogen delivery tube road；The separation
Device includes membrane separation device.
Embodiment three
The difference between this embodiment and the first embodiment lies in the present embodiment, the reformer further includes quick start and fills
It puts；The device for rapidly starting provides the startup energy for methanol-water reformation hydrogen production equipment.The device for rapidly starting includes first
Starter, the second starter.First starter includes the first heating arrangements, the first gasification pipe, the first gasification
The internal diameter of pipeline is 1~2mm, and the first gasification pipe is closely wound on the first heating arrangements；First gasification pipe
One end connects storage container, and methanol is sent into the first gasification pipe by raw material conveying device；First gasification pipe it is another
End exports vaporized methanol, then passes through ignition mechanism ignition；Alternatively, the other end of the first gasification pipe is exported by gas
The methanol of change, and the methanol temperature exported reaches self-ignition point, methanol is from direct spontaneous combustion after the output of the first gasification pipe.Described second
Starter includes the second gasification pipe, and the main body of the second gasification pipe is set to the reformer chamber, the first gasification pipe or/
The second gasification pipe is heated while heating with the methanol of the second gasification pipe output for reformer chamber, it will be in the second gasification pipe
Methanol gasifying；The reformer chamber inner wall is equipped with heating pipeline, heats in pipeline and is placed with catalyst；The device for rapidly starting passes through
The heating pipeline is heated to attach most importance to the heating of whole room；After the hydrogen generating system starts, hydrogen generating system passes through hydrogen made from hydrogen producer
The energy of the air lift needed for for operation.
The initial start energy of the device for rapidly starting can be several solar energy starting modules, solar energy starting module
Including sequentially connected solar panel, solar energy-electric energy conversion circuit, solar cell；Solar energy starting module is first
Heating arrangements provide electric energy；Alternatively, the initial start energy of the device for rapidly starting is manual generator, manual generator will
The power storage sent out is in battery.
Example IV
The difference between this embodiment and the first embodiment lies in the present embodiment, the hydrogen producer includes electromagnetic heater
(being used for heating for reformer chamber, separation chamber, the combustion heating of methanol or hydrogen is replaced by electrical heating)；The hydrogen gas generation is set
Standby connection hydrogen producer, hydrogen producer is delivered to by the Partial DC electricity sent out；Hydrogen producer passes through oneself direct current obtained
Drive electromagnetic heater is reformer chamber, separation chamber is heated；Meanwhile the direct current sent out is also delivered to each equipment of system,
It is run for each equipment, while also supplies hydrogen generating equipment self-operating.
Electromagnetic heater includes the separation cylinder body reformed cylinder body, form separation chamber for forming reformer chamber, is set to reformation
The first heating coil outside cylinder body, detach cylinder body outside the second heating coil, reform cylinder body, separation cylinder body in temperature sensing
Device, pressure sensor and electromagnetic controller；The data that electromagnetic controller is sensed according to temperature sensor, pressure sensor
The electric current of the first heating coil, the second heating coil is controlled, reformer chamber, separation chamber can be made moment to reach set temperature.
In conclusion the water hydrogen power generation base station proposed by the present invention with remote monitoring function, is reformed using methanol-water
The electric energy work that hydrogen manufacturing is sent out, can power for communication base station in the place of no power grid, improve the convenience of arrangement of base stations, subtract
Few pollution to environment；It can ensure the steady operation of each base station in the work of long-range monitoring base station, while save artificial simultaneously
Cost.The present invention can also effectively utilize generating electricity by natural energy, and can store extra electric energy in a manner of methanol, power
Peak can be generated electricity by methanol.The present invention is more advantageous to fully utilizing the energy, energy conservation and environmental protection.
Here description of the invention and application are illustrative, are not wishing to limit the scope of the invention to above-described embodiment
In.The deformation and change of embodiments disclosed herein are possible, real for those skilled in the art
The replacement and equivalent various parts for applying example are well known.It should be appreciated by the person skilled in the art that not departing from the present invention
Spirit or essential characteristics in the case of, the present invention can in other forms, structure, arrangement, ratio and with other components,
Material and component are realized.In the case where not departing from scope and spirit of the present invention, can to embodiments disclosed herein into
The other deformations of row and change.
Claims (5)
1. it is a kind of with remote monitoring function water hydrogen power generation base station, which is characterized in that including water hydrogen generator, base station ontology,
Monitoring and controlling terminal；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, and terminal control unit connects respectively
Wireless communication module, input/output module are connect, monitoring and controlling terminal passes through wireless communication mode and water hydrogen generator, base station ontology
Communication to water hydrogen generator, base station ontology remotely monitor or/and control；
The base station ontology includes base station towers, antenna for base station, base transceiver station, base station controller；Base station day is set on base station towers
Line, base transceiver station connect antenna for base station, base station controller respectively；The water hydrogen generator connects base station receipts by cable respectively
Send out platform, base station controller, antenna for base station.
2. the water hydrogen power generation base station according to claim 1 with remote monitoring function, it is characterised in that：
The water hydrogen generator includes methanol-water device for producing hydrogen, hydrogen fuel cell, air pump, control circuit board；Methanol-water hydrogen manufacturing
Device includes delivery pump, heat exchanger, reformer, membrane separator；
The methanol-water storage container is equipped with the first temperature sensor, liquid level sensor, and being equipped with second temperature in heat exchanger senses
Device, first flow sensor, reformer is interior to be equipped with third temperature sensor, air flow inlet, the air stream outlet point of hydrogen fuel cell
It She Zhi not pressure sensor and solenoid valve；
The control circuit board connects delivery pump respectively, and second temperature sensor, first flow sensor in heat exchanger are reformed
Third temperature sensor in device, the pressure sensor and solenoid valve of hydrogen fuel cell, and control the work of all parts；
The methanol-water raw material of liquid is stored in the methanol-water storage container；The delivery pump is used for methanol-water storage container
In methanol-water raw material the reformer chamber of reformer is pumped to by conveyance conduit；The heat exchanger is installed on the defeated of methanol-water raw material
It send on pipeline, methanol-water raw material exchanges heat in heat exchanger with the high-temperature hydrogen of reformer output, methanol-water material temperature liter
Height, hydrogen temperature reduce；Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through membrane separator
Obtain hydrogen；Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell；Hydrogen passes through hydrogen with the oxygen in air
Fuel cell occurs redox reaction and produces electricl energy.
3. the water hydrogen power generation base station according to claim 1 with remote monitoring function, it is characterised in that：
The hydrogen gas generation equipment further includes hydrogen conveying monitoring module, generated energy monitoring modular, electricity demand monitoring modular, electricity
Judgment module, power supply handover module, charge control module, extra electricity conveyor module；
The hydrogen conveying monitoring module is monitoring the amounts of hydrogen of methanol-water reformation hydrogen production equipment conveying；
The generated energy monitoring modular is conveyed to monitor the fuel cell system using the methanol-water reformation hydrogen production equipment
Hydrogen electricity obtained in real time；
The electricity demand monitoring modular is monitoring real-time power demand；
The electricity judgment module compares to the data for obtaining the generated energy monitoring modular with electricity demand monitoring modular
It is right, judge electricity obtained in real time and the relationship of real-time power demand, and comparison result is fed back into power supply handover module, extra
Electricity conveyor module；
The power supply handover module is to when electricity judgment module obtains that electricity obtained is less than real-time power demand in real time, control
Buffered sources processed are the power supply for electrical equipment for having power demand；
The extra electricity conveyor module is more than real-time power demand to obtain electricity obtained in real time in electricity judgment module
When, charging for buffered sources or/and part electricity is delivered to the methanol-water reformation hydrogen production extra electric energy sets
It is standby, electric installation is needed to provide electric energy for the methanol-water reformation hydrogen production equipment；The methanol-water reformation hydrogen production equipment needs Denso
Put electric heater and control circuit board, each sensor including being heated for reformer chamber.
4. the water hydrogen power generation base station according to claim 1 with remote monitoring function, it is characterised in that：
The fuel cell system connects low-temperature cogeneration unit, and low-temperature cogeneration unit utilizes the heat of fuel cell system
Energy, the residual air temperature of the methanol-water reformation hydrogen production equipment and residual air combustion power generation；
The low-temperature cogeneration unit connects generating set switch control unit, and the connection of generating set switch control unit is several
Temperature sensor, when the data of each temperature sensor senses meet sets requirement, control low-temperature cogeneration unit is opened；
When the data of each temperature sensor senses meet sets requirement, control low-temperature cogeneration unit is closed.
5. the water hydrogen power generation base station according to claim 1 with remote monitoring function, it is characterised in that：
The water hydrogen generator further includes electricity demand forecasting module, hydrogen buffering storage container；
The electricity demand forecasting module is to according in the consumption habit of historical data or/and different user prediction setting time
Electricity consumption；
The electricity demand forecasting module includes electricity consumption historical data base, user's living habit database, customer position information and obtains
Unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit；
The electricity consumption historical data base records each electricity consumption and sets to store the electricity consumption situation of each electrical equipment in setting time
It is standby to be opened by which user, closed by which or which user's use, by which user；User beats opening/closing electrical equipment and sets
User's living habit data, user's real-time position information in fixing time；
User's living habit database is practised to record the user for the portable electronic piece terminal storage that user carries at any time life
Used data；The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip difference
Connect myoelectric sensor, wireless communication module；Myoelectric sensor records the real-time myoelectricity data of user；
The customer position information acquiring unit is obtaining the real-time position information of user；
Each electrical equipment is respectively provided with user identification unit, and the user identification unit is to when opening electrical equipment, closing
Identification opens, closes the user of the electrical equipment during electrical equipment, at the same every setting time identify electrical equipment by which or
Which user uses；The user identification unit is face recognition device；
The user is accustomed to analytic unit to the use according to each user that electricity consumption historical data base records to each electrical equipment
Electric situation with reference to user's living habit data of user's living habit data-base recording, therefrom show that each electrical equipment is opened
And the rule closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens first every time
The probability of the second electrical equipment of the second electrical equipment or opening whether can be opened after electrical equipment all in setting time is more than
Given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit identifies single in user
When member recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be opened in setting time；Institute
It states user and is accustomed to analytic unit to judge whether the service condition of each electrical equipment meets with user's myoelectricity data variation rule
Given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur identical
The look-ahead that is used as the electrical equipment of user's myoelectricity data variation rule, and be sent to electricity demand forecasting unit；Institute
Electricity demand forecasting unit is stated when the user's myoelectricity data for recognizing myoelectric sensor sensing have corresponding changing rule, prediction pair
Using electric equipment setting time service condition；
The electrical equipment is accustomed to analytic unit to the electricity consumption feelings of each electrical equipment recorded according to electricity consumption historical data base
Condition obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；Electricity consumption is set
Standby custom analytic unit judges sometime section, each electrical equipment is no to be opened according to electricity consumption historical data base；If so,
Setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit does before time interval arrival and stores up in advance
Hydrogen prepares；
The electricity demand forecasting unit to according to electricity consumption historical data base, user's living habit database, portable electronic piece terminal,
Customer position information acquiring unit, user identification unit, user is accustomed to analytic unit, electrical equipment is accustomed to the data of analytic unit
Predict the electricity consumption situation in setting time, if predict that the electric energy that given threshold is had more than in setting time needs consumption, control
Methanol-water reformation hydrogen production equipment processed improves hydrogen manufacturing amount, and hydrogen partial is stored in hydrogen buffering storage container and is delayed as electricity consumption
Punching；
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will be opened in setting time for selection by the user
Electrical equipment；After the information for receiving user feedback, given a forecast judgement according to the selection of user；
The hydrogen buffering storage container is sent out to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation for follow-up hydrogen
Electric equipment power generation is prepared；
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense the gas in hydrogen buffering storage container
Pressure；
The methanol-water reformation hydrogen production equipment include hydrogen conveying the pump housing, hydrogen delivery controller, hydrogen delivery controller according to
The transmission power of the real-time barometric information control hydrogen conveying pump housing of the hydrogen gas pressure sensor sensing；Transmission power is with hydrogen
The increase of air pressure in gas buffer-stored container and increase, reduced with the reduction of air pressure in hydrogen buffering storage container；
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container, according to
Pressure size in hydrogen buffering storage container makes adjustments；If pressure in hydrogen buffering storage container is more than/less than setting pressure
By force, volume adjustment mechanism increases/reduces the volume of hydrogen buffering storage container by adjusting the position of side wall.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611263828.1A CN108258286B (en) | 2016-12-28 | 2016-12-28 | Water hydrogen power generation base station with remote monitoring function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611263828.1A CN108258286B (en) | 2016-12-28 | 2016-12-28 | Water hydrogen power generation base station with remote monitoring function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108258286A true CN108258286A (en) | 2018-07-06 |
| CN108258286B CN108258286B (en) | 2024-06-04 |
Family
ID=62721280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611263828.1A Active CN108258286B (en) | 2016-12-28 | 2016-12-28 | Water hydrogen power generation base station with remote monitoring function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108258286B (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102635256A (en) * | 2012-03-21 | 2012-08-15 | 浙江瑞能通信科技有限公司 | Self-unloading emergency communication base station |
| CN102942276A (en) * | 2012-12-13 | 2013-02-27 | 山西太钢不锈钢股份有限公司 | Boiler feedwater treatment method and treatment system related to reuse of reclaimed water |
| CN104577163A (en) * | 2014-12-01 | 2015-04-29 | 广东合即得能源科技有限公司 | Hydrogen power generation system and power generation method |
| CN105060247A (en) * | 2015-08-06 | 2015-11-18 | 广东合即得能源科技有限公司 | Starting system used for starting reforming hydrogen production apparatus |
| CN204905991U (en) * | 2015-08-04 | 2015-12-23 | 李航伟 | Fuel cell basic station stand -by power supply system of methyl alcohol hydrogen manufacturing energy storage |
| CN105244518A (en) * | 2015-10-22 | 2016-01-13 | 上海合既得动氢机器有限公司 | Water hydrogen monitoring equipment |
| CN105783322A (en) * | 2016-04-23 | 2016-07-20 | 广东能态科技投资有限公司 | Water-hydrogen electricity generation heat pump air-conditioning system for communication base station and heating and refrigeration method |
| CN205453398U (en) * | 2015-12-25 | 2016-08-10 | 伍复军 | Integrated power production system of high temperature fuel cell and rotatory heat engine |
| CN106252692A (en) * | 2016-10-11 | 2016-12-21 | 广东能态科技投资有限公司 | A kind of methanol-water reformation hydrogen production electromotor for communication base station |
| CN206471423U (en) * | 2016-12-28 | 2017-09-05 | 广东能态科技投资有限公司 | A kind of water hydrogen generating base station with remote monitoring function |
| CN108258276A (en) * | 2016-12-28 | 2018-07-06 | 广东能态科技投资有限公司 | A kind of water hydrogen power generation base station for being automatically injected raw material |
-
2016
- 2016-12-28 CN CN201611263828.1A patent/CN108258286B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102635256A (en) * | 2012-03-21 | 2012-08-15 | 浙江瑞能通信科技有限公司 | Self-unloading emergency communication base station |
| CN102942276A (en) * | 2012-12-13 | 2013-02-27 | 山西太钢不锈钢股份有限公司 | Boiler feedwater treatment method and treatment system related to reuse of reclaimed water |
| CN104577163A (en) * | 2014-12-01 | 2015-04-29 | 广东合即得能源科技有限公司 | Hydrogen power generation system and power generation method |
| CN204905991U (en) * | 2015-08-04 | 2015-12-23 | 李航伟 | Fuel cell basic station stand -by power supply system of methyl alcohol hydrogen manufacturing energy storage |
| CN105060247A (en) * | 2015-08-06 | 2015-11-18 | 广东合即得能源科技有限公司 | Starting system used for starting reforming hydrogen production apparatus |
| CN105244518A (en) * | 2015-10-22 | 2016-01-13 | 上海合既得动氢机器有限公司 | Water hydrogen monitoring equipment |
| CN205453398U (en) * | 2015-12-25 | 2016-08-10 | 伍复军 | Integrated power production system of high temperature fuel cell and rotatory heat engine |
| CN105783322A (en) * | 2016-04-23 | 2016-07-20 | 广东能态科技投资有限公司 | Water-hydrogen electricity generation heat pump air-conditioning system for communication base station and heating and refrigeration method |
| CN106252692A (en) * | 2016-10-11 | 2016-12-21 | 广东能态科技投资有限公司 | A kind of methanol-water reformation hydrogen production electromotor for communication base station |
| CN206471423U (en) * | 2016-12-28 | 2017-09-05 | 广东能态科技投资有限公司 | A kind of water hydrogen generating base station with remote monitoring function |
| CN108258276A (en) * | 2016-12-28 | 2018-07-06 | 广东能态科技投资有限公司 | A kind of water hydrogen power generation base station for being automatically injected raw material |
Non-Patent Citations (1)
| Title |
|---|
| 廖同庆等: "《物联网概论》", 合肥工业大学出版社, pages: 95 - 96 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108258286B (en) | 2024-06-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108249399A (en) | The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy | |
| CN108258276A (en) | A kind of water hydrogen power generation base station for being automatically injected raw material | |
| CN105169559A (en) | Water hydrogen defibrillator | |
| CN105752311A (en) | Carbon dioxide cycled water-hydrogen-powered hot-air balloon | |
| CN205429080U (en) | Electric automobile water hydrogen charging device | |
| CN108258785A (en) | A kind of base station of water hydrogen generator powered | |
| CN108258273A (en) | A kind of water hydrogen electric vehicle | |
| CN108255284A (en) | A kind of gestural control system and electric vehicle | |
| CN108248403A (en) | A kind of water hydrogen powered vehicle | |
| CN108248411A (en) | A kind of vehicles | |
| CN108258279A (en) | A kind of electric vehicle with water cooling hydrogen fuel cell | |
| CN108248409A (en) | A kind of electric automobile charging pile with reserve battery | |
| CN108258286A (en) | A kind of water hydrogen power generation base station with remote monitoring function | |
| CN108258278A (en) | A kind of full-time four-wheel drive water hydrogen electric vehicle | |
| CN105305545A (en) | Water-hydrogen mobile charger | |
| CN108258275A (en) | A kind of power generator that automatic adjusument can be done according to electricity consumption | |
| CN108248402A (en) | A kind of electric vehicle of energy remote control | |
| CN108248407A (en) | A kind of electric vehicle with buffered sources | |
| CN108258786A (en) | A kind of base station that can utilize natural energy resources | |
| CN108258272A (en) | A kind of generator with air-cooled hydrogen fuel cell | |
| CN108258270A (en) | A kind of water hydrogen plug-in mixed power electric car | |
| CN108258282A (en) | A kind of water hydrogen generator for having the function of to do electric energy storage in advance | |
| CN108258274A (en) | A kind of water hydrogen generator with remote control function | |
| CN108258265A (en) | It is a kind of that there is the generator of gesture identification | |
| CN108258284A (en) | A kind of generating equipment with buffered sources |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |