CN108249399A - The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy - Google Patents

The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy Download PDF

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Publication number
CN108249399A
CN108249399A CN201611238528.8A CN201611238528A CN108249399A CN 108249399 A CN108249399 A CN 108249399A CN 201611238528 A CN201611238528 A CN 201611238528A CN 108249399 A CN108249399 A CN 108249399A
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hydrogen
methanol
user
data
pipeline
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向华
李文霞
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Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
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Shanghai Hejide Dynamic Hydrogen Machine Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Present invention is disclosed a kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, including storage container, raw material conveying device, methanol-water transfer pipeline, reformer, separator, hydrogen delivery tube road, control circuit board, monitoring and controlling terminal；Raw material conveying device connects storage container and reformer respectively by methanol-water transfer pipeline, and reformer chamber includes hollow circuit cylinder housing, heating and gasifying pipeline, catalyst is equipped in hollow circuit cylinder housing；The part of heating and gasifying pipeline is set in hollow circuit cylinder housing, is wrapped up by catalyst；Monitoring and controlling terminal connects control circuit board by wireless communication mode, and control circuit board is carried out remotely to monitor or/and control.Methanol-water reformation hydrogen production equipment proposed by the present invention reforms the hydrogen for being made stable, high conversion rate using methanol-water, while equipment volume is small, easy to remove.Hydrogen obtained can be used for generating electricity, and pernicious gas will not be generated in hydrogen manufacturing and power generation process, reduce the pollution to environment.

Description

The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy
Technical field
The invention belongs to technical field of hydrogen preparation, are related to a kind of hydrogen producer more particularly to a kind of energy electricity consumption in real time prison The methanol-water reformation hydrogen production equipment of control.
Background technology
In numerous new energy, Hydrogen Energy will become the 21 century optimal energy.It is this is because identical heavy burning In the case of the coal of amount, gasoline and hydrogen, the energy that hydrogen generates is most, and the product that it burns is water, without lime-ash and Exhaust gas does not pollute the environment；And what coal and oil combustion generated is carbon dioxide and sulfur dioxide, can generate greenhouse effects respectively And acid rain.Coal and petroleum reserves are limited, and hydrogen is mainly stored in water, and unique product is also water after burning, can be in a steady stream Hydrogen is constantly be generated, is never finished.
Hydrogen is a kind of colourless gas.One gram of Hydrogen Energy of burning releases the heat of 142 kilojoules that, is the 3 of gasoline calorific value Times.The weight of hydrogen is particularly lightweight, it is all lighter mostly than gasoline, natural gas, kerosene, thus carries, transports conveniently, is space flight, aviation Wait the most suitable fuel of the high-speed flights vehicles.Hydrogen can burn in oxygen, and the temperature of hydrogen flame may be up to 2500 DEG C, Thus people often with hydrogen cut or weld steel material.
In the Nature, the distribution of hydrogen is very extensive.Water is exactly big " warehouse " of hydrogen, wherein containing 11% hydrogen.In soil There are about 1.5% hydrogen；All contain hydrogen in oil, coal, natural gas, animal and plant body etc..The main body of hydrogen is with the shape of compound water Existing for formula, and earth surface about 70% is covered by water, and moisture storage capacity is very big, accordingly, it can be said that hydrogen be " it is inexhaustible, use it It is inexhaustible " the energy.If can with suitable method from water preparing hydrogen, then hydrogen also will be a kind of comparatively inexpensive energy of price Source.
Hydrogen has many uses, strong applicability.It can not only be used as fuel, and metal hydride has chemical energy, thermal energy The function of mutually being converted with mechanical energy.For example, hydrogen storage metal, which has to inhale hydrogen heat release and absorb heat, puts the ability of hydrogen, it can be by heat storage Get up, used as heating and air-conditioning in room.
Hydrogen is used on automobile first as gaseous fuel.In May, 1976, the U.S. develop one kind and make fuel with hydrogen Automobile；Later, Japan also succeeded in developing a kind of automobile using liquified hydrogen as fuel；The latter stage seventies, preceding Germany are run quickly Hydrogen is tested by motor corporation of speeding, they have only used five kilograms of hydrogen, just make 110 kilometers of running car.
By the use of hydrogen as motor vehicle fuel, not only totally, easily start at low temperature, and small to the corrosiveness of engine, The service life of engine can be extended.Since hydrogen can be mixed uniformly with air, can save completely used on general automobile Vaporizer, so as to the construction of the existing automobile of simplification.More interestingly, as long as adding in 4% hydrogen in the oil.With It is as automobile engine fuel, so that it may fuel-economizing 40%, and without making great improvement to petrol engine.
Hydrogen easily becomes liquid in certain pressure at a temperature of, thus it is used iron flask vehicle, on-highway tractor or wheel Ship Transportation is all very convenient.The hydrogen of liquid both can be used as the fuel of automobile, aircraft, it is also possible to make the fuel of rocket, guided missile.The U.S. flies The Long March carrier rocket that the Apollo Personnel investigation Program of the past moon " number spaceship and China launch a man-made satellite., is all to make fuel with liquified hydrogen 's.
In addition, Hydrogen Energy can also be directly translated into electric energy using hydrogen-hydrogen fuel cell, the utilization for making Hydrogen Energy is more square Just.At present, this fuel cell is used on spaceship and submarine, and effect is pretty good.Certainly, due to cost compared with Height is also difficult to generally use for the moment.
The annual output of hydrogen is about 36,000,000 tons in the world now, wherein being mostly from oil, coal and natural gas It produces, this must consume fossil fuel natively very in short supply；The hydrogen for separately having 4% is produced with the method for electrolysis water, but The electric energy of consumption is too many, very not cost-effective, and therefore, people are trying to explore to study hydrogen manufacturing new method.And reform system with methanol, water Hydrogen can reduce the energy consumption in Chemical Manufacture and reduce cost, be expected to substitute the work of " water electrolysis hydrogen production " that is referred to as electricity-eating tiger Skill utilizes advanced methanol vapor to reform -- pressure swing adsorption making pure hydrogen and rich in CO2Mixed gas, by into one The post processing of step can obtain hydrogen and carbon dioxide gas simultaneously.
Methanol passes through catalyst, under the effect of the catalyst, generation first with vapor under certain temperature, pressure condition The transformationreation of alcohol cracking reaction and carbon monoxide generates hydrogen and carbon dioxide, this is a multigroup part, the gas-solid more reacted is urged Change reaction system.Reactional equation is as follows：
CH3OH→CO+2H2 (1)
H2O+CO→CO2+H2 (2)
CH3OH+H2O→CO2+3H2 (3)
The H of reforming reaction generation2And CO2, using palladium UF membrane by H2And CO2Separation, obtains high-purity hydrogen.Transformation is inhaled The energy consumption of attached method is high, equipment is big, and is not suitable for small-scale hydrogen and prepares.In addition, the degree of intelligence of existing hydrogen manufacturing mode also has It waits to improve, it is impossible to meet the needs of development in science and technology.
In view of this, nowadays there is an urgent need to design a kind of new hydrogen generating system, on existing for overcoming in a manner of existing hydrogen manufacturing State defect.
Invention content
The technical problems to be solved by the invention are：The methanol-water reformation hydrogen production for providing a kind of real-time power monitoring of energy is set It is standby, the hydrogen for being made stable, high conversion rate are reformed using methanol-water, while equipment volume is small, it is easy to remove.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：
A kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, including storage container, raw material conveying device, methanol Water transfer pipeline, separator, hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge pipe, starts reformer Device, control circuit board, monitoring and controlling terminal；The control circuit board connects raw material conveying device, reformer, separation respectively Device controls each device to work；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, terminal control unit point Not Lian Jie wireless communication module, input/output module, monitoring and controlling terminal by wireless communication mode connect control circuit board, it is right Control circuit board remotely monitor or/and control；
The raw material conveying device connects storage container and reformer, the raw material respectively by methanol-water transfer pipeline Conveying device is by the methanol-water feedstock transportation in storage container to reformer；
The reformer connects separator, and separator connects hydrogen delivery tube road, carbon dioxide collection pipe respectively Road, residual air discharge pipe；The separator includes membrane separation device；
The storage container includes：Container, the space mechanism being set in container, the interval being connect with space mechanism driving Mechanism, Separation control module, interval induction module；Container is at least divided into two spaces by the space mechanism；In two spaces, One placing response liquid, the release of opposite side setting hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide； Separation control module connects interval driving mechanism, interval induction module respectively；The interval driving mechanism includes motor, flu spacer Module is answered to include pressure sensor or/and liquid level sensor；It is described to be spaced induction module to sense reaction liquid in container Amount, while sense the amount of the release of hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide；And by sensed data It is sent to Separation control module；The data control interval driving mechanism that the Separation control module senses according to interval induction module Action to space mechanism；When liquid in storage container is reduced or carbon dioxide increases up to setting condition, interval driving Mechanism driving space mechanism action reduces the volume of reaction liquid, increases the volume of carbon dioxide；The storage container further includes Liquefying plant or/and solidification equipment, by the co 2 liquefaction being collected into or/and curing；
The reformer includes heat exchanger, vaporizer, reformer chamber, separation chamber, and the membrane separation device is set to separation Interior, separation chamber are set to the top of reformer chamber；Methanol-water raw material enters vaporizer after exchanging heat in heat exchanger and vaporizes；Vaporization Methanol steam and water vapour afterwards enters reformer chamber, and reformer chamber is equipped with catalyst, and reformer chamber lower part and middle portion temperature are 300 DEG C ~420 DEG C, the temperature on the reformer chamber top is 400 DEG C~570 DEG C；Reformer chamber is connect with separation chamber by connecting line, even The all or part for taking over road is set to the top of reformer chamber, and it is defeated from reformer chamber to continue heating by the high temperature on reformer chamber top The gas gone out；The connecting line is as the buffering between reformer chamber and separation chamber so that the temperature of the gas exported from reformer chamber Degree is identical or close with the temperature of separation chamber；The indoor temperature of separation is set as 350 DEG C~570 DEG C, indoor from detaching The aerogenesis end of membrane separation device obtains hydrogen；Pressurization cooling processing is carried out to residual air simultaneously so that carbon dioxide becomes liquid two Carbonoxide or dry ice collect carbon dioxide from the residual air of membrane separation device generation, pass through carbon dioxide collection Pipeline transport；Institute State hydrogen partial made from reformer or/and residual air maintains reformer to run by burning；
Hydrogen made from the methanol-water reformation hydrogen production equipment is delivered to membrane separation device and is detached, for detaching hydrogen Membrane separation device inside and outside pressure difference be more than or equal to 0.7MPa；The membrane separation device is in porous ceramic surface Vacuum Deposition The membrane separation device of palladium-silver, film plating layer are palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%~78%, and silver accounts for 22%~25%；
The heat exchanger includes methanol-water and preheats pipeline, and vaporizer includes heating and gasifying pipeline；
Described reformer one end is equipped with starter, which includes cup holder, and methanol-water is equipped on cup holder Preheat pipeline, heating and gasifying pipeline, igniter and temperature detection device；The raw material input channel input first alcohol and water is former Material, raw material input channel are connected with heating and gasifying pipeline, and first alcohol and water raw material enters heating and gasifying pipe through raw material input channel Lu Hou is exported from the end of heating and gasifying pipeline；The position of the igniter is corresponding with the end of heating and gasifying pipeline, uses The first alcohol and water raw material exported in heating and gasifying pipeline is lighted a fire, and first alcohol and water raw material is through ignition device after-burning It burns, heating and gasifying pipeline is heated, make the first alcohol and water material gasification in heating and gasifying pipeline and increase burning rapidly by force Degree, and then heated for reformer；The temperature detection device is used to detect the temperature by heating and gasifying pipeline；It is described to reform dress It puts after starting hydrogen manufacturing, hydrogen partial made from reformer or/and residual air maintain reformer to run by burning；
The bottom side of the cup holder is equipped with air inlet cover board, the air inlet cover board be equipped with air duct, outside air can through the air duct into Enter to reformer；The raw material input channel is equipped with solenoid valve, so that raw material input channel is controlled to open or close, together When control raw material input channel flow；
The heating and gasifying pipeline includes straight-through pipeline section, pigtail and upper arch pipeline section successively, and the first alcohol and water is former Material declines, then exported after upper arch pipeline section after straight-through pipeline section rises to extreme higher position, then through pigtail spiral；It is described heavy Whole room includes hollow circuit cylinder housing, and catalyst is equipped in hollow circuit cylinder housing；The pigtail part setting of heating and gasifying pipeline It is wrapped up in hollow circuit cylinder housing, by catalyst；
A part for the methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water original in shape of threads pipeline Material；Shape of threads pipeline wraps the residual air discharge pipe of reformer；Residual air discharge pipe temperature after shape of threads pipeline drops Low, shape of threads pipeline temperature after residual air discharge pipe increases；One end of shape of threads pipeline is equipped with input port, and the other end is set There are two output port, each output port is equipped with valve；The other parts of one output port connection methanol-water transfer pipeline, separately An outer output port is connected to input port by circulation line；The set temperature at the output port close to shape of threads pipeline Sensor, temperature sensor connection pre-add heat controller；Temperature data and reformation of the pre-add heat controller according to temperature sensor The switch of raw materials requirement two valves of adjusting of equipment and the aperture of valve；
The reformer further includes device for rapidly starting；The device for rapidly starting is carried for methanol-water reformation hydrogen production equipment For starting the energy；The device for rapidly starting includes the first starter, the second starter；First starter includes First heating arrangements, the first gasification pipe, the internal diameter of the first gasification pipe is 1~2mm, and the first gasification pipe is closely wound in On first heating arrangements；Methanol, is sent by one end connection storage container of first gasification pipe by raw material conveying device In first gasification pipe；The other end of first gasification pipe exports vaporized methanol, then passes through ignition mechanism ignition； Alternatively, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature exported reaches self-ignition point, and methanol is from the Direct spontaneous combustion after the output of one gasification pipe；Second starter includes the second gasification pipe, the main body of the second gasification pipe The reformer chamber is set to, while the methanol that the first gasification pipe or/and the second gasification pipe export is heated for reformer chamber The second gasification pipe is heated, by the methanol gasifying in the second gasification pipe；The reformer chamber inner wall is equipped with heating pipeline, heating tube Catalyst is placed in road；The device for rapidly starting is heated by heating attach most importance to whole room of the heating pipeline；The hydrogen generating system After startup, hydrogen generating system provides the energy needed for operation by hydrogen made from hydrogen producer；
The initial start energy of the device for rapidly starting is several solar energy starting modules, and solar energy starting module includes Sequentially connected solar panel, solar energy-electric energy conversion circuit, solar cell；Solar energy starting module is the first heating Mechanism provides electric energy；Alternatively, the initial start energy of the device for rapidly starting is manual generator, manual generator will be sent out Power storage in battery；
Hydrogen obtained is passed through hydrogen delivery tube road real-time Transmission to hydrogen gas generation by the methanol-water reformation hydrogen production equipment Equipment；The hydrogen delivery tube road is equipped with air pressure regulator, for adjusting the air pressure in hydrogen delivery tube road；The hydrogen hair Electric equipment utilizes hydrogen gas generation made from methanol-water reformation hydrogen production equipment；
The methanol-water reformation hydrogen production equipment includes air pressure regulator, and air pressure regulator includes microprocessor, gas Pressure sensor, valve positioner, air outlet valve, outlet pipe；The gas pressure sensor is set in hydrogen delivery tube road, To sense the barometric information in hydrogen delivery tube road, and the barometric information of sensing is sent to microprocessor；The microprocessor The barometric information received from gas pressure sensor is compared device with given threshold section；When the pressure data received Higher than the maximum value in given threshold section, microprocessor control valve controller opens air outlet valve setting time so that hydrogen is defeated Air pressure in pipeline is sent to be in setting range, while one end connection air outlet valve of outlet pipe, the other end are delivered to described reform and fill It puts, by burning be reformer, separator heats；When the pressure data received is less than the minimum in given threshold section Value, microprocessor control the conveying speed of the raw material conveying device quickening raw material；
The methanol-water reformation hydrogen production equipment further includes electric energy estimation block, hydrogen prepares detection module, power storage mould Block；Need when the electric energy estimation block is to estimate whether the electric energy that hydrogen gas generation equipment is sent out in real time can meet reformation, separation The electric energy to be consumed；If it is satisfied, then close device for rapidly starting；
The hydrogen prepares detection module and is used for detecting whether the hydrogen that hydrogen producer is prepared in real time is stablized；If hydrogen producer The hydrogen of preparation is unstable, then device for rapidly starting is controlled to be again started up, and obtained electric energy part is stored in power storage Module is used when electric energy is not enough to and provides the consumption of hydrogen producer；
The methanol-water reformation hydrogen production equipment further includes main storage container, and it is single that main storage container includes the identification of the first liquid level Member, valve, the conveying pump housing, connecting line；To identify the liquid level of main storage container, connecting line is set first liquid level recognition unit There are valve and the conveying pump housing；
The storage container is equipped with the second liquid level identification mechanism, to identify the liquid level of storage container；In storage container Liquid level be less than setting value when, conveying the pump housing methanol-water raw material is conveyed from main storage container to storage container；
The methanol-water reformation hydrogen production equipment further include speech database, sound identification module, voice command execution module, Voice self-learning module, speech database update module；
The speech database is to voice data and each voice data is corresponding performs order；
The sound identification module is the voice data in the voice data obtained and the speech database to be carried out It compares, if there is the voice data met in speech database, comparison result is fed back into voice command execution module；
Institute's speech commands execution module is to according to the corresponding order of the recognition result of sound identification module execution；
The voice self-learning module compares logarithm to set specific voice for it according to the speech utterance of user custom According to；Voice comparison data is accustomed to self study according to the pronunciation of user by voice self-learning module and is obtained；
The speech database update module to by the voice self-learning module to set specific language set by user Sound comparison data is updated in speech database so that user is set in speech database has specific voice comparison data Library；
Specifically, the voice self-learning module judges the first voice number to obtain the first voice data of user According to whether having record, if no record, its voice value sequence is initialized；If there is record, the voice of first voice data is obtained Value sequence；At least one data are recorded in voice value sequence, which represents the voice of certain voice data and another voice data Value, when which reaches given threshold, represents that certain voice data is close with another voice data, it is believed that the two corresponds to same Voice command；
If sound identification module fails to find corresponding voice data in speech database or by user feedback voice Identification module identifies mistake；If user sent out in setting time second speech data by sound identification module identify successfully or Person user sends control command by other approach, the corresponding voice data of the control command is second speech data；Then by The speech value that one voice data corresponds to second speech data increases setting value, then, judges whether the speech value reaches setting threshold Value；If reaching given threshold, in the corresponding voice comparison data library of the user, the first voice data is increased into the second voice Voice data corresponding to the corresponding control command of data, and the comparison priority of the first voice data is more than the second voice number According to preferentially being compared in follow-up comparison process；
The methanol-water reformation hydrogen production equipment further include gesture database, gesture recognition module, gesture command execution module, Gesture self-learning module, gesture database update module；
The gesture database is storing gesture data and each gesture data is corresponding performs order；
The gesture recognition module is the gesture data in the gesture data obtained and the gesture database to be carried out It compares, if there is the gesture data met in gesture database, comparison result is fed back into gesture command execution module；
The gesture command execution module is to according to the corresponding order of the recognition result of gesture recognition module execution；
The gesture self-learning module is that it sets specific gesture comparison data to be accustomed to according to the gesture of user；Hand Gesture comparison data is accustomed to self study according to the gesture of user by gesture self-learning module and is obtained；
The gesture database update module to by the gesture self-learning module to set specific hand set by user Gesture comparison data is updated in gesture database so that user is set in gesture database has specific gesture comparison data Library；
Specifically, the gesture self-learning module judges the first gesture number to obtain the first gesture data of user According to whether having record, if no record, its gesture value sequence is initialized；If there is record, the gesture of the first gesture data is obtained Value sequence；At least one data are recorded in gesture value sequence, which represents the gesture of certain gesture data and another another data Value, when which reaches given threshold, represents that certain gesture data is close with another another data, it is believed that the two corresponds to same Gesture command；
If gesture recognition module fails to find corresponding gesture data in gesture database or by user feedback gesture Identification module identifies mistake；If user sent out in setting time second gesture data by gesture recognition module identify successfully or Person user sends control command by other approach, the corresponding gesture data of the control command is second gesture data；Then by The gesture value that one gesture data corresponds to second gesture data increases setting value, then, judges whether the gesture value reaches setting threshold Value；If reaching given threshold, in the corresponding gesture comparison data library of the user, first gesture data are increased into second gesture Gesture data corresponding to the corresponding control command of data, and the comparison priority of first gesture data is more than second gesture number According to preferentially being compared in follow-up comparison process；
The methanol-water reformation hydrogen production equipment further includes electricity demand forecasting module, hydrogen buffering storage container；
The electricity demand forecasting module is to according to the consumption habit of historical data or/and different user prediction setting time Interior electricity consumption；
The electricity demand forecasting module includes electricity consumption historical data base, user's living habit database, customer position information Acquiring unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit；
The electricity consumption historical data base records each use to store the electricity consumption situation of each electrical equipment in setting time Electric equipment opened by which user, is closed by which or which user's use, by which user；User plays opening/closing electricity consumption and sets User's living habit data, user's real-time position information in standby setting time；
User's living habit database is given birth to record the user for the portable electronic piece terminal storage that user carries at any time Custom data living；The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip Myoelectric sensor, wireless communication module are connected respectively；Myoelectric sensor records the real-time myoelectricity data of user；
The customer position information acquiring unit is obtaining the real-time position information of user；
Each electrical equipment is respectively provided with user identification unit, the user identification unit to when opening electrical equipment, The user of the electrical equipment is opened, closes in identification when closing electrical equipment, while identifies electrical equipment by which every setting time A or which user uses；The user identification unit is face recognition device；
The user is accustomed to analytic unit to each user for being recorded according to electricity consumption historical data base to each electrical equipment Electricity consumption situation, with reference to user's living habit data of user's living habit data-base recording, therefrom obtain each electrical equipment The rule unlatched and closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens every time The second electrical equipment whether can be opened after first electrical equipment all in setting time or opens the probability of the second electrical equipment More than given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit is known in user When other unit recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be beaten in setting time It opens；The user is accustomed to analytic unit to judge whether are the service condition of each electrical equipment and user's myoelectricity data variation rule Meet given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur The look-ahead that identical user's myoelectricity data variation rule is used as the electrical equipment, and it is sent to electricity demand forecasting list Member；The electricity demand forecasting unit when there is corresponding changing rule in the user's myoelectricity data for recognizing myoelectric sensor sensing, The corresponding electrical equipment of prediction is in the service condition of setting time；
The electrical equipment is accustomed to analytic unit to the use of each electrical equipment recorded according to electricity consumption historical data base Electric situation obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；With Electric equipment is accustomed to analytic unit according to electricity consumption historical data base, judges sometime section, each electrical equipment is no to be opened；If It is that setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit is carried before time interval arrival Preceding hydrogen storage prepares；
The electricity demand forecasting unit is to according to electricity consumption historical data base, user's living habit database, portable electronic piece Terminal, customer position information acquiring unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit Data prediction setting time in electricity consumption situation, if having more than the electric energy of given threshold in prediction setting time needs to consume When, control methanol-water reformation hydrogen production equipment improves hydrogen manufacturing amount, and using hydrogen partial be stored in hydrogen buffering storage container as Electricity consumption buffers；
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will in setting time for selection by the user The electrical equipment of opening；After the information for receiving user feedback, given a forecast judgement according to the selection of user；
The hydrogen buffering storage container is follow-up hydrogen to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation Gas power generation is prepared；
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense in hydrogen buffering storage container Air pressure；
The methanol-water reformation hydrogen production equipment includes the hydrogen conveying pump housing, hydrogen delivery controller, hydrogen delivery controller The transmission power of the real-time barometric information control hydrogen conveying pump housing sensed according to the hydrogen gas pressure sensor；Transmission power with It the increase of air pressure in hydrogen buffering storage container and increases, reduced with the reduction of air pressure in hydrogen buffering storage container；
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container, It is made adjustments according to the pressure size in hydrogen buffering storage container；If pressure in hydrogen buffering storage container is more than/less than setting Level pressure is strong, and volume adjustment mechanism increases/reduce the volume of hydrogen buffering storage container by adjusting the position of side wall.
A kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, including storage container, raw material conveying device, methanol Water transfer pipeline, separator, hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge pipe, starts reformer Device, control circuit board, monitoring and controlling terminal；The control circuit board connects raw material conveying device, reformer, separation respectively Device controls each device to work；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, terminal control unit point Not Lian Jie wireless communication module, input/output module, monitoring and controlling terminal by wireless communication mode connect control circuit board, it is right Control circuit board remotely monitor or/and control；
The raw material conveying device connects storage container and reformer, the raw material respectively by methanol-water transfer pipeline Conveying device is by the methanol-water feedstock transportation in storage container to reformer；
The reformer connects separator, separator connection hydrogen delivery tube road；The separator includes film Separator；
The reformer chamber includes hollow circuit cylinder housing, heating and gasifying pipeline, and catalyst is equipped in hollow circuit cylinder housing；Heating The part of gasification pipe is set in hollow circuit cylinder housing, is wrapped up by catalyst.
The beneficial effects of the present invention are：The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy proposed by the present invention, The hydrogen for being made stable, high conversion rate are reformed using methanol-water, while equipment volume is small, it is easy to remove.Hydrogen obtained can For power generation, pernicious gas will not be generated in hydrogen manufacturing and power generation process, reduces the pollution to environment.It is can simultaneously be effectively sharp With generating electricity by natural energy, and extra electric energy in a manner of methanol can be stored, can be generated electricity on power supply peak by methanol.This hair It is bright to be more advantageous to fully utilizing the energy, energy conservation and environmental protection.
Description of the drawings
Fig. 1 is the structure diagram of water hydrogen generator of the present invention.
Fig. 2 is the composition schematic diagram of water hydrogen generator of the present invention.
Fig. 3 is the structure diagram of methanol-water reformation hydrogen production equipment.
Fig. 4 is the composition schematic diagram of methanol-water reformation hydrogen production equipment
Fig. 5 is the structure diagram of storage container.
Fig. 6 is the composition schematic diagram of fuel cell system in present system.
Fig. 7 is the composition schematic diagram of methanol Preparation equipment in water hydrogen generator of the present invention.
Fig. 8 is the composition schematic diagram of the methanol-water reformation hydrogen production equipment equipped with safety valve.
Specific embodiment
The preferred embodiment that the invention will now be described in detail with reference to the accompanying drawings.
Embodiment one
It please refers to Fig.1, Fig. 2, present invention is disclosed a kind of High-efficient Water hydrogen generators (to introduce methanol-water reformation hydrogen production to set It is standby), the water hydrogen generator includes：Methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3, wind energy hair Electric equipment 4, steam-electric power plant 5, charge storage unit 6, charging control unit 7, water-electrolytic hydrogen making equipment 8, main control unit 9, prison Survey terminal 10, control terminal (other generator units, such as marsh gas power generation unit can also be included).
The basic composition of water hydrogen generator is that those skilled in the art can be basic according to the related patents of the applicant (the patent of invention of such as three mandates realized：Chinese patent CN201210339912.2, it is a kind of to prepare hydrogen using methanol-water System and method；Chinese patent CN201310578035.9, instant preparing hydrogen, generating power system and method；Chinese patent CN A kind of 201310520538.0, instant preparing hydrogen, generating power system and method), but here in order to embody the present invention disclose it is abundant, this In also slightly introduce, and it is partly improved simultaneously.
The main control unit 9 connect respectively methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3, Wind energy generating plant 4, steam-electric power plant 5, charge storage unit 6, charging control unit 7, water-electrolytic hydrogen making equipment 8, monitoring are eventually End 10, control methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2, methanol Preparation equipment 3, wind energy generating plant 4, solar energy The work of generating equipment 5, charging control unit 7, water-electrolytic hydrogen making equipment 8, and believe to the correlation of 10 sending device of monitoring terminal Breath.The monitoring terminal, control terminal respectively include wireless communication unit, and main control unit wireless telecommunications, and monitoring terminal is from master The status information that unit obtains equipment is controlled, control terminal sends control command to main control unit.Monitoring terminal can also be set to In methanol-water reformation hydrogen production equipment 1, control is monitored to methanol-water reformation hydrogen production equipment 1.
The methanol-water reformation hydrogen production equipment 1 is connect with hydrogen gas generation equipment 2, methanol Preparation equipment 3, hydrogen gas generation equipment 2 connect with methanol Preparation equipment 3；Methanol Preparation equipment 3 is worked by the electric energy that hydrogen gas generation equipment 2 is sent out.
The wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2 connect electrical equipment 11, energy respectively Directly power for electrical equipment 11；Electrical equipment 11 include methanol-water reformation hydrogen production equipment 1, hydrogen gas generation equipment 2 and this be Electricity requiring equipment except system.
The wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2 connect charging control unit 7 respectively, It is charged by charging control unit for charge storage unit 6.
The main control unit 9 is also to obtain the use electricity condition of electrical equipment 11, so as to obtain real-time power demand data； Meanwhile the real-time generated energy number of the acquisition of main control unit 9 wind energy generating plant 4, steam-electric power plant 5, hydrogen gas generation equipment 2 According to.
The main control unit 9 does corresponding control according to real-time power demand data, real-time generated energy data；When generated energy number During according to more than power demand data, control charging control unit charges extra electric energy for charge storage unit；When generated energy data are small When power demand data, by starting charge storage unit as power supply for electrical equipment.
In the present embodiment, the main control unit includes power supply dispatching subelement, to monitor the electricity consumption of the electrical equipment Power when the rated output power of hydrogen gas generation equipment is more than the electric power of electrical equipment, controls hydrogen gas generation tables of equipment It is solely power supply for electrical equipment；When monitoring that electric power increases and change rate is more than given threshold, hydrogen gas generation equipment is controlled And charge storage unit is power supply for electrical equipment jointly；When hydrogen gas generation equipment breaks down, control charge storage unit is electrical equipment Power supply；The power supply dispatching subelement also to the rated output power for judging hydrogen gas generation equipment be more than the electrical equipment Electric power when, judge the charge storage unit whether power shortage, such as power shortage, then the electric energy additionally exported using hydrogen gas generation equipment It charges for charge storage unit.
The water-electrolytic hydrogen making equipment 8 is to surplus made from the utilization wind energy generating plant 4, steam-electric power plant 5 Hydrogen, oxygen is made by electrolysis water in remaining electric energy；Hydrogen obtained is delivered to methanol Preparation equipment 3, in case preparing methanol；System The oxygen obtained stores, and when fuel cell system (part for hydrogen gas generation equipment 2) needs, is delivered to fuel cell system System.
Please refer to Fig. 3, Fig. 4, the methanol-water reformation hydrogen production equipment 1 include storage container 130, raw material conveying device 101, Methanol-water transfer pipeline 102, reformer 103, separator 104, hydrogen delivery tube road 105, carbon dioxide collection pipeline 106th, residual air discharge pipe 107, starter 108, control circuit board 109.
The control circuit board 109 connects raw material conveying device 101, reformer 103, separator 104 respectively, control Each device work.
The raw material conveying device 101 connects storage container 130 and reformer respectively by methanol-water transfer pipeline 102 103, the raw material conveying device 101 is by the methanol-water feedstock transportation in storage container 130 to reformer 103.
The reformer 103 connects separator 104, and separator 104 connects hydrogen delivery tube road 105, two respectively Carbonoxide collecting 106, residual air discharge pipe 107；The separator includes membrane separation device.
Referring to Fig. 6, the storage container 103 includes：Vessel 1031, the interval being set in vessel 1031 Mechanism 1032, the interval driving mechanism being connect with space mechanism 1032, Separation control module, interval induction module.
Vessel 1031 is at least divided into two spaces by the space mechanism 1032；In two spaces, one is placed instead Answer liquid, the release of opposite side setting hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide.Vessel 1031 are equipped with sliding slot 1033 with the junction of space mechanism 1032, and the both ends of space mechanism 1032 are set in sliding slot 1033, energy It is slided along sliding slot 1033.
Separation control module connects interval driving mechanism, interval induction module respectively.The interval driving mechanism includes electricity Machine, interval induction module include pressure sensor or/and liquid level sensor；The interval induction module is anti-in container to sense The amount of liquid is answered, while senses the amount of the release of hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide；It and will Sensed data is sent to Separation control module.The data control interval that the Separation control module senses according to interval induction module Action of the driving mechanism to space mechanism；When liquid in storage container is reduced or carbon dioxide increases up to setting condition, Driving mechanism driving space mechanism action is spaced, reduces the volume of reaction liquid, increases the volume of carbon dioxide.It in this way can be While preparing hydrogen, the carbon dioxide of release is collected, reduces the discharge of carbon dioxide gas, the carbon dioxide of collection can be with Raw material as subsequent handling.The storage container 103 can also include co 2 liquefaction device or/and solidification equipment, will The co 2 liquefaction being collected into or/and curing.
The reformer includes heat exchanger, vaporizer, reformer chamber, separation chamber, and the membrane separation device is set to separation Interior, separation chamber are set to the top of reformer chamber.Methanol-water raw material enters vaporizer after exchanging heat in heat exchanger and vaporizes；Vaporization Methanol steam and water vapour afterwards enters reformer chamber, and reformer chamber is equipped with catalyst, and reformer chamber lower part and middle portion temperature are 300 DEG C ~420 DEG C, the temperature on the reformer chamber top is 400 DEG C~570 DEG C；Reformer chamber is connect with separation chamber by connecting line, even The all or part for taking over road is set to the top of reformer chamber, and it is defeated from reformer chamber to continue heating by the high temperature on reformer chamber top The gas gone out；The connecting line is as the buffering between reformer chamber and separation chamber so that the temperature of the gas exported from reformer chamber Degree is identical or close with the temperature of separation chamber；The indoor temperature of separation is set as 350 DEG C~570 DEG C, indoor from detaching The aerogenesis end of membrane separation device obtains hydrogen.By above-mentioned improvement, it can ensure the low temperature requirements of reformer chamber catalyst respectively, And the high temperature requirement of separation chamber, and then improve hydrogen preparation efficiency；Meanwhile preheating method of the invention (is set separation chamber In the top of reformer chamber) it is very convenient.Pressurization cooling processing is carried out to residual air simultaneously so that carbon dioxide becomes liquid dioxy Change carbon or dry ice, collect carbon dioxide in the residual air generated from membrane separation device, pass through carbon dioxide collection Pipeline transport；It is described Hydrogen partial made from reformer or/and residual air maintain reformer to run by burning.
The raw material conveying device provides power, by the feedstock transportation in storage container to device for producing hydrogen；The raw material is defeated Device is sent to provide the pressure of 0.15~5MPa to raw material so that hydrogen made from device for producing hydrogen has enough pressure.The system Hydrogen is delivered to membrane separation device and is detached made from hydrogen production device, for detach the inside and outside pressure of the membrane separation device of hydrogen it Difference is more than or equal to 0.7MPa.Pass through the improvement so that hydrogen made from device for producing hydrogen has enough pressure, can improve hydrogen manufacturing effect The purity of rate and obtained hydrogen.
Hydrogen made from the methanol-water reformation hydrogen production equipment is delivered to membrane separation device and is detached, for detaching hydrogen Membrane separation device inside and outside pressure difference be more than or equal to 0.7MPa；The membrane separation device is in porous ceramic surface Vacuum Deposition The membrane separation device of palladium-silver, film plating layer are palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%~78%, and silver accounts for 22%~25%.
The catalyst include the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, Zn oxide, Rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%~1.8% of catalyst gross mass, Pd contents account for 1.1%~4%, Cu of catalyst gross mass oxide account for catalyst gross mass 6%~12%, Fe oxidation The oxide that object accounts for 3%~8%, Zn of catalyst gross mass accounts for the 8%~20% of catalyst gross mass, rare-earth oxide The 6%~40% of catalyst gross mass is accounted for, remaining is transition metal oxide.Alternatively, the catalyst is copper-based catalysts, packet It includes substance and its mass fraction is：3-17 parts of CuO, 3-18 parts of ZnO, 0.5-3 parts of ZrO, 55-80 parts of Al2O3, 1-3 parts CeO2, 1-3 parts of La2O3。
The heat exchanger includes methanol-water and preheats pipeline, and vaporizer includes heating and gasifying pipeline.The entirety of reformer 103 A substantially hollow cylinder 1031, the top of hollow cylinder 1031 are equipped with gas vent 1032.103 one end of reformer peace Equipped with starter 108, which includes cup holder 1033, and methanol-water preheating pipeline, heating are equipped on cup holder 1033 Gasification pipe, igniter and temperature detection device；The raw material input channel inputs first alcohol and water raw material, raw material input channel It is connected with heating and gasifying pipeline, first alcohol and water raw material is after raw material input channel enters heating and gasifying pipeline, from heating and gasifying The end output of pipeline；The position of the igniter is corresponding with the end of heating and gasifying pipeline, for heating and gasifying pipe The first alcohol and water raw material exported in road is lighted a fire, and first alcohol and water raw material is through ignition device after-combustion, to heating and gasifying pipe Road is heated, and is made the first alcohol and water material gasification in heating and gasifying pipeline and is increased combustion intensity rapidly, and then it is self-contained to attach most importance to Put heating；The temperature detection device is used to detect the temperature by heating and gasifying pipeline；After the reformer starts hydrogen manufacturing, weight Hydrogen partial made from engagement positions or/and residual air maintain reformer to run by burning.
The bottom side of the cup holder is equipped with air inlet cover board, the air inlet cover board be equipped with air duct, outside air can through the air duct into Enter to reformer；The raw material input channel is equipped with solenoid valve, so that raw material input channel is controlled to open or close, together When control raw material input channel flow.
After the hydrogen producer starts, hydrogen producer provides the energy needed for operation by hydrogen made from device for producing hydrogen； At this point it is possible to close starter.Since hydrogen partial made from device for producing hydrogen or/and residual air maintain hydrogen producer by burning Operation, so as to reduce the dependence to extra power, adaptive ability is strong.
The heating and gasifying pipeline includes straight-through pipeline section, pigtail and upper arch pipeline section successively, and the first alcohol and water is former Material declines, then exported after upper arch pipeline section after straight-through pipeline section rises to extreme higher position, then through pigtail spiral；It is described heavy Whole room includes hollow circuit cylinder housing, and catalyst is equipped in hollow circuit cylinder housing；The pigtail part setting of heating and gasifying pipeline It is wrapped up in hollow circuit cylinder housing, by catalyst.
A part for the methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water original in shape of threads pipeline Material；Shape of threads pipeline wraps the residual air discharge pipe of reformer；Residual air discharge pipe temperature after shape of threads pipeline drops Low, shape of threads pipeline temperature after residual air discharge pipe increases；One end of shape of threads pipeline is equipped with input port, and the other end is set There are two output port, each output port is equipped with valve；The other parts of one output port connection methanol-water transfer pipeline, separately An outer output port is connected to input port by circulation line；The set temperature at the output port close to shape of threads pipeline Sensor, temperature sensor connection pre-add heat controller；Temperature data and reformation of the pre-add heat controller according to temperature sensor The switch of raw materials requirement two valves of adjusting of equipment and the aperture of valve.
In addition, referring to Fig. 8, the hydrogen delivery tube road 105 is equipped with spring safety valve 1051, spring safety valve 1051 wraps It includes valve body, spring mechanism, bounce end；The raw material conveying device 101 includes delivery pump, bounces switch of the end close to delivery pump Setting (certain raw material conveying device 101 or other power plants), feedstock transportation dress can be disconnected when bouncing end and bouncing The switch put.By setting mechanical safety valve on hydrogen delivery tube road, when air pressure reaches setting value, mechanical safety valve is opened, and Raw material conveying device can be controlled to stop transferring raw material.So as to improve the safety of equipment operation, hydrogen leak and quick-fried is prevented It is fried.
Specifically, in the present embodiment, the switch of the delivery pump includes contact-segment 1052 and three ports, three ports point It Wei not first port 1053, second port 1054, third port 1055.One end of the contact-segment 1052 is rotationally arranged at First port 1053, first port 1053 connect delivery pump；The other end of contact-segment 1052 can contact second port 1054 or the Three ports 1055.
The second port 1054 connects power supply, when first port 1053 connects second port 1054, can control delivery pump Work.The third port 1055 connects alarm transmitting device, when first port connects third port 1055, can control raw material Conveying device (such as delivery pump) does not work, while alarm transmitting device sends warning message (such as by way of short message) and extremely corresponds to Server or client, can notify corresponding personnel.
Hydrogen obtained is passed through hydrogen delivery tube road real-time Transmission to hydrogen gas generation by the methanol-water reformation hydrogen production equipment Equipment；The hydrogen delivery tube road is equipped with air pressure regulator, for adjusting the air pressure in hydrogen delivery tube road；The hydrogen hair Electric equipment utilizes hydrogen gas generation made from methanol-water reformation hydrogen production equipment.
The air pressure regulator includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, air outlet pipe Road；The gas pressure sensor is set in hydrogen delivery tube road, to sense the barometric information in hydrogen delivery tube road, and The barometric information of sensing is sent to microprocessor；The barometric information that the microprocessor will be received from gas pressure sensor It is compared with given threshold section；When the pressure data received is higher than the maximum value in given threshold section, microprocessor control Valve positioner processed opens air outlet valve setting time so that air pressure is in setting range, while air outlet pipe in hydrogen delivery tube road One end connection air outlet valve on road, the other end are delivered to the reformer, and by burning be reformer, separator heats； When the pressure data received is less than the minimum value in given threshold section, it is former that microprocessor controls the raw material conveying device to accelerate The conveying speed of material.
The methanol-water reformation hydrogen production equipment further includes electric energy estimation block, hydrogen prepares detection module, power storage mould Block；Need when the electric energy estimation block is to estimate whether the electric energy that hydrogen gas generation equipment is sent out in real time can meet reformation, separation The electric energy to be consumed；If it is satisfied, then close starter/device for rapidly starting.
The hydrogen prepares detection module and is used for detecting whether the hydrogen that hydrogen producer is prepared in real time is stablized；If hydrogen producer The hydrogen of preparation is unstable, then starter/device for rapidly starting is controlled to be again started up, and obtained electric energy part is stored in Power storage module is used when electric energy is not enough to and provides the consumption of hydrogen producer.
The hydrogen gas generation equipment includes fuel cell system 208, buffered sources 206, and the connection of fuel cell system 208 is slow Rush power supply 206；The buffered sources 206 are lithium battery or super capacitor.
Referring to Fig. 5, in the present embodiment, fuel cell system includes：Gas supply device, pile 201；The gas supplies To device by the use of the gas compressed as power, it is delivered to automatically in pile 201.
In the present embodiment, gas supply device is compressed gas feedway 202, and the compressed gas is delivered to a mixing Enter pile 201, one end connection air of mixing vessel 203 after container 203；Compressed gas generates after entering mixing vessel 203 Power by natural air by setting ratio inspiration pile react, adjust oxygen content.
The fuel cell system further includes air intake conduit, outlet pipe, and air intake conduit, outlet pipe pass through Cross humidification system 204.The gas of the compression is mainly oxygen (or air)；Natural air is being mixed with compressed oxygen Enter pile 201 after container mixing.
The fuel cell system further includes gas regulating system, and gas regulating system is set in mixing vessel 203；Institute It states gas regulating system and includes valve regulated control device and oxygen content sensor or/and compressed gas compression ratio sensing Device.
The oxygen content sensor is incited somebody to action to sense the content of oxygen in the air and oxygen that are mixed in mixing vessel The data sensed are sent to valve regulated control device.
The compressed gas compression ratio sensor sends the data sensed to sense the compression ratio of compressed oxygen To valve regulated control device.
The valve regulated control device is according to the sensing of oxygen content sensor or/and compressed gas compression ratio sensor As a result oxygen delivery valve door, air delivery valve are adjusted, controls conveying ratio (such as natural air of compressed oxygen, natural air Ratio can be 0-70%)；Compressed oxygen enters the power generated after mixing vessel and mixed gas is pushed to pile reaction, profit Dilution decompression is done with natural air.
The humidification system 204 includes humidity exchanging container, humidity exchanges pipeline, and it is air intake duct that humidity, which exchanges pipeline, The part on road；Humidity exchanging container is delivered to by outlet pipe by the gas of fuel cell reaction.
The material that the humidity exchanges pipeline is only permeable airtight so that gas carries out humidity friendship with natural air after reaction It changes, and can not circulate between gas.Humidity exchanges pipeline spiral in humidity exchanging container and sets, and can fully carry out humidity friendship It changes.
The hydrogen gas generation equipment further include hydrogen conveying monitoring module, generated energy monitoring modular, electricity demand monitoring modular, Electricity judgment module, power supply handover module, charge control module, extra electricity conveyor module.
The hydrogen conveying monitoring module is monitoring the amounts of hydrogen of methanol-water reformation hydrogen production equipment conveying.
The generated energy monitoring modular utilizes the methanol-water reformation hydrogen production equipment to monitor the fuel cell system The hydrogen of conveying electricity obtained in real time.
The electricity demand monitoring modular is monitoring real-time power demand.
The electricity judgment module to by the data that the generated energy monitoring modular and electricity demand monitoring modular obtain into Row compares, and judges electricity obtained in real time and the relationship of real-time power demand, and by comparison result feed back to power supply handover module, Extra electricity conveyor module.
The power supply handover module is less than real-time power demand to obtain electricity obtained in real time in electricity judgment module When, control buffered sources are the power supply for electrical equipment for having power demand.
The extra electricity conveyor module is more than real-time electricity consumption to obtain electricity obtained in real time in electricity judgment module During demand, extra electric energy is charged for buffered sources or/and part electricity is delivered to the methanol-water reformation hydrogen production Equipment needs electric installation to provide electric energy for the methanol-water reformation hydrogen production equipment；The methanol-water reformation hydrogen production equipment needs electricity Device includes the electric heater and control circuit board, each sensor for reformer chamber heating.
The fuel cell system connects low-temperature cogeneration unit, and low-temperature cogeneration unit utilizes fuel cell system Thermal energy, the residual air temperature of the methanol-water reformation hydrogen production equipment and residual air combustion power generation.
The low-temperature cogeneration unit connects generating set switch control unit, the connection of generating set switch control unit If dry temperature sensor, when the data of each temperature sensor senses meet sets requirement, low-temperature cogeneration unit is controlled It opens；When the data of each temperature sensor senses meet sets requirement, control low-temperature cogeneration unit is closed.
The hydrogen gas generation equipment further includes control parameter logging modle, historical data base, historical data acquisition module, reality When control parameter acquisition module, data comparing module, adaptation module.
For the control parameter logging modle recording control parameter into historical data base, control parameter includes work In mean power within the setting period of electrical equipment mark, the electrical equipment in each work, ambient parameter data, generated energy Data, hydrogen supply, methanol-water feedstock transportation amount.
The historical data base to storing control parameter historical data.
The historical data acquisition module is to the acquisition history control parameter from historical data base.
The real-time control parameter acquisition module is obtaining real-time control parameter.
The data comparing module is to the real-time control parameter that obtains real-time control parameter acquisition module and history number The history control parameter obtained according to acquisition module is compared, and the electrical equipment in comparison work identifies, in each work emphatically Electrical equipment is setting the mean power in the period, ambient parameter data；It obtains and real-time control parameter similarity is highest goes through History control parameter.
The adaptation module is to the highest history control parameter of similarity that is obtained according to the data comparing module Methanol-water raw material is laid in, and in this, as the reference for being initially powered up hydrogen manufacturing amount under state.
The hydrogen gas generation equipment further includes Collection utilization device；The Collection utilization device connection hydrogen gas generating system Vent passageway collects hydrogen, oxygen gas and water respectively from the gas of discharge, sub for hydrogen manufacturing using the hydrogen, oxygen that are collected into System or/and hydrogen gas generating system use, raw material of the water being collected into as hydrogen manufacturing subsystem, so as to recycle.
The Collection utilization device includes hydrogen/oxygen separator, hydrogen separator, hydrogen check-valves, oxygen separator, oxygen Hydrogen by hydrogen and oxygen separation, is then separated from water, oxygen is separated from water by check-valves respectively.
Referring to Fig. 7, the methanol Preparation equipment includes：Nitrogen gas conveying device A1, hydrogen conveyor A2, carbon dioxide Conveying device A3, the first mixer A4, the second gaseous mixture A5, micro fixed-bed reactor A7, counterbalance valve A8, alcohol-water separation device A6, chromatograph A9, methanol liquefying plant, methanol collection vessel, main control module.The carbon dioxide conveying device connects the storage Deposit the side of container collection carbon dioxide；The methanol being prepared is delivered to the methanol water mixed liquid side of storage container.
The nitrogen gas conveying device A1 includes nitrogen storage container, the first transfer pipeline, and the first transfer pipeline is equipped with first Shut-off valve A11, the first mass flowmenter A12.
The carbon dioxide conveying device A3 includes carbon dioxide storage container, the second transfer pipeline, the second transfer pipeline Equipped with the second shut-off valve, the second mass flowmenter.
The hydrogen conveyor A3 includes hydrogen storage vessel, third transfer pipeline, the 4th transfer pipeline, third conveying Pipeline is equipped with third shut-off valve, third mass flowmenter, and the 4th transfer pipeline is equipped with the 4th shut-off valve, the 4th mass flowmenter.
The hydrogen storage vessel A3 is connect by third transfer pipeline with the first transfer pipeline, third transfer pipeline and One transfer pipeline is intersected in one first triple valve A13.
The hydrogen storage vessel is connect by the 4th transfer pipeline with the second transfer pipeline, the 4th transfer pipeline and second Transfer pipeline is intersected in one first four-way valve A14.
The first triple valve A13 is connect with the first mixer A4, the other end and the second triple valve of the first mixer A4 A15 connections；Second triple valve A15 connects micro fixed-bed reactor A7 by the 5th transfer pipeline, and the 5th transfer pipeline is equipped with 5th mass flowmenter, pressure gage.
The other end of the micro fixed-bed reactor A7 connects the 4th triple valve A16, and the 4th triple valve A16 is also connected with carrying on the back The other end of pressure valve A8, counterbalance valve A8 connect one second four-way valve A10.
The first four-way valve A14 is connect with the second mixer A5, the other end and the third triple valve of the second mixer A5 A17 connections；Alcohol-water separation device A6, the second triple valve A15 connections third triple valve A17, alcohol-water separation device A6, methanol solution makeup It puts, chromatograph A9 the second four-way valves of connection A10；Methanol liquefying plant is connect with methanol collection vessel.
The master control module controls all parts action, the ratio for first controlling high pure nitrogen and high-purity hydrogen to set are passed through It is emptied after the mixing of first mixer by catalyst bed, treats to switch gas as hydrogen and carbon dioxide after the completion of catalyst reduction Gaseous mixture, gas boosts to certain pressure through counterbalance valve by catalyst bed and isolates Methanol product through alcohol-water separation device again And water, unreacted gas continue through reactor cycles reaction after unstripped gas supplements.
The methanol-water reformation hydrogen production equipment further includes：Methanol water collecting device, methanol concentration sensor, concentration allotment dress It puts, high concentration methanol water container.
The fuel cell system includes water collecting device, the first heat-exchanger rig, air compression plant.
The methanol Preparation equipment includes carbon dioxide interfacing conveyor, hydrogen interfacing conveyor, and carbon dioxide interfacing conveyor connects The carbon dioxide collection pipeline of the methanol-water reformation hydrogen production equipment is connect, hydrogen interfacing conveyor connects the methanol-water reformation hydrogen production The hydrogen delivery tube road of equipment.
The methanol-water reformation hydrogen production equipment will partly be delivered to fuel cell system in hydrogen obtained, partly pass through combustion Burn the operation for maintaining methanol-water reformation hydrogen production equipment；The carbon dioxide of collection is delivered to methanol Preparation equipment, the residual air of discharge By burning for the operation for maintaining methanol-water reformation hydrogen production equipment.
The fuel cell system sets the electrical energy transportation of part generation to methanol-water reformation hydrogen production equipment, methanol preparation Standby, the water that fuel cell system is collected is delivered to methanol-water reformation hydrogen production equipment；The heat of fuel cell system discharge passes through the One heat-exchanger rig is the methanol-water raw material preheating of methanol-water reformation hydrogen production equipment.
Methanol aqueous solution is made in the methanol Preparation equipment, is delivered to methanol-water reformation hydrogen production equipment.
The methanol water collecting device connects methanol Preparation equipment, water-soluble to collect methanol made from methanol Preparation equipment Liquid.
The methanol concentration sensor is set in methanol water collecting device, dense to sense the methanol in methanol aqueous solution Degree.
The concentration deployment device include allocates container, first allotment valve body, second allotment valve body, third allotment valve body, Rabbling mechanism, allotment control unit, the first allotment valve body, the second allotment valve body are respectively equipped with valve body control mechanism.
The methanol water collecting device, water collecting device, high concentration methanol water container are respectively by respective pipeline and defeated Pump connection allocates container is sent, rabbling mechanism is set in allocates container.
The first allotment of methanol water collecting device setting valve body, water collecting device setting the second allotment valve body, high concentration Methanol water container setting third allocates valve body；Allotment control unit calculates methanol-water according to the data that methanol concentration sensor senses The proportioning of solution or/and water or/and high concentration methanol aqueous solution, control methanol water collecting device, water collecting device, high concentration first Alcohol water container corresponds to the switch of allotment valve body so that in the methanol aqueous solution allocated in allocates container, methanol concentration, which reaches, to be set Definite value.
The water hydrogen generator further includes main storage container, and main storage container includes the first liquid level recognition unit, valve, defeated Send the pump housing, connecting line；For first liquid level recognition unit to identify the liquid level of main storage container, connecting line is equipped with valve and defeated Send the pump housing.The storage container is equipped with the second liquid level identification mechanism, to identify the liquid level of storage container；In storage container When liquid level is less than setting value, the conveying pump housing conveys methanol-water raw material from main storage container to storage container.
The water hydrogen generator or control terminal further include speech database, sound identification module, voice command and perform mould Block, voice self-learning module, speech database update module.
The speech database is to voice data and each voice data is corresponding performs order.The voice Identification module is the voice data of acquisition to be compared with the voice data in the speech database, if speech database It is middle to there is the voice data met, comparison result is fed back into voice command execution module.Institute's speech commands execution module is used To perform corresponding order according to the recognition result of sound identification module.The voice self-learning module is to the language according to user Sound sounding custom sets specific voice comparison data for it；Voice comparison data is by voice self-learning module according to user's Pronunciation custom self study obtains.The speech database update module to by the voice self-learning module for setting user set Fixed special sound comparison data is updated in speech database so that user is set in speech database has specific voice Comparison data library.
Specifically, the voice self-learning module judges the first voice number to obtain the first voice data of user According to whether having record, if no record, its voice value sequence is initialized；If there is record, the voice of first voice data is obtained Value sequence；At least one data are recorded in voice value sequence, which represents the voice of certain voice data and another voice data Value, when which reaches given threshold, represents that certain voice data is close with another voice data, it is believed that the two corresponds to same Voice command；
If sound identification module fails to find corresponding voice data in speech database or by user feedback voice Identification module identifies mistake；If user sent out in setting time second speech data by sound identification module identify successfully or Person user sends control command by other approach, the corresponding voice data of the control command is second speech data；Then by The speech value that one voice data corresponds to second speech data increases setting value, then, judges whether the speech value reaches setting threshold Value；If reaching given threshold, in the corresponding voice comparison data library of the user, the first voice data is increased into the second voice Voice data corresponding to the corresponding control command of data, and the comparison priority of the first voice data is more than the second voice number According to preferentially being compared in follow-up comparison process.
The water hydrogen generator or control terminal further include gesture database, gesture recognition module, gesture command and perform mould Block, gesture self-learning module, gesture database update module.
The gesture database is storing gesture data and each gesture data is corresponding performs order.The gesture Identification module is the gesture data of acquisition to be compared with the gesture data in the gesture database, if gesture database It is middle to there is the gesture data met, comparison result is fed back into gesture command execution module.The gesture command execution module is used To perform corresponding order according to the recognition result of gesture recognition module.The gesture self-learning module is to the hand according to user Gesture custom sets specific gesture comparison data for it；Gesture comparison data is by gesture self-learning module according to the gesture of user Custom self study obtains.The gesture database update module is to set by user to set by the gesture self-learning module Certain gestures comparison data is updated in gesture database so that user is set in gesture database and is compared with specific gesture Database.
Specifically, the gesture self-learning module judges the first gesture number to obtain the first gesture data of user According to whether having record, if no record, its gesture value sequence is initialized；If there is record, the gesture of the first gesture data is obtained Value sequence；At least one data are recorded in gesture value sequence, which represents the gesture of certain gesture data and another another data Value, when which reaches given threshold, represents that certain gesture data is close with another another data, it is believed that the two corresponds to same Gesture command.
If gesture recognition module fails to find corresponding gesture data in gesture database or by user feedback gesture Identification module identifies mistake；If user sent out in setting time second gesture data by gesture recognition module identify successfully or Person user sends control command by other approach, the corresponding gesture data of the control command is second gesture data；Then by The gesture value that one gesture data corresponds to second gesture data increases setting value, then, judges whether the gesture value reaches setting threshold Value；If reaching given threshold, in the corresponding gesture comparison data library of the user, first gesture data are increased into second gesture Gesture data corresponding to the corresponding control command of data, and the comparison priority of first gesture data is more than second gesture number According to preferentially being compared in follow-up comparison process.
The water hydrogen generator further includes electricity demand forecasting module, hydrogen buffering storage container.The electricity demand forecasting mould Block is to according to the electricity consumption in the consumption habit of historical data or/and different user prediction setting time.The electricity consumption is pre- It surveys module and includes electricity consumption historical data base, user's living habit database, customer position information acquiring unit, user's identification list Member, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit.
The electricity consumption historical data base records each use to store the electricity consumption situation of each electrical equipment in setting time Electric equipment opened by which user, is closed by which or which user's use, by which user；User plays opening/closing electricity consumption and sets User's living habit data, user's real-time position information in standby setting time.
User's living habit database is given birth to record the user for the portable electronic piece terminal storage that user carries at any time Custom data living.The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip Myoelectric sensor, wireless communication module are connected respectively；Myoelectric sensor records the real-time myoelectricity data of user.
The customer position information acquiring unit is obtaining the real-time position information of user.Each electrical equipment is respectively provided with User identification unit, identification opening, closing when the user identification unit is to when opening electrical equipment, closing electrical equipment The user of the electrical equipment, while identify that electrical equipment is used by which or which user every setting time；The user knows Other unit is face recognition device.
The user is accustomed to analytic unit to each user for being recorded according to electricity consumption historical data base to each electrical equipment Electricity consumption situation, with reference to user's living habit data of user's living habit data-base recording, therefrom obtain each electrical equipment The rule unlatched and closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens every time The second electrical equipment whether can be opened after first electrical equipment all in setting time or opens the probability of the second electrical equipment More than given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit is known in user When other unit recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be beaten in setting time It opens.The user is accustomed to analytic unit to judge whether are the service condition of each electrical equipment and user's myoelectricity data variation rule Meet given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur The look-ahead that identical user's myoelectricity data variation rule is used as the electrical equipment, and it is sent to electricity demand forecasting list Member；The electricity demand forecasting unit when there is corresponding changing rule in the user's myoelectricity data for recognizing myoelectric sensor sensing, The corresponding electrical equipment of prediction is in the service condition of setting time.
The electrical equipment is accustomed to analytic unit to the use of each electrical equipment recorded according to electricity consumption historical data base Electric situation obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；With Electric equipment is accustomed to analytic unit according to electricity consumption historical data base, judges sometime section, each electrical equipment is no to be opened；If It is that setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit is carried before time interval arrival Preceding hydrogen storage prepares.
The electricity demand forecasting unit is to according to electricity consumption historical data base, user's living habit database, portable electronic piece Terminal, customer position information acquiring unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit Data prediction setting time in electricity consumption situation, if having more than the electric energy of given threshold in prediction setting time needs to consume When, control methanol-water reformation hydrogen production equipment improves hydrogen manufacturing amount, and using hydrogen partial be stored in hydrogen buffering storage container as Electricity consumption buffers.
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will in setting time for selection by the user The electrical equipment of opening；After the information for receiving user feedback, given a forecast judgement according to the selection of user.
The hydrogen buffering storage container is follow-up hydrogen to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation Gas power generation is prepared.
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense in hydrogen buffering storage container Air pressure.
The methanol-water reformation hydrogen production equipment includes the hydrogen conveying pump housing, hydrogen delivery controller, hydrogen delivery controller The transmission power of the real-time barometric information control hydrogen conveying pump housing sensed according to the hydrogen gas pressure sensor；Transmission power with It the increase of air pressure in hydrogen buffering storage container and increases, reduced with the reduction of air pressure in hydrogen buffering storage container.
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container, It is made adjustments according to the pressure size in hydrogen buffering storage container；If pressure in hydrogen buffering storage container is more than/less than setting Level pressure is strong, and volume adjustment mechanism increases/reduce the volume of hydrogen buffering storage container by adjusting the position of side wall.
Embodiment two
A kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, including storage container, raw material conveying device, methanol Water transfer pipeline, separator, hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge pipe, starts reformer Device, control circuit board, monitoring and controlling terminal；The control circuit board connects raw material conveying device, reformer, separation respectively Device controls each device to work；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, terminal control unit point Not Lian Jie wireless communication module, input/output module, monitoring and controlling terminal by wireless communication mode connect control circuit board, it is right Control circuit board remotely monitor or/and control；
The raw material conveying device connects storage container and reformer, the raw material respectively by methanol-water transfer pipeline Conveying device is by the methanol-water feedstock transportation in storage container to reformer；
The reformer connects separator, separator connection hydrogen delivery tube road；The separator includes film Separator；
The reformer chamber includes hollow circuit cylinder housing, heating and gasifying pipeline, and catalyst is equipped in hollow circuit cylinder housing；Heating The part of gasification pipe is set in hollow circuit cylinder housing, is wrapped up by catalyst.
The present invention can be preheated preferably for methanol water liquid, and heating and gasifying pipeline is avoided the feelings of peeling disengaging occur Condition effectively extends the service life of pipeline.
Embodiment three
The difference between this embodiment and the first embodiment lies in the present embodiment, the reformer further includes quick start and fills It puts；The device for rapidly starting provides the startup energy for methanol-water reformation hydrogen production equipment.The device for rapidly starting includes first Starter, the second starter.First starter includes the first heating arrangements, the first gasification pipe, the first gasification The internal diameter of pipeline is 1~2mm, and the first gasification pipe is closely wound on the first heating arrangements；First gasification pipe One end connects storage container, and methanol is sent into the first gasification pipe by raw material conveying device；First gasification pipe it is another End exports vaporized methanol, then passes through ignition mechanism ignition；Alternatively, the other end of the first gasification pipe is exported by gas The methanol of change, and the methanol temperature exported reaches self-ignition point, methanol is from direct spontaneous combustion after the output of the first gasification pipe.Described second Starter includes the second gasification pipe, and the main body of the second gasification pipe is set to the reformer chamber, the first gasification pipe or/ The second gasification pipe is heated while heating with the methanol of the second gasification pipe output for reformer chamber, it will be in the second gasification pipe Methanol gasifying；The reformer chamber inner wall is equipped with heating pipeline, heats in pipeline and is placed with catalyst；The device for rapidly starting passes through The heating pipeline is heated to attach most importance to the heating of whole room；After the hydrogen generating system starts, hydrogen generating system passes through hydrogen made from hydrogen producer The energy of the air lift needed for for operation.
The initial start energy of the device for rapidly starting can be several solar energy starting modules, solar energy starting module Including sequentially connected solar panel, solar energy-electric energy conversion circuit, solar cell；Solar energy starting module is first Heating arrangements provide electric energy；Alternatively, the initial start energy of the device for rapidly starting is manual generator, manual generator will The power storage sent out is in battery.
Example IV
The difference between this embodiment and the first embodiment lies in the present embodiment, the hydrogen producer includes electromagnetic heater (being used for heating for reformer chamber, separation chamber, the combustion heating of methanol or hydrogen is replaced by electrical heating)；The hydrogen gas generation is set Standby connection hydrogen producer, hydrogen producer is delivered to by the Partial DC electricity sent out；Hydrogen producer passes through oneself direct current obtained Drive electromagnetic heater is reformer chamber, separation chamber is heated；Meanwhile the direct current sent out is also delivered to each equipment of system, It is run for each equipment, while also supplies hydrogen generating equipment self-operating.
Electromagnetic heater includes the separation cylinder body reformed cylinder body, form separation chamber for forming reformer chamber, is set to reformation The first heating coil outside cylinder body, detach cylinder body outside the second heating coil, reform cylinder body, separation cylinder body in temperature sensing Device, pressure sensor and electromagnetic controller；The data that electromagnetic controller is sensed according to temperature sensor, pressure sensor The electric current of the first heating coil, the second heating coil is controlled, reformer chamber, separation chamber can be made moment to reach set temperature.
In conclusion the methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy proposed by the present invention, using methanol-water The hydrogen for being made stable, high conversion rate are reformed, while equipment volume is small, it is easy to remove.Hydrogen obtained can be used for generating electricity, system Pernicious gas will not be generated in hydrogen and power generation process, reduces the pollution to environment.Can simultaneously be effectively sent out using natural energy resources Electricity, and extra electric energy can be stored in a manner of methanol, it can be generated electricity on power supply peak by methanol.The present invention is more advantageous to filling Divide ground using the energy, energy conservation and environmental protection.
Here description of the invention and application are illustrative, are not wishing to limit the scope of the invention to above-described embodiment In.The deformation and change of embodiments disclosed herein are possible, real for those skilled in the art The replacement and equivalent various parts for applying example are well known.It should be appreciated by the person skilled in the art that not departing from the present invention Spirit or essential characteristics in the case of, the present invention can in other forms, structure, arrangement, ratio and with other components, Material and component are realized.In the case where not departing from scope and spirit of the present invention, can to embodiments disclosed herein into The other deformations of row and change.

Claims (5)

1. a kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, which is characterized in that including storage container, feedstock transportation Device, methanol-water transfer pipeline, reformer, separator, hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge Pipeline, starter, control circuit board, monitoring and controlling terminal；The control circuit board connects raw material conveying device, reforms respectively Device, separator control each device to work；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, and terminal control unit connects respectively Wireless communication module, input/output module are connect, monitoring and controlling terminal connects control circuit board by wireless communication mode, to control Circuit board remotely monitor or/and control；
The raw material conveying device connects storage container and reformer, the feedstock transportation respectively by methanol-water transfer pipeline Device is by the methanol-water feedstock transportation in storage container to reformer；
The reformer connects separator, and separator connects hydrogen delivery tube road, carbon dioxide collection pipeline, remaining respectively Gas discharge pipe；The separator includes membrane separation device；
The storage container includes：Container, the space mechanism being set in container, the interval driving machine being connect with space mechanism Structure, Separation control module, interval induction module；Container is at least divided into two spaces by the space mechanism；In two spaces, one A placing response liquid, the release of opposite side setting hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide；Between Interval driving mechanism, interval induction module are connected respectively every control module；The interval driving mechanism includes motor, and flu spacer should Module includes pressure sensor or/and liquid level sensor；It is described interval induction module to sense the amount of reaction liquid in container, The amount of the release of hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide is sensed simultaneously；And sensed data is sent out It send to Separation control module；The data control interval driving mechanism pair that the Separation control module senses according to interval induction module The action of space mechanism；When liquid in storage container is reduced or carbon dioxide increases up to setting condition, it is spaced driving machine Structure driving space mechanism action reduces the volume of reaction liquid, increases the volume of carbon dioxide；The storage container further includes liquid Makeup is put or/and solidification equipment, by the co 2 liquefaction being collected into or/and curing；
The reformer includes heat exchanger, vaporizer, reformer chamber, separation chamber, and the membrane separation device is set in separation chamber, Separation chamber is set to the top of reformer chamber；Methanol-water raw material enters vaporizer after exchanging heat in heat exchanger and vaporizes；After vaporization Methanol steam and water vapour enter reformer chamber, reformer chamber be equipped with catalyst, reformer chamber lower part and middle portion temperature for 300 DEG C~ 420 DEG C, the temperature on the reformer chamber top is 400 DEG C~570 DEG C；Reformer chamber is connect with separation chamber by connecting line, connection The all or part of pipeline is set to the top of reformer chamber, can continue heating by the high temperature on reformer chamber top and be exported from reformer chamber Gas；The connecting line is as the buffering between reformer chamber and separation chamber so that the temperature of the gas exported from reformer chamber It is identical or close with the temperature of separation chamber；The indoor temperature of separation is set as 350 DEG C~570 DEG C, from the indoor film of separation The aerogenesis end of separator obtains hydrogen；Pressurization cooling processing is carried out to residual air simultaneously so that carbon dioxide becomes liquid dioxy Change carbon or dry ice, collect carbon dioxide in the residual air generated from membrane separation device, pass through carbon dioxide collection Pipeline transport；It is described Hydrogen partial made from reformer or/and residual air maintain reformer to run by burning；
Hydrogen made from the methanol-water reformation hydrogen production equipment is delivered to membrane separation device and is detached, for detaching the film of hydrogen The difference of the inside and outside pressure of separator is more than or equal to 0.7M Pa；The membrane separation device is in porous ceramic surface Vacuum Deposition palladium The membrane separation device of silver alloy, film plating layer are palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%~78%, and silver accounts for 22%~25%；
The heat exchanger includes methanol-water and preheats pipeline, and vaporizer includes heating and gasifying pipeline；
Described reformer one end is equipped with starter, which includes cup holder, and methanol-water preheating is equipped on cup holder Pipeline, heating and gasifying pipeline, igniter and temperature detection device；The raw material input channel inputs first alcohol and water raw material, former Material input channel be connected with heating and gasifying pipeline, first alcohol and water raw material after raw material input channel enters heating and gasifying pipeline, It is exported from the end of heating and gasifying pipeline；The position of the igniter is corresponding with the end of heating and gasifying pipeline, for pair The first alcohol and water raw material exported in heating and gasifying pipeline is lighted a fire, and first alcohol and water raw material is right through ignition device after-combustion Heating and gasifying pipeline is heated, and is made the first alcohol and water material gasification in heating and gasifying pipeline and is increased combustion intensity rapidly, into And it is reformer heating；The temperature detection device is used to detect the temperature by heating and gasifying pipeline；The reformer opens After dynamic hydrogen manufacturing, hydrogen partial made from reformer or/and residual air maintain reformer to run by burning；
The bottom side of the cup holder is equipped with air inlet cover board, which is equipped with air duct, and outside air can be entered to through the air duct In reformer；The raw material input channel is equipped with solenoid valve, so that raw material input channel is controlled to open or close, same to time control The flow of raw material input channel processed；
The heating and gasifying pipeline includes straight-through pipeline section, pigtail and upper arch pipeline section, the first alcohol and water raw material warp successively After straight-through pipeline section rises to extreme higher position, then through the decline of pigtail spiral, then exported after upper arch pipeline section；The reformer chamber Including hollow circuit cylinder housing, catalyst is equipped in hollow circuit cylinder housing；During the pigtail part of heating and gasifying pipeline is set to It is wrapped up in hollow round column housing, by catalyst；
A part for the methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water raw material in shape of threads pipeline； Shape of threads pipeline wraps the residual air discharge pipe of reformer；Residual air discharge pipe temperature after shape of threads pipeline reduces, Shape of threads pipeline temperature after residual air discharge pipe increases；One end of shape of threads pipeline is equipped with input port, and the other end is equipped with Two output ports, each output port are equipped with valve；The other parts of one output port connection methanol-water transfer pipeline, in addition One output port is connected to input port by circulation line；Set temperature passes at the output port close to shape of threads pipeline Sensor, temperature sensor connection pre-add heat controller；Pre-add heat controller is set according to the temperature data and reformation of temperature sensor The standby switch of raw materials requirement two valves of adjusting and the aperture of valve；
The reformer further includes device for rapidly starting；The device for rapidly starting is provided for methanol-water reformation hydrogen production equipment and is opened Energy source；The device for rapidly starting includes the first starter, the second starter；First starter includes first Heating arrangements, the first gasification pipe, the internal diameter of the first gasification pipe is 1~2mm, and the first gasification pipe is closely wound in first On heating arrangements；One end connection storage container of first gasification pipe, first is sent methanol by raw material conveying device In gasification pipe；The other end of first gasification pipe exports vaporized methanol, then passes through ignition mechanism ignition；Or Person, the other end of the first gasification pipe export vaporized methanol, and the methanol temperature exported reaches self-ignition point, and methanol is from first Direct spontaneous combustion after gasification pipe output；Second starter includes the second gasification pipe, and the main body of the second gasification pipe is set The reformer chamber is placed in, the methanol that the first gasification pipe or/and the second gasification pipe export adds while heating for reformer chamber Hot second gasification pipe, by the methanol gasifying in the second gasification pipe；The reformer chamber inner wall is equipped with heating pipeline, heats pipeline Inside it is placed with catalyst；The device for rapidly starting is heated by heating attach most importance to whole room of the heating pipeline；The hydrogen generating system opens After dynamic, hydrogen generating system provides the energy needed for operation by hydrogen made from hydrogen producer；
The initial start energy of the device for rapidly starting is several solar energy starting modules, and solar energy starting module is included successively Solar panel, solar energy-electric energy conversion circuit, the solar cell of connection；Solar energy starting module is the first heating arrangements Electric energy is provided；Alternatively, the initial start energy of the device for rapidly starting is manual generator, the electricity that manual generator will be sent out It can be stored in battery；
Hydrogen obtained is passed through hydrogen delivery tube road real-time Transmission to hydrogen gas generation equipment by the methanol-water reformation hydrogen production equipment； The hydrogen delivery tube road is equipped with air pressure regulator, for adjusting the air pressure in hydrogen delivery tube road；The hydrogen gas generation is set It is standby to utilize hydrogen gas generation made from methanol-water reformation hydrogen production equipment；
The methanol-water reformation hydrogen production equipment includes air pressure regulator, and air pressure regulator includes microprocessor, gas pressure Sensor, valve positioner, air outlet valve, outlet pipe；The gas pressure sensor is set in hydrogen delivery tube road, to Sense the barometric information in hydrogen delivery tube road, and the barometric information of sensing is sent to microprocessor；The microprocessor will The barometric information received from gas pressure sensor is compared with given threshold section；When the pressure data received is higher than The maximum value in given threshold section, microprocessor control valve controller open air outlet valve setting time so that hydrogen delivery tube Air pressure is in setting range in road, while one end connection air outlet valve of outlet pipe, the other end are delivered to the reformer, lead to Burning is crossed to heat for reformer, separator；When the pressure data received is less than the minimum value in given threshold section, micro- place Manage the conveying speed that device controls the raw material conveying device to accelerate raw material；
The methanol-water reformation hydrogen production equipment further includes electric energy estimation block, hydrogen prepares detection module, power storage module；Institute Needs consume when stating electric energy estimation block to estimate whether the electric energy that hydrogen gas generation equipment is sent out in real time can meet reformation, separation Electric energy；If it is satisfied, then close device for rapidly starting；
The hydrogen prepares detection module and is used for detecting whether the hydrogen that hydrogen producer is prepared in real time is stablized；If prepared by hydrogen producer Hydrogen it is unstable, then device for rapidly starting is controlled to be again started up, and obtained electric energy part is stored in power storage module, It is used when electric energy is not enough to and provides the consumption of hydrogen producer；
The methanol-water reformation hydrogen production equipment further includes main storage container, and main storage container includes the first liquid level recognition unit, valve Door, the conveying pump housing, connecting line；For first liquid level recognition unit to identify the liquid level of main storage container, connecting line is equipped with valve Door and the conveying pump housing；
The storage container is equipped with the second liquid level identification mechanism, to identify the liquid level of storage container；Liquid in storage container When position is less than setting value, the conveying pump housing conveys methanol-water raw material from main storage container to storage container；
The methanol-water reformation hydrogen production equipment further includes speech database, sound identification module, voice command execution module, voice Self-learning module, speech database update module；
The speech database is to voice data and each voice data is corresponding performs order；
The sound identification module the voice data of acquisition to be compared with the voice data in the speech database, If there is the voice data met in speech database, comparison result is fed back into voice command execution module；
Institute's speech commands execution module is to according to the corresponding order of the recognition result of sound identification module execution；
The voice self-learning module is that it sets specific voice comparison data to be accustomed to according to the speech utterance of user；Language Sound comparison data is accustomed to self study according to the pronunciation of user by voice self-learning module and is obtained；
The speech database update module to by the voice self-learning module to set special sound ratio set by user Data are updated in speech database so that user is set in speech database has specific voice comparison data library；
Specifically, the voice self-learning module judges that first voice data is to obtain the first voice data of user It is no to have record, if no record, initialize its voice value sequence；If there is record, the speech value sequence of first voice data is obtained Row；At least one data are recorded in voice value sequence, which represents the speech value of certain voice data and another voice data, should When speech value reaches given threshold, represent that certain voice data is close with another voice data, it is believed that the two corresponds to same voice Order；
If sound identification module fails to find corresponding voice data in speech database or by user feedback speech recognition Module identifies mistake；If user sends out second speech data in setting time and is identified successfully by sound identification module, Huo Zheyong Family sends control command by other approach, the corresponding voice data of the control command is second speech data；Then by the first language The speech value that sound data correspond to second speech data increases setting value, then, judges whether the speech value reaches given threshold；If Reach given threshold, then in the corresponding voice comparison data library of the user, the first voice data is increased into second speech data Voice data corresponding to corresponding control command, and the comparison priority of the first voice data is more than second speech data, It is preferentially compared in follow-up comparison process；
The methanol-water reformation hydrogen production equipment further includes gesture database, gesture recognition module, gesture command execution module, gesture Self-learning module, gesture database update module；
The gesture database is storing gesture data and each gesture data is corresponding performs order；
The gesture recognition module the gesture data of acquisition to be compared with the gesture data in the gesture database, If there is the gesture data met in gesture database, comparison result is fed back into gesture command execution module；
The gesture command execution module is to according to the corresponding order of the recognition result of gesture recognition module execution；
The gesture self-learning module is that it sets specific gesture comparison data to be accustomed to according to the gesture of user；Gesture ratio It is accustomed to self study according to the gesture of user by gesture self-learning module to data to obtain；
The gesture database update module to by the gesture self-learning module to set certain gestures ratio set by user Data are updated in gesture database so that user is set in gesture database has specific gesture comparison data library；
Specifically, the gesture self-learning module judges that the first gesture data are to obtain the first gesture data of user It is no to have record, if no record, initialize its gesture value sequence；If there is record, the gesture value sequence of the first gesture data is obtained Row；At least one data are recorded in gesture value sequence, which represents the gesture value of certain gesture data and another another data, should When gesture value reaches given threshold, represent that certain gesture data is close with another another data, it is believed that the two corresponds to same gesture Order；
If gesture recognition module fails to find corresponding gesture data in gesture database or by user feedback gesture identification Module identifies mistake；If user sends out second gesture data in setting time and is identified successfully by gesture recognition module, Huo Zheyong Family sends control command by other approach, the corresponding gesture data of the control command is second gesture data；It then will be first-hand The gesture value that gesture data correspond to second gesture data increases setting value, then, judges whether the gesture value reaches given threshold；If Reach given threshold, then in the corresponding gesture comparison data library of the user, first gesture data are increased into second gesture data Gesture data corresponding to corresponding control command, and the comparison priority of first gesture data is more than second gesture data, It is preferentially compared in follow-up comparison process；
The methanol-water reformation hydrogen production equipment further includes electricity demand forecasting module, hydrogen buffering storage container；
The electricity demand forecasting module is to according in the consumption habit of historical data or/and different user prediction setting time Electricity consumption；
The electricity demand forecasting module includes electricity consumption historical data base, user's living habit database, customer position information and obtains Unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit；
The electricity consumption historical data base records each electricity consumption and sets to store the electricity consumption situation of each electrical equipment in setting time It is standby to be opened by which user, closed by which or which user's use, by which user；User beats opening/closing electrical equipment and sets User's living habit data, user's real-time position information in fixing time；
User's living habit database is practised to record the user for the portable electronic piece terminal storage that user carries at any time life Used data；The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip difference Connect myoelectric sensor, wireless communication module；Myoelectric sensor records the real-time myoelectricity data of user；
The customer position information acquiring unit is obtaining the real-time position information of user；
Each electrical equipment is respectively provided with user identification unit, and the user identification unit is to when opening electrical equipment, closing Identification opens, closes the user of the electrical equipment during electrical equipment, at the same every setting time identify electrical equipment by which or Which user uses；The user identification unit is face recognition device；
The user is accustomed to analytic unit to the use according to each user that electricity consumption historical data base records to each electrical equipment Electric situation with reference to user's living habit data of user's living habit data-base recording, therefrom show that each electrical equipment is opened And the rule closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens first every time The probability of the second electrical equipment of the second electrical equipment or opening whether can be opened after electrical equipment all in setting time is more than Given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit identifies single in user When member recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be opened in setting time；Institute It states user and is accustomed to analytic unit to judge whether the service condition of each electrical equipment meets with user's myoelectricity data variation rule Given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur identical The look-ahead that is used as the electrical equipment of user's myoelectricity data variation rule, and be sent to electricity demand forecasting unit；Institute Electricity demand forecasting unit is stated when the user's myoelectricity data for recognizing myoelectric sensor sensing have corresponding changing rule, prediction pair Using electric equipment setting time service condition；
The electrical equipment is accustomed to analytic unit to the electricity consumption feelings of each electrical equipment recorded according to electricity consumption historical data base Condition obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；Electricity consumption is set Standby custom analytic unit judges sometime section, each electrical equipment is no to be opened according to electricity consumption historical data base；If so, Setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit does before time interval arrival and stores up in advance Hydrogen prepares；
The electricity demand forecasting unit to according to electricity consumption historical data base, user's living habit database, portable electronic piece terminal, Customer position information acquiring unit, user identification unit, user is accustomed to analytic unit, electrical equipment is accustomed to the data of analytic unit Predict the electricity consumption situation in setting time, if predict that the electric energy that given threshold is had more than in setting time needs consumption, control Methanol-water reformation hydrogen production equipment processed improves hydrogen manufacturing amount, and hydrogen partial is stored in hydrogen buffering storage container and is delayed as electricity consumption Punching；
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will be opened in setting time for selection by the user Electrical equipment；After the information for receiving user feedback, given a forecast judgement according to the selection of user；
The hydrogen buffering storage container is sent out to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation for follow-up hydrogen Electric equipment power generation is prepared；
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense the gas in hydrogen buffering storage container Pressure；
The methanol-water reformation hydrogen production equipment include hydrogen conveying the pump housing, hydrogen delivery controller, hydrogen delivery controller according to The transmission power of the real-time barometric information control hydrogen conveying pump housing of the hydrogen gas pressure sensor sensing；Transmission power is with hydrogen The increase of air pressure in gas buffer-stored container and increase, reduced with the reduction of air pressure in hydrogen buffering storage container；
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container, according to Pressure size in hydrogen buffering storage container makes adjustments；If pressure in hydrogen buffering storage container is more than/less than setting pressure By force, volume adjustment mechanism increases/reduces the volume of hydrogen buffering storage container by adjusting the position of side wall.
2. a kind of methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy, which is characterized in that including storage container, feedstock transportation Device, methanol-water transfer pipeline, reformer, separator, hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge Pipeline, starter, control circuit board, monitoring and controlling terminal；The control circuit board connects raw material conveying device, reforms respectively Device, separator control each device to work；
The monitoring and controlling terminal includes terminal control unit, wireless communication module, input/output module, and terminal control unit connects respectively Wireless communication module, input/output module are connect, monitoring and controlling terminal connects control circuit board by wireless communication mode, to control Circuit board remotely monitor or/and control；
The raw material conveying device connects storage container and reformer, the feedstock transportation respectively by methanol-water transfer pipeline Device is by the methanol-water feedstock transportation in storage container to reformer；
The reformer connects separator, separator connection hydrogen delivery tube road；The separator includes UF membrane Device；
The reformer chamber includes hollow circuit cylinder housing, heating and gasifying pipeline, and catalyst is equipped in hollow circuit cylinder housing；Heating and gasifying The part of pipeline is set in hollow circuit cylinder housing, is wrapped up by catalyst.
3. the methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy according to claim 2, it is characterised in that：
The methanol-water reformation hydrogen production equipment further includes carbon dioxide collection pipeline, residual air discharge pipe, starter；Separation dress Put connection hydrogen delivery tube road, carbon dioxide collection pipeline, residual air discharge pipe respectively；
The storage container includes：Container, the space mechanism being set in container, the interval driving machine being connect with space mechanism Structure, Separation control module, interval induction module；Container is at least divided into two spaces by the space mechanism；In two spaces, one A placing response liquid, the release of opposite side setting hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide；Between Interval driving mechanism, interval induction module are connected respectively every control module；The interval driving mechanism includes motor, and flu spacer should Module includes pressure sensor or/and liquid level sensor；It is described interval induction module to sense the amount of reaction liquid in container, The amount of the release of hydrogen gas generation equipment, the liquid then compressed or solid carbon dioxide is sensed simultaneously；And sensed data is sent out It send to Separation control module；The data control interval driving mechanism pair that the Separation control module senses according to interval induction module The action of space mechanism；When liquid in storage container is reduced or carbon dioxide increases up to setting condition, it is spaced driving machine Structure driving space mechanism action reduces the volume of reaction liquid, increases the volume of carbon dioxide；The storage container further includes liquid Makeup is put or/and solidification equipment, by the co 2 liquefaction being collected into or/and curing；
The reformer includes heat exchanger, vaporizer, reformer chamber, separation chamber, and the membrane separation device is set in separation chamber, Separation chamber is set to the top of reformer chamber；Methanol-water raw material enters vaporizer after exchanging heat in heat exchanger and vaporizes；After vaporization Methanol steam and water vapour enter reformer chamber, reformer chamber be equipped with catalyst, reformer chamber lower part and middle portion temperature for 300 DEG C~ 420 DEG C, the temperature on the reformer chamber top is 400 DEG C~570 DEG C；Reformer chamber is connect with separation chamber by connecting line, connection The all or part of pipeline is set to the top of reformer chamber, can continue heating by the high temperature on reformer chamber top and be exported from reformer chamber Gas；The connecting line is as the buffering between reformer chamber and separation chamber so that the temperature of the gas exported from reformer chamber It is identical or close with the temperature of separation chamber；The indoor temperature of separation is set as 350 DEG C~570 DEG C, from the indoor film of separation The aerogenesis end of separator obtains hydrogen；Pressurization cooling processing is carried out to residual air simultaneously so that carbon dioxide becomes liquid dioxy Change carbon or dry ice, collect carbon dioxide in the residual air generated from membrane separation device, pass through carbon dioxide collection Pipeline transport；It is described Hydrogen partial made from reformer or/and residual air maintain reformer to run by burning；
Hydrogen made from the methanol-water reformation hydrogen production equipment is delivered to membrane separation device and is detached, for detaching the film of hydrogen The difference of the inside and outside pressure of separator is more than or equal to 0.7M Pa；The membrane separation device is in porous ceramic surface Vacuum Deposition palladium The membrane separation device of silver alloy, film plating layer are palladium-silver；
The heat exchanger includes methanol-water and preheats pipeline, and vaporizer includes heating and gasifying pipeline；
Described reformer one end is equipped with starter, which includes cup holder, and methanol-water preheating is equipped on cup holder Pipeline, heating and gasifying pipeline, igniter and temperature detection device；The raw material input channel inputs first alcohol and water raw material, former Material input channel be connected with heating and gasifying pipeline, first alcohol and water raw material after raw material input channel enters heating and gasifying pipeline, It is exported from the end of heating and gasifying pipeline；The position of the igniter is corresponding with the end of heating and gasifying pipeline, for pair The first alcohol and water raw material exported in heating and gasifying pipeline is lighted a fire, and first alcohol and water raw material is right through ignition device after-combustion Heating and gasifying pipeline is heated, and is made the first alcohol and water material gasification in heating and gasifying pipeline and is increased combustion intensity rapidly, into And it is reformer heating；The temperature detection device is used to detect the temperature by heating and gasifying pipeline；The reformer opens After dynamic hydrogen manufacturing, hydrogen partial made from reformer or/and residual air maintain reformer to run by burning；
The bottom side of the cup holder is equipped with air inlet cover board, which is equipped with air duct, and outside air can be entered to through the air duct In reformer；The raw material input channel is equipped with solenoid valve, so that raw material input channel is controlled to open or close, same to time control The flow of raw material input channel processed；
The heating and gasifying pipeline includes straight-through pipeline section, pigtail and upper arch pipeline section, the first alcohol and water raw material warp successively After straight-through pipeline section rises to extreme higher position, then through the decline of pigtail spiral, then exported after upper arch pipeline section；
A part for the methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water raw material in shape of threads pipeline； Shape of threads pipeline wraps the residual air discharge pipe of reformer；Residual air discharge pipe temperature after shape of threads pipeline reduces, Shape of threads pipeline temperature after residual air discharge pipe increases；One end of shape of threads pipeline is equipped with input port, and the other end is equipped with Two output ports, each output port are equipped with valve；The other parts of one output port connection methanol-water transfer pipeline, in addition One output port is connected to input port by circulation line；Set temperature passes at the output port close to shape of threads pipeline Sensor, temperature sensor connection pre-add heat controller；Pre-add heat controller is set according to the temperature data and reformation of temperature sensor The standby switch of raw materials requirement two valves of adjusting and the aperture of valve；
The reformer further includes device for rapidly starting；The device for rapidly starting is provided for methanol-water reformation hydrogen production equipment and is opened Energy source；The device for rapidly starting includes the first starter, the second starter；First starter includes first Heating arrangements, the first gasification pipe, the internal diameter of the first gasification pipe is 1~2mm, and the first gasification pipe is closely wound in first On heating arrangements；One end connection storage container of first gasification pipe, first is sent methanol by raw material conveying device In gasification pipe；The other end of first gasification pipe exports vaporized methanol, then passes through ignition mechanism ignition；Or Person, the other end of the first gasification pipe export vaporized methanol, and the methanol temperature exported reaches self-ignition point, and methanol is from first Direct spontaneous combustion after gasification pipe output；Second starter includes the second gasification pipe, and the main body of the second gasification pipe is set The reformer chamber is placed in, the methanol that the first gasification pipe or/and the second gasification pipe export adds while heating for reformer chamber Hot second gasification pipe, by the methanol gasifying in the second gasification pipe；The reformer chamber inner wall is equipped with heating pipeline, heats pipeline Inside it is placed with catalyst；The device for rapidly starting is heated by heating attach most importance to whole room of the heating pipeline；The hydrogen generating system opens After dynamic, hydrogen generating system provides the energy needed for operation by hydrogen made from hydrogen producer；
The initial start energy of the device for rapidly starting is several solar energy starting modules, and solar energy starting module is included successively Solar panel, solar energy-electric energy conversion circuit, the solar cell of connection；Solar energy starting module is the first heating arrangements Electric energy is provided；Alternatively, the initial start energy of the device for rapidly starting is manual generator, the electricity that manual generator will be sent out It can be stored in battery；
Hydrogen obtained is passed through hydrogen delivery tube road real-time Transmission to hydrogen gas generation equipment by the methanol-water reformation hydrogen production equipment； The hydrogen delivery tube road is equipped with air pressure regulator, for adjusting the air pressure in hydrogen delivery tube road；The hydrogen gas generation is set It is standby to utilize hydrogen gas generation made from methanol-water reformation hydrogen production equipment；
The methanol-water reformation hydrogen production equipment includes air pressure regulator, and air pressure regulator includes microprocessor, gas pressure Sensor, valve positioner, air outlet valve, outlet pipe；The gas pressure sensor is set in hydrogen delivery tube road, to Sense the barometric information in hydrogen delivery tube road, and the barometric information of sensing is sent to microprocessor；The microprocessor will The barometric information received from gas pressure sensor is compared with given threshold section；When the pressure data received is higher than The maximum value in given threshold section, microprocessor control valve controller open air outlet valve setting time so that hydrogen delivery tube Air pressure is in setting range in road, while one end connection air outlet valve of outlet pipe, the other end are delivered to the reformer, lead to Burning is crossed to heat for reformer, separator；When the pressure data received is less than the minimum value in given threshold section, micro- place Manage the conveying speed that device controls the raw material conveying device to accelerate raw material；
The methanol-water reformation hydrogen production equipment further includes electric energy estimation block, hydrogen prepares detection module, power storage module；Institute Needs consume when stating electric energy estimation block to estimate whether the electric energy that hydrogen gas generation equipment is sent out in real time can meet reformation, separation Electric energy；If it is satisfied, then close device for rapidly starting；
The hydrogen prepares detection module and is used for detecting whether the hydrogen that hydrogen producer is prepared in real time is stablized；If prepared by hydrogen producer Hydrogen it is unstable, then device for rapidly starting is controlled to be again started up, and obtained electric energy part is stored in power storage module, It is used when electric energy is not enough to and provides the consumption of hydrogen producer.
4. the methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy according to claim 2, it is characterised in that：
The methanol-water reformation hydrogen production equipment further includes：Methanol water collecting device, methanol concentration sensor, concentration deployment device, High concentration methanol water container；
The fuel cell system includes water collecting device, the first heat-exchanger rig, air compression plant；
The methanol Preparation equipment includes carbon dioxide interfacing conveyor, hydrogen interfacing conveyor, carbon dioxide interfacing conveyor connection institute The carbon dioxide collection pipeline of methanol-water reformation hydrogen production equipment is stated, hydrogen interfacing conveyor connects the methanol-water reformation hydrogen production equipment Hydrogen delivery tube road；
The methanol-water reformation hydrogen production equipment will partly be delivered to fuel cell system in hydrogen obtained, partly be tieed up by burning Hold the operation of methanol-water reformation hydrogen production equipment；The carbon dioxide of collection is delivered to methanol Preparation equipment, the residual air of discharge passes through It burns for the operation for maintaining methanol-water reformation hydrogen production equipment；
The fuel cell system by the electrical energy transportation of part generation to methanol-water reformation hydrogen production equipment, methanol Preparation equipment, combustion The water that material battery system is collected is delivered to methanol-water reformation hydrogen production equipment；The heat of fuel cell system discharge passes through the first heat exchange Device is the methanol-water raw material preheating of methanol-water reformation hydrogen production equipment；
Methanol aqueous solution is made in the methanol Preparation equipment, is delivered to methanol-water reformation hydrogen production equipment；
The methanol water collecting device connects methanol Preparation equipment, to collect methanol aqueous solution made from methanol Preparation equipment；
The methanol concentration sensor is set in methanol water collecting device, to sense the methanol concentration in methanol aqueous solution；
The concentration deployment device includes allocates container, the first allotment valve body, the second allotment valve body, third allotment valve body, stirring Mechanism, allotment control unit, the first allotment valve body, the second allotment valve body are respectively equipped with valve body control mechanism；
The methanol water collecting device, water collecting device, high concentration methanol water container pass through respective pipeline and delivery pump respectively Allocates container is connected, rabbling mechanism is set in allocates container；
The first allotment of methanol water collecting device setting valve body, water collecting device setting the second allotment valve body, high concentration methanol Water container setting third allocates valve body；Allotment control unit calculates methanol aqueous solution according to the data that methanol concentration sensor senses Or/and the proportioning of water or/and high concentration methanol aqueous solution, control methanol water collecting device, water collecting device, high concentration methanol water Container corresponds to the switch of allotment valve body so that in the methanol aqueous solution allocated in allocates container, methanol concentration reaches setting value.
5. the methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy according to claim 2, it is characterised in that：
The methanol-water reformation hydrogen production equipment further includes electricity demand forecasting module, hydrogen buffering storage container；
The electricity demand forecasting module is to according in the consumption habit of historical data or/and different user prediction setting time Electricity consumption；
The electricity demand forecasting module includes electricity consumption historical data base, user's living habit database, customer position information and obtains Unit, user identification unit, user are accustomed to analytic unit, electrical equipment custom analytic unit, electricity demand forecasting unit；
The electricity consumption historical data base records each electricity consumption and sets to store the electricity consumption situation of each electrical equipment in setting time It is standby to be opened by which user, closed by which or which user's use, by which user；User beats opening/closing electrical equipment and sets User's living habit data, user's real-time position information in fixing time；
User's living habit database is practised to record the user for the portable electronic piece terminal storage that user carries at any time life Used data；The portable electronic piece terminal includes Master control chip, myoelectric sensor, wireless communication module, Master control chip difference Connect myoelectric sensor, wireless communication module；Myoelectric sensor records the real-time myoelectricity data of user；
The customer position information acquiring unit is obtaining the real-time position information of user；
Each electrical equipment is respectively provided with user identification unit, and the user identification unit is to when opening electrical equipment, closing Identification opens, closes the user of the electrical equipment during electrical equipment, at the same every setting time identify electrical equipment by which or Which user uses；The user identification unit is face recognition device；
The user is accustomed to analytic unit to the use according to each user that electricity consumption historical data base records to each electrical equipment Electric situation with reference to user's living habit data of user's living habit data-base recording, therefrom show that each electrical equipment is opened And the rule closed；The user is accustomed to analytic unit according to electricity consumption historical data base, judges that set user opens first every time The probability of the second electrical equipment of the second electrical equipment or opening whether can be opened after electrical equipment all in setting time is more than Given threshold；If so, setting data are sent to electricity demand forecasting unit；The electricity demand forecasting unit identifies single in user When member recognizes the user the first electrical equipment of opening, judge that the second electrical equipment is expected to be opened in setting time；Institute It states user and is accustomed to analytic unit to judge whether the service condition of each electrical equipment meets with user's myoelectricity data variation rule Given threshold, if satisfied, being then associated with the service condition of each electrical equipment with user's myoelectricity data variation rule；If occur identical The look-ahead that is used as the electrical equipment of user's myoelectricity data variation rule, and be sent to electricity demand forecasting unit；Institute Electricity demand forecasting unit is stated when the user's myoelectricity data for recognizing myoelectric sensor sensing have corresponding changing rule, prediction pair Using electric equipment setting time service condition；
The electrical equipment is accustomed to analytic unit to the electricity consumption feelings of each electrical equipment recorded according to electricity consumption historical data base Condition obtains the related information of wherein electrical equipment switch, therefrom obtains the rule that each electrical equipment unlatches and closes；Electricity consumption is set Standby custom analytic unit judges sometime section, each electrical equipment is no to be opened according to electricity consumption historical data base；If so, Setting data are then sent to electricity demand forecasting unit；The electricity demand forecasting unit does before time interval arrival and stores up in advance Hydrogen prepares；
The electricity demand forecasting unit to according to electricity consumption historical data base, user's living habit database, portable electronic piece terminal, Customer position information acquiring unit, user identification unit, user is accustomed to analytic unit, electrical equipment is accustomed to the data of analytic unit Predict the electricity consumption situation in setting time, if predict that the electric energy that given threshold is had more than in setting time needs consumption, control Methanol-water reformation hydrogen production equipment processed improves hydrogen manufacturing amount, and hydrogen partial is stored in hydrogen buffering storage container and is delayed as electricity consumption Punching；
The electricity demand forecasting unit is additionally provided with electrical equipment Selection Floater, with will be opened in setting time for selection by the user Electrical equipment；After the information for receiving user feedback, given a forecast judgement according to the selection of user；
The hydrogen buffering storage container is sent out to store the hydrogen partial of methanol-water reformation hydrogen production equipment generation for follow-up hydrogen Electric equipment power generation is prepared；
Hydrogen gas pressure sensor is equipped in the hydrogen buffering storage container, to sense the gas in hydrogen buffering storage container Pressure；
The methanol-water reformation hydrogen production equipment include hydrogen conveying the pump housing, hydrogen delivery controller, hydrogen delivery controller according to The transmission power of the real-time barometric information control hydrogen conveying pump housing of the hydrogen gas pressure sensor sensing；Transmission power is with hydrogen The increase of air pressure in gas buffer-stored container and increase, reduced with the reduction of air pressure in hydrogen buffering storage container；
The hydrogen buffering storage container is equipped with volume adjustment mechanism, to adjust the volume of hydrogen buffering storage container, according to Pressure size in hydrogen buffering storage container makes adjustments；If pressure in hydrogen buffering storage container is more than/less than setting pressure By force, volume adjustment mechanism increases/reduces the volume of hydrogen buffering storage container by adjusting the position of side wall.
CN201611238528.8A 2016-12-28 2016-12-28 The methanol-water reformation hydrogen production equipment of the real-time power monitoring of energy Pending CN108249399A (en)

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CN109250685A (en) * 2018-11-09 2019-01-22 沈阳航空航天大学 The vehicle-mounted methanol reforming system and control method of hydrogen-rich gas are produced using tail gas
CN109950574A (en) * 2019-02-18 2019-06-28 德州新动能铁塔发电有限公司 A kind of water hydrogen electricity generation system based on natural energy resources
CN110817798A (en) * 2019-10-28 2020-02-21 中科液态阳光(苏州)氢能科技发展有限公司 Methanol steam and hydrogen mixed gas integrated medium-pressure hydrogen production system and method thereof
CN110817797A (en) * 2019-10-28 2020-02-21 中科液态阳光(苏州)氢能科技发展有限公司 Reforming and separating integrated high-pressure hydrogen production system and hydrogen production method thereof
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CN111071989A (en) * 2019-10-28 2020-04-28 中科液态阳光(苏州)氢能科技发展有限公司 Methanol steam and hydrogen mixer integrated low-pressure hydrogen production system and method thereof
CN113772624A (en) * 2021-11-09 2021-12-10 江苏中科聚元氢能源科技有限公司 Device for converting methanol into hydrogen energy
CN114779863A (en) * 2022-06-14 2022-07-22 山东智奇环境技术有限公司 Automatic change hydrogen manufacturing intelligence control system
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CN109250685A (en) * 2018-11-09 2019-01-22 沈阳航空航天大学 The vehicle-mounted methanol reforming system and control method of hydrogen-rich gas are produced using tail gas
CN109250685B (en) * 2018-11-09 2023-11-10 沈阳航空航天大学 Vehicle-mounted methanol reforming system for preparing hydrogen-rich gas by utilizing tail gas and control method
CN109950574A (en) * 2019-02-18 2019-06-28 德州新动能铁塔发电有限公司 A kind of water hydrogen electricity generation system based on natural energy resources
CN110817798B (en) * 2019-10-28 2023-08-22 中科液态阳光(苏州)氢能科技发展有限公司 Medium pressure hydrogen production method
CN110937572A (en) * 2019-10-28 2020-03-31 中科液态阳光(苏州)氢能科技发展有限公司 Reforming and separating integrated low-pressure hydrogen production system and hydrogen production method thereof
CN111071989A (en) * 2019-10-28 2020-04-28 中科液态阳光(苏州)氢能科技发展有限公司 Methanol steam and hydrogen mixer integrated low-pressure hydrogen production system and method thereof
CN110937572B (en) * 2019-10-28 2023-08-01 中科液态阳光(苏州)氢能科技发展有限公司 Reforming and separating integrated low-pressure hydrogen production system and hydrogen production method thereof
CN110817797B (en) * 2019-10-28 2023-08-01 中科液态阳光(苏州)氢能科技发展有限公司 Reforming and separating integrated high-pressure hydrogen production system and hydrogen production method thereof
CN111071989B (en) * 2019-10-28 2023-08-01 中科液态阳光(苏州)氢能科技发展有限公司 Low pressure hydrogen production process
CN110817797A (en) * 2019-10-28 2020-02-21 中科液态阳光(苏州)氢能科技发展有限公司 Reforming and separating integrated high-pressure hydrogen production system and hydrogen production method thereof
CN110817798A (en) * 2019-10-28 2020-02-21 中科液态阳光(苏州)氢能科技发展有限公司 Methanol steam and hydrogen mixed gas integrated medium-pressure hydrogen production system and method thereof
CN113772624A (en) * 2021-11-09 2021-12-10 江苏中科聚元氢能源科技有限公司 Device for converting methanol into hydrogen energy
CN114779863A (en) * 2022-06-14 2022-07-22 山东智奇环境技术有限公司 Automatic change hydrogen manufacturing intelligence control system
CN114779863B (en) * 2022-06-14 2022-09-13 山东智奇环境技术有限公司 Automatic hydrogen production intelligent control system
CN118206073A (en) * 2024-01-15 2024-06-18 广州安赛化工有限公司 System and method for preparing dry ice by high-pressure internal differential hydrogen production
CN118206073B (en) * 2024-01-15 2024-09-20 广州安赛化工有限公司 System and method for preparing dry ice by high-pressure internal differential hydrogen production

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